CN107364203B - A kind of radiation-proof fabric and its production method - Google Patents
A kind of radiation-proof fabric and its production method Download PDFInfo
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- CN107364203B CN107364203B CN201710722786.1A CN201710722786A CN107364203B CN 107364203 B CN107364203 B CN 107364203B CN 201710722786 A CN201710722786 A CN 201710722786A CN 107364203 B CN107364203 B CN 107364203B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
- B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/212—Electromagnetic interference shielding
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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- Ceramic Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention proposes a kind of radiation-proof fabric and its production method, radiation-proof fabric includes base cloth layer, radiation protection resin layer, auxiliary layer, protective layer and wearing layer, protective layer includes three-layer protection cloth, three-layer protection cloth passes through the immersion of nano-silver ionic water, improve the radiation-proof effect of protective layer, using plain weave connection weaving between three-layer protection cloth, left twill tissue and the connection of twill left to right weave are respectively adopted between auxiliary layer and wearing layer and protective layer, has effectively ensured the stability of radiation-proof fabric structure.Radiation-proof fabric of the present invention and its production method have the advantages that radiation-proof fabric stabilized structure, radiation-proof effect are good, water-fastness, that service life, production method has been effectively ensured is reasonable.
Description
Technical field
The present invention relates to the production of fabric structure and fabric aspect, in particular to a kind of radiation-proof fabric and its producer
Method.
Background technique
In addition to ultraviolet radiation also creates electromagenetic wave radiation in people's living environment, and with the continuous development of society,
Electronics and IT products around people are more and more, and electromagenetic wave radiation density is also increasingly stronger therewith, and electromagenetic wave radiation all can be right
The health of people has an impact, and becomes the stealthy killer of health of people, some prevent around electronics and IT products
Cactus etc. plays ineffective for preventing from radiating, and has some researchers to have developed and absorbs most electromagnetic wave
The device of radiation, but the general weight of device is big, it is not portable, can not large area use.
The fabrics such as clothes, curtain, sack product is widely applied in life by people, and these thing underpants
Clothes, sack etc. are also convenient for carrying, therefore the fabric for producing a kind of radiation protection is necessary.
Summary of the invention
It is an object of the invention to provide a kind of radiation-proof fabric and its production methods, solve above-mentioned prior art problem.
The present invention proposes that a kind of radiation-proof fabric, radiation-proof fabric include base cloth layer, radiation protection resin layer, auxiliary layer, prevent
Sheath and wearing layer, between the base cloth layer and auxiliary layer be equipped with radiation protection resin layer, the protective layer be located at auxiliary layer with
Between wearing layer, the protective layer includes three-layer protection cloth, three-layer protection cloth be respectively the first protective cloth, the second protective cloth and
The production method of third protective cloth, the protective layer is as follows:
A: production bottom, by between the first protective cloth and the second protective cloth, the second protective cloth with
Plain weave connection weaving between third protective cloth using 1/1 is at base fabric；
B: then base fabric is immersed into nano-silver ionic water and is crosslinked 20-30min, takes after the completion of crosslinking by production protective layer
First protective cloth is first placed 3-4min upwards, stirs base fabric by base fabric out, and third protective cloth is placed upwards, keeps 4-5min,
Then base fabric is immersed into nano-silver ionic water again and is crosslinked 10-15min again, base fabric, dewatered drying are taken out after the completion of crosslinking
Arrive on time protective layer.
A kind of production method of the radiation-proof fabric, comprising the following steps:
1) auxiliary layer and wearing layer are connected, using 2/1 left twill tissue by the first protective cloth on auxiliary layer and protective layer
Weaving connection, the third protective cloth on wearing layer and protective layer is weaved connect using 1/2 twill left to right tissue；
2) base cloth layer is connected, the radiation protection resin layer of 0.1-0.4mm is smeared on base cloth layer, is then tightly attached to auxiliary layer
On radiation protection resin layer, hot pressing is carried out, the temperature of hot pressing is 30-60 DEG C, is cooled and shaped after the completion of compacting and obtains radiation protection
Fabric.
Wherein, what first protective cloth, the second protective cloth and third protective cloth were all made of is that warp and weft are mutually knitted
It constitutes, the matrix of the warp and weft is the cotton yarn that number is 50.
Wherein, the base cloth layer is the fabric of dacron cotton using the matrix of warp and weft, what auxiliary layer used
The matrix for being warp and weft is numb and cotton blended yarn weaved fabric, and wearing layer is bamboo charcoal fiber using the matrix of warp and weft
With the blended yarn weaved fabric of fiber crops.
It wherein, include following component: silicone acrylic emulsion, epoxy resin, polyacrylic acid in the formula of the radiation protection resin layer
Ester, peach rouge, rosin, beeswax powder, pearl powder, deionized water, ethyl cellulose, polyvinyl alcohol, nano-aluminum hydroxide, sodium silicate,
Nano silica, talcum powder.
Further, in the formula of the radiation protection resin layer each component parts by weight are as follows: 35-50 parts of silicone acrylic emulsion,
50-60 parts of epoxy resin, 20-35 parts of polyacrylate, 10-15 parts of peach rouge, 5-10 parts of rosin, 10-15 parts of beeswax powder, pearl powder
8-12 parts, 30-45 parts of deionized water, 15-20 parts of ethyl cellulose, 18-23 parts of polyvinyl alcohol, 20-25 parts of nano-aluminum hydroxide,
8-10 parts of sodium silicate, 10-15 parts of nano silica, 8-12 parts of talcum powder.
Further, in the formula of the radiation protection resin layer each component parts by weight are as follows: silicone acrylic emulsion 40-45
Part, 53-58 parts of epoxy resin, 25-30 parts of polyacrylate, 12-14 parts of peach rouge, 6-8 parts of rosin, 12-14 parts of beeswax powder, pearl
9-11 parts of powder, 35-40 parts of deionized water, 16-18 parts of ethyl cellulose, 20-22 parts of polyvinyl alcohol, nano-aluminum hydroxide 22-23
Part, 8.5-9.5 parts of sodium silicate, 12-13 parts of nano silica, 10-11 parts of talcum powder.
The preparation process of radiation protection resin layer includes the following steps:
A, beeswax and pearl are crushed using grinding device, obtained mesh number be 60 mesh beeswax powder and mesh number be 70 mesh pearl
Powder；
B, by silicone acrylic emulsion, epoxy resin, polyacrylate, 3/4 deionized water be added in heating device and stir
Mixed processing is mixed, temperature is 60-80 DEG C when being stirred, and 15min is stirred with the revolving speed of 80-120r/min, then by polyethylene
Pure and mild sodium silicate sequentially adds in heating device, keeps temperature-resistant, stirs 10min with the revolving speed of 80-120r/min；
C, then the deionized water of the peach rouge crushed and 1/8 is added to heating container by low-temperature grinding peach rouge and rosin
In, it is kept for 60-80 DEG C, 10min is stirred with the revolving speed of 60r/min using agitating device, obtains peach gum colloid, the pine that will be crushed
Fragrant and 1/8 deionized water is added in another heating container, is kept for 70-80 DEG C, utilizes agitating device turning with 60r/min
Speed stirring 8min, obtains rosin colloid；
D, it will be mixed in the peach gum colloid and the heating device that is added sequentially in step b of rosin colloid in step c
Stirring, temperature when being stirred are 70-80 DEG C, stir 20min with the revolving speed of 60-80r/min, then be added into heating device
Beeswax powder and pearl powder in ethyl cellulose, nano-aluminum hydroxide, nano silica, talcum powder and step a, with 70-
The revolving speed of 90r/min stirs 15min, then works by heater stop, the temperature of the mixture in heating device is gradually
It reduces, is constantly stirred during cooling with the revolving speed of 50-60r/min, the temperature of object to be mixed stops after being reduced to 15 DEG C
Radiation protection resin layer can be obtained in stirring.
Wherein, the silver ion agent of 10-15 nanometer in the nano-silver ionic water including 600-750ppm, deionized water with
And acidity regulator, the silver ion agent of the 10-15 nanometer of 600-750ppm, deionized water and acidity in nano-silver ionic water
The weight fraction ratio of regulator is 1:15:0.8.
It further, include acetic acid, adipic acid, fumaric acid and sorbic acid in the acidity regulator, in acidity regulator
Acetic acid, adipic acid, fumaric acid and sorbic acid weight fraction ratio be 1.5:1.2:1:1.
The advantages of a kind of radiation-proof fabric of the present invention and its production method are as follows: the structure of radiation-proof fabric and anti-spoke
The production method for penetrating fabric is reasonable, and the sound construction of radiation-proof fabric, radiation-proof effect is good, water-fastness, the touching of radiation-proof fabric
It touches sense to be improved, the service life of radiation-proof fabric is effectively guaranteed.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of radiation-proof fabric in one embodiment of the present invention.
Specific embodiment
As shown in Figure 1, the present invention proposes a kind of radiation-proof fabric and its production method, radiation-proof fabric include base cloth layer 1,
Radiation protection resin layer 2, auxiliary layer 3, protective layer 4 and wearing layer 5 are equipped with radiation protection tree between the base cloth layer 1 and auxiliary layer 3
Rouge layer 2, the protective layer 4 are located between auxiliary layer 3 and wearing layer 5, and wherein protective layer 4 includes three-layer protection cloth, three-layer protection
Cloth is respectively the first protective cloth, the second protective cloth and third protective cloth, and the production method of the protective layer 4 is as follows:
A: production bottom will adopt between the first protective cloth and the second protective cloth, between the second protective cloth and third protective cloth
With 1/1 plain weave connection weaving at base fabric；
B: then base fabric is immersed into nano-silver ionic water and is crosslinked 20-30min, takes after the completion of crosslinking by production protective layer 4
First protective cloth is first placed 3-4min upwards, stirs base fabric by base fabric out, and third protective cloth is placed upwards, keeps 4-5min,
Then base fabric is immersed into nano-silver ionic water again and is crosslinked 10-15min again, base fabric, dewatered drying are taken out after the completion of crosslinking
Arrive on time protective layer 4.Enable in this way silver ion can the more preferable distribution more evenly on protective layer 4, be protective layer 4
Radiation protection and antibacterial
The effect of sterilization is more preferable.
A kind of production method of the radiation-proof fabric, comprising the following steps:
1) auxiliary layer 3 and wearing layer 5 are connected, is prevented auxiliary layer 3 and first on protective layer 4 using 2/1 left twill tissue
Cloth weaving connection is protected, the third protective cloth on wearing layer 5 and protective layer 4 is weaved using 1/2 twill left to right tissue and is connected；；
2) base cloth layer 1 is connected, the radiation protection resin layer 2 of 0.1-0.4mm is smeared on base cloth layer 1, it is then that auxiliary layer 3 is tight
It is attached on radiation protection resin layer 2, carries out hot pressing, the temperature of hot pressing is 30-60 DEG C, is cooled and shaped and is prevented after the completion of compacting
Radiation fabric.
A kind of production method of the radiation-proof fabric, comprising the following steps:
1) auxiliary layer 3 and wearing layer 5 are connected, is protected first on 3 protective layer 4 of auxiliary layer using 2/1 left twill tissue
Cloth weaving connection, the third protective cloth on wearing layer 5 and protective layer 4 is weaved using 1/2 twill left to right tissue and is connected, in this way can
Bonding strength between enough effective protection auxiliary layers 3 and wearing layer 5 and protective layer 4, and can effectively ensure that in protective layer 4 the
The integrality of two protective cloths, the effective effect for guaranteeing radiation protection；
2) base cloth layer 1 is connected, the radiation protection resin layer 2 of 0.1-0.4mm is smeared on base cloth layer 1, it is then that auxiliary layer 3 is tight
It is attached on radiation protection resin layer 2, carries out hot pressing, the temperature of hot pressing is 30-60 DEG C, is cooled and shaped and is prevented after the completion of compacting
Radiation fabric enables to base cloth layer 1, radiation protection resin 2 and the mutual bonding strength of auxiliary layer 3 to be guaranteed, from
And achieve the effect that the service life for guaranteeing radiation-proof fabric.
Wherein, what first protective cloth, the second protective cloth and third protective cloth were all made of is that warp and weft are mutually knitted
It constitutes, the matrix of the warp and weft is the cotton yarn that number is 50.
Wherein, the base cloth layer 1 is the fabric of dacron cotton using the matrix of warp and weft, and auxiliary layer 3 uses
Be warp and weft matrix be fiber crops and cotton blended yarn weaved fabric, the fastness of auxiliary layer 3 is effectively guaranteed, while also guaranteeing
Comfort level when entire radiation-proof fabric uses, wearing layer 5 are bamboo charcoal fiber and fiber crops using the matrix of warp and weft
Blended yarn weaved fabric, wearing layer 5 made of bamboo charcoal fiber and fiber crops can be filtered to through the light of cloth, while be also enhanced whole
The moisture absorption of a radiation-proof cloth is ventilative, restraining and sterilizing bacteria, cool in summer and warm in winter, environmentally protective characteristic.
Wherein, the silver ion agent of 10-15 nanometer in the nano-silver ionic water including 600-750ppm, deionized water with
And acidity regulator, the silver ion agent of the 10-15 nanometer of 600-750ppm, deionized water and acidity in nano-silver ionic water
The weight fraction ratio of regulator is 1:15:0.8, includes acetic acid, adipic acid, fumaric acid and sorb in the acidity regulator
Acid, acetic acid in acidity regulator, adipic acid, fumaric acid and sorbic acid weight fraction ratio be 1.5:1.2:1:1.
The preparation process of radiation protection resin layer includes the following steps:
A, beeswax and pearl are crushed using grinding device, obtained mesh number be 60 mesh beeswax powder and mesh number be 70 mesh pearl
Powder；
B, by silicone acrylic emulsion, epoxy resin, polyacrylate, 3/4 deionized water be added in heating device and stir
Mixed processing is mixed, temperature is 60-80 DEG C when being stirred, and 15min is stirred with the revolving speed of 80-120r/min, then by polyethylene
Pure and mild sodium silicate sequentially adds in heating device, keeps temperature-resistant, stirs 10min with the revolving speed of 80-120r/min；
C, then the deionized water of the peach rouge crushed and 1/8 is added to heating container by low-temperature grinding peach rouge and rosin
In, it is kept for 60-80 DEG C, 10min is stirred with the revolving speed of 60r/min using agitating device, obtains peach gum colloid, the pine that will be crushed
Fragrant and 1/8 deionized water is added in another heating container, is kept for 70-80 DEG C, utilizes agitating device turning with 60r/min
Speed stirring 8min, obtains rosin colloid；
D, it will be mixed in the peach gum colloid and the heating device that is added sequentially in step b of rosin colloid in step c
Stirring, temperature when being stirred are 70-80 DEG C, stir 20min with the revolving speed of 60-80r/min, then be added into heating device
Beeswax powder and pearl powder in ethyl cellulose, nano-aluminum hydroxide, nano silica, talcum powder and step a, with 70-
The revolving speed of 90r/min stirs 15min, then works by heater stop, the temperature of the mixture in heating device is gradually
It reduces, is constantly stirred during cooling with the revolving speed of 50-60r/min, the temperature of object to be mixed stops after being reduced to 15 DEG C
Radiation protection resin layer can be obtained in stirring.
Embodiment 1
According to each component in the formula of the radiation protection resin layer 2 of the preparation process production of above-mentioned radiation protection resin layer 2
Parts by weight are as follows: 40 parts of silicone acrylic emulsion, 58 parts of epoxy resin, 30 parts of polyacrylate, 12 parts of peach rouge, 8 parts of rosin, beeswax powder
12 parts, 11 parts of pearl powder, 40 parts of deionized water, 18 parts of ethyl cellulose, 20 parts of polyvinyl alcohol, 22 parts of nano-aluminum hydroxide, bubble
9.5 parts of choline, 13 parts of nano silica, 10 parts of talcum powder.
Embodiment 2
According to each component in the formula of the radiation protection resin layer 2 of the preparation process production of above-mentioned radiation protection resin layer 2
Parts by weight are as follows: 45 parts of silicone acrylic emulsion, 53 parts of epoxy resin, 25 parts of polyacrylate, 14 parts of peach rouge, 6 parts of rosin, beeswax powder
14 parts, 9 parts of pearl powder, 35 parts of deionized water, 16 parts of ethyl cellulose, 22 parts of polyvinyl alcohol, 23 parts of nano-aluminum hydroxide, alveolation
8.5 parts of alkali, 12 parts of nano silica, 11 parts of talcum powder.
Embodiment 3
According to each component in the formula of the radiation protection resin layer 2 of the preparation process production of above-mentioned radiation protection resin layer 2
Parts by weight are as follows: 42 parts of silicone acrylic emulsion, 55 parts of epoxy resin, 28 parts of polyacrylate, 13 parts of peach rouge, 7 parts of rosin, beeswax powder
13 parts, 10 parts of pearl powder, 37 parts of deionized water, 17.5 parts of ethyl cellulose, 21 parts of polyvinyl alcohol, nano-aluminum hydroxide 22.5
Part, 9 parts of sodium silicate, 12.6 parts of nano silica, 10.4 parts of talcum powder.
The fastness to washing for the radiation protection resin layer 2 produced according to above embodiments 1- embodiment 3, bonding strength, acid and alkali-resistance are rotten
Erosion, ageing-resistant and radiation-proof effect are all fine, especially produce according to the formula of radiation protection resin layer 2 described in embodiment 3
The fastness to washing of radiation protection resin layer 2, bonding strength, acid-alkali-corrosive-resisting, ageing-resistant and radiation-proof effect resultant effect most
It is good.
The above is only preferred embodiment of the invention, it is noted that those skilled in the art, not
Under the premise of being detached from the invention design, some similar deformation and improvement can be made, these also should be regarded as the present invention
Protection scope within.
Claims (8)
1. a kind of radiation-proof fabric, which is characterized in that radiation-proof fabric includes base cloth layer (1), radiation protection resin layer (2), auxiliary
Layer (3), protective layer (4) and wearing layer (5) are equipped with radiation protection resin layer (2) between the base cloth layer (1) and auxiliary layer (3),
The protective layer (4) is located between auxiliary layer (3) and wearing layer (5), and the protective layer (4) includes three-layer protection cloth, and three layers anti-
Protecting cloth is respectively the first protective cloth, the second protective cloth and third protective cloth, and the production method of the protective layer (4) is as follows:
A: production bottom, by between the first protective cloth and the second protective cloth, between the second protective cloth and third protective cloth use 1/1
Plain weave connection weaving at base fabric；
B: then base fabric is immersed into nano-silver ionic water and is crosslinked 20-30min by production protective layer (4), take out after the completion of crosslinking
First protective cloth is first placed 3-4min upwards, stirs base fabric by base fabric, and third protective cloth is placed upwards, keeps 4-5min, so
Base fabric is immersed into nano-silver ionic water again afterwards and is crosslinked 10-15min again, base fabric is taken out after the completion of crosslinking, dewatered drying obtains
To protective layer (4).
2. a kind of production method of radiation-proof fabric described in claim 1, which comprises the following steps:
1) connection auxiliary layer (3) and wearing layer (5), using 2/1 left twill tissue by auxiliary layer (3) and the on protective layer (4)
The weaving connection of one protective cloth, the third protective cloth on wearing layer (5) and protective layer (4) is weaved connect using 1/2 twill left to right tissue
It connects；
2) base cloth layer (1) is connected, the radiation protection resin layer (2) of 0.1-0.4mm is smeared on base cloth layer (1), then by auxiliary layer
(3) it is tightly attached on radiation protection resin layer (2), carries out hot pressing, the temperature of hot pressing is 30-60 DEG C, is cooled to after the completion of compacting
Type obtains radiation-proof fabric.
3. a kind of radiation-proof fabric according to claim 1, which is characterized in that first protective cloth, the second protective cloth
And what third protective cloth was all made of is that warp and weft are mutually configured to, the matrix of the warp and weft is that number is 50
Cotton yarn.
4. a kind of radiation-proof fabric according to claim 1, which is characterized in that the base cloth layer (1) is using warp
Matrix with weft is the fabric of dacron cotton, and auxiliary layer (3) is numb and cotton blended using the matrix of warp and weft
Fabric, wearing layer (5) are bamboo charcoal fiber and numb blended yarn weaved fabric using the matrix of warp and weft.
5. a kind of radiation-proof fabric according to claim 1, which is characterized in that the formula of the radiation protection resin layer (2)
In include following component: silicone acrylic emulsion, epoxy resin, polyacrylate, peach rouge, rosin, beeswax powder, pearl powder, deionized water,
Ethyl cellulose, polyvinyl alcohol, nano-aluminum hydroxide, sodium silicate, nano silica, talcum powder.
6. a kind of radiation-proof fabric according to claim 5, which is characterized in that the formula of the radiation protection resin layer (2)
In each component parts by weight are as follows: 35-50 parts of silicone acrylic emulsion, 50-60 parts of epoxy resin, 20-35 parts of polyacrylate, peach rouge
10-15 parts, 5-10 parts of rosin, 10-15 parts of beeswax powder, 8-12 parts of pearl powder, 30-45 parts of deionized water, ethyl cellulose 15-20
Part, 18-23 parts of polyvinyl alcohol, 20-25 parts of nano-aluminum hydroxide, 8-10 parts of sodium silicate, 10-15 parts of nano silica, talcum
8-12 parts of powder.
7. a kind of radiation-proof fabric according to claim 1, which is characterized in that include 600- in the nano-silver ionic water
Silver ion agent, deionized water and the acidity regulator of the 10-15 nanometer of 750ppm, 600-750ppm in nano-silver ionic water
The weight fraction ratio of 10-15 nanometers of silver ion agent, deionized water and acidity regulator is 1:15:0.8.
8. a kind of radiation-proof fabric according to claim 7, which is characterized in that in the acidity regulator include acetic acid,
Adipic acid, fumaric acid and sorbic acid, acetic acid in acidity regulator, adipic acid, fumaric acid and sorbic acid weight fraction ratio
For 1.5:1.2:1:1.
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| CN112831149B (en) * | 2021-01-14 | 2023-08-15 | 杭州纪川科技有限公司 | Composite fabric and production method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2004086413A1 (en) * | 2003-03-24 | 2004-10-07 | Edil Natura S.A. S. Di N. Limardo & C. | Anti-radiation protection mat and relative manufacturing method |
| CN101078180A (en) * | 2006-05-23 | 2007-11-28 | 青岛红领集团有限公司 | Antibiotic radiation proof treatment method for fabric and clothes |
| CN106956476A (en) * | 2017-03-30 | 2017-07-18 | 临沂中瑞防辐射科技有限公司 | A kind of radiation-proof fabric |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004086413A1 (en) * | 2003-03-24 | 2004-10-07 | Edil Natura S.A. S. Di N. Limardo & C. | Anti-radiation protection mat and relative manufacturing method |
| CN101078180A (en) * | 2006-05-23 | 2007-11-28 | 青岛红领集团有限公司 | Antibiotic radiation proof treatment method for fabric and clothes |
| CN106956476A (en) * | 2017-03-30 | 2017-07-18 | 临沂中瑞防辐射科技有限公司 | A kind of radiation-proof fabric |
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