CN106544751A - A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof - Google Patents

A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof Download PDF

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Publication number
CN106544751A
CN106544751A CN201611112503.3A CN201611112503A CN106544751A CN 106544751 A CN106544751 A CN 106544751A CN 201611112503 A CN201611112503 A CN 201611112503A CN 106544751 A CN106544751 A CN 106544751A
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CN
China
Prior art keywords
bamboo
filament fibre
bamboo filament
nylon66 fiber
deodorization
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611112503.3A
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Chinese (zh)
Inventor
夏栋梁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huaining County Leopard Garments Co Ltd
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Huaining County Leopard Garments Co Ltd
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Publication date
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Priority to CN201611112503.3A priority Critical patent/CN106544751A/en
Publication of CN106544751A publication Critical patent/CN106544751A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59Polyamides; Polyimides
    • D06M15/592Polyamides; Polyimides made from polymerised unsaturated fatty acids and polyamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Abstract

The invention discloses a kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof, it is characterised in that be made up of the raw material of following weight portion:Bamboo filament fibre powder 5 10, nylon66 fiber 30 40, PEG400 25, sodium periodate solution 10 20, PAMAM 15 25, Anion(R)Serial anionic additive 48, methylcellulose 24, dodecyl sodium sulfate 12, bamboo charcoal powder 36, distilled water 20 30;Fabric soft fluffy of the present invention, while bamboo filament fibre gives the excellent absorb-discharge humid of fabric, gas permeability, very strong natural antibacterial, antibacterial, deodorization and anti-ultraviolet function.

Description

A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and its preparation Method
Technical field
The present invention relates to garment material technical field, and in particular to a kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending change Property spinning fabric and preparation method thereof.
Background technology
As the step of social development is increasingly faster and the arrival of electronization society, the health of people is virtually being received Very big impact, in huge life stress, life, ubiquitous electromagenetic wave radiation, is harmful in furniture and other daily necessitiess Release of chemicals etc., all jeopardizes the health of people.So, increasing people pursues a kind of healthy lifestyles, And this pursuit most directly performance be exactly people in the selection of clothes or home textile product, can eliminate naturally or weaken these The product of the injury of Factors on Human body will become the first-selection of people.And bamboo filament fibre has not available for many other fibers Advantage, such as excellent absorb-discharge humid, gas permeability, very strong natural antibacterial, antibacterial, deodorization and anti-ultraviolet function, are a kind of Good environment protection type functional fiber.Using the premium properties of bamboo filament fibre, the bamboo filament fibre fabric of research and development both had comfortably, The performance of warming, good luster, has wear-resistant, antibacterial, ultra-violet radiation resisting, moisture absorption ventilative, nice and cool the characteristics of be dried again, belongs to High-grade fabric, structural adjustment, product up-gradation to textile industry and expands export, improves competitiveness in the international market and all have Highly important meaning.
He Xiao exists《The ultra-fine bamboo charcoal micropowder blending and modifying spinning researchs of PA66/》Middle utilization PA66 and bamboo charcoal micropowder are by blending Spinning is prepared for a kind of fabric, but when which is applied to garment material, it is bad also to there is gas permeability, deodorization and sterilization, no Energy anion releasing reaches the shortcoming of health-care effect.
The content of the invention
Based on more than thinking, the present invention is intended to provide a kind of deodorization and sterilization, antiultraviolet, can be with anion releasing Garment material and preparation method thereof, to solve the problems, such as the above.
The technical problem to be solved is realized using following technical scheme:
A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric, it is characterised in that be by the original of following weight portion Material is made:
Bamboo filament fibre powder 5-10, nylon66 fiber 30-40, PEG-4000 2-5, sodium periodate solution 10-20, PAMAM 15- 25, Anion(R)Serial anionic additive 4-8, methylcellulose 2-4, dodecyl sodium sulfate 1-2, bamboo charcoal powder 3-6, distillation Water 20-30;
The PAMAM is polyamidoamine dendrimer;The concentration of sodium periodate solution is 0.1-10g/L;PAMAM is molten Liquid concentration is 1-10g/L.
A kind of described deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof, its feature It is to be made up of following steps:
A. bamboo filament fibre powder is placed in into lucifuge oxidation reaction 3-5h in sodium periodate solution, reaction temperature is 40-110 DEG C, mistake Filter, washing, drying, obtain aoxidizing bamboo fibre;Oxidation bamboo fibre is immersed in into 3-6h in PAMAM solution, reaction temperature 25-85 DEG C, filtering drying simultaneously grinds, and obtains PAMAM grafting bamboo filament fibre powder;
B. by Anion(R)Serial anionic additive, methylcellulose, dodecyl sodium sulfate are added in distilled water, are mixed Conjunction stirs after making negative solution, adds PAMAM grafting bamboo filament fibre powder, bamboo charcoal powder, ultrasonic disperse obtained by step a It is uniform and soak 30-50min, filter, 25 DEG C are dried 10-15h, obtain mixture, standby;
C. mixture, nylon66 fiber, polyethylene glycol obtained by step b are put in mixing screw extruder and melts, then Jing spinning, After fabric is obtained after weaving, again fabric is soaked in negative solution obtained by step b, and after ultrasonic vibration 10-20min, Baker is put into, 2-5min is bakeed, is taken out.
A kind of described deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof, its feature It is that melt temperature is 150-200 DEG C in step c, spinning temperature is 250-300 DEG C.
The invention has the beneficial effects as follows:Jing after sodium periodate oxidation, the oh group on its surface is oxidized to bamboo filament fibre Aldehyde radical even carboxyl, crosslinks reaction with the amino on PAMAM surfaces, so as to PAMAM is grafted on bamboo filament fibre, not only Can make bamboo filament fibre more soft fluffy, and enhance the fusion of bamboo filament fibre and nylon substrates, while bamboo filament fibre tool There are excellent absorb-discharge humid, a gas permeability, very strong natural antibacterial, antibacterial, deodorization and anti-ultraviolet function;The bamboo silk being grafted Fiber and bamboo charcoal powder have good adsorption capacity, constantly can discharge in use after absorption anionic additive bear from Son, when being applied to clothes liner, with calmness, analgesia, antibechic, antipruritic, increasing appetite, hypotensive effect, and after weaving Soak again, consolidated this effect.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.
Embodiment
A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric, it is characterised in that be by following weight portion Raw material make:
Bamboo filament fibre powder 10, nylon66 fiber 40, PEG-4000 5, sodium periodate solution 20, PAMAM1 25, Anion(R)System Row anionic additive 8, methylcellulose 4, dodecyl sodium sulfate 2, bamboo charcoal powder 6, distilled water 30;
The PAMAM is polyamidoamine dendrimer;The concentration of sodium periodate solution is 0.1-10g/L;PAMAM is molten Liquid concentration is 1-10g/L.
A kind of described deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof, its feature It is to be made up of following steps:
A. bamboo filament fibre powder is placed in into lucifuge oxidation reaction 3-5h in sodium periodate solution, reaction temperature is 40-110 DEG C, mistake Filter, washing, drying, obtain aoxidizing bamboo fibre;Oxidation bamboo fibre is immersed in into 3-6h in PAMAM solution, reaction temperature 25-85 DEG C, filtering drying simultaneously grinds, and obtains PAMAM grafting bamboo filament fibre powder;
B. by Anion(R)Serial anionic additive, methylcellulose, dodecyl sodium sulfate are added in distilled water, are mixed Conjunction stirs after making negative solution, adds PAMAM grafting bamboo filament fibre powder, bamboo charcoal powder, ultrasonic disperse obtained by step a It is uniform and soak 30-50min, filter, 25 DEG C are dried 10-15h, obtain mixture, standby;
C. mixture, nylon66 fiber, polyethylene glycol obtained by step b are put in mixing screw extruder and melts, then Jing spinning, After fabric is obtained after weaving, again fabric is soaked in negative solution obtained by step b, and after ultrasonic vibration 10-20min, Baker is put into, 2-5min is bakeed, is taken out.
A kind of described deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof, its feature It is that melt temperature is 150-200 DEG C in step c, spinning temperature is 250-300 DEG C.
The present invention technical parameter be:Ultraviolet tranmittance >=92%;Elongation at break >=145%.

Claims (3)

1. a kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric, it is characterised in that be by following weight portion Raw material is made:
Bamboo filament fibre powder 5-10, nylon66 fiber 30-40, PEG-4000 2-5, sodium periodate solution 10-20, PAMAM 15- 25, Anion(R)Serial anionic additive 4-8, methylcellulose 2-4, dodecyl sodium sulfate 1-2, bamboo charcoal powder 3-6, distillation Water 20-30;
The PAMAM is polyamidoamine dendrimer;The concentration of sodium periodate solution is 0.1-10g/L;PAMAM is molten Liquid concentration is 1-10g/L.
2. a kind of deodorization and sterilization bamboo filament fibre according to claim 1, nylon66 fiber blending and modifying spinning fabric and its preparation Method, it is characterised in that be made up of following steps:
A. bamboo filament fibre powder is placed in into lucifuge oxidation reaction 3-5h in sodium periodate solution, reaction temperature is 40-110 DEG C, mistake Filter, washing, drying, obtain aoxidizing bamboo fibre;Oxidation bamboo fibre is immersed in into 3-6h in PAMAM solution, reaction temperature 25-85 DEG C, filtering drying simultaneously grinds, and obtains PAMAM grafting bamboo filament fibre powder;
B. by Anion(R)Serial anionic additive, methylcellulose, dodecyl sodium sulfate are added in distilled water, are mixed Conjunction stirs after making negative solution, adds PAMAM grafting bamboo filament fibre powder, bamboo charcoal powder, ultrasonic disperse obtained by step a It is uniform and soak 30-50min, filter, 25 DEG C are dried 10-15h, obtain mixture, standby;
C. mixture, nylon66 fiber, polyethylene glycol obtained by step b are put in mixing screw extruder and melts, then Jing spinning, After fabric is obtained after weaving, again fabric is soaked in negative solution obtained by step b, and after ultrasonic vibration 10-20min, Baker is put into, 2-5min is bakeed, is taken out.
3. a kind of deodorization and sterilization bamboo filament fibre according to claim 2, nylon66 fiber blending and modifying spinning fabric and its preparation Method, it is characterised in that melt temperature is 150-200 DEG C in step c, spinning temperature is 250-300 DEG C.
CN201611112503.3A 2016-12-07 2016-12-07 A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof Pending CN106544751A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611112503.3A CN106544751A (en) 2016-12-07 2016-12-07 A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201611112503.3A CN106544751A (en) 2016-12-07 2016-12-07 A kind of deodorization and sterilization bamboo filament fibre, nylon66 fiber blending and modifying spinning fabric and preparation method thereof

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102619085A (en) * 2012-04-06 2012-08-01 福建锦江科技有限公司 Deodorization polyamide fiber and preparation method thereof
CN102732018A (en) * 2012-07-03 2012-10-17 金发科技股份有限公司 Nylon 66 composite and preparation method thereof
CN105623257A (en) * 2016-04-06 2016-06-01 苏州甫众塑胶有限公司 Nylon 66 composite sound-insulation material and preparation method thereof
CN106120150A (en) * 2016-08-24 2016-11-16 安徽省太湖泽泓塑业有限公司 A kind of can continuously releasing negative oxygen ion containing bamboo filament fibre non-woven fabrics and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102619085A (en) * 2012-04-06 2012-08-01 福建锦江科技有限公司 Deodorization polyamide fiber and preparation method thereof
CN102732018A (en) * 2012-07-03 2012-10-17 金发科技股份有限公司 Nylon 66 composite and preparation method thereof
CN105623257A (en) * 2016-04-06 2016-06-01 苏州甫众塑胶有限公司 Nylon 66 composite sound-insulation material and preparation method thereof
CN106120150A (en) * 2016-08-24 2016-11-16 安徽省太湖泽泓塑业有限公司 A kind of can continuously releasing negative oxygen ion containing bamboo filament fibre non-woven fabrics and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
贺晓: "PA66/超细竹炭微粉共混改性纺丝研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *

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Application publication date: 20170329