CN108676306A - 一种3d打印用材料 - Google Patents
一种3d打印用材料 Download PDFInfo
- Publication number
- CN108676306A CN108676306A CN201810608770.2A CN201810608770A CN108676306A CN 108676306 A CN108676306 A CN 108676306A CN 201810608770 A CN201810608770 A CN 201810608770A CN 108676306 A CN108676306 A CN 108676306A
- Authority
- CN
- China
- Prior art keywords
- parts
- printing
- printing material
- material according
- inorfil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 51
- 238000010146 3D printing Methods 0.000 title claims abstract description 45
- 239000003999 initiator Substances 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 11
- 241000219071 Malvaceae Species 0.000 claims abstract description 9
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical group CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002070 nanowire Substances 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 5
- 239000004917 carbon fiber Substances 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- 229910006636 γ-AlOOH Inorganic materials 0.000 claims description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 3
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 3
- 229940044192 2-hydroxyethyl methacrylate Drugs 0.000 claims description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 6
- 238000007639 printing Methods 0.000 abstract description 6
- 230000002708 enhancing effect Effects 0.000 abstract description 5
- 239000004925 Acrylic resin Substances 0.000 abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 abstract description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004615 ingredient Substances 0.000 abstract description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract description 2
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 230000006872 improvement Effects 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- 244000146553 Ceiba pentandra Species 0.000 description 1
- 235000003301 Ceiba pentandra Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 125000000532 dioxanyl group Chemical group 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Abstract
本发明属于3D打印材料技术领域，特别涉及一种3D打印用材料，按重量份计，所述3D打印用材料包括：丙烯酸5‑20份；丙烯酸甲酯20‑40份；甲基丙烯酸糠酯20‑40份；溶剂40‑80份；交联剂30‑50份；引发剂0.1‑1份；无机纤维1‑10份；多面体低聚倍半硅氧烷0.5‑5份；木棉花花托颗粒0.5‑5份。相对于现有技术，本发明通过在丙烯酸树脂中引入添加成分(包括无机纤维、多面体低聚倍半硅氧烷和木棉花花托颗粒)，可以使得该材料的光学和机械性能得到一定程度的增强，并具有较高的打印精度和优良的柔韧性，具体表现为拉伸强度、弹性模量、断裂伸长率、弯曲强度等性能指标。
Description
技术领域
本发明属于3D打印材料技术领域，特别涉及一种3D打印用材料。
背景技术
上世纪80年代，3D打印技术诞生，与传统的“去除”的加工方法不停，3D打印是一种自下而上的制造方式，也被称作增材制造技术，即通过层层堆积的方式实现数字模型到实物的构建。由于其简便、快捷优势，自诞生以来，3D打印技术便受到了极大的关注并因此得到了快速发展。近几十年来，3D打印技术在工业设计、建筑、汽车、航空航天、牙科、教育等领域都有所应用，但其应用和发展仍然受到诸多因素的限制。除了仪器设备及打印过程参数之外，原材料也是影响3D打印产品质量的关键因素，它将直接影响最终产品的表面质量、耐热性、韧性等。因此，开发具有优越的综合性能的复合材料来克服单一材料的缺陷和应用局限性是这一领域的研究热点。
光敏树脂是一种能够在光的作用下发生聚合反应由液态转变为固态的物质，将其作为增材制造方式的3D打印技术，与传统制造过程相比，具有简便、快捷和精度高等优点，因此，近年来人们对于3D打印技术的关注日益增多。近年来，作为光敏树脂的丙烯酸树脂由于本身机械强度较差，需对其进行改性才能满足高精度、高强度、结构复杂的器件的制造需求。
有鉴于此，本发明旨在提供一种3D打印用材料，其通过在丙烯酸树脂中引入添加成分，可以使得该材料的光学和机械性能得到一定程度的增强，并具有较高的打印精度和优良的柔韧性。
发明内容
本发明的目的在于：针对现有技术的不足，而提供一种3D打印用材料，其通过在丙烯酸树脂中引入添加成分，可以使得该材料的光学和机械性能得到一定程度的增强，并具有较高的打印精度和优良的柔韧性。
为了实现上述目的，本发明所采用如下技术方案：
一种3D打印用材料，按重量份计，所述3D打印用材料包括：
其中，丙烯酸、丙烯酸甲酯和甲基丙烯酸糠酯在引发剂的引发下、交联剂的交联作用下聚合成丙烯酸光敏树脂，无机纤维可以起到增强的效果，由于光敏树脂在光照固化期间容易发生翘曲变形，且光敏树脂固化后的强力普遍较低，光敏树脂的这两个缺点严重阻碍了光固化3D打印设备在工业领域中的快速发展，在光敏树脂中加入无机纤维可以解决光敏树脂成型后强力不足的问题，防止其翘曲变形。多面体低聚倍半硅氧烷(POSS)本身就是无机-有机杂化的结构，其中的Si-O-Si无机内核具有优良的热稳定性和结构稳定性，而有机取代基组成的外壳则可以赋予POSS良好的有机相容性及溶解性，POSS的加入可以提高材料的热稳定性。木棉花花托颗粒具有很强的柔韧性，加入该颗粒可以提高材料的韧性。
作为本发明3D打印用材料的一种改进，按重量份计，所述3D打印用材料包括：
作为本发明3D打印用材料的一种改进，所述溶剂为醋酸乙酯、环己烷、正已烷、二氧六环和丙酮的至少一种。
作为本发明3D打印用材料的一种改进，所述交联剂为丙烯酸-2-羟乙酯、丙烯酸-2-羟丙酯、甲基丙烯酸-2-羟乙酯和甲基丙烯酸-2-羟丙酯中的至少一种。
作为本发明3D打印用材料的一种改进，所述引发剂为多面体低聚倍半硅氧烷-二苯甲酮光引发剂。该引发剂具有稳定性高、光活性好的优点，其是通过将POSS引入二苯甲酮中而形成的杂化型光引发剂。
作为本发明3D打印用材料的一种改进，所述无机纤维为长度为0.5mm-3mm、直径为50nm-100nm的短切碳纤维，或者为3-(三甲氧基甲硅基)甲基丙烯酸丙酯修饰的γ-AlOOH纳米线，或者为3-(三甲氧基甲硅基)甲基丙烯酸丙酯修饰的γ-Al2O3纳米线。碳纤维具有高比模量、耐高温、高比强度、抗化学腐蚀、高热导等优点，而且在有机溶剂、酸、碱中不溶胀。γ-Al2O3纳米线和γ-AlOOH纳米线本身具有优异的力学性能，将其加入材料中，可以明显增强材料的力学性能。经过修饰后的γ-Al2O3纳米线和γ-AlOOH纳米线可以增强二者与树脂之间的相互作用力。
作为本发明3D打印用材料的一种改进，所述木棉花花托颗粒的粒径为0.5μm-50μm。
总之，相对于现有技术，本发明通过在丙烯酸树脂中引入添加成分(包括无机纤维、多面体低聚倍半硅氧烷和木棉花花托颗粒)，可以使得该材料的光学和机械性能得到一定程度的增强，并具有较高的打印精度和优良的柔韧性，具体表现为拉伸强度、弹性模量、断裂伸长率、弯曲强度等性能指标。
具体实施方式
下面结合实施例，对本发明作进一步详细的描述，但本发明的实施方式不限于此。
实施例1
本实施例提供了一种3D打印用材料，按重量份计，所述3D打印用材料包括：
溶剂为醋酸乙酯，交联剂为丙烯酸-2-羟乙酯，引发剂为多面体低聚倍半硅氧烷-二苯甲酮光引发剂，无机纤维为长度为0.5mm-3mm、直径为50nm-100nm的短切碳纤维，木棉花花托颗粒的粒径为0.5μm-50μm。
实施例2
本实施例提供了一种3D打印用材料，按重量份计，所述3D打印用材料包括：
溶剂为环己烷，交联剂为丙烯酸-2-羟丙酯，引发剂为多面体低聚倍半硅氧烷-二苯甲酮光引发剂，无机纤维为长度为3-(三甲氧基甲硅基)甲基丙烯酸丙酯修饰的γ-AlOOH纳米线。木棉花花托颗粒的粒径为0.5μm-50μm。
实施例3
本实施例提供了一种3D打印用材料，按重量份计，所述3D打印用材料包括：
实施例4
本实施例提供了一种3D打印用材料，按重量份计，所述3D打印用材料包括：
溶剂为二氧六环，交联剂为甲基丙烯酸-2-羟丙酯，引发剂为多面体低聚倍半硅氧烷-二苯甲酮光引发剂。无机纤维为长度为3-(三甲氧基甲硅基)甲基丙烯酸丙酯修饰的γ-Al2O3纳米线。木棉花花托颗粒的粒径为0.5μm-50μm。
实施例5
本实施例提供了一种3D打印用材料，按重量份计，所述3D打印用材料包括：
溶剂为丙酮，交联剂为丙烯酸-2-羟乙酯，引发剂为多面体低聚倍半硅氧烷-二苯甲酮光引发剂，无机纤维为长度为0.5mm-3mm、直径为50nm-100nm的短切碳纤维，木棉花花托颗粒的粒径为0.5μm-50μm。
测试实施例1至5的材料固化后的弯曲强度、弯曲模量、拉伸强度、弹性模量、艾氏耐冲击强度，所得结果见表1。
表1：实施例1至5的材料固化后的物理性能参数。
由表1可知，本发明的弯曲强度、弯曲模量、拉伸强度、弹性模量、艾氏耐冲击强度等性能指标良好，证明本发明的材料打印出来的实体成品具有良好的力学性能、高打印精度和优良的柔韧性
根据上述说明书的揭示和教导，本发明所属领域的技术人员还可以对上述实施方式进行变更和修改。因此，本发明并不局限于上面揭示和描述的具体实施方式，对本发明的一些修改和变更也应当落入本发明的权利要求的保护范围内。此外，尽管本说明书中使用了一些特定的术语，但这些术语只是为了方便说明，并不对本发明构成任何限制。
Claims (7)
1.一种3D打印用材料，其特征在于，按重量份计，所述3D打印用材料包括：
2.根据权利要求1所述的3D打印用材料，其特征在于，按重量份计，所述3D打印用材料包括：
3.根据权利要求1所述的3D打印用材料，其特征在于，所述溶剂为醋酸乙酯、环己烷、正已烷、二氧六环和丙酮的至少一种。
4.根据权利要求1所述的3D打印用材料，其特征在于，所述交联剂为丙烯酸-2-羟乙酯、丙烯酸-2-羟丙酯、甲基丙烯酸-2-羟乙酯和甲基丙烯酸-2-羟丙酯中的至少一种。
5.根据权利要求1所述的3D打印用材料，其特征在于，所述引发剂为多面体低聚倍半硅氧烷-二苯甲酮光引发剂。
6.根据权利要求1所述的3D打印用材料，其特征在于，所述无机纤维为长度为0.5mm-3mm、直径为50nm-100nm的短切碳纤维，或者为3-(三甲氧基甲硅基)甲基丙烯酸丙酯修饰的γ-AlOOH纳米线，或者为3-(三甲氧基甲硅基)甲基丙烯酸丙酯修饰的γ-Al2O3纳米线。
7.根据权利要求1所述的3D打印用材料，其特征在于，所述木棉花花托颗粒的粒径为0.5μm-50μm。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810608770.2A CN108676306A (zh) | 2018-06-13 | 2018-06-13 | 一种3d打印用材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810608770.2A CN108676306A (zh) | 2018-06-13 | 2018-06-13 | 一种3d打印用材料 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108676306A true CN108676306A (zh) | 2018-10-19 |
Family
ID=63811079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810608770.2A Pending CN108676306A (zh) | 2018-06-13 | 2018-06-13 | 一种3d打印用材料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108676306A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109275983A (zh) * | 2018-09-30 | 2019-01-29 | 嘉兴学院 | 一种高柔性鞋垫及其制备方法 |
| WO2022268609A1 (en) * | 2021-06-24 | 2022-12-29 | Basf Se | Composition for 3d-printing, 3d-printed object formed therefrom and process for forming the same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013109755A1 (de) * | 2013-09-06 | 2015-03-12 | Rent A Scientist Gmbh | Leitfähiger Klebstoff |
| CN106832091A (zh) * | 2017-01-18 | 2017-06-13 | 福建省支点三维科技有限公司 | 一种热固性聚丙烯酸酯树脂3d打印材料及其制备方法 |
| CN106883328A (zh) * | 2017-01-18 | 2017-06-23 | 福建省支点三维科技有限公司 | 一种户外用的聚丙烯酸酯树脂3d打印材料及其制备方法 |
| CN107274969A (zh) * | 2016-04-04 | 2017-10-20 | 施乐公司 | 预期或指示结构损害的3d打印导电组合物 |
| CN108117624A (zh) * | 2018-01-24 | 2018-06-05 | 中国科学院福建物质结构研究所 | 一种含poss 3d打印光敏树脂的制备及应用 |
-
2018
- 2018-06-13 CN CN201810608770.2A patent/CN108676306A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013109755A1 (de) * | 2013-09-06 | 2015-03-12 | Rent A Scientist Gmbh | Leitfähiger Klebstoff |
| CN107274969A (zh) * | 2016-04-04 | 2017-10-20 | 施乐公司 | 预期或指示结构损害的3d打印导电组合物 |
| CN106832091A (zh) * | 2017-01-18 | 2017-06-13 | 福建省支点三维科技有限公司 | 一种热固性聚丙烯酸酯树脂3d打印材料及其制备方法 |
| CN106883328A (zh) * | 2017-01-18 | 2017-06-23 | 福建省支点三维科技有限公司 | 一种户外用的聚丙烯酸酯树脂3d打印材料及其制备方法 |
| CN108117624A (zh) * | 2018-01-24 | 2018-06-05 | 中国科学院福建物质结构研究所 | 一种含poss 3d打印光敏树脂的制备及应用 |
Non-Patent Citations (1)
| Title |
|---|
| 屠振密等编: "《电沉积纳米晶材料技术》", 国防工业出版社, pages: 30 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109275983A (zh) * | 2018-09-30 | 2019-01-29 | 嘉兴学院 | 一种高柔性鞋垫及其制备方法 |
| CN109275983B (zh) * | 2018-09-30 | 2021-03-23 | 嘉兴学院 | 一种高柔性鞋垫及其制备方法 |
| WO2022268609A1 (en) * | 2021-06-24 | 2022-12-29 | Basf Se | Composition for 3d-printing, 3d-printed object formed therefrom and process for forming the same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108676306A (zh) | 一种3d打印用材料 | |
| CN107936682A (zh) | 光固化3d打印聚酰亚胺墨水及其制备方法与应用 | |
| JP5455730B2 (ja) | 加飾用ハードコートフィルム、加飾フィルムおよび加飾成形品 | |
| JP2014221912A (ja) | 反射防止コーティング | |
| TWI691563B (zh) | 光可固化塗料組合物及其應用 | |
| JP2010284910A (ja) | 加飾用ハードコートフィルム、加飾フィルムおよび加飾成形品 | |
| CN1051739A (zh) | 处理基材的方法 | |
| CN1938607A (zh) | 低反射部件 | |
| TW200905380A (en) | Pellicle frame | |
| JPWO2019194198A1 (ja) | 樹脂組成物、光ファイバのセカンダリ被覆材料及び光ファイバ | |
| KR20140050296A (ko) | 실세스퀴옥산을 포함하는 조성물과 그 제조 방법, 및 이를 이용한 하드 코팅막과 그 제조 방법 | |
| CN108003536A (zh) | 一种高透光亚克力板材及其制备方法 | |
| KR20090125747A (ko) | 눈부심 방지 필름용 입자, 및 눈부심 방지 필름용 입자 조성물 | |
| CN103946284B (zh) | 透明性及耐冲击性优秀的丙烯酸树脂膜及其制备方法 | |
| TW201943061A (zh) | 柔性顯示裝置覆蓋基板及使用其之柔性顯示裝置 | |
| CN108219608A (zh) | 一种白石墨烯复合树脂硬化液及pet硬化层的制备方法 | |
| CN110917044A (zh) | 一种3d打印高透明度氧化锆陶瓷牙冠材料 | |
| Miao et al. | Dynamic crack initiation and growth in cellulose nanopaper | |
| CN110919950A (zh) | 一种增亮膜的软模具成型工艺及由其制得的产品 | |
| TW201018581A (en) | Method for manufacturing multi-function plastic thin film and IMD process using the same | |
| EP2630189A2 (en) | Polymerizable composition and optical sheet comprising cured resin layer formed therefrom | |
| JPWO2020008912A1 (ja) | 光学シート用光硬化性インク | |
| WO2021082257A1 (zh) | 物理水凝胶及其制备方法 | |
| JP7388425B2 (ja) | 光ファイバ | |
| JP2009199044A (ja) | 位相差フィルム |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 523000 Silver Spring Industrial Zone, Qingxi Town, Guangdong, Dongguan Applicant after: DONGGUAN EONTEC Co.,Ltd. Applicant after: DONGGUAN MEIAN MAGNESIUM TECHNOLOGY Co.,Ltd. Address before: 523000, 2, building three, headquarters of Songshan Lake hi tech Development Zone, Dongguan, Guangdong Applicant before: DONGGUAN EONTEC Co.,Ltd. Applicant before: DONGGUAN MEIAN MAGNESIUM TECHNOLOGY Co.,Ltd. |
|
| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181019 |
|
| RJ01 | Rejection of invention patent application after publication |