CN108778349B - 香料组合物 - Google Patents
香料组合物 Download PDFInfo
- Publication number
- CN108778349B CN108778349B CN201780017329.0A CN201780017329A CN108778349B CN 108778349 B CN108778349 B CN 108778349B CN 201780017329 A CN201780017329 A CN 201780017329A CN 108778349 B CN108778349 B CN 108778349B
- Authority
- CN
- China
- Prior art keywords
- perfume
- phytoncide
- pinene
- composition
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 143
- 239000002304 perfume Substances 0.000 title claims abstract description 105
- 239000003205 fragrance Substances 0.000 claims abstract description 46
- 239000002904 solvent Substances 0.000 claims abstract description 29
- 239000012298 atmosphere Substances 0.000 claims abstract description 10
- 238000013270 controlled release Methods 0.000 claims abstract description 7
- 239000002386 air freshener Substances 0.000 claims description 57
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 44
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 claims description 32
- -1 daminene Chemical compound 0.000 claims description 29
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims description 26
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims description 25
- BQOFWKZOCNGFEC-UHFFFAOYSA-N carene Chemical compound C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 claims description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 17
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims description 16
- 235000001510 limonene Nutrition 0.000 claims description 16
- 229940087305 limonene Drugs 0.000 claims description 16
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 claims description 14
- IRAQOCYXUMOFCW-OSFYFWSMSA-N cedr-8-ene Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(C)=CC2 IRAQOCYXUMOFCW-OSFYFWSMSA-N 0.000 claims description 12
- 238000001704 evaporation Methods 0.000 claims description 12
- 230000008020 evaporation Effects 0.000 claims description 12
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 claims description 12
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 11
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims description 10
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 238000009826 distribution Methods 0.000 claims description 9
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims description 8
- 229930006739 camphene Natural products 0.000 claims description 8
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims description 8
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 claims description 8
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 7
- 150000007823 ocimene derivatives Chemical class 0.000 claims description 7
- YKFLAYDHMOASIY-UHFFFAOYSA-N terpinene-gamma Natural products CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 claims description 7
- IHPKGUQCSIINRJ-UHFFFAOYSA-N β-ocimene Natural products CC(C)=CCC=C(C)C=C IHPKGUQCSIINRJ-UHFFFAOYSA-N 0.000 claims description 7
- CQUAYTJDLQBXCQ-NHYWBVRUSA-N (-)-isolongifolene Chemical compound C([C@@H](C1)C2(C)C)C[C@]31C2=CCCC3(C)C CQUAYTJDLQBXCQ-NHYWBVRUSA-N 0.000 claims description 6
- CXENHBSYCFFKJS-UHFFFAOYSA-N (3E,6E)-3,7,11-Trimethyl-1,3,6,10-dodecatetraene Natural products CC(C)=CCCC(C)=CCC=C(C)C=C CXENHBSYCFFKJS-UHFFFAOYSA-N 0.000 claims description 6
- GQVMHMFBVWSSPF-SOYUKNQTSA-N (4E,6E)-2,6-dimethylocta-2,4,6-triene Chemical compound C\C=C(/C)\C=C\C=C(C)C GQVMHMFBVWSSPF-SOYUKNQTSA-N 0.000 claims description 6
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 claims description 6
- FAMPSKZZVDUYOS-UHFFFAOYSA-N alpha-Caryophyllene Natural products CC1=CCC(C)(C)C=CCC(C)=CCC1 FAMPSKZZVDUYOS-UHFFFAOYSA-N 0.000 claims description 6
- NPNUFJAVOOONJE-UHFFFAOYSA-N beta-cariophyllene Natural products C1CC(C)=CCCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-UHFFFAOYSA-N 0.000 claims description 6
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 claims description 6
- 229940117948 caryophyllene Drugs 0.000 claims description 6
- GQVMHMFBVWSSPF-UHFFFAOYSA-N cis-alloocimene Natural products CC=C(C)C=CC=C(C)C GQVMHMFBVWSSPF-UHFFFAOYSA-N 0.000 claims description 6
- IRAQOCYXUMOFCW-UHFFFAOYSA-N di-epi-alpha-cedrene Natural products C1C23C(C)CCC3C(C)(C)C1C(C)=CC2 IRAQOCYXUMOFCW-UHFFFAOYSA-N 0.000 claims description 6
- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 claims description 6
- 229930009668 farnesene Natural products 0.000 claims description 6
- FAMJUFMHYAFYNU-JTQLQIEISA-N (4r)-1-methyl-4-propan-2-ylcyclohexene Chemical compound CC(C)[C@@H]1CCC(C)=CC1 FAMJUFMHYAFYNU-JTQLQIEISA-N 0.000 claims description 5
- XBGUIVFBMBVUEG-UHFFFAOYSA-N 1-methyl-4-(1,5-dimethyl-4-hexenylidene)-1-cyclohexene Chemical compound CC(C)=CCCC(C)=C1CCC(C)=CC1 XBGUIVFBMBVUEG-UHFFFAOYSA-N 0.000 claims description 5
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 claims description 5
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 5
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 5
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 claims description 5
- YHBUQBJHSRGZNF-HNNXBMFYSA-N alpha-bisabolene Natural products CC(C)=CCC=C(C)[C@@H]1CCC(C)=CC1 YHBUQBJHSRGZNF-HNNXBMFYSA-N 0.000 claims description 5
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 claims description 5
- 229930003493 bisabolene Natural products 0.000 claims description 5
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 claims description 5
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 5
- CCRCUPLGCSFEDV-UHFFFAOYSA-N methyl cinnamate Chemical compound COC(=O)C=CC1=CC=CC=C1 CCRCUPLGCSFEDV-UHFFFAOYSA-N 0.000 claims description 5
- GJQIMXVRFNLMTB-UHFFFAOYSA-N nonyl acetate Chemical compound CCCCCCCCCOC(C)=O GJQIMXVRFNLMTB-UHFFFAOYSA-N 0.000 claims description 5
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 4
- KRLBLPBPZSSIGH-CSKARUKUSA-N (6e)-3,7-dimethylnona-1,6-dien-3-ol Chemical compound CC\C(C)=C\CCC(C)(O)C=C KRLBLPBPZSSIGH-CSKARUKUSA-N 0.000 claims description 4
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 claims description 4
- JRTBBCBDKSRRCY-UHFFFAOYSA-N 3,7-dimethyloct-6-en-3-ol Chemical compound CCC(C)(O)CCC=C(C)C JRTBBCBDKSRRCY-UHFFFAOYSA-N 0.000 claims description 4
- UWKAYLJWKGQEPM-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl acetate Chemical compound CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 claims description 4
- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical compound CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 claims description 4
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 4
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims description 4
- 229930006978 terpinene Natural products 0.000 claims description 4
- 150000003507 terpinene derivatives Chemical class 0.000 claims description 4
- VSRVCSJJKWDZSH-UHFFFAOYSA-N (3-pentyloxan-4-yl) acetate Chemical compound CCCCCC1COCCC1OC(C)=O VSRVCSJJKWDZSH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001875 1-phenylethyl acetate Substances 0.000 claims description 3
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 3
- XFDQLDNQZFOAFK-UHFFFAOYSA-N 2-benzoyloxyethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOC(=O)C1=CC=CC=C1 XFDQLDNQZFOAFK-UHFFFAOYSA-N 0.000 claims description 3
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 claims description 3
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 claims description 3
- YVSNOTITPICPTB-UHFFFAOYSA-N 4-methyl-2-(2-methylpropyl)oxan-4-ol Chemical compound CC(C)CC1CC(C)(O)CCO1 YVSNOTITPICPTB-UHFFFAOYSA-N 0.000 claims description 3
- RDHNTAXPFZIMDN-UHFFFAOYSA-N 6,6-Dimethoxy-2,5,5-trimethyl-2-hexene Chemical compound COC(OC)C(C)(C)CC=C(C)C RDHNTAXPFZIMDN-UHFFFAOYSA-N 0.000 claims description 3
- WFDABEPFJQIGFC-UHFFFAOYSA-N C(CC)(=O)OC1=CC=C2C=CCC2=C1C Chemical compound C(CC)(=O)OC1=CC=C2C=CCC2=C1C WFDABEPFJQIGFC-UHFFFAOYSA-N 0.000 claims description 3
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 claims description 3
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 claims description 3
- RNVYQYLELCKWAN-UHFFFAOYSA-N solketal Chemical compound CC1(C)OCC(CO)O1 RNVYQYLELCKWAN-UHFFFAOYSA-N 0.000 claims description 3
- FINOAUDUYKVGDS-UHFFFAOYSA-N (2-tert-butylcyclohexyl) acetate Chemical compound CC(=O)OC1CCCCC1C(C)(C)C FINOAUDUYKVGDS-UHFFFAOYSA-N 0.000 claims description 2
- RLXAQIXESOWNGY-UHFFFAOYSA-N 1-methyl-4-propan-2-ylbenzene Chemical compound CC(C)C1=CC=C(C)C=C1.CC(C)C1=CC=C(C)C=C1 RLXAQIXESOWNGY-UHFFFAOYSA-N 0.000 claims description 2
- RQXTZKGDMNIWJF-UHFFFAOYSA-N 2-butan-2-ylcyclohexan-1-one Chemical compound CCC(C)C1CCCCC1=O RQXTZKGDMNIWJF-UHFFFAOYSA-N 0.000 claims description 2
- MBZRJSQZCBXRGK-UHFFFAOYSA-N 4-tert-Butylcyclohexyl acetate Chemical compound CC(=O)OC1CCC(C(C)(C)C)CC1 MBZRJSQZCBXRGK-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229940007550 benzyl acetate Drugs 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- LAVARTIQQDZFNT-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-yl acetate Chemical compound COCC(C)OCC(C)OC(C)=O LAVARTIQQDZFNT-UHFFFAOYSA-N 0.000 claims 3
- WRFXXJKURVTLSY-UHFFFAOYSA-N 2,6-dimethyloctan-2-ol Chemical compound CCC(C)CCCC(C)(C)O WRFXXJKURVTLSY-UHFFFAOYSA-N 0.000 claims 1
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 229930003658 monoterpene Natural products 0.000 description 10
- 150000002773 monoterpene derivatives Chemical class 0.000 description 10
- 235000002577 monoterpenes Nutrition 0.000 description 10
- NDVASEGYNIMXJL-UHFFFAOYSA-N sabinene Chemical compound C=C1CCC2(C(C)C)C1C2 NDVASEGYNIMXJL-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 9
- KQAZVFVOEIRWHN-UHFFFAOYSA-N alpha-thujene Natural products CC1=CCC2(C(C)C)C1C2 KQAZVFVOEIRWHN-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000004580 weight loss Effects 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 6
- 229940022663 acetate Drugs 0.000 description 6
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- NDVASEGYNIMXJL-NXEZZACHSA-N (+)-sabinene Natural products C=C1CC[C@@]2(C(C)C)[C@@H]1C2 NDVASEGYNIMXJL-NXEZZACHSA-N 0.000 description 4
- IHPKGUQCSIINRJ-CSKARUKUSA-N (E)-beta-ocimene Chemical compound CC(C)=CC\C=C(/C)C=C IHPKGUQCSIINRJ-CSKARUKUSA-N 0.000 description 4
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 description 4
- 240000005020 Acaciella glauca Species 0.000 description 4
- 235000008582 Pinus sylvestris Nutrition 0.000 description 4
- 241000219492 Quercus Species 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229930006722 beta-pinene Natural products 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 4
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 4
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 4
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 4
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 4
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 4
- 239000001839 pinus sylvestris Substances 0.000 description 4
- 229930006696 sabinene Natural products 0.000 description 4
- 150000003505 terpenes Chemical class 0.000 description 4
- 235000007586 terpenes Nutrition 0.000 description 4
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 4
- QRPLZGZHJABGRS-UHFFFAOYSA-N xi-5-Dodecanolide Chemical compound CCCCCCCC1CCCC(=O)O1 QRPLZGZHJABGRS-UHFFFAOYSA-N 0.000 description 4
- OGLDWXZKYODSOB-UHFFFAOYSA-N α-phellandrene Chemical compound CC(C)C1CC=C(C)C=C1 OGLDWXZKYODSOB-UHFFFAOYSA-N 0.000 description 4
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 3
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 3
- OALYTRUKMRCXNH-UHFFFAOYSA-N (R)- Dihydro-5-pentyl-2(3H)-furanone Natural products CCCCCC1CCC(=O)O1 OALYTRUKMRCXNH-UHFFFAOYSA-N 0.000 description 3
- HGDVHRITTGWMJK-UHFFFAOYSA-N 2,6-dimethylheptan-2-ol Chemical compound CC(C)CCCC(C)(C)O HGDVHRITTGWMJK-UHFFFAOYSA-N 0.000 description 3
- BGTBFNDXYDYBEY-FNORWQNLSA-N 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one Chemical compound C\C=C\C(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-FNORWQNLSA-N 0.000 description 3
- PXIKRTCSSLJURC-UHFFFAOYSA-N Dihydroeugenol Chemical compound CCCC1=CC=C(O)C(OC)=C1 PXIKRTCSSLJURC-UHFFFAOYSA-N 0.000 description 3
- YIKYNHJUKRTCJL-UHFFFAOYSA-N Ethyl maltol Chemical compound CCC=1OC=CC(=O)C=1O YIKYNHJUKRTCJL-UHFFFAOYSA-N 0.000 description 3
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 3
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229930008394 dihydromyrcenol Natural products 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229930002839 ionone Natural products 0.000 description 3
- 150000002499 ionone derivatives Chemical class 0.000 description 3
- YJSUCBQWLKRPDL-UHFFFAOYSA-N isocyclocitral Chemical compound CC1CC(C)=CC(C)C1C=O YJSUCBQWLKRPDL-UHFFFAOYSA-N 0.000 description 3
- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 description 3
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 3
- CCRCUPLGCSFEDV-BQYQJAHWSA-N methyl trans-cinnamate Chemical compound COC(=O)\C=C\C1=CC=CC=C1 CCRCUPLGCSFEDV-BQYQJAHWSA-N 0.000 description 3
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 3
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 3
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 3
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 2
- OPFTUNCRGUEPRZ-QLFBSQMISA-N (-)-beta-elemene Chemical compound CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 description 2
- ULDHMXUKGWMISQ-SECBINFHSA-N (-)-carvone Chemical compound CC(=C)[C@@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-SECBINFHSA-N 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 2
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 2
- ZWKNLRXFUTWSOY-QPJJXVBHSA-N (e)-3-phenylprop-2-enenitrile Chemical compound N#C\C=C\C1=CC=CC=C1 ZWKNLRXFUTWSOY-QPJJXVBHSA-N 0.000 description 2
- GJJSUPSPZIZYPM-UHFFFAOYSA-N 1,4-dioxacyclohexadecane-5,16-dione Chemical compound O=C1CCCCCCCCCCC(=O)OCCO1 GJJSUPSPZIZYPM-UHFFFAOYSA-N 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- DRLRGHZJOQGQEC-UHFFFAOYSA-N 2-(2-methoxypropoxy)propyl acetate Chemical class COC(C)COC(C)COC(C)=O DRLRGHZJOQGQEC-UHFFFAOYSA-N 0.000 description 2
- GKGOLPMYJJXRGD-UHFFFAOYSA-N 2-methyl-4-propyl-1,3-oxathiane Chemical compound CCCC1CCOC(C)S1 GKGOLPMYJJXRGD-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- IBVJWOMJGCHRRW-UHFFFAOYSA-N 3,7,7-Trimethylbicyclo[4.1.0]hept-2-ene Chemical compound C1CC(C)=CC2C(C)(C)C12 IBVJWOMJGCHRRW-UHFFFAOYSA-N 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- 240000000731 Fagus sylvatica Species 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- LQKRYVGRPXFFAV-UHFFFAOYSA-N Phenylmethylglycidic ester Chemical compound CCOC(=O)C1OC1(C)C1=CC=CC=C1 LQKRYVGRPXFFAV-UHFFFAOYSA-N 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- BCOXBEHFBZOJJZ-UHFFFAOYSA-N Z-hex-3-en-1-yl benzoate Natural products CCC=CCCOC(=O)C1=CC=CC=C1 BCOXBEHFBZOJJZ-UHFFFAOYSA-N 0.000 description 2
- LMETVDMCIJNNKH-UHFFFAOYSA-N [(3,7-Dimethyl-6-octenyl)oxy]acetaldehyde Chemical compound CC(C)=CCCC(C)CCOCC=O LMETVDMCIJNNKH-UHFFFAOYSA-N 0.000 description 2
- 150000008062 acetophenones Chemical class 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- UZFLPKAIBPNNCA-BQYQJAHWSA-N alpha-ionone Chemical compound CC(=O)\C=C\C1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-BQYQJAHWSA-N 0.000 description 2
- OGLDWXZKYODSOB-SNVBAGLBSA-N alpha-phellandrene Natural products CC(C)[C@H]1CC=C(C)C=C1 OGLDWXZKYODSOB-SNVBAGLBSA-N 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 2
- 229940117916 cinnamic aldehyde Drugs 0.000 description 2
- 235000000484 citronellol Nutrition 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 239000000306 component Substances 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- PPXUHEORWJQRHJ-UHFFFAOYSA-N ethyl isovalerate Chemical compound CCOC(=O)CC(C)C PPXUHEORWJQRHJ-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- IFYYFLINQYPWGJ-UHFFFAOYSA-N gamma-decalactone Chemical compound CCCCCCC1CCC(=O)O1 IFYYFLINQYPWGJ-UHFFFAOYSA-N 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 2
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
- ZNJFBWYDHIGLCU-HWKXXFMVSA-N jasmonic acid Chemical compound CC\C=C/C[C@@H]1[C@@H](CC(O)=O)CCC1=O ZNJFBWYDHIGLCU-HWKXXFMVSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- NTLJTUMJJWVCTL-UHFFFAOYSA-N methyl non-2-ynoate Chemical compound CCCCCCC#CC(=O)OC NTLJTUMJJWVCTL-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- VWMVAQHMFFZQGD-UHFFFAOYSA-N p-Hydroxybenzyl acetone Natural products CC(=O)CC1=CC=C(O)C=C1 VWMVAQHMFFZQGD-UHFFFAOYSA-N 0.000 description 2
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- NJGBTKGETPDVIK-UHFFFAOYSA-N raspberry ketone Chemical compound CC(=O)CCC1=CC=C(O)C=C1 NJGBTKGETPDVIK-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229930004725 sesquiterpene Natural products 0.000 description 2
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BQOFWKZOCNGFEC-BDAKNGLRSA-N (+)-Delta3-carene Chemical compound C1C(C)=CC[C@H]2C(C)(C)[C@@H]12 BQOFWKZOCNGFEC-BDAKNGLRSA-N 0.000 description 1
- OPFTUNCRGUEPRZ-UHFFFAOYSA-N (+)-beta-Elemen Natural products CC(=C)C1CCC(C)(C=C)C(C(C)=C)C1 OPFTUNCRGUEPRZ-UHFFFAOYSA-N 0.000 description 1
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- LFJQCDVYDGGFCH-JTQLQIEISA-N (+)-β-phellandrene Chemical compound CC(C)[C@@H]1CCC(=C)C=C1 LFJQCDVYDGGFCH-JTQLQIEISA-N 0.000 description 1
- FUCYIEXQVQJBKY-ZFWWWQNUSA-N (+)-δ-Cadinene Chemical compound C1CC(C)=C[C@H]2[C@H](C(C)C)CCC(C)=C21 FUCYIEXQVQJBKY-ZFWWWQNUSA-N 0.000 description 1
- LFJQCDVYDGGFCH-SNVBAGLBSA-N (+/-)-beta-Phellandrene Natural products CC(C)[C@H]1CCC(=C)C=C1 LFJQCDVYDGGFCH-SNVBAGLBSA-N 0.000 description 1
- CRPUJAZIXJMDBK-BDAKNGLRSA-N (-)-camphene Chemical compound C1C[C@H]2C(=C)C(C)(C)[C@@H]1C2 CRPUJAZIXJMDBK-BDAKNGLRSA-N 0.000 description 1
- 229930006714 (-)-camphene Natural products 0.000 description 1
- 229930006727 (-)-endo-fenchol Natural products 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- DAWDTDPJINNEJM-UHFFFAOYSA-N (2,4a,5,8a-tetramethyl-1,2,3,4,7,8-hexahydronaphthalen-1-yl) formate Chemical compound CC1=CCCC2(C)C(OC=O)C(C)CCC21C DAWDTDPJINNEJM-UHFFFAOYSA-N 0.000 description 1
- 239000001811 (2R,4R)-2-methyl-4-propyl-1,3-oxathiane Substances 0.000 description 1
- DHJVLXVXNFUSMU-YANFREPOSA-N (2e,6z)-3,7-dimethylnona-2,6-dienenitrile Chemical compound CC\C(C)=C/CC\C(C)=C\C#N DHJVLXVXNFUSMU-YANFREPOSA-N 0.000 description 1
- BCOXBEHFBZOJJZ-ARJAWSKDSA-N (3Z)-hex-3-en-1-yl benzoate Chemical compound CC\C=C/CCOC(=O)C1=CC=CC=C1 BCOXBEHFBZOJJZ-ARJAWSKDSA-N 0.000 description 1
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 description 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N (E)-Geraniol Chemical compound CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 1
- WUIFRGYQELQKDN-NTMALXAHSA-N (E)-Ocimene Natural products CC(C)CC\C=C(\C)C=C WUIFRGYQELQKDN-NTMALXAHSA-N 0.000 description 1
- YHBUQBJHSRGZNF-VGOFMYFVSA-N (E)-alpha-bisabolene Chemical compound CC(C)=CC\C=C(/C)C1CCC(C)=CC1 YHBUQBJHSRGZNF-VGOFMYFVSA-N 0.000 description 1
- 239000001454 (E)-dec-4-enal Substances 0.000 description 1
- ITLSMVWXXNJUQO-FLYFVYFHSA-N (E)-hex-2-enal Chemical compound CCC\C=C\C=O.CCC\C=C\C=O ITLSMVWXXNJUQO-FLYFVYFHSA-N 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- TYDDWHVJHGIJCW-OLKPEBQYSA-N (Z)-Ocimene Natural products O[C@@H](C(=C)C)C/C=C(/C=C)\C TYDDWHVJHGIJCW-OLKPEBQYSA-N 0.000 description 1
- IHPKGUQCSIINRJ-NTMALXAHSA-N (Z)-beta-ocimene Chemical compound CC(C)=CC\C=C(\C)C=C IHPKGUQCSIINRJ-NTMALXAHSA-N 0.000 description 1
- XEJGJTYRUWUFFD-FNORWQNLSA-N (e)-1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one Chemical compound C\C=C\C(=O)C1C(C)C=CCC1(C)C XEJGJTYRUWUFFD-FNORWQNLSA-N 0.000 description 1
- KHQDWCKZXLWDNM-KPKJPENVSA-N (e)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol Chemical compound CC\C(CO)=C/CC1CC=C(C)C1(C)C KHQDWCKZXLWDNM-KPKJPENVSA-N 0.000 description 1
- RNLHVODSMDJCBR-SOFGYWHQSA-N (e)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol Chemical compound CC(O)C(C)\C=C\C1CC=C(C)C1(C)C RNLHVODSMDJCBR-SOFGYWHQSA-N 0.000 description 1
- CWRKZMLUDFBPAO-VOTSOKGWSA-N (e)-dec-4-enal Chemical compound CCCCC\C=C\CCC=O CWRKZMLUDFBPAO-VOTSOKGWSA-N 0.000 description 1
- RPLWLQJSZFPHGM-NSCUHMNNSA-N (e)-undec-9-enenitrile Chemical compound C\C=C\CCCCCCCC#N RPLWLQJSZFPHGM-NSCUHMNNSA-N 0.000 description 1
- MEJYWDUBOCZFFS-RKZGRAQHSA-N (ne)-n-[(6e)-2,4,4,7-tetramethylnona-6,8-dien-3-ylidene]hydroxylamine Chemical compound CC(C)C(=N/O)\C(C)(C)C\C=C(/C)C=C MEJYWDUBOCZFFS-RKZGRAQHSA-N 0.000 description 1
- YYMCVDNIIFNDJK-XFQWXJFMSA-N (z)-1-(3-fluorophenyl)-n-[(z)-(3-fluorophenyl)methylideneamino]methanimine Chemical compound FC1=CC=CC(\C=N/N=C\C=2C=C(F)C=CC=2)=C1 YYMCVDNIIFNDJK-XFQWXJFMSA-N 0.000 description 1
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
- WEZPLQKRXDBPEP-UHFFFAOYSA-N 1-(1-propoxypropan-2-yloxy)propan-2-ol Chemical compound CCCOCC(C)OCC(C)O WEZPLQKRXDBPEP-UHFFFAOYSA-N 0.000 description 1
- FVUGZKDGWGKCFE-UHFFFAOYSA-N 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalen-2-yl)ethanone Chemical compound CC1(C)CCCC2=C1CC(C(C)=O)(C)C(C)C2 FVUGZKDGWGKCFE-UHFFFAOYSA-N 0.000 description 1
- CRIGTVCBMUKRSL-FNORWQNLSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone Chemical compound C\C=C\C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-FNORWQNLSA-N 0.000 description 1
- IOFYRNMXFRRJPS-UHFFFAOYSA-N 1-(3,3-dimethylcyclohexen-1-yl)pent-4-en-1-one Chemical compound CC1(C)CCCC(C(=O)CCC=C)=C1 IOFYRNMXFRRJPS-UHFFFAOYSA-N 0.000 description 1
- NFASPEPDTMCBEN-UHFFFAOYSA-N 1-(3,3-dimethylcyclohexyl)ethyl formate Chemical compound O=COC(C)C1CCCC(C)(C)C1 NFASPEPDTMCBEN-UHFFFAOYSA-N 0.000 description 1
- QZZBJCFNHPYNKO-UHFFFAOYSA-N 1-Phenylethane-1-thiol Chemical compound CC(S)C1=CC=CC=C1 QZZBJCFNHPYNKO-UHFFFAOYSA-N 0.000 description 1
- ZTEQNJCQZLIKKA-QJKGBGACSA-N 1-[(2E,5Z,9Z)-2,7,8-trimethylcyclododeca-2,5,9-trien-1-yl]ethanone Chemical compound C/C=1/C(CC\C=C/C(C(\C=C/C/C=1)C)C)C(C)=O ZTEQNJCQZLIKKA-QJKGBGACSA-N 0.000 description 1
- OTAKUJWURRXKOW-HYXAFXHYSA-N 1-[(3z)-cyclooct-3-en-1-yl]ethanone Chemical compound CC(=O)C1CCCC\C=C/C1 OTAKUJWURRXKOW-HYXAFXHYSA-N 0.000 description 1
- PMKDAPPYGOWKLX-UHFFFAOYSA-N 1-methyl-3-(2-methylpropyl)cyclohexan-1-ol Chemical compound CC(C)CC1CCCC(C)(O)C1 PMKDAPPYGOWKLX-UHFFFAOYSA-N 0.000 description 1
- FAMJUFMHYAFYNU-UHFFFAOYSA-N 1-methyl-4-(propan-2-yl)cyclohex-1-ene Chemical compound CC(C)C1CCC(C)=CC1 FAMJUFMHYAFYNU-UHFFFAOYSA-N 0.000 description 1
- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 description 1
- IEZPIUQRQRWIFE-UHFFFAOYSA-N 2,4,6-trimethyl-4-phenyl-1,3-dioxane Chemical compound O1C(C)OC(C)CC1(C)C1=CC=CC=C1 IEZPIUQRQRWIFE-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- UEGBWDUVDAKUGA-UHFFFAOYSA-N 2,6,10-trimethylundec-9-enal Chemical compound CC(C)=CCCC(C)CCCC(C)C=O UEGBWDUVDAKUGA-UHFFFAOYSA-N 0.000 description 1
- MNHPIPXJWPEIDB-UHFFFAOYSA-N 2-(2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undec-5-en-5-yl)propan-1-ol Chemical compound CC1(C)CCC(C(CO)C)=C2C(C)(C)C3CC21CC3 MNHPIPXJWPEIDB-UHFFFAOYSA-N 0.000 description 1
- FUNYLZYOEJSMTO-UHFFFAOYSA-N 2-(2,4-dimethylcyclohexyl)pyridine Chemical compound CC1CC(C)CCC1C1=CC=CC=N1 FUNYLZYOEJSMTO-UHFFFAOYSA-N 0.000 description 1
- HOLAFQHNGXOLHE-UHFFFAOYSA-N 2-(cyclohexylmethyl)-4,4,6-trimethyl-1,3-dioxane Chemical compound O1C(C)CC(C)(C)OC1CC1CCCCC1 HOLAFQHNGXOLHE-UHFFFAOYSA-N 0.000 description 1
- IBVJWOMJGCHRRW-DTWKUNHWSA-N 2-Carene Natural products C1CC(C)=C[C@H]2C(C)(C)[C@@H]12 IBVJWOMJGCHRRW-DTWKUNHWSA-N 0.000 description 1
- FLUWAIIVLCVEKF-UHFFFAOYSA-N 2-Methyl-1-phenyl-2-propanyl acetate Chemical compound CC(=O)OC(C)(C)CC1=CC=CC=C1 FLUWAIIVLCVEKF-UHFFFAOYSA-N 0.000 description 1
- SJWKGDGUQTWDRV-UHFFFAOYSA-N 2-Propenyl heptanoate Chemical compound CCCCCCC(=O)OCC=C SJWKGDGUQTWDRV-UHFFFAOYSA-N 0.000 description 1
- XSAYZAUNJMRRIR-UHFFFAOYSA-N 2-acetylnaphthalene Chemical compound C1=CC=CC2=CC(C(=O)C)=CC=C21 XSAYZAUNJMRRIR-UHFFFAOYSA-N 0.000 description 1
- LKUDTTGAGPETJH-UHFFFAOYSA-N 2-amino-3-methylbenzoic acid;methyl 2-aminobenzoate Chemical compound COC(=O)C1=CC=CC=C1N.CC1=CC=CC(C(O)=O)=C1N LKUDTTGAGPETJH-UHFFFAOYSA-N 0.000 description 1
- BDIZOKISHHUZPI-UHFFFAOYSA-N 2-cyclohexylidene-2-(2-methylphenyl)acetonitrile Chemical compound CC1=CC=CC=C1C(C#N)=C1CCCCC1 BDIZOKISHHUZPI-UHFFFAOYSA-N 0.000 description 1
- AKTCCXLADQEENK-UHFFFAOYSA-N 2-ethyloctanoic acid hexyl butanoate Chemical compound C(CCCCC)C(C(=O)O)CC.C(CCCCC)OC(CCC)=O AKTCCXLADQEENK-UHFFFAOYSA-N 0.000 description 1
- JTHVYOIHZNYRCC-UHFFFAOYSA-N 2-hexylcyclopentan-1-one Chemical compound CCCCCCC1CCCC1=O JTHVYOIHZNYRCC-UHFFFAOYSA-N 0.000 description 1
- OFLXNHNYPQPQKW-UHFFFAOYSA-N 2-isopropyl-4-methylthiazole Chemical compound CC(C)C1=NC(C)=CS1 OFLXNHNYPQPQKW-UHFFFAOYSA-N 0.000 description 1
- LSAOROFQQDIDSZ-BJILWQEISA-N 2-methoxy-4-prop-1-enylphenol 2-methoxy-4-[(E)-prop-1-enyl]phenol Chemical compound COC1=CC(C=CC)=CC=C1O.COC1=CC(\C=C\C)=CC=C1O LSAOROFQQDIDSZ-BJILWQEISA-N 0.000 description 1
- VWFJDQUYCIWHTN-YFVJMOTDSA-N 2-trans,6-trans-farnesyl diphosphate Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CO[P@](O)(=O)OP(O)(O)=O VWFJDQUYCIWHTN-YFVJMOTDSA-N 0.000 description 1
- PANBRUWVURLWGY-UHFFFAOYSA-N 2-undecenal Chemical compound CCCCCCCCC=CC=O PANBRUWVURLWGY-UHFFFAOYSA-N 0.000 description 1
- XEFKRPWKRQTXDA-UHFFFAOYSA-N 3,4,5,6,6-pentamethylheptan-2-ol Chemical compound CC(O)C(C)C(C)C(C)C(C)(C)C XEFKRPWKRQTXDA-UHFFFAOYSA-N 0.000 description 1
- ZJPKYCLAROITRY-UHFFFAOYSA-N 3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene Chemical compound CCOC(C)OC(C)(C=C)CCC=C(C)C ZJPKYCLAROITRY-UHFFFAOYSA-N 0.000 description 1
- OHRBQTOZYGEWCJ-UHFFFAOYSA-N 3-(3-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=CC(C(C)CC=O)=C1 OHRBQTOZYGEWCJ-UHFFFAOYSA-N 0.000 description 1
- JFTSYAALCNQOKO-UHFFFAOYSA-N 3-(4-ethylphenyl)-2,2-dimethylpropanal Chemical compound CCC1=CC=C(CC(C)(C)C=O)C=C1 JFTSYAALCNQOKO-UHFFFAOYSA-N 0.000 description 1
- JRJBVWJSTHECJK-PKNBQFBNSA-N 3-Methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one Chemical compound CC(=O)C(\C)=C\C1C(C)=CCCC1(C)C JRJBVWJSTHECJK-PKNBQFBNSA-N 0.000 description 1
- GTNCESCYZPMXCJ-UHFFFAOYSA-N 3-Phenylpropyl propanoate Chemical compound CCC(=O)OCCCC1=CC=CC=C1 GTNCESCYZPMXCJ-UHFFFAOYSA-N 0.000 description 1
- UKZXPOJABTXLMK-UHFFFAOYSA-N 3-[2-methyl-4-(2-methylpropyl)phenyl]propanal Chemical compound CC(C)CC1=CC=C(CCC=O)C(C)=C1 UKZXPOJABTXLMK-UHFFFAOYSA-N 0.000 description 1
- OKANGIKHTABXMV-UHFFFAOYSA-N 3-ethyl-7-methyloct-6-en-3-ol Chemical compound CCC(O)(CC)CCC=C(C)C OKANGIKHTABXMV-UHFFFAOYSA-N 0.000 description 1
- CLBXCDSXUXNOIM-UHFFFAOYSA-N 3-oxidanylbutan-2-one Chemical compound CC(O)C(C)=O.CC(O)C(C)=O CLBXCDSXUXNOIM-UHFFFAOYSA-N 0.000 description 1
- KUKRLSJNTMLPPK-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2(C)C=CC1C2(C)C KUKRLSJNTMLPPK-UHFFFAOYSA-N 0.000 description 1
- ORMHZBNNECIKOH-UHFFFAOYSA-N 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)(O)CCCC1=CCC(C=O)CC1 ORMHZBNNECIKOH-UHFFFAOYSA-N 0.000 description 1
- BWJMAXUUBRFWGV-UHFFFAOYSA-N 5-tert-butyl-2-methyl-5-propyl-2h-furan Chemical compound CCCC1(C(C)(C)C)OC(C)C=C1 BWJMAXUUBRFWGV-UHFFFAOYSA-N 0.000 description 1
- NKDJGNROVOPIGT-UHFFFAOYSA-N 8,8-dimethyl-9-propan-2-yl-6,10-dioxaspiro[4.5]decane Chemical compound O1CC(C)(C)C(C(C)C)OC11CCCC1 NKDJGNROVOPIGT-UHFFFAOYSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- TWXUTZNBHUWMKJ-UHFFFAOYSA-N Allyl cyclohexylpropionate Chemical compound C=CCOC(=O)CCC1CCCCC1 TWXUTZNBHUWMKJ-UHFFFAOYSA-N 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- GLVKGYRREXOCIB-UHFFFAOYSA-N Bornylene Natural products CC1CCC(C(C)(C)C)C=C1 GLVKGYRREXOCIB-UHFFFAOYSA-N 0.000 description 1
- AQIBWSUENREQQC-UHFFFAOYSA-N C(C(C)C)(=O)OC1=CC=C2C=CCC2=C1C Chemical compound C(C(C)C)(=O)OC1=CC=C2C=CCC2=C1C AQIBWSUENREQQC-UHFFFAOYSA-N 0.000 description 1
- MQMRXMIRDIJQCS-UHFFFAOYSA-N C(C)(C)(C)C1C(CCCC1)CC(=O)O.C(C)(=O)OC1C(CCCC1)C(C)(C)C Chemical compound C(C)(C)(C)C1C(CCCC1)CC(=O)O.C(C)(=O)OC1C(CCCC1)C(C)(C)C MQMRXMIRDIJQCS-UHFFFAOYSA-N 0.000 description 1
- NXCDRDHCBASGOR-UHFFFAOYSA-N C(C)(C)(C)C1CCC(CC1)CC(=O)O.C(C)(=O)OC1CCC(CC1)C(C)(C)C Chemical compound C(C)(C)(C)C1CCC(CC1)CC(=O)O.C(C)(=O)OC1CCC(CC1)C(C)(C)C NXCDRDHCBASGOR-UHFFFAOYSA-N 0.000 description 1
- WXKDRDMUAZOKAK-UHFFFAOYSA-N C(C=CC1=CC=CC=C1)CC(=O)O.C(C)(=O)OCC=CC1=CC=CC=C1 Chemical compound C(C=CC1=CC=CC=C1)CC(=O)O.C(C)(=O)OCC=CC1=CC=CC=C1 WXKDRDMUAZOKAK-UHFFFAOYSA-N 0.000 description 1
- XRVIGWYBPZBVAN-UHFFFAOYSA-N C(CCCCC)C(C(=O)O)(C)C.C(C(C)C)(=O)OCCCCCC Chemical compound C(CCCCC)C(C(=O)O)(C)C.C(C(C)C)(=O)OCCCCCC XRVIGWYBPZBVAN-UHFFFAOYSA-N 0.000 description 1
- NPNUFJAVOOONJE-WDZFZDKYSA-N C1CC(/C)=C\CCC(=C)C2CC(C)(C)C21 Chemical compound C1CC(/C)=C\CCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-WDZFZDKYSA-N 0.000 description 1
- IROHAHSEZJNYEB-UHFFFAOYSA-N CC(C(=O)O)=CCC.CC(C(=O)O)=CCC Chemical compound CC(C(=O)O)=CCC.CC(C(=O)O)=CCC IROHAHSEZJNYEB-UHFFFAOYSA-N 0.000 description 1
- RISCJGALTMEEOK-UHFFFAOYSA-N CC(CC1=CC=CC=C1)(C)C(C(=O)O)CC.CC(C(=O)OC(C1=CC=CC=C1)(C)C)CC Chemical compound CC(CC1=CC=CC=C1)(C)C(C(=O)O)CC.CC(C(=O)OC(C1=CC=CC=C1)(C)C)CC RISCJGALTMEEOK-UHFFFAOYSA-N 0.000 description 1
- VKJQTVIFAUYGAQ-UHFFFAOYSA-N CC(CCC(CC)=O)C.C(CC(C)C)C(=O)CC Chemical compound CC(CCC(CC)=O)C.C(CC(C)C)C(=O)CC VKJQTVIFAUYGAQ-UHFFFAOYSA-N 0.000 description 1
- QGOOLEUSWTYQBT-UHFFFAOYSA-N COC1=CC=C(C=C1)CCC(C)=O.COC(C(CC)=O)C1=CC=CC=C1 Chemical compound COC1=CC=C(C=C1)CCC(C)=O.COC(C(CC)=O)C1=CC=CC=C1 QGOOLEUSWTYQBT-UHFFFAOYSA-N 0.000 description 1
- WZRWUOBXDCITPG-VRTOBVRTSA-N C\C(=C/CC)\C(CCCCC)O.CC(=CCCCCCCCC)O Chemical compound C\C(=C/CC)\C(CCCCC)O.CC(=CCCCCCCCC)O WZRWUOBXDCITPG-VRTOBVRTSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- JOZKFWLRHCDGJA-LLVKDONJSA-N Citronellyl acetate Natural products CC(=O)OCC[C@H](C)CCC=C(C)C JOZKFWLRHCDGJA-LLVKDONJSA-N 0.000 description 1
- 235000005976 Citrus sinensis Nutrition 0.000 description 1
- 240000002319 Citrus sinensis Species 0.000 description 1
- VLXDPFLIRFYIME-GZBLMMOJSA-N Copaene Natural products C1C=C(C)[C@H]2[C@]3(C)CC[C@H](C(C)C)[C@H]2[C@@H]31 VLXDPFLIRFYIME-GZBLMMOJSA-N 0.000 description 1
- 235000014493 Crataegus Nutrition 0.000 description 1
- 241001092040 Crataegus Species 0.000 description 1
- PANKHBYNKQNAHN-JTBLXSOISA-N Crocetin Natural products OC(=O)C(\C)=C/C=C/C(/C)=C\C=C\C=C(\C)/C=C/C=C(/C)C(O)=O PANKHBYNKQNAHN-JTBLXSOISA-N 0.000 description 1
- 244000301850 Cupressus sempervirens Species 0.000 description 1
- 102100020740 Dolichol phosphate-mannose biosynthesis regulatory protein Human genes 0.000 description 1
- HZPKNSYIDSNZKW-UHFFFAOYSA-N Ethyl 2-methylpentanoate Chemical compound CCCC(C)C(=O)OCC HZPKNSYIDSNZKW-UHFFFAOYSA-N 0.000 description 1
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 1
- 244000004281 Eucalyptus maculata Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 235000004994 Fagus sylvatica subsp sylvatica Nutrition 0.000 description 1
- VWFJDQUYCIWHTN-UHFFFAOYSA-N Farnesyl pyrophosphate Natural products CC(C)=CCCC(C)=CCCC(C)=CCOP(O)(=O)OP(O)(O)=O VWFJDQUYCIWHTN-UHFFFAOYSA-N 0.000 description 1
- IAIHUHQCLTYTSF-MRTMQBJTSA-N Fenchyl alcohol Chemical compound C1C[C@]2(C)[C@H](O)C(C)(C)[C@H]1C2 IAIHUHQCLTYTSF-MRTMQBJTSA-N 0.000 description 1
- 241000116713 Ferula gummosa Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- GVVPGTZRZFNKDS-YFHOEESVSA-N Geranyl diphosphate Natural products CC(C)=CCC\C(C)=C/COP(O)(=O)OP(O)(O)=O GVVPGTZRZFNKDS-YFHOEESVSA-N 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 101000932183 Homo sapiens Dolichol phosphate-mannose biosynthesis regulatory protein Proteins 0.000 description 1
- 229930183419 Irisone Natural products 0.000 description 1
- QILMAYXCYBTEDM-IWQZZHSRSA-N Isoambrettolide Chemical compound O=C1CCCCCCC\C=C/CCCCCCO1 QILMAYXCYBTEDM-IWQZZHSRSA-N 0.000 description 1
- ZPUKHRHPJKNORC-UHFFFAOYSA-N Longifolene Natural products CC1(C)CCCC2(C)C3CCC1(C3)C2=C ZPUKHRHPJKNORC-UHFFFAOYSA-N 0.000 description 1
- QTDMGAWIBXJNRR-UHFFFAOYSA-N Mangostin Natural products CC(=CCc1c(O)cc2Oc3cc(C)c(O)c(CC=C(C)C)c3C(=O)c2c1O)C QTDMGAWIBXJNRR-UHFFFAOYSA-N 0.000 description 1
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 description 1
- ZWNPUELCBZVMDA-CMDGGOBGSA-N Methyl 2-nonenoate Chemical compound CCCCCC\C=C\C(=O)OC ZWNPUELCBZVMDA-CMDGGOBGSA-N 0.000 description 1
- QPJVMBTYPHYUOC-UHFFFAOYSA-N Methyl benzoate Natural products COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 1
- FTXUQEKXCJSWMO-UHFFFAOYSA-N Nonanolactone Chemical compound O=C1CCCCCCCCO1 FTXUQEKXCJSWMO-UHFFFAOYSA-N 0.000 description 1
- VWUBZANPHLSNIC-UHFFFAOYSA-N O(C1=CC=CC=C1)CC=O.O(C1=CC=CC=C1)CC=O Chemical compound O(C1=CC=CC=C1)CC=O.O(C1=CC=CC=C1)CC=O VWUBZANPHLSNIC-UHFFFAOYSA-N 0.000 description 1
- MSFLYJIWLHSQLG-UHFFFAOYSA-N Octahydro-2H-1-benzopyran-2-one Chemical compound C1CCCC2OC(=O)CCC21 MSFLYJIWLHSQLG-UHFFFAOYSA-N 0.000 description 1
- IHPVFYLOGNNZLA-UHFFFAOYSA-N Phytoalexin Natural products COC1=CC=CC=C1C1OC(C=C2C(OCO2)=C2OC)=C2C(=O)C1 IHPVFYLOGNNZLA-UHFFFAOYSA-N 0.000 description 1
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical compound CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 240000009089 Quercus robur Species 0.000 description 1
- 235000011471 Quercus robur Nutrition 0.000 description 1
- GPMLJOOQCIHFET-UHFFFAOYSA-N Rhubafuran Chemical compound C1OC(C)CC1(C)C1=CC=CC=C1 GPMLJOOQCIHFET-UHFFFAOYSA-N 0.000 description 1
- ISQRJFLLIDGZEP-CMWLGVBASA-N Sophoricoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=C(C=2C(C3=C(O)C=C(O)C=C3OC=2)=O)C=C1 ISQRJFLLIDGZEP-CMWLGVBASA-N 0.000 description 1
- ISQRJFLLIDGZEP-KJRRRBQDSA-N Sophoricoside Natural products O([C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](CO)O1)c1ccc(C=2C(=O)c3c(O)cc(O)cc3OC=2)cc1 ISQRJFLLIDGZEP-KJRRRBQDSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- MTFNRLDCFXVGOM-ARJAWSKDSA-N [(Z)-hept-4-enyl] hydrogen carbonate Chemical compound CC\C=C/CCCOC(O)=O MTFNRLDCFXVGOM-ARJAWSKDSA-N 0.000 description 1
- FMFHUEMLVAIBFI-BQYQJAHWSA-N [(e)-2-phenylethenyl] acetate Chemical compound CC(=O)O\C=C\C1=CC=CC=C1 FMFHUEMLVAIBFI-BQYQJAHWSA-N 0.000 description 1
- FZLOGXXTGWFQFP-UHFFFAOYSA-N [1-methyl-2-(5-methylhex-4-en-2-yl)cyclopropyl]methanol Chemical compound CC(C)=CCC(C)C1CC1(C)CO FZLOGXXTGWFQFP-UHFFFAOYSA-N 0.000 description 1
- ZYIJXTQXQNXPSH-FMIVXFBMSA-N [2-[(e)-3,5-dimethylhex-3-en-2-yl]oxy-2-methylpropyl] cyclopropanecarboxylate Chemical compound CC(C)\C=C(/C)C(C)OC(C)(C)COC(=O)C1CC1 ZYIJXTQXQNXPSH-FMIVXFBMSA-N 0.000 description 1
- BZLYOWSSNHNYKW-UHFFFAOYSA-N [2-[1-(3,3-dimethylcyclohexyl)ethoxy]-2-methylpropyl] cyclopropanecarboxylate Chemical compound C1CCC(C)(C)CC1C(C)OC(C)(C)COC(=O)C1CC1 BZLYOWSSNHNYKW-UHFFFAOYSA-N 0.000 description 1
- CVPZXHCZKMFVOZ-UHFFFAOYSA-N [4-(benzoyloxymethyl)cyclohexyl]methyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(CC1)CCC1COC(=O)C1=CC=CC=C1 CVPZXHCZKMFVOZ-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- QMAYBMKBYCGXDH-UHFFFAOYSA-N alpha-amorphene Natural products C1CC(C)=CC2C(C(C)C)CC=C(C)C21 QMAYBMKBYCGXDH-UHFFFAOYSA-N 0.000 description 1
- UZFLPKAIBPNNCA-UHFFFAOYSA-N alpha-ionone Natural products CC(=O)C=CC1C(C)=CCCC1(C)C UZFLPKAIBPNNCA-UHFFFAOYSA-N 0.000 description 1
- GNRIZKKCNOBBMO-UHFFFAOYSA-N alpha-mangostin Chemical compound OC1=C(CC=C(C)C)C(O)=C2C(=O)C3=C(CC=C(C)C)C(OC)=C(O)C=C3OC2=C1 GNRIZKKCNOBBMO-UHFFFAOYSA-N 0.000 description 1
- ZVFQDLCERPGZMO-UHFFFAOYSA-N alpha-mangostin Natural products OC1=C(CC=C(C)C)C(O)=C2C(=O)C3=C(CC=C(C)C)C(OC)=C(O)C=C3CC2=C1 ZVFQDLCERPGZMO-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229940011037 anethole Drugs 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 239000000926 atmospheric chemistry Substances 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- POIARNZEYGURDG-FNORWQNLSA-N beta-damascenone Chemical compound C\C=C\C(=O)C1=C(C)C=CCC1(C)C POIARNZEYGURDG-FNORWQNLSA-N 0.000 description 1
- LFJQCDVYDGGFCH-UHFFFAOYSA-N beta-phellandrene Natural products CC(C)C1CCC(=C)C=C1 LFJQCDVYDGGFCH-UHFFFAOYSA-N 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 230000006696 biosynthetic metabolic pathway Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- 239000001191 butyl (2R)-2-hydroxypropanoate Substances 0.000 description 1
- BRDOFYPYQFDHOQ-UHFFFAOYSA-N butyl acetate;hexanoic acid Chemical compound CCCCCC(O)=O.CCCCOC(C)=O BRDOFYPYQFDHOQ-UHFFFAOYSA-N 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- SWUIQEBPZIHZQS-UHFFFAOYSA-N calone Chemical compound O1CC(=O)COC2=CC(C)=CC=C21 SWUIQEBPZIHZQS-UHFFFAOYSA-N 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930006737 car-3-ene Natural products 0.000 description 1
- 150000001717 carbocyclic compounds Chemical class 0.000 description 1
- PANKHBYNKQNAHN-JUMCEFIXSA-N carotenoid dicarboxylic acid Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C(=O)O)C=CC=C(/C)C(=O)O PANKHBYNKQNAHN-JUMCEFIXSA-N 0.000 description 1
- MIZGSAALSYARKU-UHFFFAOYSA-N cashmeran Chemical compound CC1(C)C(C)C(C)(C)C2=C1C(=O)CCC2 MIZGSAALSYARKU-UHFFFAOYSA-N 0.000 description 1
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 description 1
- 229940026455 cedrol Drugs 0.000 description 1
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- QZHPTGXQGDFGEN-UHFFFAOYSA-N chromene Chemical compound C1=CC=C2C=C[CH]OC2=C1 QZHPTGXQGDFGEN-UHFFFAOYSA-N 0.000 description 1
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 description 1
- IEPWIPZLLIOZLU-ARJAWSKDSA-N cis-3-Hexenyl salicylate Chemical compound CC\C=C/CCOC(=O)C1=CC=CC=C1O IEPWIPZLLIOZLU-ARJAWSKDSA-N 0.000 description 1
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- VLXDPFLIRFYIME-BTFPBAQTSA-N copaene Chemical compound C1C=C(C)[C@H]2[C@]3(C)CC[C@@H](C(C)C)[C@H]2[C@@H]31 VLXDPFLIRFYIME-BTFPBAQTSA-N 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 229940019836 cyclamen aldehyde Drugs 0.000 description 1
- BLBJUGKATXCWET-UHFFFAOYSA-N cyclaprop Chemical compound C12CC=CC2C2CC(OC(=O)CC)C1C2 BLBJUGKATXCWET-UHFFFAOYSA-N 0.000 description 1
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 229930007927 cymene Natural products 0.000 description 1
- YOCDGWMCBBMMGJ-UHFFFAOYSA-N delta-cadinene Natural products C1C=C(C)CC2C(C(C)C)CCC(=C)C21 YOCDGWMCBBMMGJ-UHFFFAOYSA-N 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000001813 ethyl (2R)-2-methylbutanoate Substances 0.000 description 1
- 239000001449 ethyl (2R)-2-methylpentanoate Substances 0.000 description 1
- KYEZYLFPHRVFBF-UHFFFAOYSA-N ethyl 2,6,6-trimethylcyclohexa-1,3-diene-1-carboxylate Chemical compound CCOC(=O)C1=C(C)C=CCC1(C)C KYEZYLFPHRVFBF-UHFFFAOYSA-N 0.000 description 1
- HCRBXQFHJMCTLF-UHFFFAOYSA-N ethyl 2-methylbutyrate Chemical compound CCOC(=O)C(C)CC HCRBXQFHJMCTLF-UHFFFAOYSA-N 0.000 description 1
- SSAHOVVSGAUNEL-UHFFFAOYSA-N ethyl butanoate;2-ethylbutanoic acid Chemical compound CCCC(=O)OCC.CCC(CC)C(O)=O SSAHOVVSGAUNEL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940093503 ethyl maltol Drugs 0.000 description 1
- 229940073505 ethyl vanillin Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- IAIHUHQCLTYTSF-UHFFFAOYSA-N fenchyl alcohol Natural products C1CC2(C)C(O)C(C)(C)C1C2 IAIHUHQCLTYTSF-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 239000004864 galbanum Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- GVVPGTZRZFNKDS-JXMROGBWSA-N geranyl diphosphate Chemical compound CC(C)=CCC\C(C)=C\CO[P@](O)(=O)OP(O)(O)=O GVVPGTZRZFNKDS-JXMROGBWSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- GIMBWMBFSHKEQU-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O.CCCCCC(C)=O GIMBWMBFSHKEQU-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- UWKQSNNFCGGAFS-XIFFEERXSA-N irinotecan Chemical compound C1=C2C(CC)=C3CN(C(C4=C([C@@](C(=O)OC4)(O)CC)C=4)=O)C=4C3=NC2=CC=C1OC(=O)N(CC1)CCC1N1CCCCC1 UWKQSNNFCGGAFS-XIFFEERXSA-N 0.000 description 1
- 229960004768 irinotecan Drugs 0.000 description 1
- 229940094941 isoamyl butyrate Drugs 0.000 description 1
- 125000005921 isopentoxy group Chemical group 0.000 description 1
- 108010075483 isoprene synthase Proteins 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
- YLQLGTFGVSLQJL-UHFFFAOYSA-N methyl 1,4-dimethylcyclohexane-1-carboxylate Chemical compound COC(=O)C1(C)CCC(C)CC1 YLQLGTFGVSLQJL-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- HRGPYCVTDOECMG-RHBQXOTJSA-N methyl cedryl ether Chemical compound C1[C@@]23[C@H](C)CC[C@H]2C(C)(C)[C@]1([H])[C@@](OC)(C)CC3 HRGPYCVTDOECMG-RHBQXOTJSA-N 0.000 description 1
- JPTOCTSNXXKSSN-UHFFFAOYSA-N methylheptenone Chemical compound CCCC=CC(=O)CC JPTOCTSNXXKSSN-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000037125 natural defense Effects 0.000 description 1
- 210000000822 natural killer cell Anatomy 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 229930006904 p-menthan-3-one Natural products 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- XVFMGWDSJLBXDZ-UHFFFAOYSA-O pelargonidin Chemical compound C1=CC(O)=CC=C1C(C(=C1)O)=[O+]C2=C1C(O)=CC(O)=C2 XVFMGWDSJLBXDZ-UHFFFAOYSA-O 0.000 description 1
- HKUHOPQRJKPJCJ-UHFFFAOYSA-N pelargonidin Natural products OC1=Cc2c(O)cc(O)cc2OC1c1ccc(O)cc1 HKUHOPQRJKPJCJ-UHFFFAOYSA-N 0.000 description 1
- 235000006251 pelargonidin Nutrition 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000280 phytoalexin Substances 0.000 description 1
- 150000001857 phytoalexin derivatives Chemical class 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- CBIDRCWHNCKSTO-UHFFFAOYSA-N prenyl diphosphate Chemical compound CC(C)=CCO[P@](O)(=O)OP(O)(O)=O CBIDRCWHNCKSTO-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- USDOQCCMRDNVAH-UHFFFAOYSA-N sigma-cadinene Natural products C1C=C(C)CC2C(C(C)C)CC=C(C)C21 USDOQCCMRDNVAH-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 229930195079 sophoraflavone Natural products 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000013179 statistical model Methods 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- DKZBBWMURDFHNE-UHFFFAOYSA-N trans-coniferylaldehyde Natural products COC1=CC(C=CC=O)=CC=C1O DKZBBWMURDFHNE-UHFFFAOYSA-N 0.000 description 1
- RRBYUSWBLVXTQN-UHFFFAOYSA-N tricyclene Chemical compound C12CC3CC2C1(C)C3(C)C RRBYUSWBLVXTQN-UHFFFAOYSA-N 0.000 description 1
- RRBYUSWBLVXTQN-VZCHMASFSA-N tricyclene Natural products C([C@@H]12)C3C[C@H]1C2(C)C3(C)C RRBYUSWBLVXTQN-VZCHMASFSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 description 1
- DFUVGLKCFAASAU-UHFFFAOYSA-N β-vetivene Chemical compound C1C2CCC1C1CC(C(C)C)CC1C2=C DFUVGLKCFAASAU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/12—Apparatus, e.g. holders, therefor
- A61L9/127—Apparatus, e.g. holders, therefor comprising a wick
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
- C11B9/0019—Aliphatic compounds containing oxygen as the only heteroatom carbocylic acids; Salts or esters thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/10—Apparatus features
- A61L2209/13—Dispensing or storing means for active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/10—Apparatus features
- A61L2209/13—Dispensing or storing means for active compounds
- A61L2209/135—Vaporisers for active components
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Abstract
提供了香料组合物，其具有在大气中控制释放的植物杀菌素，以生成类似于森林的空气环境的空气条件。该香料组合物包含a)至少约0.6％重量的至少一种植物杀菌素；和b)香料混合物，其包含(i)至少一种溶剂；和(ii)至少一种香味组分。至少约25％重量的所述至少一种植物杀菌素选自蒎烯α、蒎烯β及其组合。
Description
发明领域
本公开涉及空气清新剂。特别地，本公开涉及空气清新剂香料组合物，其在大气中提供增强和控制的植物杀菌素的释放。更具体地，本公开涉及空气清新剂香料组合物，其在大气中提供持续释放的植物杀菌素以产生类似于森林中的空气环境的空气条件。
发明背景
使用装置例如主动和被动空气清新器，包括电插入式空气清新器，蜡烛，气溶胶扩散器，喷雾器，膜空气清新器等，以向房间内的空气提供美妙和清爽的香味是众所周知的。市场上存在许多此类装置，还有许多香料可供选择。目标消费者利益包括例如邻近气味的愉悦，享乐，恶臭中和以及驱虫性。
森林浴是亚洲国家的一种流行运动，其为塑身的一种手段，包括在森林里散步和做有氧运动。人们认为，森林浴之旅对人类产生了积极影响，例如压力和焦虑缓解，平静和恢复活力作用。人们认识到，这些益处与森林大气中植物杀菌素或木油精油成分的存在有关。特别地，已经记载了植物杀菌素的存在与人类天然杀伤细胞的活性之间的相关性。参见例如Q.Li等，International Journal of Immunopathology and Pharmacology 22(2009)第951至959页及其中引用的参考文献。通过将个体暴露于天然森林，特别是那些由树脂树或桉属树木所生长的森林的大气所引起的生物体的天然防御的增强也是众所周知的。这些植物杀菌剂是萜和倍半萜类的挥发性分子，它们由木材本身产生，而这种产生在树脂树如松树和柏树中尤其重要。
然而，人们忙于工作，且往往没有时间去森林享受森林中的空气环境，尤其是城市中的居民。因此，仍然需要提供一种空气清新剂装置，其产生森林空气的健康和治疗益处并将其传递给内部环境。
发明概述
在一个实施方案中，香料组合物具有在大气中控制释放的植物杀菌素，以产生类似于森林的空气环境的空气条件，该香料组合物包含a)至少约0.6％重量的至少一种植物杀菌素；和b)香料混合物，其包含(i)至少一种溶剂；和(ii)至少一种香味组分。至少约25％重量的所述至少一种植物杀菌素选自蒎烯α、蒎烯β及其组合。
在另一个实施方案中，空气清新剂装置包括香料组合物，该香料组合物具有在大气中控制释放的植物杀菌素，以产生类似于森林的空气环境的空气条件。该香料组合物包含(a)至少约0.6％的至少一种植物杀菌素，其选自蒎烯α、蒎烯β及其组合；和(b)香料混合物，其包含(i)至少一种溶剂；和(ii)至少一种香味组分。该香料组合物具有约0.8μg/m3/小时至约10μg/m3/小时的植物杀菌素蒸发速率，该蒸发速率相对恒定至少至少30天。
在另一个实施方案中，自动气溶胶空气清新剂装置包括香料组合物，该香料组合物具有在大气中控制释放的植物杀菌素，以产生类似于森林的空气环境的空气条件。该香料组合物包含至少一种植物杀菌素，其选自蒎烯α、蒎烯β及其组合。该香料组合物具有约0.8μg/m3/小时至约10μg/m3/小时的植物杀菌素蒸发速率，该蒸发速率相对恒定至少至少30天。
通过阅读本公开，具体实施方案的这些和其它特征、方面和优点对于本领域技术人员将变得显而易见。
发明详述
以下文本阐述了本公开的许多不同实施方案的广泛描述。该描述仅被解释为示例性的，并未描述每个可能的实施方案，因为描述每个可能的实施方案即使并非不可能也是不切实际的。应当理解，本文所述的任何特征，特性，成分，组成，组分，产品，步骤或方法可以全部或部分地删除，组合或替代本文所述的任何其它特征，特性，成分，组成，组分，产品，步骤或方法。使用当前技术或在本专利申请日之后开发的技术可以实现许多替代实施方案，这仍然落入权利要求的范围内。本文引用的所有出版物和专利均通过引用并入本文。
植物杀菌素是植物来源的生物活性物质，其杀死或抑制细菌，微观真菌和昆虫的生长和发育。植物杀菌剂在植物免疫中起重要作用。它们是由B.P.Tokin在1928年发现的。产生植物杀菌素的能力是在其历史发展过程中获得的所有植物的共同属性。当植物受伤时，植物杀菌素的分泌增加。主要在日本进行的各种临床研究表明，植物杀菌素对人类健康也有积极作用。
植物杀菌素在化学组成方面可变。它们通常由一组化合物组成，例如糖苷，萜类化合物，单宁成分，植物抗毒素，广豆根黄酮甙(sophoraflavone)，α.倒捻子素和均二苯代乙烯寡聚体。然而，用于空气清新剂应用的感兴趣部分包括在25℃下蒸气压高于约0.001mm/Hg的植物杀菌素，在另一个实施方案中包括在25℃下蒸气压高于约0.01mm/Hg的植物杀菌素，并且在另一个实施方案中包括在25℃下蒸气压高于约0.1mm/Hg的植物杀菌素。这类植物杀菌素的非限制性实例包括单萜烯，例如苧烯(limonene)、α-蒎烯、β-蒎烯、β-月桂烯、三环烯、崁烯、δ-3-蒈烯、2-蒈烯、α-萜品烯、γ-萜品烯、萜品油烯、樟脑、崁烯、对伞花烃(para-cymene)、α-水芹烯、β-水芹烯、桧烯、顺式-罗勒烯、β-罗勒烯、α-崖柏烯、β-榄香烯、冰片烯；和倍半萜类，例如金合欢烯、
烯(copaene)、石竹烯、α-长叶烯、α-雪松烯、γ-衣兰油烯(gamma-muurolene)、δ-杜松烯；及其衍生物，例如榄香醇、雪松醇、α-桉叶油醇等。
更一般地，任何衍生自焦磷酸异戊烯酯的烃，通过涉及焦磷酸异戊烯酯与焦磷酸二甲基烯丙酯缩合成焦磷酸香叶酯和焦磷酸金合欢酯的生物合成途径，或焦磷酸异戊烯酯与异戊二烯合酶之间的反应，因有利于本公开而成为关注的。
植物杀菌素的自然排放水平可能是变化的，并且取决于树种以及是否在白天或夜间评估排放。例如，众所周知，森林大气中萜烯的最高浓度是在凌晨4点左右发现的。例如，R.Janson，J.Atmospheric Chemistry 14(1992)385-394页报道了白天的总单萜浓度为约0.01至约0.5ppbv(十亿分之几份体积)，而夜间为约0.2至约8ppbv。考虑到理想气体的定律和单萜的分子量为136g/mol，这些相当于白天约0.05至约2.8ng/l或0.05至约2.8微克/立方米的浓度；和夜间约1.1至约44.5ng/l或约1.1至44.5微克/立方米。
此外，单个单萜的比例可以从一个树种到另一个树种而变化。因此，例如，树木排放的单萜总量中α-蒎烯的部分可以是约0(2)至约100％重量(wt％)，而括号之间的数字是指在(S.Moukhtar，Thesis，Institur National Polytechnique de Toulouse，2005)中公布的最低测量值。根据相同的来源，最重要的单萜的相应范围在下面以wt％列出：α-蒎烯(约0(3.9)至约55wt％)；δ-3-蒈烯(约0(0.1)至约30wt％)；崁烯(约0(1,1)至约25wt％)；苧烯(约0(0.1)至约90wt％)；月桂烯(约0(0.4)至约55wt％)；桧烯(约0(0.7)至约75wt％)；反式-罗勒烯(约0(14.7)至约50wt％)；对伞花烃(Para-cimene)(约0(0.1)至约20wt％)；萜品油烯(约0(0.5)至约16wt％)；α-萜品醇(约0(0.5)至约20wt％)。
为了示例这点，例如，均匀种植有欧洲赤松(Pinus Sylvestris)的林地可以排放出单萜类的混合物，其平均由约52wt％α-蒎烯、约8wt％β-蒎烯、约26wt％δ-3-蒈烯、约7wt％崁烯、约4wt％苧烯和约4wt％月桂烯组成，而均匀种植有欧洲栎(Quercis Robur)的林地可以平均排放出约35wt％α-蒎烯、约6wt％β-蒎烯、约0.3wt％δ-3-蒈烯、约6.8wt％崁烯、约13wt％苧烯、约0.5wt％月桂烯、约0.7wt％桧烯、约15wt％反式-罗勒烯、约12wt％对伞花烃(para-cimene)和约12％萜品油烯；且欧洲山毛榉(Fagus Sylvatica)可以排放出3wt％α-蒎烯、约8.5wt％β-蒎烯、约3wt％苧烯、约3wt％月桂烯、约75wt％桧烯、约1.5wt％α-崖柏烯、约8wt％α-水芹烯、约7.5wt％γ-萜品油烯和约1wt％萜品油烯。
与植物杀菌剂的浓度一起，本公开的另一个感兴趣的特征是植物杀菌素在自然界中的排放速率。该速率通常以在303K下每克和每小时干木材的微克植物杀菌素表示。根据定义，在60℃的水消除之后确定干木材的质量直至达到质量恒定。对于大多数树木，总单萜的排放速率约为约0.1至约50微克/克干物质/小时，视季节而定(J.Llusia，J.Penuelas，American J.Botany，87(2000)133-140页)，在另一个实施方案中，为约0.1mg/h至约15微克/克干物质/小时，在另一个实施方案中为约0.1mg/h至约5微克/克干物质/小时(S.Moukhtar，Thesis，Institur National Polytechnique de Toulouse，2005)。另一方面，活树由约50至约75wt％的水构成，这意味着活树具有约25％-50％的干木材。典型的针叶树林例如欧洲赤松具有约1000kg/m2的湿生物量(参见G.Allwine等，“Application ofAtmospheric Tracer Technique to Determine Biogenic Hydrocarbon Fluxes from anOak Forest”，B.A.Hutchinson和B.B.Hicks(eds)，D Reidel Publishing Company，1985，361-382页)，这相当于250-500kg的干物质。因此，该生物质排放的单萜的总量约为25至约25000mg/m2/小时，在另一个实施方案中约为25至约7500mg/m2/小时，在另一个实施方案中为约25至约2500mg/m2/小时。然而，G.Allwine(文献同上)进行的流量测量表明，测量的排放值远小于这些值，这启示由于外部风和垂直对流/扩散效应的作用，稀释因子为约30至800。应用这样的稀释因子，有效局部排放值为约0.03至约30mg/m2/小时，在另一个实施方案中为约0.03至约10mg/m2/小时，在另一个实施方案中为约0.03至约3mg/m2/小时。最后，这些值需要除以15，这是树的平均高度的一半(以米为单位)(参见，例如University ofArkansas Publication FSA5021)，以获得位于距离地面2m以内体积中的排放速率的近似值，即在森林中行走的人在该位置会感觉到对他/她有益的植物杀菌素。这导致该位置处的局部排放值为约1至约1000微克/m3/小时，在另一个实施方案中为约1至约300微克/m3/小时，在另一个实施方案中为约1至约100微克/m3/小时。
香料组合物
根据本公开，香料组合物包含植物杀菌素、溶剂和香味组分的混合物。
植物杀菌素
根据一个实施方案，本公开的香料组合物可以包含至少一种植物杀菌素。适合的植物杀菌素可以在25℃下具有高于约0.001mm/Hg的蒸气压；在另一个实施方案中，在25℃下具有高于约0.01mm/Hg的蒸气压；并且在另一个实施方案中在25℃下具有高于约0.1mm/Hg的蒸气压。
然而，申请人已经发现，在空气清新剂的环境中，组分的蒸气压可以有利地被其标准平衡顶空浓度
替代。
以微克/升(μg/L)表示的标准平衡顶空浓度
是指该组分在25℃的温度下并在1大气压下与凝聚形式(即固体或液体形式)平衡的组分浓度。它可以通过使用本领域中任何已知的定量顶空分析技术来测量。适合的方法描述于Mueller和Lamparsky，Perfumes：Art，Science and Technology，第6章，“The Measurement of Odors”，176-179页(Elsevier 1991)中。
在一个实例中，可以如下测量
将500mg试验化合物加入顶空容器中，然后将其密封。然后将容器在恒定的25℃下温育直至化合物在气相和液相之间达到平衡。使用Porapak Q作为吸附剂将限定体积的该饱和顶空(通常为0.5-1.0升)捕集在微过滤器上。用适当的溶剂(通常为30-100微升甲基叔丁基醚)过滤提取后，通过GC分析提取物的等分试样。通过外标校准方法进行定量。可以从通过微过滤器吸入的顶空体积和注入气相色谱仪的过滤器提取物的等分试样计算原始顶空中的浓度(以μg/L表示)。获得给定测试化合物的最终顶空浓度值，作为每个三次独立测量的平均值。上文描述的技术的进一步信息可以在Etzweiler，F.；Senn E.和Neuner-Jehle N.，Ber.Bunsen-Ges.Phys.Chem.1984，88，578-583的文章中找到。
本公开示例性的植物杀菌素可以包括、但不限于(E)-1-甲基-4-(6-甲基庚-2,5-二烯-2-基)环己-1-烯，例如红没药烯；(1S,4R)-2,2-二甲基-3-亚甲基二环[2.2.1]庚烷，例如崁烯；(Z)-4,11,11-三甲基-8-亚甲基二环[7.2.0]十一碳-4-烯，例如石竹烯；(1S,8aR)-1,4,4,6-四甲基-2,3,3a,4,5,8-六氢-1H-5,8a-亚甲基甘菊环，例如α雪松烯；1-甲基-4-丙-2-基苯，例如对伞花烃(CIMENE PARA)；3,7,7-三甲基二环[4.1.0]庚-3-烯，例如δ-3-蒈烯；1-甲基-4-(丙-1-烯-2-基)环己-1-烯，例如双戊烯；(E)-7,11-二甲基-3-亚甲基十二碳-1,6,10-三烯，例如金合欢烯；(2S)-1,3,4,5,6,7-六氢-1,1,5,5-四甲基-2H-2,4a-亚甲基萘，例如异长叶烯；1-甲基-4-丙-1-烯-2-基环己烯，例如D-苧烯；1-甲基-4-丙-2-基苯，例如对伞花烃(CIMENE PARA)；1-甲基-4-丙-2-基环己烯，例如对薄荷烯；7-甲基-3-亚甲基辛-1,6-二烯，例如月桂烯；(E)-3,7-二甲基辛-1,3,6-三烯，例如罗勒烯；1-甲基-4-丙-2-基苯，例如别罗勒烯(ALOOCIMENE)；2,6,6-三甲基二环[3.1.1]庚-2-烯，例如蒎烯α；6,6-二甲基-2-亚甲基二环[3.1.1]庚烷，例如(蒎烯β)；(4aS,8S,8aS)-4,4,8a-三甲基-7-亚甲基-8-(3-亚甲基戊-4-烯基)-2,3,4a,5,6,8-六氢-1H-萘，例如香紫苏烯(SCLARENE)；1-甲基-4-丙-2-基环己-1,3-二烯，例如萜品烯α；1-甲基-4-丙-2-基环己-1,4-二烯，例如萜品烯γ；1-甲基-4-(丙-2-亚基)环己-1-烯，例如萜品油烯；2-异丙基-8-亚甲基十氢-4,7-亚甲基甘菊环，例如岩兰烯(VETYVENE)。
申请人发现，对于本公开的空气清新剂香料组合物，空气中的浓度与纯植物杀菌剂的
浓度乘以组合物中该植物杀菌素的浓度(wt％)成正比。如本文所用，“挥发性植物杀菌素”是指具有大于约1000μg/L的植物杀菌素的
(即，在25℃下高于约0.1mmHg的蒸气压)。这允许直接预测空气清新剂组合物中的植物杀菌素浓度，其是在空气中提供期望的植物杀菌素浓度分布所需的。
所述香料组合物可以包含占该香料组合物重量约0.1％至约15％或该范围内的任意单个数值的一种或多种植物杀菌素。在另一个实施方案中，该香料组合物可以包含占该香料组合物重量至少约0.6％的一种或多种植物杀菌素；在另一个实施方案中，该香料组合物可以包含占该香料组合物重量至少约0.8％的一种或多种植物杀菌素；并且在另一个实施方案中，该香料组合物可以包含占该香料组合物重量至少约1.1％的一种或多种植物杀菌素。
在一个实施方案中，所述植物杀菌素包括至少约25wt％的一种或多种植物杀菌素，其选自蒎烯α、蒎烯β及其混合物。在另一个实施方案中，所述香料组合物包含至少35wt％的一种或多种植物杀菌素，其选自蒎烯α、蒎烯β及其混合物。在另一个实施方案中，所述香料组合物包含至少50wt％的一种或多种植物杀菌素，其选自蒎烯α、蒎烯β及其混合物。
在另一个实施方案中，所述香料组合物包含约0.1％至约0.9wt％的蒎烯α；约0.1wt％至约0.9wt％的蒎烯β；和约0.1wt％至约0.9wt％的一种或多种植物杀菌素，其选自红没药烯、崁烯、石竹烯、α雪松烯、对伞花烃(CIMENE PARA)、δ-3-蒈烯、双戊烯、D-苧烯、金合欢烯、异长叶烯、对伞花烃(PARA CIMENE)、对薄荷烯、月桂烯、罗勒烯、别罗勒烯、香紫苏烯、萜品烯α、萜品烯γ、萜品油烯、岩兰烯及其混合物。在另一个实施方案中，所述香料组合物包含约0.3wt％至约0.5wt％的蒎烯α；约0.3wt％至约0.5wt％蒎烯β；和约0.3wt％至约0.5wt％的一种或多种植物杀菌素，其选自红没药烯、崁烯、石竹烯、α雪松烯、对伞花烃(CIMENE PARA)、δ-3-蒈烯、双戊烯、D-苧烯、金合欢烯、异长叶烯、对伞花烃(PARA CIMENE)、对薄荷烯、月桂烯、罗勒烯、别罗勒烯、香紫苏烯、萜品烯α、萜品烯γ、萜品油烯、岩兰烯及其混合物。
在另一个实施方案中，所述香料组合物模拟由松树(欧洲赤松)森林排放的植物杀菌素组合物。特别地，所述香料组合物包含约0.07wt％至约0.9wt％的蒎烯α；约0.02wt％至约0.2wt％的蒎烯β；约0.1wt％至约1.1wt％的δ-3-蒈烯；约0.01wt％至约0.1wt％的崁烯和约0.02wt％至约0.2wt％的苧烯。在另一个实施方案中，所述香料组合物包含约0.27wt％至约0.4wt％的蒎烯α；约0.07wt％至约0.1wt％的蒎烯β；约0.35wt％至约0.5wt％的δ-3-蒈烯；约0.04wt％至约0.1wt％的崁烯和约0.06wt％至约0.1wt％的苧烯。
在另一个实施方案中，所述香料组合物模拟由橡树(欧洲栎)森林排放的植物杀菌素组合物。特别地，所述香料组合物包含约0.03wt％至约0.4wt％的蒎烯α；约0.01wt％至约0.1wt％的蒎烯β；约0.03wt％至约0.4wt％的对伞花烃(PARA-CIMENE)；约0.01wt％至约0.1wt％的崁烯；约0.05wt％至约0.7wt％的罗勒烯；约0.03wt％至约0.4wt％的萜品油烯；和约0.04wt％至约0.4wt％的苧烯。在另一个实施方案中，所述香料组合物包含约0.13wt％至约0.2wt％的蒎烯α；约0.04wt％至约0.1wt％的蒎烯β；约0.12wt％至约0.2wt％的对伞花烃(PARA-CIMENE)；约0.05wt％至约1.1wt％的崁烯；约0.21wt％至约0.3wt％的罗勒烯；约0.13wt％至约0.2wt％的萜品油烯；和约0.14wt％至约0.2wt％的苧烯。
溶剂
根据一个实施方案，本公开的香料组合物可以包含至少一种溶剂。适合的溶剂可以具有至多约0.5mmHg的蒸气压(相当于至多约4000至约5000μg/L的
)，视分子量的不同而定；在另一个实施方案中，所述溶剂具有至多约0.1mmHg的蒸气压(相当于至多约500至约700μg/L的
)，视分子量的不同而定。
适合的溶剂或溶剂混合物可以包括、但不限于一缩二丙二醇甲基醚、二缩三丙二醇甲基醚，例如DOWANOL TPM，购自Dow Chemicals；一缩二丙二醇甲基醚乙酸酯，例如DOWANOL DPMA，购自Dow Chemicals；一缩二丙二醇正丙基醚，例如DOWANOL DPnP，购自DowChemicals；一缩二丙二醇正丁基醚，例如DOWANOL DPnB，购自Dow Chemicals；一缩二丙二醇、丙二醇、ISOPAR H至ISOPAR Z，购自ExxonMobil Chemicals；戊二酸二甲酯和己二酸二甲酯混合物，例如FLEXISOLVE，购自Flexisolve Technology；2,2-二甲基-1,3-二氧戊环-4-甲醇，例如AUGEO-CLEAN MULTI，购自Rhodia；ETHYLENE GLYCOL DIBENZOATE，例如BENZOFLEX P200，购自Eastman；和3-甲基-3-甲氧基丁醇，购自Kuraray。
在一个实施方案中，本公开的香料组合物包含约10至约75wt％水平的溶剂，在另一个实施方案中，约25至约60wt％，并且在另一个实施方案中，约30至约50wt％。
香味组分
根据一个实施方案，用于根据本公开的香料组合物的香味组分可选自天然产物，例如精油，净油，香树脂，树脂，浸膏和合成香味组分，例如烃类，醇类，醛类，酮类，醚类，酸类，缩醛类，缩酮类和腈类，包括饱和与不饱和化合物，脂族、碳环和杂环化合物，或任何上述的前体。可以使用的香味剂组合物的其它实例描述于H1468(United States StatutoryInvention Registration或S.Arctander“Perfume and Flavor Chemicals：第1卷，Allured Publishing Corporation 1969或其任何后续版本，以及IFRA(InternationalFragrance Research Association)数据库和RIFM(Research Institute of FragranceMaterials)数据库，其中每一个都通过引用整体并入本文。
用于空气清新剂香料组合物的适合的香味组分包括、但不限于2-甲基2-戊烯酸(2-甲基-戊-2-烯酸)；乙偶姻(3-羟基丁-2-酮)；特级苯乙酮(苯乙酮)；乙酸邻叔丁基环己酯(乙酸2-(叔丁基)环己酯)；壬醇(壬-1-醇)；癸醛(癸醛)；十一碳烯醛(十一碳-10-烯醛)；月桂醛(月桂醛)；己醛(己-1-醇)；辛醛(辛醛)；壬醛(壬醛)；乙酸二甲基庚酯(乙酸2,6-二甲基庚-4-基酯)；烯丙基戊基羟乙酸酯(2-(异戊基氧基)乙酸烯丙酯)；烯丙基环己基丙酸酯(3-环己基丙酸烯丙酯)；庚酸烯丙酯；AMBERMAX(1,3,4,5,6,7-六氢-β,1,1,5,5-五甲基-2H-2,4a-亚甲基萘-8-乙醇)；黄葵内酯((Z)-氧杂环十七碳-10-烯-2-酮)；
(3a,6,6,9a-四甲基十二氢萘并[2,1-b]呋喃)；合成茴脑((E)-1-甲氧基-4-(丙-1-烯-1-基)苯)；
(1-苯基乙硫醇)；阿佛曼酯(甲酸1-(3,3-二甲基环己基)乙酯)；AUBEPINE PARA CRESOL(4-甲氧基苯甲醛)；AZURONE(7-异戊基-2H-苯并[b][1,4]二噁庚因-3(4H)-酮)；乙酸苄酯；苄醇；双环壬内酯(八氢-2H-色烯-2-酮)；龙脑晶体((1S,2S,4S)-1,7,7-三甲基二环[2.2.1]庚-2-醇)；乙酸丁酯(乙酸丁酯)；丁酰乳酸丁酯(丁酸1-丁氧基-1-氧代丙-2-基酯)；左旋香芹酮(2-甲基-5-(丙-1-烯-2-基)环己-2-烯酮)；
(1,1,2,3,3-五甲基-2,3,6,7-四氢-1H-茚-4(5H)-酮)；
(5-叔丁基-2-甲基-5-丙基-2H-呋喃)；柏木基甲基醚((1R,6S,8aS)-6-甲氧基-1,4,4,6-四甲基八氢-1H-5,8a-亚甲基甘菊环)；
(3a,6,6,9a-四甲基-2,4,5,5a,7,8,9,9b-八氢-1H-苯并[e][1]苯并呋喃)；肉桂腈(肉桂腈)；肉桂醛(肉桂醛)；乙酸肉桂酯(乙酸肉桂酯)；柠檬醛((E)-3,7-二甲基辛-2,6-二烯醛)；香茅醇(3,7-二甲基辛-6-烯-1-醇)；乙酸香茅酯(乙酸3,7-二甲基辛-6-烯-1-基酯)；香茅基氧基乙醛(2-((3,7-二甲基辛-6-烯-1-基)氧基)乙醛)；
(乙酸2-(叔戊基)环己酯)；香豆素(2H-色烯-2-酮)；女贞醛(2,4-二甲基环己-3-烯甲醛)；兔耳草醛(3-(4-异丙基苯基)-2-甲基丙醛)；环格蓬酯(2-(环己基氧基)乙酸烯丙酯)；CYCLOHEXAL(4-(4-羟基-4-甲基戊基)环己-3-烯甲醛)；对伞花烃(CYMENE PARA)(对伞花烃(p-cymene))；CYPRISATE(1,4-二甲基环己烷甲酸甲酯)；突厥烯酮((E)-1-(2,6,6-三甲基环己-1,3-二烯-1-基)丁-2-烯-1-酮)；突厥酮α((E)-1-(2,6,6-三甲基环己-2-烯-1-基)丁-2-烯-1-酮)；突厥酮δ((E)-1-(2,6,6-三甲基环己-3-烯-1-基)丁-2-烯-1-酮)；癸内酯γ(5-己基氧戊环-2-酮)；癸烯醛-4-反式((E)-癸-4-烯醛)；丙二酸二乙酯；二氢丁香酚(2-甲氧基-4-丙基苯酚)；二氢芳樟醇(3,7-二甲基辛-6-烯-3-醇)；二氢月桂烯醇(2,6-二甲基辛-7-烯-2-醇)；二甲基庚醇(DIMETOL)(2,6-二甲基庚-2-醇)；二甲基苄基甲基乙酸酯(乙酸2-甲基-1-苯基丙-2-基酯)；二甲基苄基甲基丁酸酯(丁酸2-甲基-1-苯基丙-2-基酯)；二氢月桂醇(DIMYRCETOL)(2,6-二甲基辛-7-烯-2-醇)；δ十二内酯(6-庚基四氢-2H-吡喃-2-酮)；
((E)-3-甲基-5-(2,2,3-三甲基环戊-3-烯-1-基)戊-4-烯-2-醇)；爱林太尔(3-(1-乙氧基乙氧基)-3,7-二甲基辛-1,6-二烯)；乙酰乙酸乙酯；丁酸乙酯(丁酸乙酯)；庚酸乙酯；乙基异戊基酮(6-甲基庚-3-酮)；异戊酸乙酯(3-甲基丁酸乙酯)；乙基芳樟醇((E)-3,7-二甲基壬-1,6-二烯-3-醇)；乙基麦芽酚(2-乙基-3-羟基-4H-吡喃-4-酮)；甲基-2-丁酸乙酯(2-甲基丁酸乙酯)；藏红花酸乙酯(2,6,6-三甲基环己-1,3-二烯-1-甲酸乙酯)；乙基香草醛(3-乙氧基-4-羟基苯甲醛)；桉叶素((1s,4s)-1,3,3-三甲基-2-氧杂二环[2.2.2]辛烷)；丁香酚(4-烯丙基-2-甲氧基苯酚)；合成橡苔(2,4-二羟基-3,6-二甲基苯甲酸甲酯)；葑醇((1S,2R,4R)-1,3,3-三甲基二环[2.2.1]庚-2-醇)；
(3-(4-乙基苯基)-2,2-二甲基丙醛)；
(3-(3-异丙基苯基)丁醛)；
((E)-十一碳-9-烯腈)；丙酸三环癸烯酯丙酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯)；
(2,4,6-三甲基-4-苯基-1,3-二噁烷)；铃兰吡喃(四氢-4-甲基-2-(2-甲基丙基)-2H-吡喃-4-醇)；格蓬酮(1-(3,3-二甲基环己-1-烯-1-基)戊-4-烯-1-酮)；乙酸苏合香酯(乙酸1-苯基乙酯)；异丁酸三环癸烯酯(异丁酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯)；香叶醇((E)-3,7-二甲基辛-2,6-二烯-1-醇)；二氢茉莉酮酸甲酯(3-氧代-2-戊基环戊烷乙酸甲酯)；洋茉莉醛晶体(苯并[d][1,3]间二氧杂环戊烯-5-甲醛)；乙酸顺式-3-己烯基酯(乙酸顺式-己-3-烯基酯)；苯甲酸顺式-3-己烯基酯(苯甲酸(Z)-己-3-烯-1-基酯)；水杨酸顺式-3-己烯基酯(2-羟基苯甲酸(Z)-己-3-烯-1-基酯)；丁酸己酯(丁酸己酯)；异丁酸己酯(异丁酸己酯)；紫罗兰酮β(IONONE BETA)((E)-4-(2,6,6-三甲基环己-1-烯-1-基)丁-3-烯-2-酮)；纯紫罗兰酮(IRISONE PURE)((E)-4-(2,6,6-三甲基环己-2-烯-1-基)丁-3-烯-2-酮)；ISO E
(1-(2,3,8,8-四甲基-1,2,3,4,5,6,7,8-八氢萘-2-基)乙酮)；丁酸异戊酯(丁酸异戊酯)；异环柠檬醛(ISOCYCLOCITRAL)(2,4,6-三甲基环己-3-烯甲醛)；异丁香酚((E)-2-甲氧基-4-(丙-1-烯-1-基)苯酚)；异薄荷酮DL(2-异丙基-5-甲基环己酮)；异戊酸异戊酯(3-甲基丁酸异戊酯)；异丙基-2甲基-4噻唑(2-异丙基-4-甲基噻唑)；
70((E)-3-甲基-4-(2,6,6-三甲基环己-2-烯-1-基)丁-3-烯-2-酮)；JAMACYCLENE(乙酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯)；
(2-己基环戊酮)；茉莉酯(乙酸(3-戊基噁烷-4-基)酯)；
((1-甲基-2-((1,2,2-三甲基二环[3.1.0]己-3-基)甲基)环丙基)甲醇)；
(3,4,5,6,6-五甲基庚-2-醇)；雷冰诺星((3E,6E)-2,4,4,7-四甲基壬-6,8-二烯-3-酮肟)；
((2E,6Z)-3,7-二甲基壬-2,6-二烯腈)；
((Z)-己-3-烯-1-基甲基碳酸酯)；芳樟醇(3,7-二甲基辛-1,6-二烯-3-醇)；乙酸芳樟酯(乙酸3,7-二甲基辛-1,6-二烯-3-基酯)；马赛醛(二环[2.2.2]辛-5-烯-2-甲醛)；MAHONIAL((4E)-9-羟基-5,9-二甲基-4-癸醛)；母菊酯(2-甲基戊酸乙酯)；薄荷醇(2-异丙基-5-甲基环己醇)；甲氧基苯基丁酮(4-(4-甲氧基苯基)丁-2-酮)；甲基戊基酮(庚-2-酮)；邻氨基苯甲酸甲酯(2-氨基苯甲酸甲酯)；肉桂酸甲酯(肉桂酸甲酯)；甲基庚烯酮(6-甲基庚-5-烯-2-酮)；甲基己基酮(辛-2-酮)；METHYL
(6,6-二甲氧基-2,5,5-三甲基己-2-烯)；麝香C14(1,4-二氧杂环十六烷-5,16-二酮)；月桂烯90(7-甲基-3-亚甲基辛-1,6-二烯)；新福力酯((E)-壬-2-烯酸甲酯)；乙酸壬酯；OPALAL(7-异丙基-8,8-二甲基-6,10-二氧杂螺[4.5]癸烷)；甜橙精(1-(2-萘基)-乙酮)；
50％/TEC(2-甲基-4-丙基-1,3-氧硫杂环己烷)；甲酸八氢萘酯(甲酸2,4a,5,8a-四甲基-1,2,3,4,4a,7,8,8a-八氢萘-1-基酯)；
(2-乙基-N-甲基-N-(间甲苯基)丁酰胺)；乙酸对叔丁基环己酯(乙酸4-(叔丁基)环己酯)；桃醛(5-庚基二氢呋喃-2(3H)-酮)；四氢香叶醇(3,7-二甲基辛-1-醇)；PETALIA(2-亚环己基-2-(邻甲苯基)乙腈)；苯氧基乙醛(2-苯氧基乙醛)；苯乙醇(2-苯基乙醇)；椰子醛(5-戊基二氢呋喃-2(3H)-酮)；
((E)-2-乙基-4-(2,2,3-三甲基环戊-3-烯-1-基)丁-2-烯-1-醇)；覆盆子酮(N112)(4-(4-羟苯基)丁-2-酮)；RESEDAL(2-(环己基甲基)-4,4,6-三甲基-1,3-二噁烷)；
(2,4-二甲基-4-苯基四氢呋喃)；SERENOLIDE(环丙烷甲酸2-(1-(3,3-二甲基环己基)乙氧基)-2-甲基丙基酯)；ROSSITOL(3-异丁基-1-甲基环己醇)；ROSYFOLIA(1-甲基-2-(5-甲基己-4-烯-2-基)环丙基)-甲醇)；草莓醛(STRAWBERRY PURE)(乙基甲基苯基缩水甘油酸酯)；
(环丙烷甲酸(E)-2-((3,5-二甲基己-3-烯-2-基)氧基)-2-甲基丙基酯)；四氢芳樟醇(3,7-二甲基辛-3-醇)；四氢香叶烯醇(2,6-二甲基辛-2-醇)；乙酸萜烯酯(乙酸2-(4-甲基环己-3-烯-1-基)丙-2-基酯)；萜品醇(2-(4-甲基环己-3-烯-1-基)丙-2-醇)；麝香草酚晶体(2-异丙基-5-甲基苯酚；反式-2-己烯醛(E-己-2-烯醛)；TRICYCLAL(2,4-二甲基环己-3-烯甲醛)；草青醛(3-苯基丁醛)；TRIMOFIX
(1-((2E,5Z,9Z)-2,7,8-三甲基环十二碳-2,5,9-三烯-1-基)乙酮)；甲基癸烯醇((E)-4-甲基癸-3-烯-5-醇)；香草醛(4-羟基-3-甲氧基苯甲醛)；
(2-(2,4-二甲基环己基)吡啶)；和3-(4-异丁基-2-甲基苯基)丙醛；阿道克醛(2,6,10-三甲基十一碳-9-烯醛)；海酮(CALONE)(7-甲基-2H-苯并[b][1,4]二噁庚因-3(4H)-酮)；甲基辛炔碳酸酯(壬-2-炔酸甲酯)；清风醛((3aR,4R,6S,7R,7aR)-6-甲氧基八氢-1H-4,7-亚甲基茚-1-甲醛)；TANAISONE((Z)-1-(环辛-3-烯-1-基)乙酮)；福力酯(辛-2-炔酸甲酯)。
一种或多种香味组分的总量可以占香料组合物重量的约10％至约80％，或该范围内的任何个别数量。在另一个实施方案中，所述一种或多种香味组分可以以约20％至约60％重量的量存在于香料组合物中；并且在又一个实施方案中，所述一种或多种香味组分可以以约30％至约50％重量的量存在于香料组合物中。
申请人已经发现，为了将具有高蒸气压的某些植物杀菌素(例如上文提到的单萜)经由空气清新剂递送到空气中，香料组合物必须符合某些设计规则。特别地，申请人发现某些香料组合物组分(包括溶剂和香味组分)的分布是控制挥发性植物杀菌素蒸发速率的关键参数。令人惊讶的是，申请人已经发现，使用具有约1至约3000μg/L范围的标准平衡顶空浓度
的香料组合物组分的某种分布，能够控制
浓度高于30,000μg/L的挥发性植物杀菌素的释放。
在一个实施方案中，所述香料混合物展示出标准平衡顶空浓度
分布曲线，其具有大于约95wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约10,000μg/L的
约40wt％至约85wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约1,000μg/L的
约20wt％至约75wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约300μg/L的
和约10wt％至约50wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约100μg/L的
在另一个实施方案中，所述香料混合物展示出标准平衡顶空浓度
分布曲线，其具有95wt％或97wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约10,000μg/L的
约40wt％至约85wt％或约55wt％至约80wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约1,000μg/L的
约20wt％至约75wt％或约40wt％至约60wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约300μg/L的
和约10wt％至约50wt％或约10wt％至约25wt％的选自溶剂和香味组分的香料组合物组分展示出小于或等于约100μg/L的
具有约1,000至约10,000μg/L的
的适合的香料组合物组分包括、但不限于乙酸(2S,4S)-1,7,7-三甲基二环[2.2.1]庚-2-基酯；例如乙酸龙脑酯
3,7-二甲基辛-3-醇，例如，四氢芳樟醇
2,6-二甲基辛-7-烯-2-醇，例如，二氢月桂烯醇
3,7-二甲基辛-1,6-二烯-3-醇，例如，芳樟醇
丙二酸二乙酯，例如，丙二酸二乙酯
一缩二丙二醇甲基醚，例如，DOWANOL DPM
2,6-二甲基辛-7-烯-2-醇，例如二氢月桂醇
2-(仲丁基)环己酮，例如，鲜薄荷酮
乙酸壬酯
6,6-二甲氧基-2,5,5-三甲基己-2-烯，例如圆柚甲烷
庚酸乙酯，例如，庚酸乙酯
3-氧代丁酸乙酯，例如乙酰乙酸乙酯
乙酸己酯
具有约300至约1,000μg/L的
的适合的香料组合物组分包括、但不限于2-(4-甲基环己-3-烯-1-基)丙-2-醇，例如，纯萜品醇
乙酸4-(叔丁基)环己酯，例如，乙酸对叔丁基环己酯
苯甲醇，例如，特级苄醇
乙酸2-(4-甲基环己-3-烯-1-基)丙-2-基酯，例如，乙酸萜品酯
(E)-3,7-二甲基壬-1,6-二烯-3-醇，例如，乙基芳樟醇
2,6-二甲基辛-2-醇，例如，四氢香叶烯醇
3,7-二甲基辛-6-烯-3-醇，例如，二氢芳樟醇
乙酸1-苯基乙酯，例如乙酸苏合香酯
乙酸2-(叔丁基)环己酯，例如，乙酸邻叔丁基环己酯
乙酸苄酯
一缩二丙二醇甲基醚乙酸酯，例如DOWANOL DPMA
乙酸3,7-二甲基辛-1,6-二烯-3-基酯，例如，乙酸芳樟酯
具有约100至约300μg/L的
的适合的香料组合物组分包括、但不限于丙酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯，例如，丙酸三环癸烯酯
乙酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯，例如，乙酸三环癸烯酯
2-苯基乙醇，例如，苯乙醇
二缩三丙二醇甲基醚，例如，DOWANOL TPM
戊二酸二甲酯和己二酸二甲酯混合物，例如，FLEXISOLVE，购自Flexisolve Technology(平均
)。
具有小于或等于约100μg/L的
的适合的香料组合物组分包括、但不限于一缩二丙二醇正丁基醚，例如，DOWANOL DPnB
购自Dow Chemicals；四氢-4-甲基-2-(2-甲基丙基)-2H-吡喃-4-醇，例如铃兰吡喃
一缩二丙二醇
3-苯基丙-2-烯酸甲酯，例如，肉桂酸甲酯
乙酸(3-戊基噁烷-4-基)酯，例如茉莉酯
任选的组分
根据使用方法的不同，香料组合物可任选地包括其它成分，包括但不限于增稠剂，胶凝剂，粘度/凝胶强度调节剂，溶剂，稳定剂，表面活性剂，螯合剂，氧化剂和UV阻断剂。
空气清新剂装置
术语“空气清新剂装置”包括允许挥发性物质的至少一些蒸发的任意适合的表面。可以使用具有任意适合尺寸、形状、形式或构造的空气清新剂装置。适合的空气清新剂装置可由任意适合的材料制成，包括但不限于：天然材料，人造材料，纤维材料，非纤维材料，多孔材料，无孔材料及其组合。在某些实施方案中，本文使用的空气清新剂装置在性质上是不助燃的，并且包括用于将任何类型的挥发性物质(例如液体)分配到空气中的任何装置(例如香料，除臭剂，消毒剂或杀虫剂活性剂)。在某些非限制性实施方案中，典型的空气清新剂装置利用芯、凝胶和/或多孔表面和排放区域的组合来从液体流体贮存器分配挥发性液体。
在一个实施方案中，空气清新剂装置是电液芯空气清新剂装置。电液芯空气清新剂装置或液体电芯空气清新器是指包括电或电池操作的能量源的装置或系统，其包括加热的液体芯递送系统，压电喷涂系统，电喷雾装置或Venturi装置。在另一个实施方案中，空气清新剂装置是被动空气清新器。
已知电液芯空气清新剂装置用于将挥发性液体分配到空气中，例如香料。典型的空气清新剂装置利用芯和排放区域的组合来从液体流体贮存器分配挥发性液体。理想地，空气清新剂装置应当几乎不需要或不需要维护，并且应该以允许挥发性物质以稳定和受控的速率分配到指定区域的方式进行，同时在装置的寿命期间保持其排放完整性。在此寿命期间，预期满足以下条件：(i)香料释放到空气中的速率是连续且几乎恒定的，即速率释放不随时间显著变化，(ii)香气的分布几乎保持不变，即香料的气味特征随着时间的推移基本保持不变。(iii)香料的释放方式使得香料的整体在空气清新剂的使用寿命期间蒸发，即没有遗留在装置中的香料残留物。
但是，上述条件不容易实现。空气清新剂的主要困难是在装置的整个寿命期间获得恒定的气味释放。这主要是由于香味组分具有跨越几个数量级的蒸气压，例如在25℃下0.0001-10mmHg和以上。因此，组分的差别蒸发经常发生，其中最易挥发的组分从空气清新剂装置中比不易挥发的组分更快地耗尽，导致香料特征随时间的不期望的变形。例如，当从空气清新剂装置蒸发时，具有柑橘木质特征的香味可能在几小时或几天内失去其柑橘香调，而较不新鲜和清新的木质香调可能会保留数周。预计这种效应会发生在萜烯族的多种植物杀菌素中，其特征在于高蒸气压。这是申请人必须解决的额外困难，以获得空气清新剂香料组合物，其在给定时间段(例如，30、40或60天)内提供期望的植物杀菌素释放速率。
然而，为了考虑适用于在例如房间、办公室和公寓的封闭环境中使用的空气清新剂的管理限制，本公开的植物杀菌素的蒸发速率可以限制在约0.1-100微克/立方米/小时之间的范围内。在一个实施方案中，本公开的空气清新剂香料组合物提供植物杀菌素在空气中的蒸发速率，其在约0.1至约100微克/立方米/小时的范围内；在另一个实施方案中，蒸发速率可以在约0.5至约50微克/立方米/小时之间的范围内；并且在又一个实施方案中，蒸发速率可以在约0.8至约10微克/立方米/小时之间的范围内。在多于一种植物杀菌素释放到空气中的情况下，上述蒸发速率是指香料组合物中有关植物杀菌素的总量。
在另一个实施方案中，空气清新剂装置是一种气溶胶发生器，其通过打开阀门的方式操作，按照这种方式，包含在加压容器中的空气清新剂组合物被驱动通过喷嘴并以多个液滴的形式分散到空气中。推动组合物通过喷嘴的驱动力是容器内部与空气之间的压力差。可以通过使用者的手指或机械凸轮轴的作用推动阀门开启器打开阀门。US6644507B2(其全部内容并入本文)公开了一种装置，其中阀门通过由发动机驱动的机械机构周期性地打开。发动机根据传感器信号启动，确定房间是否正在使用。或者，该装置可具有两个容器和双喷嘴系统，其也可由发动机致动，例如在US20100038452A1中公开的，并且该文献整体并入本文。
在另一个实施方案中，气溶胶发生器是压电元件，其直接施加在空气清新剂组合物的表面上。这类装置在US7622073B2中公开，其全部内容结合于此。
实施例
给出以下实施例仅用于示例的目的，而不应解释为对本发明的限制，因为在不脱离本公开的精神和范围的情况下，本发明的许多变化是可能的。实施例2是用于本公开清新剂的适合的香料组合物。实施例1是对比例。
实施例1和2
香料组合物
制备两种空气清新剂香料组合物。实施例2具有根据本公开的
分布和等于1.1％的植物杀菌素(蒎烯α)水平。将所述香料组合物报告于表1中。
表1
用于电插入式空气清新器的香料组合物(实施例1和2)(所有数值均为重量百分比(wt％))。
1DOWANOL TPM(Dow Chemicals提供)
2DOWANOL DPMA(Dow Chemicals提供)
在开始(第1天)和在62.5±2.5℃的温度下操作10和20天后称重含有18ml香料组合物(实施例1和2)的电插入式空气清新器。表2中报告了％重量损失(与香料组合物的初始重量有关)。
表2
| 10天后％重量损失 | 20天后％重量损失 | |
| 实施例1 | 30 | 55 |
| 实施例2 | 27 | 50 |
当重量损失达到约61％时，对于实施例1和2停止蒸发。特别地，对于实施例1，蒸发在第23天时停止(61.6％重量损失)，并且对于实施例2，在第26天停止蒸发(61.2％重量损失)。分析实施例以确定剩余的植物杀菌素的量并在表3中报告。
表3
从表2和表3中可以明显看出，具有HSi 0值分布在本发明范围之外的实施例1在20天后导致植物杀菌素损失，这一损失过高而不能保证在例如二或三个额外周的电插入式空气清新器操作之后释放出足够的植物杀菌素。
实施例3-6
不同类型香料组合物的制备及植物杀菌素蒸发速率的评价
根据实施例2制备四种不同的空气清新剂香料组合物(实施例3-6)，并置于电插入式空气清新器中。每个实施例含有1.1wt％的植物杀菌素。实施例3使用新鲜制备的空气清新剂，而实施例4-6使用老化的空气清新剂。在本文上下文中，“老化”是指电插入式空气清新器在开放室中使用直至达到一定的重量损失，在本情况下为61wt％和81wt％。基于空气浓度确定每个实施例的总植物杀菌素排放率，并在表4中报告。
表4
制备实施例4-6，并且使其通过在62.5+/-2.5℃的温度下加热2小时30分钟的电插入式空气清新器在23m3的室中蒸发。在最后30分钟内，以50ml/min对室内的空气进行取样，其中在该取样时间内，将植物杀菌素捕获到6mm玻璃解吸管中，用于装有TENAX TA吸附剂的Gerstel TDS 2+TDS。然后将样品在Gerstel TDS装置中热解吸并在-47℃下在Gerstel CIS装置中捕集。通过使用28℃/min的加热速率加热样品10分钟至280℃来进行热解吸。使用分流进样将冷冻捕获的分子在300℃下快速解吸到GC Rtx-5毛细管柱中，并根据标准方法进行气相色谱分析。通过应用约4.3的稀释因子将23立方米中测量的植物杀菌素浓度转换为100立方米的值。关于实施例4-6，使电插入式空气清新器蒸发直至61％的组合物已经损失(即重量损失为61％)。
这些实施例表明，应用本公开的组合物规则，植物杀菌素的总排放速率及其在空气中的浓度在期望的范围内。
本文公开的尺寸和值不应理解为严格限于所述的精确数值。相反，除非另有说明，否则每个这样的尺寸旨在表示所述值和围绕该值的功能等效范围。例如，公开为“40mm”的尺寸旨在表示“约40mm”。
虽然已经示例和描述了本发明的特定实施方案，但是对于本领域技术人员来说显而易见的是，在不脱离本发明的精神和范围的情况下，可以进行各种其它改变和变型。因此，预期在待批权利要求中涵盖在本发明范围内的所有这类改变和变型。
Claims (16)
1.香料组合物，具有在大气中控制释放的植物杀菌素，以生成类似于森林的空气环境的空气条件，该组合物包含：
a)至少0.6％重量的至少一种植物杀菌素，其中至少25％重量的所述至少一种植物杀菌素选自蒎烯α、蒎烯β及其组合；和
b)香料混合物，其包含(i)至少一种溶剂；和(ii)至少一种香味组分，
其中所述香料混合物展示出标准平衡顶空浓度
分布曲线，其中大于95wt％的香料混合物展示出小于或等于10,000μg/L的
40wt％至85wt％的香料混合物展示出小于或等于1,000μg/L的
20wt％至75wt％的香料混合物展示出小于或等于300μg/L的
和5wt％至50wt％的香料混合物展示出小于或等于100μg/L的
2.权利要求1的香料组合物，其中该香料组合物包含至少1.1％的所述至少一种植物杀菌素。
3.权利要求1的香料组合物，其中至少35％的所述至少一种植物杀菌素选自蒎烯α、蒎烯β及其组合。
4.权利要求1的香料组合物，还包含一种或多种植物杀菌素，其选自红没药烯、崁烯、石竹烯、α雪松烯、δ-3-蒈烯、双戊烯、金合欢烯、异长叶烯、d-苧烯、对伞花烃、对薄荷烯、月桂烯、罗勒烯、别罗勒烯(aloocimene)、香紫苏烯、萜品烯α、萜品烯γ、萜品油烯、岩兰烯(vetyvene)及其组合。
5.权利要求1的香料组合物，其中所述至少一种溶剂选自一缩二丙二醇甲基醚，二缩三丙二醇甲基醚；一缩二丙二醇甲基醚乙酸酯；一缩二丙二醇正丙基醚；一缩二丙二醇正丁基醚；一缩二丙二醇；丙二醇；异构烷烃溶剂h至异构烷烃溶剂z；戊二酸二甲酯和己二酸二甲酯混合物；2,2-二甲基-1,3-二氧戊环-4-甲醇；二苯甲酸乙二醇酯；3-甲基-3-甲氧基丁醇及其组合。
6.权利要求1的香料组合物，其中所述至少一种香味组分的存在量为香料组合物重量的10％至80％。
7.权利要求1的香料组合物，其中具有1,000至10,000μg/L的
的香料混合物组分选自乙酸(2S,4S)-1,7,7-三甲基二环[2.2.1]庚-2-基酯；3,7-二甲基辛-3-醇；3,7-二甲基辛-1,6-二烯-3-醇；丙二酸二乙酯；一缩二丙二醇甲基醚；2,6-二甲基辛-7-烯-2-醇；2-(仲丁基)环己酮；乙酸壬酯；6,6-二甲氧基-2,5,5-三甲基己-2-烯；庚酸乙酯；3-氧代丁酸乙酯；乙酸己酯及其组合。
8.权利要求1的香料组合物，其中具有300至1,000μg/L的
的香料混合物组分选自2-(4-甲基环己-3-烯-1-基)丙-2-醇；乙酸4-(叔丁基)环己酯；苯甲醇；乙酸2-(4-甲基环己-3-烯-1-基)丙-2-基酯；(E)-3,7-二甲基壬-1,6-二烯-3-醇；2,6-二甲基辛-2-醇；3,7-二甲基辛-6-烯-3-醇；乙酸1-苯乙酯；乙酸2-(叔丁基)环己酯；乙酸苄酯；一缩二丙二醇甲基醚乙酸酯；乙酸3,7-二甲基辛-1,6-二烯-3-基酯；及其组合。
9.权利要求1的香料组合物，其中具有100至300μg/L的
的香料混合物组分选自丙酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯；乙酸(3aR,6S,7aS)-3a,4,5,6,7,7a-六氢-1H-4,7-亚甲基茚-6-基酯；2-苯基乙醇；二缩三丙二醇甲基醚；戊二酸二甲酯和己二酸二甲酯混合物；及其组合。
10.权利要求1的香料组合物，其中具有小于或等于100μg/L的
的香料混合物组分选自一缩二丙二醇正丁基醚；四氢-4-甲基-2-(2-甲基丙基)-2H-吡喃-4-醇；一缩二丙二醇；3-苯基丙-2-烯酸甲酯；乙酸(3-戊基噁烷-4-基)酯及其组合。
11.空气清新剂装置，包括：
香料组合物，其具有在大气中控制释放的植物杀菌素，以生成类似于森林的空气环境的空气条件，该组合物包含(a)至少0.6％的至少一种植物杀菌素，其中至少25％重量的所述至少一种植物杀菌素选自蒎烯α、蒎烯β及其组合；和(b)香料混合物，其包含(i)至少一种溶剂；和(ii)至少一种香味组分；其中该香料组合物具有0.8μg/m3/小时至10μg/m3/小时的植物杀菌素蒸发速率，该蒸发速率相对恒定至少30天；并且其中所述香料混合物展示出标准平衡顶空浓度
分布曲线，其中大于95wt％的香料混合物展示出小于或等于10,000μg/L的
40wt％至85wt％的香料混合物展示出小于或等于1,000μg/L的
20wt％至75wt％的香料混合物展示出小于或等于300μg/L的
和5wt％至50wt％的香料混合物展示出小于或等于100μg/L的
12.权利要求11的空气清新剂装置，其中所述香料组合物包含至少1.1％的所述至少一种植物杀菌素。
13.权利要求11的空气清新剂装置，其中所述香料组合物包含0.07wt％至0.9wt％的蒎烯α；0.02wt％至0.2wt％的蒎烯β；0.1wt％至1.1wt％的δ-3-蒈烯；0.01wt％至0.1wt％的崁烯和0.02wt％至0.2wt％的苧烯。
14.权利要求11的空气清新剂装置，其中所述香料组合物包含0.03wt％至0.4wt％的蒎烯α；0.01wt％至0.1wt％的蒎烯β；0.03wt％至0.4wt％的对伞花烃(para-cimene)；0.01wt％至0.1wt％的崁烯；0.05wt％至0.7wt％的罗勒烯；0.03wt％至0.4wt％的萜品油烯；和0.04wt％至0.4wt％的苧烯。
15.权利要求11的空气清新剂装置，其中所述香料组合物还包含一种或多种植物杀菌素，其选自红没药烯、崁烯、石竹烯、α雪松烯、δ-3-蒈烯、双戊烯、金合欢烯、异长叶烯、d-苧烯、对伞花烃，对薄荷烯、月桂烯、罗勒烯、别罗勒烯、香紫苏烯、萜品烯α、萜品烯γ、萜品油烯、岩兰烯及其组合。
16.权利要求11的空气清新剂装置，其中所述至少一种溶剂选自一缩二丙二醇甲基醚、二缩三丙二醇甲基醚；一缩二丙二醇甲基醚乙酸酯；一缩二丙二醇正丙基醚；一缩二丙二醇正丁基醚；一缩二丙二醇；丙二醇；异构烷烃溶剂h至异构烷烃溶剂z；戊二酸二甲酯和己二酸二甲酯混合物；2,2-二甲基-1,3-二氧戊环-4-甲醇；二苯甲酸乙二醇酯；3-甲基-3-甲氧基丁醇及其组合。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1604290.5 | 2016-03-14 | ||
| GBGB1604290.5A GB201604290D0 (en) | 2016-03-14 | 2016-03-14 | Perfume compositions |
| PCT/EP2017/055783 WO2017157824A1 (en) | 2016-03-14 | 2017-03-13 | Perfume compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108778349A CN108778349A (zh) | 2018-11-09 |
| CN108778349B true CN108778349B (zh) | 2021-03-23 |
Family
ID=55952274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780017329.0A Active CN108778349B (zh) | 2016-03-14 | 2017-03-13 | 香料组合物 |
Country Status (11)
| Country | Link |
|---|---|
| US (4) | US9868923B2 (zh) |
| EP (1) | EP3429641A1 (zh) |
| JP (1) | JP6771578B2 (zh) |
| KR (1) | KR102327892B1 (zh) |
| CN (1) | CN108778349B (zh) |
| BR (1) | BR112018067322B1 (zh) |
| GB (1) | GB201604290D0 (zh) |
| MX (1) | MX2018010431A (zh) |
| RU (1) | RU2018134053A (zh) |
| WO (1) | WO2017157824A1 (zh) |
| ZA (1) | ZA201805603B (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3294347A1 (en) * | 2015-05-13 | 2018-03-21 | Givaudan SA | Improvements in or relating to organic compounds |
| KR102166256B1 (ko) * | 2019-01-25 | 2020-10-15 | 한국콜마주식회사 | 사위질빵꽃의 향취를 재현한 향료 조성물 |
| CN110327770A (zh) * | 2019-05-30 | 2019-10-15 | 天津箐润环保科技发展有限公司 | 一种除甲醛的组合物及其制法 |
| KR102472364B1 (ko) * | 2020-01-23 | 2022-11-30 | 대경대학교 산학협력단 | 천연원료를 이용한 어린이용 디퓨저 조성물 및 이의 제조방법 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6053148A (ja) * | 1984-04-28 | 1985-03-26 | 大洋香料株式会社 | ゲル状芳香剤組成物 |
| JP2001178808A (ja) * | 1999-12-27 | 2001-07-03 | Lion Corp | 芳香消臭器 |
| EP0930090B1 (en) * | 1998-01-14 | 2007-03-14 | Ecolab Inc. | Peroxyacid compound use in odor reduction |
| CN101036797A (zh) * | 2007-04-25 | 2007-09-19 | 上海应用技术学院 | 空气清新剂组合物 |
| JP2010023033A (ja) * | 2009-10-05 | 2010-02-04 | Panasonic Electric Works Co Ltd | 静電霧化装置 |
| CN101829346A (zh) * | 2010-05-06 | 2010-09-15 | 浙江爱科乐环保有限公司 | 空气净化剂 |
| WO2015181257A2 (en) * | 2014-05-27 | 2015-12-03 | Givaudan Sa | Perfume compositions |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04139104A (ja) | 1990-09-29 | 1992-05-13 | Arakawa Chem Ind Co Ltd | 殺虫剤 |
| US6800119B2 (en) * | 2003-02-21 | 2004-10-05 | Chang Gung Biotechnology Co., Ltd. | Apparatus for generating the air condition resembling the air environment in a forest |
| WO2007022589A1 (en) * | 2005-08-24 | 2007-03-01 | Neuroscent Pty Ltd | Methods of relieving stress |
| KR20080081633A (ko) | 2007-03-06 | 2008-09-10 | 주식회사 엘지생활건강 | 항균비누 조성물 |
| JP2009028704A (ja) * | 2007-07-27 | 2009-02-12 | Fumie Fujimoto | 液体吸着式空気清浄機 |
| JP2009189765A (ja) * | 2008-02-14 | 2009-08-27 | ▲徳▼島 晃 | フイトンチッド発生装置 |
| WO2009117623A2 (en) | 2008-03-19 | 2009-09-24 | Tyratech, Inc. | Pest control using natural pest control agent blends |
| JP5692844B2 (ja) * | 2010-09-24 | 2015-04-01 | 高砂香料工業株式会社 | スルフィド類用消臭剤組成物 |
| PL2629807T3 (pl) * | 2010-10-22 | 2017-08-31 | Agilex Flavor&Fragrances | Wodne kompozycje odświeżacza powietrza |
| KR101233788B1 (ko) | 2010-10-22 | 2013-02-15 | (주) 피러스 | 잣나무 구과에서 추출한 피톤치드를 함유하는 천연 항균제 및 이를 포함하는 과실의 병해 방재 소재 |
| CN102550610B (zh) | 2010-12-07 | 2014-12-10 | 菲勒斯株式会社 | 含有从红松球果中提取的植物杀菌素的天然抗菌剂及包含它的水果病害防除原料 |
| KR101177305B1 (ko) | 2011-04-29 | 2012-08-30 | 전남대학교산학협력단 | 피톤치드 저장 및 서방출용 고분자 필름 및 이의 제조방법 |
| KR20140038690A (ko) | 2012-09-21 | 2014-03-31 | 강춘식 | 편백추출액을 가지는 항균탈취팩 |
| FR3010602B1 (fr) | 2013-09-10 | 2015-10-02 | Commissariat Energie Atomique | Dispositif et procede d'acquisition compressive d'images |
| US10774288B2 (en) * | 2013-09-18 | 2020-09-15 | The Werc Shop, LLC | Terpene-based compositions, processes, methodologies for creation and products thereby |
| CN203564579U (zh) | 2013-10-29 | 2014-04-30 | 济南新活电器有限公司 | 一种利用森林因子作为净化因子的天然空气净化系统 |
| KR101439385B1 (ko) | 2014-03-04 | 2014-09-12 | 김태성 | 탈취 및 살균력이 우수한 피톤치드 성분이 함유된 천연 조성물 |
| US11642194B2 (en) * | 2015-07-07 | 2023-05-09 | Align Technology, Inc. | Multi-material aligners |
-
2016
- 2016-03-14 GB GBGB1604290.5A patent/GB201604290D0/en not_active Ceased
-
2017
- 2017-03-13 EP EP17710260.5A patent/EP3429641A1/en active Pending
- 2017-03-13 JP JP2018548382A patent/JP6771578B2/ja active Active
- 2017-03-13 KR KR1020187026511A patent/KR102327892B1/ko active IP Right Grant
- 2017-03-13 WO PCT/EP2017/055783 patent/WO2017157824A1/en active Application Filing
- 2017-03-13 US US15/457,537 patent/US9868923B2/en active Active
- 2017-03-13 RU RU2018134053A patent/RU2018134053A/ru not_active Application Discontinuation
- 2017-03-13 MX MX2018010431A patent/MX2018010431A/es active IP Right Grant
- 2017-03-13 BR BR112018067322-6A patent/BR112018067322B1/pt active IP Right Grant
- 2017-03-13 CN CN201780017329.0A patent/CN108778349B/zh active Active
- 2017-12-11 US US15/837,639 patent/US10407644B2/en active Active
-
2018
- 2018-08-22 ZA ZA2018/05603A patent/ZA201805603B/en unknown
-
2019
- 2019-07-25 US US16/522,024 patent/US10899995B2/en active Active
-
2020
- 2020-10-27 US US17/081,005 patent/US11434448B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6053148A (ja) * | 1984-04-28 | 1985-03-26 | 大洋香料株式会社 | ゲル状芳香剤組成物 |
| EP0930090B1 (en) * | 1998-01-14 | 2007-03-14 | Ecolab Inc. | Peroxyacid compound use in odor reduction |
| JP2001178808A (ja) * | 1999-12-27 | 2001-07-03 | Lion Corp | 芳香消臭器 |
| CN101036797A (zh) * | 2007-04-25 | 2007-09-19 | 上海应用技术学院 | 空气清新剂组合物 |
| JP2010023033A (ja) * | 2009-10-05 | 2010-02-04 | Panasonic Electric Works Co Ltd | 静電霧化装置 |
| CN101829346A (zh) * | 2010-05-06 | 2010-09-15 | 浙江爱科乐环保有限公司 | 空气净化剂 |
| WO2015181257A2 (en) * | 2014-05-27 | 2015-12-03 | Givaudan Sa | Perfume compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2018134053A (ru) | 2020-04-15 |
| JP6771578B2 (ja) | 2020-10-21 |
| MX2018010431A (es) | 2019-01-14 |
| KR102327892B1 (ko) | 2021-11-17 |
| BR112018067322A2 (pt) | 2019-01-02 |
| US20190345411A1 (en) | 2019-11-14 |
| KR20180125148A (ko) | 2018-11-22 |
| US20170260476A1 (en) | 2017-09-14 |
| GB201604290D0 (en) | 2016-04-27 |
| US20180100121A1 (en) | 2018-04-12 |
| US11434448B2 (en) | 2022-09-06 |
| US10899995B2 (en) | 2021-01-26 |
| BR112018067322B1 (pt) | 2022-05-24 |
| WO2017157824A1 (en) | 2017-09-21 |
| US20210040415A1 (en) | 2021-02-11 |
| ZA201805603B (en) | 2019-06-26 |
| CN108778349A (zh) | 2018-11-09 |
| US10407644B2 (en) | 2019-09-10 |
| US9868923B2 (en) | 2018-01-16 |
| RU2018134053A3 (zh) | 2020-04-15 |
| JP2019510110A (ja) | 2019-04-11 |
| EP3429641A1 (en) | 2019-01-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11434448B2 (en) | Perfume compositions | |
| KR102008588B1 (ko) | 청향 조성물 및 그를 포함하는 장치 | |
| US11639484B2 (en) | Perfume compositions | |
| US4948047A (en) | Air freshener with microporous membrane | |
| US10576179B2 (en) | Relating to organic compounds | |
| CN111432851A (zh) | 挥发性成分限制或消除对恶臭的感知的用途 | |
| CN106458959B (zh) | 具有(4aR,5R,7aS,9R)-八氢-2,2,5,8,8,9a-六甲基-4H-4a,9-亚甲基薁并 (5,6-d)-1,3-二氧杂环戊烯的混合物 | |
| JP2018529817A (ja) | 香料組成物 | |
| JP2018524037A5 (zh) | ||
| WO2017073478A1 (ja) | エアゾール型芳香剤 | |
| US20220096355A1 (en) | Fragrance compositions | |
| CN108348629B (zh) | 香料组合物和空气清新剂装置 | |
| Kaiser | Vanishing flora–lost chemistry: The scents of endangered plants around the world | |
| CN109562032B (zh) | 包含至少二氢-5-戊基-2(3h)-呋喃酮和2,4-二甲基-4-苯基四氢呋喃的混合物及其用于掩盖异味的用途 | |
| US11427783B2 (en) | Perfuming compositions | |
| JP2023070185A (ja) | 揮散器および揮散方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |