CN106579610A - Radiation-proof bamboo filament fiber and nylon 66 blending modification spinning fabric and manufacturing method thereof - Google Patents

Radiation-proof bamboo filament fiber and nylon 66 blending modification spinning fabric and manufacturing method thereof Download PDF

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Publication number
CN106579610A
CN106579610A CN201611112482.5A CN201611112482A CN106579610A CN 106579610 A CN106579610 A CN 106579610A CN 201611112482 A CN201611112482 A CN 201611112482A CN 106579610 A CN106579610 A CN 106579610A
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China
Prior art keywords
parts
fabric
bamboo
bamboo filament
pamam
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611112482.5A
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Chinese (zh)
Inventor
夏栋梁
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Huaining County Leopard Garments Co Ltd
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Huaining County Leopard Garments Co Ltd
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Publication date
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Priority to CN201611112482.5A priority Critical patent/CN106579610A/en
Publication of CN106579610A publication Critical patent/CN106579610A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00Details of garments or of their making
    • A41D27/02Linings
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides

Abstract

The invention discloses a radiation-proof bamboo filament fiber and nylon 66 blending modification spinning fabric and a manufacturing method thereof. The fabric is characterized by being made of raw materials in the following parts by weight: 2-3 parts of silk fibers, 4-9 parts of bamboo filament fiber powders, 1-2 parts of polytetrafluoroethylene micro powders, 30-40 parts of nylon 66, 2-5 parts of polyethylene glycol-400, 10-20 parts sodium periodate, 1-2 parts of propylene glycol, 15-25 PAMAM, 4-8 parts of Anion (R) series anion additive, 2-4 parts of methylcellulose, 1-2 parts of sodium dodecyl sulfate, 3-6 parts of bamboo charcoal powders, and 20-30 parts of distilled water. The fabric is soft and fluffy, and bamboo filament fiber makes the fabric have good moisture absorption and desorption property and gas permeability, good natural antibacterial function, bacteriostasis function, odor-resistant function, and uviofast function. Combined with the added silk fibers and propylene glycol, the fabric has performance of radiation protection and flexibility.

Description

A kind of bamboo filament fibre of radioprotective, nylon66 fiber blending and modifying spinning fabric and its preparation Method
Technical field
The present invention relates to garment material technical field, and in particular to a kind of bamboo filament fibre of radioprotective, nylon66 fiber blending change Property spinning fabric and preparation method thereof.
Background technology
With the arrival that the step of social development is increasingly faster and electronization is social, the health of people is virtually being received Very big impact, ubiquitous electromagenetic wave radiation, is harmful in furniture and other the articles for daily uses in huge life stress, life Release of chemical drugss etc., all jeopardizes the health of people.So, increasing people pursues a kind of healthy lifestyles, And this pursuit most directly performance be exactly people in the selection of clothes or home textile product, can naturally eliminate or weaken these The product of the injury of Factors on Human body will become the first-selection of people.And bamboo filament fibre has not available for many other fibers Advantage, such as excellent absorb-discharge humid, breathability, very strong natural antibacterial, antibacterial, deodorant and anti-ultraviolet function, are a kind of Good environment protection type functional fiber.Using the premium properties of bamboo filament fibre, the bamboo filament fibre fabric of research and development both had comfortably, Warming, good luster performance, but with wear-resistant, antibacterial, ultra-violet radiation resisting, moisture absorption it is ventilative, it is nice and cool be dried the characteristics of, belong to High-grade fabric, structural adjustment, product up-gradation to textile industry and expands export, improves competitiveness in the international market and all have Highly important meaning.
He Xiao exists《The ultra-fine bamboo charcoal micropowder blending and modifying spinning researchs of PA66/》Middle utilization PA66 and bamboo charcoal micropowder are by blending Spinning is prepared for a kind of fabric, but when it is applied to garment material, it is bad also to there is breathability, deodorization and sterilization, no Energy anion releasing reaches the shortcoming of health-care effect.
The content of the invention
Based on more than thinking, the present invention is intended to provide a kind of deodorization and sterilization, anti-ultraviolet, can be with anion releasing Garment material and preparation method thereof, to solve the problems, such as the above.
The technical problem to be solved is realized using following technical scheme:
A kind of bamboo filament fibre of radioprotective, nylon66 fiber blending and modifying spinning fabric, it is characterised in that be by the original of following weight portion Material is made:
Silk fiber 2-3, bamboo filament fibre powder 4-9, ptfe micropowder 1-2, nylon66 fiber 30-40, PEG-4000 2- 5, sodium periodate solution 10-20, Propylene Glycol 1-2, PAMAM 15-25, Anion(R)Serial anionic additive 4-8, methyl is fine Dimension element 2-4, dodecyl sodium sulfate 1-2, bamboo charcoal powder 3-6, distilled water 20-30;
The PAMAM is polyamidoamine dendrimer;The concentration of sodium periodate solution is 0.1-10g/L;PAMAM is molten Liquid concentration is 1-10g/L.
Bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric of a kind of described radioprotective and preparation method thereof, its feature It is to be made up of following steps:
A. bamboo filament fibre powder is placed in into lucifuge oxidation reaction 3-5h in sodium periodate solution, reaction temperature is 40-110 DEG C, mistake Filter, washing, drying, obtain aoxidizing bamboo fibre;Oxidation bamboo fibre is immersed in into 3-6h in PAMAM solution, reaction temperature 25-85 DEG C, filtering drying simultaneously grinds, and obtains PAMAM grafting bamboo filament fibre powder;
B. by Anion(R)Serial anionic additive, methylcellulose, Propylene Glycol, dodecyl sodium sulfate are added to distillation In water, mixing and stirring is made after negative solution, add step a gained PAMAM grafting bamboo filament fibre powder, silk fiber, Bamboo charcoal powder, ultrasonic disperse uniformly and soaks 30-50min, filters, and 25 DEG C are dried 10-15h, obtain mixture, standby;
C. step b gained mixture, ptfe micropowder, nylon66 fiber, Polyethylene Glycol are put in mixing screw extruder Melting, then obtain after fabric Jing after spinning, weaving, fabric is soaked in step b gained negative solution again, and ultrasound shake After swinging 10-20min, baker is put into, bakees 2-5min, taken out.
Bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric of a kind of described radioprotective and preparation method thereof, its feature It is that melt temperature is 150-200 DEG C in step c, spinning temperature is 250-300 DEG C.
The invention has the beneficial effects as follows:Jing after sodium periodate oxidation, the oh group on its surface is oxidized to bamboo filament fibre Aldehyde radical even carboxyl, crosslinks reaction, so as to PAMAM is grafted on bamboo filament fibre, not only with the amino on PAMAM surfaces Can make bamboo filament fibre more soft fluffy, and enhance the fusion of bamboo filament fibre and nylon substrates, while bamboo filament fibre tool There are excellent absorb-discharge humid, a breathability, very strong natural antibacterial, antibacterial, deodorant and anti-ultraviolet function;The bamboo silk being grafted Fiber and bamboo charcoal powder have good absorbability, can constantly discharge in use after absorption anionic additive bear from Son, when being applied to clothing liner, with calmness, analgesia, antitussive, antipruritic, increasing appetite, the effect of blood pressure lowering, and after weaving Soak again, consolidated this effect;Coordinate silk fiber, Propylene Glycol of addition etc., give fabric radioprotective, flexible performance.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.
Embodiment
A kind of bamboo filament fibre of radioprotective, nylon66 fiber blending and modifying spinning fabric, it is characterised in that be by following weight portion Raw material make:
Silk fiber 3, bamboo filament fibre powder 9, ptfe micropowder 2, nylon66 fiber 40, PEG-4000 5, sodium metaperiodate is molten Liquid 20, Propylene Glycol 2, PAMAM 25, Anion(R)Serial anionic additive 8, methylcellulose 4, dodecyl sodium sulfate 2, Bamboo charcoal powder 6, distilled water 30;
The PAMAM is polyamidoamine dendrimer;The concentration of sodium periodate solution is 0.1-10g/L;PAMAM is molten Liquid concentration is 1-10g/L.
Bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric of a kind of described radioprotective and preparation method thereof, its feature It is to be made up of following steps:
A. bamboo filament fibre powder is placed in into lucifuge oxidation reaction 3-5h in sodium periodate solution, reaction temperature is 40-110 DEG C, mistake Filter, washing, drying, obtain aoxidizing bamboo fibre;Oxidation bamboo fibre is immersed in into 3-6h in PAMAM solution, reaction temperature 25-85 DEG C, filtering drying simultaneously grinds, and obtains PAMAM grafting bamboo filament fibre powder;
B. by Anion(R)Serial anionic additive, methylcellulose, Propylene Glycol, dodecyl sodium sulfate are added to distillation In water, mixing and stirring is made after negative solution, add step a gained PAMAM grafting bamboo filament fibre powder, silk fiber, Bamboo charcoal powder, ultrasonic disperse uniformly and soaks 30-50min, filters, and 25 DEG C are dried 10-15h, obtain mixture, standby;
C. step b gained mixture, ptfe micropowder, nylon66 fiber, Polyethylene Glycol are put in mixing screw extruder Melting, then obtain after fabric Jing after spinning, weaving, fabric is soaked in step b gained negative solution again, and ultrasound shake After swinging 10-20min, baker is put into, bakees 2-5min, taken out.
Bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric of a kind of described radioprotective and preparation method thereof, its feature It is that melt temperature is 150-200 DEG C in step c, spinning temperature is 250-300 DEG C.
The present invention technical parameter be:Ultraviolet tranmittance >=92%;Elongation at break >=145%.

Claims (3)

1. a kind of bamboo filament fibre of radioprotective, nylon66 fiber blending and modifying spinning fabric, it is characterised in that be by following weight portion Raw material is made:
Silk fiber 2-3, bamboo filament fibre powder 4-9, ptfe micropowder 1-2, nylon66 fiber 30-40, PEG-4000 2- 5, sodium periodate solution 10-20, Propylene Glycol 1-2, PAMAM 15-25, Anion(R)Serial anionic additive 4-8, methyl is fine Dimension element 2-4, dodecyl sodium sulfate 1-2, bamboo charcoal powder 3-6, distilled water 20-30;
The PAMAM is polyamidoamine dendrimer;The concentration of sodium periodate solution is 0.1-10g/L;PAMAM is molten Liquid concentration is 1-10g/L.
2. a kind of bamboo filament fibre of radioprotective according to claim 1, nylon66 fiber blending and modifying spinning fabric and its preparation Method, it is characterised in that be made up of following steps:
A. bamboo filament fibre powder is placed in into lucifuge oxidation reaction 3-5h in sodium periodate solution, reaction temperature is 40-110 DEG C, mistake Filter, washing, drying, obtain aoxidizing bamboo fibre;Oxidation bamboo fibre is immersed in into 3-6h in PAMAM solution, reaction temperature 25-85 DEG C, filtering drying simultaneously grinds, and obtains PAMAM grafting bamboo filament fibre powder;
B. by Anion(R)Serial anionic additive, methylcellulose, Propylene Glycol, dodecyl sodium sulfate are added to distillation In water, mixing and stirring is made after negative solution, add step a gained PAMAM grafting bamboo filament fibre powder, silk fiber, Bamboo charcoal powder, ultrasonic disperse uniformly and soaks 30-50min, filters, and 25 DEG C are dried 10-15h, obtain mixture, standby;
C. step b gained mixture, ptfe micropowder, nylon66 fiber, Polyethylene Glycol are put in mixing screw extruder Melting, then obtain after fabric Jing after spinning, weaving, fabric is soaked in step b gained negative solution again, and ultrasound shake After swinging 10-20min, baker is put into, bakees 2-5min, taken out.
3. a kind of bamboo filament fibre of radioprotective according to claim 2, nylon66 fiber blending and modifying spinning fabric and its preparation Method, it is characterised in that melt temperature is 150-200 DEG C in step c, spinning temperature is 250-300 DEG C.
CN201611112482.5A 2016-12-07 2016-12-07 Radiation-proof bamboo filament fiber and nylon 66 blending modification spinning fabric and manufacturing method thereof Pending CN106579610A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611112482.5A CN106579610A (en) 2016-12-07 2016-12-07 Radiation-proof bamboo filament fiber and nylon 66 blending modification spinning fabric and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611112482.5A CN106579610A (en) 2016-12-07 2016-12-07 Radiation-proof bamboo filament fiber and nylon 66 blending modification spinning fabric and manufacturing method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108708021A (en) * 2018-07-11 2018-10-26 苏州市天翱特种织绣有限公司 A kind of efficient radiation-proof fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104060342A (en) * 2013-03-21 2014-09-24 李柏峰 Fabric with mosquito repelling function and manufacturing method thereof
CN104389161A (en) * 2014-11-04 2015-03-04 苏州经贸职业技术学院 Preparation method of anti-crease real silk composite fabric
CN106120150A (en) * 2016-08-24 2016-11-16 安徽省太湖泽泓塑业有限公司 A kind of can continuously releasing negative oxygen ion containing bamboo filament fibre non-woven fabrics and preparation method thereof
CN106149205A (en) * 2016-08-19 2016-11-23 马鞍山湖滨无纺布科技有限公司 A kind of glossiness good, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104060342A (en) * 2013-03-21 2014-09-24 李柏峰 Fabric with mosquito repelling function and manufacturing method thereof
CN104389161A (en) * 2014-11-04 2015-03-04 苏州经贸职业技术学院 Preparation method of anti-crease real silk composite fabric
CN106149205A (en) * 2016-08-19 2016-11-23 马鞍山湖滨无纺布科技有限公司 A kind of glossiness good, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously
CN106120150A (en) * 2016-08-24 2016-11-16 安徽省太湖泽泓塑业有限公司 A kind of can continuously releasing negative oxygen ion containing bamboo filament fibre non-woven fabrics and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108708021A (en) * 2018-07-11 2018-10-26 苏州市天翱特种织绣有限公司 A kind of efficient radiation-proof fabric

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Application publication date: 20170426

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