CN108708021A - A kind of efficient radiation-proof fabric - Google Patents
A kind of efficient radiation-proof fabric Download PDFInfo
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- CN108708021A CN108708021A CN201810756289.8A CN201810756289A CN108708021A CN 108708021 A CN108708021 A CN 108708021A CN 201810756289 A CN201810756289 A CN 201810756289A CN 108708021 A CN108708021 A CN 108708021A
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- efficient radiation
- radiation
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- yarn
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- 239000004744 fabric Substances 0.000 title claims abstract description 56
- 230000005855 radiation Effects 0.000 claims abstract description 52
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 26
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 21
- 239000008103 glucose Substances 0.000 claims abstract description 21
- 108010073771 Soybean Proteins Proteins 0.000 claims abstract description 20
- 235000019710 soybean protein Nutrition 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000012153 distilled water Substances 0.000 claims abstract description 19
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004814 polyurethane Substances 0.000 claims abstract description 19
- 229920002635 polyurethane Polymers 0.000 claims abstract description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004005 microsphere Substances 0.000 claims abstract description 11
- 229910052688 Gadolinium Inorganic materials 0.000 claims abstract description 10
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000009987 spinning Methods 0.000 claims abstract description 9
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 9
- 239000010935 stainless steel Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- 238000013019 agitation Methods 0.000 claims description 18
- 239000012467 final product Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 9
- 229920000609 methyl cellulose Polymers 0.000 claims description 7
- 239000001923 methylcellulose Substances 0.000 claims description 7
- 235000010981 methylcellulose Nutrition 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 238000005119 centrifugation Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 claims description 2
- 235000013904 zinc acetate Nutrition 0.000 claims description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims 1
- 102000002322 Egg Proteins Human genes 0.000 claims 1
- 108010000912 Egg Proteins Proteins 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 244000068988 Glycine max Species 0.000 claims 1
- 235000014103 egg white Nutrition 0.000 claims 1
- 210000000969 egg white Anatomy 0.000 claims 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 230000006378 damage Effects 0.000 abstract description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 32
- 230000005670 electromagnetic radiation Effects 0.000 description 19
- 230000000694 effects Effects 0.000 description 8
- 238000011056 performance test Methods 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 206010019233 Headaches Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000869 headache Toxicity 0.000 description 2
- 210000000265 leukocyte Anatomy 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- 208000000044 Amnesia Diseases 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 208000026139 Memory disease Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 208000007443 Neurasthenia Diseases 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 206010003549 asthenia Diseases 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 210000003743 erythrocyte Anatomy 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- -1 hydroxypropyl methyl Chemical group 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000006984 memory degeneration Effects 0.000 description 1
- 208000023060 memory loss Diseases 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/12—Threads containing metallic filaments or strips
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/04—Silk
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of efficient radiation-proof fabric, the fabric uses yarn with efficient radiation proof function and stainless steel fibre is blended forms:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;The liquid with efficient radiation proof function is prepared by following component with parts by weight:Nano oxidized gadolinium 4-6 parts, samarium 2-5 parts nano oxidized, 2-3 parts of ZnO microsphere, 2-5 parts of thickener, 3-5 parts of polycrystalline iron fiber, 10-20 parts of aqueous polyurethane, 5-10 parts of pentaerythrite, glucose grafting 2-4 parts of soybean protein, 100-150 parts of distilled water.The efficient radiation-proof fabric of the present invention has efficient anti-electromagnetic radiation performance, and people can be made effectively to avoid the harm of radiation.
Description
Technical field
The present invention relates to textile material fields, and in particular to a kind of efficient radiation-proof fabric.
Background technology
Being constantly progressive and develop with science and technology, shared ratio is also more and more in people's lives for electronic equipment
Height, each class of electronic devices brings greatly help and facility to people's lives, but has also brought electromagnetic wave simultaneously
Radiation, also known as electromagnetic radiation.The 40's of last century, the U.S. and the former Soviet Union just have electromedical equipment operating personnel to feel body
The report of body discomfort, they generally feel the symptoms such as insomnia and dreamful sleep, headache and dizzy and the rising of white blood cell sum.Electromagnetic radiation pair
The influence of human body is clinically mainly shown as that neurasthenia disease group, patient will appear uncomfortable in chest, palpitaition, headache, hidrosis, nothing
The symptoms such as power, memory loss.Meanwhile electromagnetic radiation can also inhibit the generation of red blood cell, cause the quantity of white blood cell to decline, cancer
The incidence of disease rises.Electromagnetic radiation is with cumulative effect to another harm of human body.Human body is in exposure to electromagnetic radiation
Afterwards, to pass through prolonged self-regeneration, if when not yet repairing herein by electromagnetic radiation, injury will be accumulated, or even danger
And arrive life.Therefore, efficient radiation-proof fabric is developed, ensures production, living safety, health is protected, is just weaved
The extensive attention of industry, it may have vast potential for future development.
Invention content
Technical problems to be solved:The object of the present invention is to provide a kind of efficient radiation-proof fabrics, have efficient anti-electric
Magnetic radiation performance can make people effectively avoid the harm of radiation.
Technical solution:A kind of efficient radiation-proof fabric, the fabric is using the yarn with efficient radiation proof function and not
Becoming rusty, steel fibre is blended to be formed:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described to have
The liquid of efficient radiation proof function is prepared by following component with parts by weight:Nano oxidized gadolinium 4-6 parts, nano oxidized samarium 2-5
Part, 2-3 parts of ZnO microsphere, 2-5 parts of thickener, 3-5 parts of polycrystalline iron fiber, 10-20 parts of aqueous polyurethane, pentaerythrite 5-10
Part, 2-4 parts of soybean protein of glucose grafting, 100-150 parts of distilled water.
Further, the ratio of the yarn and stainless steel fibre with efficient radiation proof function is 30:1.
Further, the yarn is cotton fiber, polyester fiber or silk fiber.
Further, the thickener is methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl
One or more of cellulose, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, polyacrylic acid or Sodium Polyacrylate.
Further, the preparation method of the ZnO microsphere is:
The first step:5-7 parts of pollen, 1-2 parts of zinc acetates and 15-20 parts of methanol are mixed, is placed in vacuum tank and take out very
Manage 3-4h in vacancy;
Second step:Take out, temperature be 70-75 DEG C at carry out ultrasonic wave decentralized processing 2-3h, after place 48-50h;
Third walks:In the case where rotating speed is 8000rpm, centrifugation is dry at being placed on 100 DEG C;
4th step:Take out, be placed in Muffle furnace, temperature be 650-680 DEG C at calcining 2h to obtain the final product, heating rate be 3 DEG C/
min。。
Further, the preparation method of the liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, thickener, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20-
30min;
Second step:Pentaerythrite is added to continue to stir 5-10min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1-2h to obtain the final product.
Further, the preparation method of the glucose grafting soybean protein is:
Step(1):By soybean protein isolate and glucose with mass ratio for 1:1 amount is dissolved in distilled water, uses magnetic agitation
Machine stirs
Mix 30-40 min;
Step(2):It is placed in 6 h of pre-freeze at -60 DEG C, is put into freeze drier and is dried in vacuo to obtain freeze-dried powder;
Step(3):The aluminium box for filling freeze-dried powder is placed in bottom to fill in the drier of saturation KBr solution, is put into drying box,
55 DEG C of temperature is reacted under relative humidity 79% to obtain the final product.
Advantageous effect:
1. pentaerythrite can increase hydroxy radical content, aqueous polyurethane is improved by the binding performance of radiation protection ingredient and yarn, is made
Radiation-proof effect is obtained to increase.
2. the efficient radiation-proof fabric of the present invention has good anti-electromagnetic radiation performance, the electricity of regular handset and computer
Magnetic radiation is respectively:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test
As a result it is respectively:3.4μW/cm2With 7.3 μ W/cm2。
Specific implementation mode
Embodiment 1
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and
At:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described that there is efficient radiation proof function
Liquid be prepared with parts by weight by following component:4 parts of nano oxidized gadolinium, 2 parts of nano oxidized samarium, 2 parts of ZnO microsphere, first
2 parts of base cellulose, 10 parts of aqueous polyurethane, 5 parts of pentaerythrite, 2 parts of soybean protein of glucose grafting, steams 3 parts of polycrystalline iron fiber
100 parts of distilled water;The yarn is cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation
20min;
Second step:Pentaerythrite is added to continue to stir 5min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference
Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively
For:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished
For:1.5μW/cm2With 4.1 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Embodiment 2
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and
At:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described that there is efficient radiation proof function
Liquid be prepared with parts by weight by following component:5 parts of nano oxidized gadolinium, 4 parts of nano oxidized samarium, 2.5 parts of ZnO microsphere,
3.5 parts of carboxymethyl cellulose, 4 parts of polycrystalline iron fiber, 15 parts of aqueous polyurethane, 8 parts of pentaerythrite, glucose are grafted soybean protein
3 parts, 130 parts of distilled water;The yarn is polyester fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, carboxymethyl cellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation
25min;
Second step:Pentaerythrite is added to continue to stir 8min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1.5h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference
Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively
For:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished
For:1.3μW/cm2With 3.9 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Embodiment 3
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and
At:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described that there is efficient radiation proof function
Liquid be prepared with parts by weight by following component:6 parts of nano oxidized gadolinium, 5 parts of nano oxidized samarium, 3 parts of ZnO microsphere, hydroxyl
5 parts of ethyl cellulose, 5 parts of polycrystalline iron fiber, 20 parts of aqueous polyurethane, 10 parts of pentaerythrite, glucose are grafted soybean protein 4
Part, 150 parts of distilled water;The yarn is silk fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, hydroxyethyl cellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation
30min;
Second step:Pentaerythrite is added to continue to stir 10min;
Third walks:Remaining ingredient is added, continues magnetic agitation 2h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference
Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively
For:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished
For:1.4μW/cm2With 4.1 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Comparative example 1
Difference lies in replace nano oxidized samarium with nano oxidized gadolinium with embodiment 1 for the present embodiment.Specifically:
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and
At:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described that there is efficient radiation proof function
Liquid be prepared with parts by weight by following component:It is 6 parts of nano oxidized gadolinium, 2 parts of ZnO microsphere, 2 parts of methylcellulose, more
3 parts of brilliant iron fiber, 10 parts of aqueous polyurethane, 5 parts of pentaerythrite, 2 parts of soybean protein of glucose grafting, 100 parts of distilled water;It is described
Yarn be cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation
20min;
Second step:Pentaerythrite is added to continue to stir 5min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference
Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively
For:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished
For:5.0μW/cm2With 15.5 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Comparative example 2
Difference lies in replace glucose to be grafted soybean protein with aqueous polyurethane with embodiment 1 for the present embodiment.Specifically:
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and
At:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described that there is efficient radiation proof function
Liquid be prepared with parts by weight by following component:4 parts of nano oxidized gadolinium, 2 parts of nano oxidized samarium, 2 parts of ZnO microsphere, first
2 parts of base cellulose, 3 parts of polycrystalline iron fiber, 2 parts of aqueous polyurethane, 5 parts of pentaerythrite, 100 parts of distilled water;The yarn is
Cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation
20min;
Second step:Pentaerythrite is added to continue to stir 5min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference
Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively
For:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished
For:3.4μW/cm2With 7.3 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Comparative example 3
Difference lies in without containing pentaerythrite with embodiment 1 for the present embodiment.Specifically:
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and
At:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described that there is efficient radiation proof function
Liquid be prepared with parts by weight by following component:4 parts of nano oxidized gadolinium, 2 parts of nano oxidized samarium, 2 parts of ZnO microsphere, first
2 parts of base cellulose, 10 parts of aqueous polyurethane, 5 parts of pentaerythrite, 2 parts of soybean protein of glucose grafting, steams 3 parts of polycrystalline iron fiber
100 parts of distilled water;The yarn is cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function:
The first step:Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation
20min;
Second step:Pentaerythrite is added to continue to stir 5min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference
Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively
For:116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished
For:3.2μW/cm2With 5.1 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Above-mentioned experimental result is measured using following standard:
HJ/T10.2- 1996《Radiation environment management guideline electromagnetic radiation monitoring instrument and method》.
Claims (7)
1. a kind of efficient radiation-proof fabric, it is characterised in that:The fabric is using the yarn with efficient radiation proof function and not
Becoming rusty, steel fibre is blended to be formed:The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function;It is described to have
The liquid of efficient radiation proof function is prepared by following component with parts by weight:Nano oxidized gadolinium 4-6 parts, nano oxidized samarium 2-5
Part, 2-3 parts of ZnO microsphere, 2-5 parts of thickener, 3-5 parts of polycrystalline iron fiber, 10-20 parts of aqueous polyurethane, pentaerythrite 5-10
Part, 2-4 parts of soybean protein of glucose grafting, 100-150 parts of distilled water.
2. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that:It is described that there is efficient radiation proof function
Yarn and stainless steel fibre ratio be 30:1.
3. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that:The yarn is cotton fiber, washs
Synthetic fibre fiber or silk fiber.
4. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that:The thickener is Methyl cellulose
Element, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, polyoxygenated
One or more of ethylene, polyacrylic acid or Sodium Polyacrylate.
5. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that:The preparation of the ZnO microsphere
Method is:
The first step:5-7 parts of pollen, 1-2 parts of zinc acetates and 15-20 parts of methanol are mixed, is placed in vacuum tank and take out very
Manage 3-4h in vacancy;
Second step:Take out, temperature be 70-75 DEG C at carry out ultrasonic wave decentralized processing 2-3h, after place 48-50h;
Third walks:In the case where rotating speed is 8000rpm, centrifugation is dry at being placed on 100 DEG C;
4th step:It takes out, is placed in Muffle furnace, to obtain the final product, heating rate is 3 DEG C/min to calcining 2h at being 650-680 DEG C in temperature.
6. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that:It is described that there is efficient radiation protection work(
The preparation method of the liquid of energy:
The first step:Aqueous polyurethane, thickener, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20-
30min;
Second step:Pentaerythrite is added to continue to stir 5-10min;
Third walks:Remaining ingredient is added, continues magnetic agitation 1-2h to obtain the final product.
7. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that:The glucose is grafted soybean egg
White preparation method is:
Step(1):By soybean protein isolate and glucose with mass ratio for 1:1 amount is dissolved in distilled water, uses magnetic agitation
Machine stirs
Mix 30-40 min;
Step(2):It is placed in 6 h of pre-freeze at -60 DEG C, is put into freeze drier and is dried in vacuo to obtain freeze-dried powder;
Step(3):The aluminium box for filling freeze-dried powder is placed in bottom to fill in the drier of saturation KBr solution, is put into drying box,
55 DEG C of temperature is reacted under relative humidity 79% to obtain the final product.
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