CN108785137A - A kind of hair conditioner and preparation method thereof - Google Patents

A kind of hair conditioner and preparation method thereof Download PDF

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Publication number
CN108785137A
CN108785137A CN201710312295.XA CN201710312295A CN108785137A CN 108785137 A CN108785137 A CN 108785137A CN 201710312295 A CN201710312295 A CN 201710312295A CN 108785137 A CN108785137 A CN 108785137A
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China
Prior art keywords
hair conditioner
quality
oil
panthenol
hair
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CN201710312295.XA
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CN108785137B (en
Inventor
刘红
王曙宾
罗丽莲
肖艳皎
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Beijing Scrianen Pharmaceutical Co Ltd
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Beijing Scrianen Pharmaceutical Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/678Tocopherol, i.e. vitamin E
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

Abstract

The present invention provides a kind of hair conditioner, including 0.001~0.1wt% of folic acid;0.3~1.5wt% of vitamin E;0~1.5wt% of panthenol;0~1.5wt% of the dry tree benevolence oil of Ci A;0~2wt% of camellia seed oil;2~10wt% of cation opsonizing agent;0~5wt% of moisturizer;3~7wt% of thickener;0~0.5wt% of fragrant agent;0~1wt% of preservative;Water surplus;Contain at least one of camellia seed oil, panthenol and thorn A Gan tree benevolence oil in the hair conditioner.Compared with prior art, the present invention by by folic acid, vitamin E and panthenol, thorn A Gan tree benevolence oil and camellia seed oil in one or more combinations, and add appropriate various auxiliary agents, hair conditioner to make has higher safety and preferable hair conditioning, is particularly suitable for standby pregnant, pregnancy and nursing period women and uses.

Description

A kind of hair conditioner and preparation method thereof
Technical field
The invention belongs to household chemicals technical fields more particularly to a kind of hair conditioner and preparation method thereof.
Background technology
The hair Surface mulch of health has one layer of natural guarantor being made of the grease of one group of complete hair scale piece and naturally secret Cuticula, this layer of natural protective film easily by the undesirable elements destruction such as excessive washing, exposure in sunshine and increasingly popular hair-waving, hair dyeing, Lead to cortex water loss, keep hair withered, hair is caused to follow the string and flexibility.For maintenance hair hair scale piece, supplement The natural nutrition and moisture content lost rebuilds hair protective film, enables withered hair recapture moist, hair conditioner has been increasingly becoming daily Wash the necessary supply in shield.
But since standby pregnant, pregnancy and nursing period women are a kind of specific groups, on the one hand, due to internal estrogen action, The natural on-off cycles of hair growth phase is extended, is no longer fallen off in the hair of normal stand-down originally, hair amount is dense, and nutritional sufficiency, is easy out in addition Existing hair quality is greasy, so this types of populations is generally higher than ordinary people's cleaning hair frequency.If not intensive care, meeting is increasingly accumulated Cause hair crude, scalp itch, dandruff increase, in some instances it may even be possible to the problems such as hair loss, alopecia occur, therefore, hair conditioner is even more Indispensable hair care articles in standby pregnant, pregnancy and nursing period women hair care.But then, due to the women in standby pregnant stage in order to Ensure reproduction cell quality, the women in pregnancy is in order to ensure the good development of fetus, and women in nursing period is in order to ensure baby The safe diet of youngster, it will usually reduce the contact of chemicals.And often contain petrochemical industry origin components in common hair conditioner, peace Full property still has dispute, and risk factor is high, and standby pregnant, pregnancy and nursing period women use common hair conditioner, not only to own health There is certain influence, and is highly detrimental to fetus and the development of baby.Therefore, standby pregnant, pregnancy and nursing period women are in order to next The health in generation is considered, and hair conditioner safe, that hair conditioning is good is often difficult to find that in this section of particular time.In addition, standby pregnant, Demand of the women of pregnancy and postpartum breastfeeding phase to certain vitamins also has different from ordinary person, and common hair conditioner can not be targetedly Corresponding enough vitamin is provided for the women of standby pregnant, pregnancy and postpartum breastfeeding phase.
In order to enable standby pregnant, pregnancy and nursing period women normal care hair, exploitation it is a it is safe, hair conditioning is good Hair conditioner has very important significance for standby pregnant, pregnancy and nursing period women selection.
Invention content
In view of this, the technical problem to be solved in the present invention is to provide a kind of safe and hair conditioning good hair conditioner And preparation method thereof.
The present invention provides a kind of hair conditioner, including:
Folic acid, vitamin E, panthenol, thorn A Gan trees benevolence oil and camellia seed oil;The quality of the folic acid is hair conditioner quality 0.001%~0.1%;The quality of the vitamin E is the 0.3%~1.5% of hair conditioner quality;The quality of the panthenol is shield Send out the 0~1.5% of quality amount;The quality of the thorn A Gan trees benevolence oil is the 0~1.5% of hair conditioner quality;The camellia seed oil Quality be hair conditioner quality 0~2%;In the hair conditioner containing panthenol, thorn A Gan tree benevolence oil and camellia seed oil in extremely Few one kind.
Preferably, including:
Preferably, the cation opsonizing agent is selected from behenyl base trimethyl ammonium chloride and/or stearyl trimethyl ammonium chloride.
Preferably, the thickener is selected from stearyl alcohol, hydroxyethyl ethylcellulose, cetostearyl alcohol, xanthans and hydroxyl second One or more of base cellulose.
Preferably, the fragrant agent selected from essence, hydrosol, essential oil with one or more in fragrance grease.
Preferably, the preservative is one or more in Phenoxyethanol, methyl hydroxybenzoate and Nipasol;Or methyl It is one or more in chloroisothiazole quinoline ketone, benzyl alcohol and methylisothiazolinone;Or Phenoxyethanol and methylisothiazolinone In it is one or more;Or it is one or more in Phenoxyethanol, Sensiva SC50 and methylisothiazolinone;Or gemma bar It is one or more in bacterium tunning, propylene glycol and hexylene glycol;Or one kind in 1,2- hexylene glycols and parahydroxyacet-ophenone or It is a variety of;Or peony root extractive.
Preferably, the preservative is Phenoxyethanol, methyl hydroxybenzoate and Nipasol;The Phenoxyethanol, methyl hydroxybenzoate Mass ratio with Nipasol is (4~2):(3~1):1.
Preferably, the content of vitamin E is the 0.5%~1.5% of hair conditioner quality.
The present invention also provides a kind of preparation methods of hair conditioner, including:
S1) by the vitamin E of 0.3~1.5wt%, the camellia seed of the thorn A Gan trees benevolence oil of 0~1.5wt%, 0~2wt% Oil, the cation opsonizing agent of 2~10wt% are mixed with the oil phase raw material in the thickener of 3~7wt%, are heated to 70 DEG C~85 DEG C, the oil phase after being heated;
By 0~5wt% moisturizer, 3~7wt% thickener in Aqueous Phase Raw Material mixed with the water of surplus, be heated to 70 DEG C~85 DEG C, the water phase after being heated;
S2) water phase after the heating is mixed with the oil phase after heating and carries out emulsifying, then it is added 0.001~ The folic acid of 0.1wt%, the panthenol of 0~1.5wt%, the fragrant agent of 0~0.5wt% and the preservative of 0~1wt% stir evenly, Obtain hair conditioner;
Contain at least one of camellia seed oil, panthenol and thorn A Gan tree benevolence oil in the hair conditioner.
Preferably, the step S2) be specially:
Water phase after the heating is mixed with the oil phase after heating and carries out emulsifying, is cooled to 30 DEG C~50 DEG C, so The anti-of the folic acid of 0.001~0.1wt%, the panthenol of 0~1.5wt%, the fragrant agent of 0~0.5wt% and 0~1wt% is added afterwards Rotten agent stirs evenly, and obtains hair conditioner.
The present invention provides a kind of hair conditioner, including folic acid, vitamin E, panthenol, thorn A Gan trees benevolence oil and camellia seed oil; The quality of the folic acid is the 0.001%~0.1% of hair conditioner quality;The quality of the vitamin E is hair conditioner quality 0.3%~1.5%;The quality of the panthenol is the 0~1.5% of hair conditioner quality;The quality of the thorn A Gan trees benevolence oil is shield Send out the 0~1.5% of quality amount;The quality of the camellia seed oil is the 0~2% of hair conditioner quality;Containing general in the hair conditioner Alcohol, thorn at least one of A Gan tree benevolence oil and camellia seed oil.Compared with prior art, the present invention is by by folic acid, vitamin E And one or more combinations in panthenol, thorn A Gan tree benevolence oil and camellia seed oil, and appropriate various auxiliary agents are added, to make to obtain Hair conditioner there is higher safety and preferable hair conditioning, be particularly suitable for standby pregnant, pregnancy and nursing period women and use.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
The present invention provides a kind of hair conditioner, including folic acid, vitamin E, panthenol, thorn A Gan trees benevolence oil and camellia seed oil; The quality of the folic acid is the 0.001%~0.1% of hair conditioner quality;The quality of the vitamin E is hair conditioner quality 0.3%~1.5%;The quality of the panthenol is the 0~1.5% of hair conditioner quality;The quality of the thorn A Gan trees benevolence oil is shield Send out the 0~1.5% of quality amount;The quality of the camellia seed oil is the 0~2% of hair conditioner quality;Containing general in the hair conditioner Alcohol, thorn at least one of A Gan tree benevolence oil and camellia seed oil.
According to the present invention, the hair conditioner preferably includes:
Wherein, the present invention is not particularly limited the source of all raw materials, is commercially available.
According to the present invention, folic acid is contained in the hair conditioner, the content of the folic acid is preferably 0.001~0.1wt%;? In some embodiments provided by the invention, the content of the folic acid is preferably 0.001wt%;In some implementations provided by the invention In example, the content of the folic acid is preferably 0.01wt%;In other embodiments provided by the invention, the content of the folic acid Preferably 0.1wt%.Folic acid is a kind of important water-soluble B vitamin, is the indispensable nutrient of embryo growth and development, Pregnant woman is 4 times higher than normal person to the demand of folic acid.Folic acid deficiency can lead to fetal anomaly, it is also possible to cause the natural stream of early stage Production;Folic acid is insufficient, also results in pregnant woman and placental abruption, pregnancy-induced hypertension syndrome, megaloblastic anemia occurs;Fetus is easy Occur intrauterine growth retardation, premature labor and born low weight, and also growth and development after such fetal birth and intellectual development are all It can be affected.For the women of standby pregnant, doctor usually suggests shifting to an earlier date Supplement of folic acid.Meanwhile after folic acid enters in vivo, in folic acid Become tetrahydrofolic acid under after the reduction of reductase and the catalytic action of vitamin B12, tetrahydrofolic acid participates in many heavy in vivo The biochemical process wanted is closely related, synthesis and the amino acid metabolism of nucleic acid is directly affected, to cell division, proliferation and tissue growth With extremely important effect, it can also alleviate scalp anxiety, while there is anti-inflammatory, analgesic effect.
The content of the vitamin E is preferably 0.5~1.5wt%;In some embodiments provided by the invention, the dimension The content of raw element E is preferably 0.5wt%;In some embodiments provided by the invention, the content of the vitamin E is preferably 1wt%;In other embodiments provided by the invention, the content of the vitamin E is preferably 1.5wt%.Vitamin E (Vitamin E) is a kind of liposoluble vitamin, and hydrolysate is tocopherol, is one of most important antioxidant.Lack This vitamin may cause infertile and miscarriage, and appropriate replenishing vitamins E can be with prevention of inflammation dermatoses, baldness.
The content of the panthenol is 0~1.5%, preferably the 0~1% of hair conditioner quality;More provided by the invention In embodiment, the quality of the panthenol is preferably the 0% of hair conditioner quality;In some embodiments provided by the invention, described The quality of panthenol is preferably the 0.2% of hair conditioner quality;In some embodiments provided by the invention, the panthenol is quality It is selected as the 0.5% of hair conditioner quality;In other embodiments provided by the invention, the quality of the panthenol is preferably hair conditioner The 1% of quality.Panthenol is also known as vitamin B5, and D-pantothenyl aleohol is the d-isomer of panthenol, is colourless viscous liquid, carries special gas Taste is dissolved in water and alcohol, micro- to have hygroscopicity.D-pantothenyl aleohol has very high physiological activity, after absorption of human body, can be converted into D-VB5- The precursor of coacetylase synthesis, is presented the bioactivity of vitamin, is a kind of wetting agent and conditioning agent of good penetrability.
The quality of the thorn A Gan trees benevolence oil is 0~1.5%, preferably the 0~1% of hair conditioner quality;It is carried in the present invention In some embodiments supplied, the quality of the thorn A Gan trees benevolence oil is preferably the 0% of hair conditioner quality;Provided by the invention one In a little embodiments, the quality of the thorn A Gan trees benevolence oil is preferably the 0.3% of hair conditioner quality;In some realities provided by the invention It applies in example, the quality of the thorn A Gan trees benevolence oil is preferably the 0.5% of hair conditioner quality;In other implementations provided by the invention In example, the quality of the thorn A Gan trees benevolence oil is preferably the 1% of hair conditioner quality.The dry tree benevolence oil of Ci A contain abundant fatty acid, Sterol, vitamin e and phenolic compound, including a large amount of essential fatty acid, unsaturated fatty acid and linoleic acid, these are all It is that cannot synthesize and must be got from fat in people's inner body.Aliphatic acid maintains the hydration levels of health, research It points out that linoleic acid is applied on the skin to anti-inflammatory, reduces acne, have positive effect on moisture-keeping functions;And essential insatiable hunger It can lead to premature skin ageing and wrinkle with the shortage of aliphatic acid.The dry tree benevolence oil of Ci A also contains rare phytosterol, plant Sterol can help softening skin, stimulate pore toxin expelling, restore natural lipid barrier.Polyphenol is then well-known antioxidant, It can not only delay skin aging, can be with other antioxidants in prolonged human body, when such as vitamin E, ascorbic effect Between.
The quality of the camellia seed oil is 0~2wt% of hair conditioner quality;In some embodiments provided by the invention, The content of the camellia seed oil is preferably 0wt%;In some embodiments provided by the invention, the content of the camellia seed oil is excellent It is selected as 1wt%;In some embodiments provided by the invention, the content of the camellia seed oil is preferably 1.5wt%;In the present invention In other embodiments provided, the content of the camellia seed oil is preferably 2wt%.Camellia seed oil is also known as tea oil, is pregnant woman's production The activity of human chitinase not only can be improved in best tonic afterwards, edible camellia oil, and the secretion of tocopherol also can be improved, and improves constitution, increases Add maternal immunity power function, to improve milk volume, baby is brought more nutriments and immune substance.Pregnant woman is in postpartum The underbelly fat for eliminating period of gestation accumulation is also helped after edible, can help to restore stature rapidly.It is opened if in period of gestation Beginning edible camellia oil, effect are more preferable.Tea oil can also do the use of the ingredients in shampoo and hair conditioner, can prevent pruitus, chronic Eczema.
The content of heretofore described cation opsonizing agent is preferably 2~8wt%, more preferably 2~6wt%, further preferably For 3~5wt%, most preferably 3wt%;The cation opsonizing agent is that cation opsonizing agent well known to those skilled in the art is Can, have no special limitation, the present invention is preferably behenyl base trimethyl ammonium chloride and/or stearyl trimethyl ammonium chloride, more excellent It is selected as behenyl base trimethyl ammonium chloride and stearyl trimethyl ammonium chloride;The behenyl base trimethyl ammonium chloride and stearyl front three The mass ratio of ammonium chloride is preferably (0.5~2):(0.5~2), more preferably (1~2):(1~2) is further preferably 1.5: 1.5。
The content of the moisturizer is preferably 2~5wt%, more preferably 3~5wt%, is further preferably 5wt%;The guarantor Humectant is moisturizer well known to those skilled in the art, has no special limitation, is preferably propylene glycol in the present invention.It is described The mass ratio of propylene glycol, behenyl base trimethyl ammonium chloride and stearyl trimethyl ammonium chloride is preferably (4~6):(0.5~2): (0.5~2), more preferably (4~6):(1~2):(1~2) is further preferably (4~6):1.5:1.5, most preferably 5:1.5: 1.5。
The content of the thickener is that the content of hair conditioner is 3~7wt%, preferably 4~6wt%, more preferably 4.8%;The thickener is thickener well known to those skilled in the art, has no special limitation, preferred in of the invention It is more excellent to be one or more in stearyl alcohol, hydroxyethyl ethylcellulose, cetostearyl alcohol, xanthans and hydroxyethyl cellulose It is selected as the mixture of both stearyl alcohol and hydroxyethyl ethylcellulose;The stearyl alcohol and hydroxyethyl ethylcellulose mass ratio are excellent It is selected as (4~6):1, most preferably 5:1.
Also contain fragrant agent in hair conditioner provided by the invention, to provide hair conditioner different tastes;The fragrant agent Content is preferably 0.1~0.5wt%, more preferably 0.1~0.3wt%, is further preferably 0.1~0.2wt%, most preferably 0.15wt%;The fragrant agent is fragrant agent well known to those skilled in the art, has no special limitation, can be selected from perfume (or spice) Essence, hydrosol, essential oil with one or more in fragrance grease, preferably essence in the present invention.
According to the present invention, the content of the preservative is preferably 0.2~1wt%, more preferably 0.4~0.8wt%, then excellent It is selected as 0.5~0.7wt%, most preferably 0.6wt%;The preservative is preservative well known to those skilled in the art, Special limitation is had no, is preferably one or more in Phenoxyethanol, methyl hydroxybenzoate and Nipasol in the present invention;Or methyl It is one or more in chloroisothiazole quinoline ketone, benzyl alcohol, methylisothiazolinone;Or in Phenoxyethanol, methylisothiazolinone It is one or more;Or it is one or more in Phenoxyethanol, Sensiva SC50, methylisothiazolinone;Or bacillus It is one or more in tunning, propylene glycol, hexylene glycol;Or 1,2- hexylene glycols are one or more in parahydroxyacet-ophenone; Or peony root extractive;The more preferably mixture of Phenoxyethanol, methyl hydroxybenzoate and Nipasol three;The Phenoxyethanol, The mass ratio of methyl hydroxybenzoate and Nipasol is preferably (4~2):(3~1):1, more preferably (4~2):(2~1):1, then it is excellent It is selected as (4~2):2:1, most preferably 3:2:1.
The hair conditioner provided by the invention also water containing surplus;The water is water well known to those skilled in the art, Special limitation is had no, is preferably deionized water in the present invention.
The present invention by by folic acid, vitamin E and panthenol, thorn A Gan tree benevolence oil and camellia seed oil in one or more groups It closes, and adds appropriate various auxiliary agents, the hair conditioner to make has higher safety and preferable hair conditioning, especially suitable Standby pregnant, pregnancy and nursing period women is closed to use.
The present invention also provides a kind of preparation methods of above-mentioned hair conditioner, including:S1) by the vitamin of 0.3~1.5wt% E, the thorn A Gan trees benevolence oil of 0~1.5wt%, the camellia seed oil of 0~2wt%, the cation opsonizing agent of 2~10wt% and 3~ Oil phase raw material mixing in the thickener of 7wt%, is heated to 70 DEG C~85 DEG C, the oil phase after being heated;0~5wt% is protected Humectant, 3~7wt% thickener in Aqueous Phase Raw Material mixed with the water of surplus, be heated to 70 DEG C~85 DEG C, after being heated Water phase;S2) water phase after the heating is mixed with the oil phase after heating and carries out emulsifying, then it is added 0.001~ The folic acid of 0.1wt%, the panthenol of 0~1.5wt%, the essence of 0~0.5wt% and the preservative of 0~1wt% stir evenly, and obtain To hair conditioner;Contain at least one of camellia seed oil, panthenol and thorn A Gan tree benevolence oil in the hair conditioner.
Wherein, the folic acid, vitamin E, panthenol, thorn A Gan trees benevolence oil, camellia seed oil, cation opsonizing agent, moisturizer, Thickener, fragrant agent, preservative and water are same as above, and details are not described herein.
Oil phase raw material in vitamin E, thorn A Gan trees benevolence oil, camellia seed oil, cation opsonizing agent, thickener is mixed, The Nipasol being more preferably additionally added in preservative, is heated to 70 DEG C~85 DEG C, the oil phase after being heated.
Aqueous Phase Raw Material in moisturizer, thickener is mixed with the water of surplus, the oxybenzene being more preferably additionally added in preservative Methyl esters is then heated to 70 DEG C~85 DEG C, the water phase after being heated.
Water phase after the heating is mixed with the oil phase after heating and carries out emulsifying, preferably adds the oil phase after heating In water phase after to heating, emulsifying is then carried out;The method of the emulsifying is side well known to those skilled in the art Method has no special limitation.
After emulsifying, 30 DEG C~50 DEG C are preferably cooled to, 40 DEG C~50 DEG C is more preferably cooled to, is further preferably cooled to 45 DEG C~50 DEG C, 45 DEG C are most preferably cooled to, folic acid, panthenol, fragrant agent and preservative is then added and stirs evenly, is taken care of hair Element.
The present invention also provides a kind of application methods of above-mentioned hair conditioner:After hair washing, the hair conditioner of appropriate above-mentioned offer is taken It is applied on hair, and gently massages 2~3min, then rinsed well with clear water.
In order to further illustrate the present invention, with reference to embodiments to a kind of hair conditioner provided by the invention and its preparation side Method is described in detail.
Reagent used in following embodiment is commercially available.
Hair conditioner quality evaluating method is as follows in embodiment:Each embodiment sets 4 test groups altogether, uses embodiment respectively And the hair conditioner sample in 3 comparative examples.Artificial 20 people of every group of participation, hair amount and length are uniform, and crowd's composition is the standby pregnant phase 4 People, 1-3 4 people of month pregnant woman of pregnancy, 4 people of pregnancy pregnant woman in 3~June, be pregnant 6~9 months 4 people of pregnant woman, 4 people of nursing period women.Often After bit test participant uses hair conditioner sample, to the quality of hair conditioner (include whether it is easily clean, whether greasy, whether scalp It itches, whether be easy to comb, is whether a softer and smoother touch, whether flexible, whether be easy to molding, be whether withered, is whether glossy etc. Performance indicator) it scores, and calculate the average mark of each index.Standards of grading use 9 points of scorings, score value and corresponding impression It is shown in Table 1.
1 hair conditioner use feeling of table and corresponding score value
Score value Impression Score value Impression
1 It does not like very much (very bad) 6 Like a little (somewhat good)
2 It does not like very much (very bad) 7 Generally like (general good)
3 It does not like generally (general bad) 8 It is delithted with (fine)
4 It does not like a little (somewhat bad) 9 Enjoy a lot (very good)
5 It doesn't matter (both not liking) - -
Embodiment 1
The raw material composition of hair conditioner is shown in Table 2.
The raw material composition of hair conditioner in 2 embodiment 1 of table and comparative example 1-1~1-3
Preparation method:Aqueous Phase Raw Material (including deionized water, methyl hydroxybenzoate, propylene glycol and hydroxyethyl ethylcellulose) is added Enter main tank, is warming up to 75 DEG C;By oil phase raw material (Nipasol, vitamin E, behenyl base trimethyl ammonium chloride, stearyl trimethyl Ammonium chloride, stearyl alcohol, thorn A Gan trees benevolence oil and camellia seed oil) oil tank is added, it is warming up to 75 DEG C;Raw material in oil tank is pumped into main tank Emulsifying is cooled to 45 DEG C, adds folic acid, panthenol, Phenoxyethanol and essence and stirs evenly, and forms lotion, is taken care of hair Element, it is filling after bacterium inspection is qualified.
It scores the hair conditioner quality obtained in embodiment 1, comparative example 1-1~1-3, the results are shown in Table 3.
The quality score of hair conditioner in 3 embodiment 1 of table and comparative example 1-1~1-3
Compared with the hair conditioner in embodiment 1, the ingredient in comparative example 1-1 lacks folic acid and vitamin E, comparative example 1-2 In folic acid and vitamin E it is excessive, thorn A Gan trees benevolence oil, panthenol, camellia seed oil excess in comparative example 1-3.From hair care quality Appraisal result is measured it is found that the indices of embodiment 1 score at 8 points or more;And whether the comparative example 1-1's that ingredient lacks is easy In comb, it is whether a softer and smoother touch, whether flexible, whether be easy to molding, it is whether withered, whether the indexs such as glossy scoring it is equal Less than 7 points;The excessive comparative example 1-2 of ingredient and comparative example 1-3 score lower index be concentrated mainly on it is whether easily clean, whether It is greasy, whether 3 indexs of scalp itch, at 6.5 points or less.It follows that in embodiment 1 by reasonably match folic acid, The content of vitamin E, thorn A Gan trees benevolence oil, panthenol, camellia seed oil so that gained hair conditioner obtains good hair conditioning.
Embodiment 2
The raw material composition of hair conditioner is shown in Table 4.
The raw material composition of hair conditioner in 4 embodiment 2 of table and comparative example 2-1~2-3
The preparation method is the same as that of Example 1, and oil phase is warming up to 78 DEG C with water phase.
It scores the hair conditioner quality obtained in embodiment 2, comparative example 2-1~2-3, the results are shown in Table 5.
The quality score of hair conditioner in 5 embodiment 2 of table and comparative example 2-1~2-3
Compared with the hair conditioner in embodiment 2, the ingredient in comparative example 2-1 lacks folic acid and vitamin E, comparative example 2-2 In folic acid and vitamin E it is excessive, the thorn A Gan trees benevolence oil excess in comparative example 2-3.From hair conditioner quality score result it is found that The indices of embodiment 2 score at 8 points or more;And whether the comparative example 2-1 that ingredient lacks be easy to comb, soft It is smooth, whether flexible, whether be easy to molding, be whether withered, whether the scoring of the indexs such as glossy is below 7 points;Ingredient mistake The comparative example 2-2 of amount and comparative example 2-3 score lower index be concentrated mainly on it is whether easily clean, whether greasy, whether scalp It itches 3 indexs, at 6 points or less.It follows that by reasonably matching folic acid, vitamin E, thorn A Ganshu in embodiment 2 The content of benevolence oil so that gained hair conditioner obtains good hair conditioning.
Embodiment 3
The raw material composition of hair conditioner is shown in Table 6.
The raw material composition of hair conditioner in 6 embodiment 3 of table and comparative example 3-1~3-3
The preparation method is the same as that of Example 1, and oil phase is warming up to 85 DEG C with water phase.
It scores the hair conditioner quality obtained in embodiment 3, comparative example 3-1~3-3, the results are shown in Table 7.
The quality score of hair conditioner in 7 embodiment 3 of table and comparative example 3-1~3-3
Compared with the hair conditioner in embodiment 3, the ingredient in comparative example 3-1 lacks folic acid and vitamin E, comparative example 3-2 In folic acid and vitamin E it is excessive, the panthenol in comparative example 3-3 is excessive.From hair conditioner quality score result it is found that embodiment 3 Indices score at 8 points or more;And ingredient lack comparative example 3-1 whether be easy to comb, it is whether a softer and smoother touch, be It is no it is flexible, whether be easy to molding, be whether withered, whether the scoring of the indexs such as glossy is below 7 points;The excessive comparison of ingredient Example 3-2 and the lower index of comparative example 3-3 scorings are concentrated mainly on whether easily clean, whether greasy, whether scalp itch 3 refers to Mark, at 6.5 points or less.It follows that by reasonably matching the content of folic acid, vitamin E, panthenol in embodiment 3 so that Gained hair conditioner obtains good hair conditioning.
Embodiment 4
The raw material composition of hair conditioner is shown in Table 8.
The raw material composition of hair conditioner in 8 embodiment 4 of table and comparative example 4-1~4-3
The preparation method is the same as that of Example 1, and oil phase is warming up to 80 DEG C with water phase.
It scores the hair conditioner quality obtained in embodiment 4, comparative example 4-1~4-3, the results are shown in Table 9.
The quality score of hair conditioner in 9 embodiment 4 of table and comparative example 4-1~4-3
Compared with the hair conditioner in embodiment 4, the ingredient in comparative example 4-1 lacks folic acid and vitamin E, comparative example 4-2 In folic acid and vitamin E it is excessive, the camellia seed oil in comparative example 4-3 is excessive.From hair conditioner quality score result it is found that implementing The indices of example 4 score at 8 points or more;And ingredient lack comparative example 4-1 whether be easy to comb, it is whether soft suitable It is sliding, whether flexible, whether be easy to molding, be whether withered, whether the scoring of the indexs such as glossy is below 7 points;Ingredient is excessive Comparative example 4-2 and comparative example 4-3 score lower index be concentrated mainly on it is whether easily clean, whether greasy, whether scalp hair Itch 3 indexs, at 6.5 points or less.It follows that by reasonably matching folic acid, vitamin E, camellia seed oil in embodiment 4 Content so that gained hair conditioner obtains good hair conditioning.
Embodiment 5
The raw material composition of hair conditioner is shown in Table 10.
The raw material composition of hair conditioner in 10 embodiment 5 of table and comparative example 5-1~5-3
The preparation method is the same as that of Example 1, and oil phase is warming up to 80 DEG C with water phase.
It scores the hair conditioner quality obtained in embodiment 5, comparative example 5-1~5-3, the results are shown in Table 11.
The quality score of hair conditioner in 11 embodiment 5 of table and comparative example 5-1~5-3
Compared with the hair conditioner in embodiment 5, the ingredient in comparative example 5-1 lacks folic acid and vitamin E, comparative example 5-2 In folic acid and vitamin E it is excessive, the thorn A Gan trees benevolence oil in comparative example 5-3, camellia seed oil excess.From hair conditioner quality score As a result it is found that the indices of embodiment 5 score at 8 points or more;And whether the comparative example 5-1 that ingredient lacks is easy to comb Reason, it is whether a softer and smoother touch, whether flexible, whether be easy to molding, be whether withered, whether the scoring of the indexs such as glossy is below 7 points;Whether whether the excessive comparative example 5-2 of ingredient and the lower index of comparative example 5-3 scorings are concentrated mainly on easily cleans, is oily It is greasy, whether 3 indexs of scalp itch, at 7 points or less.It follows that by reasonably matching folic acid, dimension life in embodiment 5 The content of plain E, thorn A Gan trees benevolence oil, camellia seed oil so that gained hair conditioner obtains good hair conditioning.
Embodiment 6
The raw material composition of hair conditioner is shown in Table 12.
The raw material composition of hair conditioner in 12 embodiment 6 of table and comparative example 6-1~6-3
The preparation method is the same as that of Example 1, and oil phase is warming up to 70 DEG C with water phase.
It scores the hair conditioner quality obtained in embodiment 6, comparative example 6-1~6-3, the results are shown in Table 13.
The quality score of hair conditioner in 13 embodiment 6 of table and comparative example 6-1~6-3
Compared with the hair conditioner in embodiment 6, the ingredient in comparative example 6-1 lacks folic acid and vitamin E, comparative example 6-2 In folic acid and vitamin E it is excessive, the thorn A Gan trees benevolence oil in comparative example 6-3, panthenol excess.From hair conditioner quality score result It is found that the indices of embodiment 6 score at 8 points or more;And whether the comparative example 6-1 that ingredient lacks is easy to comb, is It is no it is a softer and smoother touch, whether flexible, whether be easy to molding, be whether withered, whether the scoring of the indexs such as glossy is below 7 points; The excessive comparative example 6-2 of ingredient and comparative example 6-3 score lower index be concentrated mainly on it is whether easily clean, whether greasy, be Whether no scalp itch is easy to comb 4 indexs, at 7.5 points or less.It follows that by reasonably matching in embodiment 6 The content of folic acid, vitamin E, thorn A Gan trees benevolence oil, panthenol so that gained hair conditioner obtains good hair conditioning.
Embodiment 7
The raw material composition of hair conditioner is shown in Table 14.
The raw material composition of hair conditioner in 14 embodiment 7 of table and comparative example 7-1~7-3
The preparation method is the same as that of Example 1, and oil phase is warming up to 80 DEG C with water phase.
It scores the hair conditioner quality obtained in embodiment 7, comparative example 7-1~7-3, the results are shown in Table 15.
The quality score of hair conditioner in 15 embodiment 7 of table and comparative example 7-1~7-3
Compared with the hair conditioner in embodiment 7, the ingredient in comparative example 7-1 lacks folic acid and vitamin E, comparative example 7-2 In folic acid and vitamin E it is excessive, the panthenol, camellia seed oil in comparative example 7-3 are excessive.It can from hair conditioner quality score result Know, the indices of embodiment 7 score at 8 points or more;And ingredient lack comparative example 7-1 whether scalp itch, whether Be easy to comb, be whether a softer and smoother touch, whether flexible, whether be easy to molding, be whether withered, whether the scoring of the indexs such as glossy It is below 7.5 points;The excessive comparative example 7-2 of ingredient and comparative example 7-3 score lower index be concentrated mainly on it is whether easily clean, It is whether greasy, whether scalp itch, whether be easy to comb 4 indexs, at 7 points or less.It follows that passing through in embodiment 1 Reasonably match the content of folic acid, vitamin E, panthenol, camellia seed oil so that gained hair conditioner obtains good hair conditioning.
The hair conditioner indices value inspection result obtained in Examples 1 to 7 is shown in Table 16.
The hair conditioner indices value inspection result obtained in 16 Examples 1 to 7 of table

Claims (10)

1. a kind of hair conditioner, which is characterized in that including folic acid, vitamin E, panthenol, thorn A Gan trees benevolence oil and camellia seed oil;It is described The quality of folic acid is the 0.001%~0.1% of hair conditioner quality;The quality of the vitamin E be hair conditioner quality 0.3%~ 1.5%;The quality of the panthenol is the 0~1.5% of hair conditioner quality;The quality of the thorn A Gan trees benevolence oil is hair conditioner quality 0~1.5%;The quality of the camellia seed oil is the 0~2% of hair conditioner quality;Contain panthenol, thorn A Gan in the hair conditioner Set at least one of benevolence oil and camellia seed oil.
2. hair conditioner according to claim 1, which is characterized in that including:
3. hair conditioner according to claim 2, which is characterized in that the cation opsonizing agent is selected from behenyl base trimethyl chlorine Change ammonium and/or stearyl trimethyl ammonium chloride.
4. hair conditioner according to claim 2, which is characterized in that it is fine that the thickener is selected from stearyl alcohol, Hydroxyethylethyl Tie up one or more of element, cetostearyl alcohol, xanthans and hydroxyethyl cellulose.
5. hair conditioner according to claim 2, which is characterized in that the fragrant agent be selected from essence, hydrosol, essential oil with perfume (or spice) It is one or more in taste grease.
6. hair conditioner according to claim 2, which is characterized in that the preservative be selected from Phenoxyethanol, methyl hydroxybenzoate with It is one or more in Nipasol;Or one kind or more in methylchloroisothiazandnone, benzyl alcohol and methylisothiazolinone Kind;Or Phenoxyethanol with it is one or more in methylisothiazolinone;Or Phenoxyethanol, Sensiva SC50 and the different thiophene of methyl It is one or more in oxazoline ketone;Or it is one or more in fermentation of bacillus product, propylene glycol and hexylene glycol;Or 1,2- oneself Glycol with it is one or more in parahydroxyacet-ophenone;Or peony root extractive.
7. hair conditioner according to claim 6, which is characterized in that the preservative is Phenoxyethanol, methyl hydroxybenzoate and hydroxyl Phenylpropyl alcohol ester;The mass ratio of the Phenoxyethanol, methyl hydroxybenzoate and Nipasol is (4~2):(3~1):1.
8. hair conditioner according to claim 1, which is characterized in that the content of vitamin E is the 0.5% of hair conditioner quality ~1.5%.
9. a kind of preparation method of hair conditioner, which is characterized in that including:
S1) by the vitamin E of 0.3~1.5wt%, the thorn A Gan trees benevolence oil of 0~1.5wt%, the camellia seed oil of 0~2wt%, 2 The cation opsonizing agent of~10wt% is mixed with the oil phase raw material in the thickener of 3~7wt%, is heated to 70 DEG C~85 DEG C, is obtained Oil phase after to heating;
By 0~5wt% moisturizer, 3~7wt% thickener in Aqueous Phase Raw Material and the water of surplus be mixed and heated to 70 DEG C~85 DEG C, the water phase after being heated;
S2) water phase after the heating is mixed with the oil phase after heating and carries out emulsifying, then it is added 0.001~ The folic acid of 0.1wt%, the panthenol of 0~1.5wt%, the fragrant agent of 0~0.5wt% and the preservative of 0~1wt% stir evenly, Obtain hair conditioner;
Contain at least one of camellia seed oil, panthenol and thorn A Gan tree benevolence oil in the hair conditioner.
10. the preparation method stated according to claim 9, which is characterized in that the step S2) be specially:
Water phase after the heating is mixed with the oil phase after heating and carries out emulsifying, is cooled to 30 DEG C~50 DEG C, is then added Enter the preservative of the folic acid of 0.001~0.1wt%, the panthenol of 0~1.5wt%, the fragrant agent of 0~0.5wt% and 0~1wt% It stirs evenly, obtains hair conditioner.
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