CN108630522A - The cleaning method of chip surface - Google Patents

The cleaning method of chip surface Download PDF

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Publication number
CN108630522A
CN108630522A CN201710173274.4A CN201710173274A CN108630522A CN 108630522 A CN108630522 A CN 108630522A CN 201710173274 A CN201710173274 A CN 201710173274A CN 108630522 A CN108630522 A CN 108630522A
Authority
CN
China
Prior art keywords
chip
cleaning method
cleaned
ultrasonic wave
chip surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710173274.4A
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Chinese (zh)
Inventor
何小麟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SAE Technologies Development Dongguan Co Ltd
Original Assignee
SAE Technologies Development Dongguan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAE Technologies Development Dongguan Co Ltd filed Critical SAE Technologies Development Dongguan Co Ltd
Priority to CN201710173274.4A priority Critical patent/CN108630522A/en
Publication of CN108630522A publication Critical patent/CN108630522A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02041Cleaning
    • H01L21/02057Cleaning during device manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/12Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations

Abstract

The present invention chip surface cleaning method, include successively:Chip is placed in alkaline solution and is cleaned using ultrasonic wave;The chip is placed in the mixed liquor of isopropyl alcohol and water and is cleaned using ultrasonic wave;The chip is placed in citric acid solution to be cleaned using ultrasonic wave;And rinse the chip with deionized water.This method can efficiently remove the residue on chip surface, prevent from causing to corrode to chip, to improve the service life of chip.

Description

The cleaning method of chip surface
Technical field
The present invention relates to semiconductor chip cleaning field more particularly to a kind of cleaning methods of chip surface.
Background technology
It is required in IC chip manufacturing process as integrated circuit feature size enters the deep-submicron stage The cleanliness factor of chip surface is higher and higher, in order to ensure the cleanliness factor on chip material surface, is deposited in the manufacturing process of integrated circuit In hundreds of road cleanings.
Traditional cleaning way is to utilize deionized water flushing chip, and in this mode, deionized water is with very high flow Impact chip, by chip impurity and pollutant wash away, to reach cleaning performance.But this cleaning method is to chip Impact force is excessive, be easy to cause the damage of element pattern, and the utilization rate of the deionized water of this cleaning way is low, causes to provide Source wastes.Another cleaning way is to carry out soaking and washing using hydrochloric acid or hydrofluoric acid, however, the cleaning effect of such cleaning method Fruit is bad, and the solution of remained on surface can cause to corrode to chip surface.
So there is an urgent need for a kind of cleaning method of improved chip surface, with the defect more than overcoming.
Invention content
The purpose of the present invention is to provide a kind of cleaning methods of chip surface, can efficiently remove residual on chip surface Object is stayed, prevents that chip is caused to corrode, to improve the service life of chip.
To achieve the above object, the cleaning method of chip surface of the invention, includes the following steps successively:
Compared with prior art, the cleaning method of chip surface of the invention uses alkaline solution, isopropyl alcohol and water successively Mixed solution, citric acid solution and deionized water cleaned, and in cleaning process use ultrasonic cleaning technology, Residue and damaging layer can be effectively removed under the booster action of supersonic oscillations, cleaning performance is more preferable, and surface cleanliness is big To improve, service life is extended.
Preferably, further including after the step of rinsing the chip with deionized water:Carbon is added in the deionized water Hydrogen solvent is cleaned.
Preferably, further including after the step of hydrocarbon solvent is cleaned is added:Chip is taken out simultaneously from cleaning solution Carry out heat content drying.
Preferably, further including before chip is placed in the step of being cleaned using ultrasonic wave in alkaline solution:Spend from Sub- water conservancy carries out prerinse with ultrasonic wave to chip, and the temperature of deionized water is 50~60 degree.
Preferably, the power of ultrasonic wave is 20W~30W, frequency is 40KHz~50KHz.
Preferably, the temperature of the alkaline solution is 80~90 degree, scavenging period in the alkaline solution for 50~ 10 minutes.
Preferably, the sodium hydroxide solution that the alkaline solution is a concentration of 2%~5%.
Preferably, the rinsing time for rinsing the chip with deionized water is 20~30 minutes.
Preferably, the pH value of the citric acid solution is 5~6.
Specific implementation mode
The cleaning method of the chip surface of the present invention is described further with reference to embodiment, but is not so limited this Invention.
One embodiment of the cleaning method of the chip surface of the present invention includes the following steps successively:
Chip is placed in alkaline solution and is cleaned using ultrasonic wave;
The chip is placed in the mixed liquor of isopropyl alcohol and water and is cleaned using ultrasonic wave;
The chip is placed in citric acid solution to be cleaned using ultrasonic wave;And
The chip is rinsed with deionized water.
The cleaning method of the chip surface of the present invention uses alkaline solution, the mixed solution of isopropyl alcohol and water, lemon successively Acid solution and deionized water are cleaned, and ultrasonic cleaning technology is used in cleaning process, in supersonic oscillations Residue and damaging layer can be effectively removed under booster action, cleaning performance is more preferable, and surface cleanliness greatly improves, service life Extended.
In another embodiment, the cleaning method of the chip surface includes the following steps successively:
Prerinse:Prerinse is carried out to chip using ultrasonic wave with deionized water, the temperature of deionized water is 50~60 degree, Specifically, the power of the ultrasonic wave is 30W, frequency 50KHz.
Alkali cleaning:Chip is placed in alkaline solution and is cleaned using ultrasonic wave, and the temperature of alkaline solution is 80~90 degree, compared with Goodly, the alkaline solution can be sodium hydroxide solution, a concentration of 2%~5%, scavenging period be 5~10 minutes, in this step In, the temperature of sodium hydroxide solution is unsuitable excessively high, is such as preferred for 20~25 degree.The power of ultrasonic wave is 20W, frequency 40KHz.
Organic solvent cleans:Chip is placed in the mixed liquor of isopropyl alcohol and water and is cleaned using ultrasonic wave, the time be 5~ 10 minutes, for the power of ultrasonic wave in 20~30W, frequency was 40KHz~50KHz.The step can active solvent removal chip surface Organic residue.
Pickling:The mixed liquor of citric acid and deionized water is prepared, the pH value of mixed liquor is 5~6.Chip is placed in the acid In property solution, by cleaned by ultrasonic vibration technology, chip surface is made quickly to carry out neutralization reaction.
Deionized water rinses:The chip is rinsed with deionized water, rinsing time is 20~30 minutes, by rinsing, chip The cleaning solutions such as acid solution, the lye on surface residual is rinsed clean.
Hydrocarbon cleaning:Hydrocarbon solvent is added in the deionized water of previous step, then excludes deionized water.
Heat content is dried:Chip is taken out to from cleaning solution and is carried out heat content drying, which utilizes the change of temperature, pressure Change, reduces the enthalpy on chip, make Liquid Residue rapid evaporation.
More than, in conjunction with preferred embodiment, present invention is described, cleaning combination alkali cleaning of the invention, organic solvent, The multiple cleanings such as pickling, deionization rinsing, and cleaned by ultrasonic vibration technology is used, to effectively remove the residual of chip surface Object and damaging layer are stayed, is prolonged the service life to reduce chip surface burn into.
Above disclosed is only presently preferred embodiments of the present invention, cannot limit the right of the present invention with this certainly Range, therefore according to equivalent variations made by scope of the present invention patent, be still within the scope of the present invention.

Claims (9)

1. a kind of cleaning method of chip surface, includes the following steps successively:
Chip is placed in alkaline solution and is cleaned using ultrasonic wave;
The chip is placed in the mixed liquor of isopropyl alcohol and water and is cleaned using ultrasonic wave;
The chip is placed in citric acid solution to be cleaned using ultrasonic wave;And
The chip is rinsed with deionized water.
2. the cleaning method of chip surface as described in claim 1, it is characterised in that:The chip is being rinsed with deionized water Further include after step:Hydrocarbon solvent is added in the deionized water to be cleaned.
3. the cleaning method of chip surface as claimed in claim 2, it is characterised in that:The step that hydrocarbon solvent is cleaned is added Further include after rapid:Chip is taken out from cleaning solution and carries out heat content drying.
4. the cleaning method of chip surface as described in claim 1, it is characterised in that:It is placed in alkaline solution and utilizes in chip Further include before the step of ultrasonic wave is cleaned:Prerinse, deionized water are carried out to chip using ultrasonic wave with deionized water Temperature be 50~60 degree.
5. the cleaning method of chip surface as described in claim 1, it is characterised in that:The power of ultrasonic wave is 20W~30W, Frequency is 40KHz~50KHz.
6. the cleaning method of chip surface as described in claim 1, it is characterised in that:The temperature of the alkaline solution be 80~ 90 degree, the scavenging period in the alkaline solution is 50~10 minutes.
7. the cleaning method of chip surface as claimed in claim 6, it is characterised in that:The alkaline solution is a concentration of 2% ~5% sodium hydroxide solution.
8. the cleaning method of chip surface as described in claim 1, it is characterised in that:The drift of the chip is rinsed with deionized water It is 20~30 minutes to wash the time.
9. the cleaning method of chip surface as described in claim 1, it is characterised in that:The pH value of the citric acid solution is 5 ~6.
CN201710173274.4A 2017-03-22 2017-03-22 The cleaning method of chip surface Pending CN108630522A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710173274.4A CN108630522A (en) 2017-03-22 2017-03-22 The cleaning method of chip surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710173274.4A CN108630522A (en) 2017-03-22 2017-03-22 The cleaning method of chip surface

Publications (1)

Publication Number Publication Date
CN108630522A true CN108630522A (en) 2018-10-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710173274.4A Pending CN108630522A (en) 2017-03-22 2017-03-22 The cleaning method of chip surface

Country Status (1)

Country Link
CN (1) CN108630522A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110434112A (en) * 2019-08-09 2019-11-12 无锡市芯飞通光电科技有限公司 A kind of chip cleaning process
CN111092011A (en) * 2018-10-23 2020-05-01 山东浪潮华光光电子股份有限公司 Treatment method for improving surface pollution of LED chip
CN111192816A (en) * 2018-11-15 2020-05-22 东莞新科技术研究开发有限公司 Semiconductor workpiece cleaning method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1787178A (en) * 2004-12-08 2006-06-14 中国电子科技集团公司第四十六研究所 Method for cleaning gallium arsenide crystal chip
CN1906738A (en) * 2004-06-28 2007-01-31 住友电气工业株式会社 GaAs substrate cleaning method, GaAs substrate manufacturing method, epitaxial substrate manufacturing method and GaAs wafer
CN101087007A (en) * 2007-05-11 2007-12-12 上海明兴开城超音波科技有限公司 Chemical etching, cleaning and drying method of single-crystal silicon solar battery and integrated processing machine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1906738A (en) * 2004-06-28 2007-01-31 住友电气工业株式会社 GaAs substrate cleaning method, GaAs substrate manufacturing method, epitaxial substrate manufacturing method and GaAs wafer
CN1787178A (en) * 2004-12-08 2006-06-14 中国电子科技集团公司第四十六研究所 Method for cleaning gallium arsenide crystal chip
CN101087007A (en) * 2007-05-11 2007-12-12 上海明兴开城超音波科技有限公司 Chemical etching, cleaning and drying method of single-crystal silicon solar battery and integrated processing machine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111092011A (en) * 2018-10-23 2020-05-01 山东浪潮华光光电子股份有限公司 Treatment method for improving surface pollution of LED chip
CN111092011B (en) * 2018-10-23 2022-09-16 山东浪潮华光光电子股份有限公司 Treatment method for improving surface pollution of LED chip
CN111192816A (en) * 2018-11-15 2020-05-22 东莞新科技术研究开发有限公司 Semiconductor workpiece cleaning method
CN110434112A (en) * 2019-08-09 2019-11-12 无锡市芯飞通光电科技有限公司 A kind of chip cleaning process

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Application publication date: 20181009