CN108605977A - A kind of granular pesticide of prevention sugarcane moth borer - Google Patents

A kind of granular pesticide of prevention sugarcane moth borer Download PDF

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Publication number
CN108605977A
CN108605977A CN201810611564.7A CN201810611564A CN108605977A CN 108605977 A CN108605977 A CN 108605977A CN 201810611564 A CN201810611564 A CN 201810611564A CN 108605977 A CN108605977 A CN 108605977A
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CN
China
Prior art keywords
phoxim
insect amide
fluorobenzene insect
sugarcane
granular pesticide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810611564.7A
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Chinese (zh)
Inventor
邓付圆
韦勇飞
吴宝国
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Guangxi Nanning Yitu Biotechnology Co Ltd
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Guangxi Nanning Yitu Biotechnology Co Ltd
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Priority to CN201810611564.7A priority Critical patent/CN108605977A/en
Publication of CN108605977A publication Critical patent/CN108605977A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of granular pesticide of prevention sugarcane moth borer, active ingredient is made of fluorobenzene insect amide and phoxim, and the weight ratio of fluorobenzene insect amide and phoxim is 1:1‑10.The present invention is notable for preventing sugarcane moth borer synergy by the rational mixture of fluorobenzene insect amide and phoxim, the shortcomings that capable of greatly improving drug effect, reduce use cost, while single dose can be overcome to easy to produce resistance.

Description

A kind of granular pesticide of prevention sugarcane moth borer
Technical field
The present invention relates to cultural control technical field, the granular pesticide of specifically a kind of prevention sugarcane moth borer.
Background technology
Sugarcane is the major economic crops in Guangxi, and sugarcane borer, sugarcane tortoise are two kinds of primary pests in Guangxi sugarcane producing region, wherein sugarcane Snout moth's larva is especially prominent to the harm of sugarcane.Sugarcane borer is all harmful in sugarcane entire growth period, and seedling stage growing point of causing harm causes withered heart seedling, Withered heart rate is generally 10%~20%, serious up to 50% or more, and middle and later periods brill moth causes harm sugarcane stem, destroys sugarcane stem tissue, hinders Sugarcane production causes windbreak, reduces yield and sugar.From 31 days October in 2013, since terbufos are forbidden producing and make With rear, sugarcane insect pest especially sugarcane moth borer becomes to be on the rise.Therefore, it is badly in need of having a kind of high-efficiency low-toxicity insecticide, can has The harm of the control sugarcane moth borer of effect.
Fluorobenzene insect amide, English name:Flubendiamide belongs to novel phthalic amide insecticides, activates blue Buddhist nun Calcium release channel in alkali recipient cell leads to the runaway release for storing calcium ion, is few in number at present to act on insect The compound of cell orchid Buddhist nun's alkali receptor, has spectrum preventive effect to lepidoptera pest, with existing insecticide no interactions resistance generate, at Worm preventive effect is limited, without ovicidal action, is slightly passed to by xylem after infiltration plant is interior, resistance of rainwater washing against.
Phoxim, English name:Phoxim is a kind of organophosphorus insecticide, with tag with stomach toxicity based on, no interior suction is made With insecticidal spectrum is wide, knocks down that power is strong, also has good action effect to the larva of a variety of lepidoptera pests.Phoxim applies in soil, residual It stays the phase very long, is suitable for preventingSubterranean pest-insect
Inventors discovered through research that by fluorobenzene insect amide and phoxim with certain weight ratio mixture, composition is to sweet Sugarcane borer worm synergy is apparent, can reduce the dosage of each single dose, mitigates drug cost.Currently, being made with fluorobenzene insect amide and phoxim For active ingredient composition be applied to sugarcane moth borer study on prevention there are no relevant reports.
Invention content
The object of the present invention is to provide a kind of granular pesticides of prevention sugarcane moth borer, have high-efficiency low-toxicity, can be significantly The advantages of improving drug effect, reducing Pesticide use amount, reduce pesticide mu input cost.
The technical solution used in the present invention is:A kind of granular pesticide of prevention sugarcane moth borer, active ingredient is by fluorobenzene The weight ratio of insect amide and phoxim composition, fluorobenzene insect amide and phoxim is 1:1-10, it is preferred that fluorobenzene insect amide and pungent sulphur The weight ratio of phosphorus is 1:5 or 1:8.
Weight percent of the fluorobenzene insect amide in granular pesticide is 0.2-2.0%, and phoxim is in pesticide Weight percent in granula is 0.4-5.0%.
The adjuvant that the granular pesticide is added includes filler, binder, dispersant, wetting agent, disintegrant, stabilization Agent or other active ingredients that are beneficial to stablize the substance played with drug effect in the formulation, are all common or fair in field of pesticide preparation Perhaps the various composition used.
The present invention has the following advantages and significant technique effect:
(1) with the composition of fluorobenzene insect amide and phoxim rational proportion, prevention sugarcane moth borer has synergistic effect, not only The plurality of advantages of original each single dose is kept, but also makes each component usage amount reduction in the case where activity is not lost in mixture, Increased to the activity of mixture.
(2) by fluorobenzene insect amide and phoxim compound, pest is made to be difficult to eliminate mode of action different insecticides simultaneously to it Influence, delay in pest population drug resistance individual to generate.
(3) present invention is prepared into granular pesticide, in conjunction with the plantation of new sugarcane or the big ridging application of sugarcane, alleviates farming behaviour Make, more saves labor.
Specific implementation mode
Technical scheme of the present invention and technique effect are described further below by way of specific embodiment, institute of the present invention The percentage stated is weight percentage.
One, indoor joint toxicity measuring test
Embodiment 1:The indoor joint toxicity measuring of fluorobenzene insect amide, phoxim and its mixture to sugarcane moth borer
1, experimental design:Experiment is using 2 instar larvae of chilo infuscatellus as test worm, reference《People's Republic of China's agricultural industry mark Quasi- NY/T1154.7-2006》, experiment is with fluorobenzene insect amide, phoxim single dose medicament as a contrast, containing fluorobenzene insect amide, pungent Comparison medicament, measurement medicament are respectively set by active constituent content at 6 gradient concentrations as medicament is measured for the mixture of sulphur phosphorus Reason, using the processing without medicament as blank control (CK).
2, test method:Using 10s dip methods, the extra liquid of test worm is drawn with filter paper, test worm is put into insect box later Middle raising each handles 3 repetitions, and it is 40 each to repeat test worm number used, and 72h checks dead borer population after medicine, calculates dead Rate and corrected mortality, it is for statistical analysis with DPS data softwares, virulence regression equation (y=a+ is acquired with least square method Bx), the LC of each medicament and is thus calculated50Value.
According to the co-toxicity coefficient method (CTC) of (1960) SunJohnson come evaluate active insecticidal components fluorobenzene insect amide, Whether phoxim is mixed has synergistic effect, co-toxicity coefficient (CTC) is calculated, when co-toxicity coefficient (CTC) >=120 table of compounding agent It is now synergistic effect;CTC≤80 show as antagonism;80<CTC<120 show as summation action.On this basis, it then carries out Field control effectiveness test.
Statistical result is as shown in table 1.
Table 1:The Toxicity Determination of fluorobenzene insect amide, phoxim and its mixture to sugarcane moth borer (chilo infuscatellus)
As known from Table 1, fluorobenzene insect amide, phoxim show obviously sugarcane moth borer within the scope of specific weight ratio Synergistic effect, wherein weight ratio be 1:5 or 1:Synergy is most notable when 8, there is good reference value in field control effectiveness test.
Two, embodiment is prepared
Embodiment 1:2.4% fluorobenzene insect amide phoxim granule
Formula:Weigh fluorobenzene insect amide 0.4% according to quantity, phoxim 2.0%, sodium lignin sulfonate 3.5% (dispersant), ten Sodium dialkyl sulfate 2.5% (wetting agent), polyvinyl alcohol 4.2% (binder), white carbon 10% (filler), diatomite (filler) Complement to 100%.
Embodiment 2:1.8% fluorobenzene insect amide phoxim granule
Formula:Fluorobenzene insect amide 0.2%, the phoxim 1.6%, (dispersion of naphthalenesulfonate formaldehyde condensation compound 2.5% are weighed according to quantity Agent), lauryl sodium sulfate 2.5% (wetting agent), polyvinyl alcohol 5.0% (binder), white carbon 15% (filler), bentonite (filler) complements to 100%.
Embodiment 3:5.5% fluorobenzene insect amide phoxim granule
Formula:Weigh fluorobenzene insect amide 0.5% according to quantity, phoxim 5%, carboxymethyl cellulose 3.5% (dispersant), 12 Sodium alkyl sulfate 2.0% (wetting agent), polyvinyl alcohol 3.5% (binder), kaolin (filler) complement to 100%.
Embodiment 4:0.6% fluorobenzene insect amide phoxim granule
Formula:Weigh fluorobenzene insect amide 0.2% according to quantity, phoxim 0.4%, carboxymethyl cellulose 5% (dispersant), 12 Sodium alkyl benzene sulfonate 3.5% (wetting agent), polyvinyl alcohol 4.2% (binder), white carbon (filler) 10%, kaolin (filler) Complement to 100%.
Embodiment 5:4.0% fluorobenzene insect amide phoxim granule
Formula:Weigh fluorobenzene insect amide 2.0% according to quantity, phoxim 2.0%, sodium lignin sulfonate 2.5% (dispersant), ten Sodium dialkyl sulfate 3.2% (wetting agent), polyvinyl alcohol 3% (binder), white carbon 10% (filler), attapulgite (filler) Complement to 100%.
Prepare the preparation method of embodiment 1-5:Each component is sufficiently mixed by formula rate, is crushed, after wetting with water again It stirs, then is granulated with screw extruder pelletizer, is sieved after dry, packaging cases to contain fluorobenzene insect amide The granular pesticide of phoxim.
Three, field control effectiveness test
Prepare the field trial that the preparation obtained by embodiment 1-2 is used to prevent sugarcane moth borer
(1) experimental design:The preparation (2.4% fluorobenzene insect amide phoxim granule) for preparing 1 gained of embodiment is made For test group 1#, amount of application is 3.0 kgs/acre;Preparation (the 1.8% fluorobenzene insect amide phoxim of 2 gained of embodiment will be prepared Granule) as test group 2#, amount of application is 4.0 kgs/acre;Using 2.4% fluorobenzene insect amide granule as control group 1#, application Amount is 4.0 kgs/acre;Using 3.0% phoxim granule as control group 2#, amount of application is 5.0 kgs/acre;1 blank pair is set According to group (CK).
(2) spraying time and method:It sowed 1 dispenser in conjunction with sugarcane on 2 25th, 2014, by mu dosage and 1:10 Dry fine earth is uniformly spread fertilizer over the fields again after mixing in kind of planting ditch, timely earthing.
(3) test result
Result investigation is carried out after sugarcane moth borer on June 28th, 2014, investigate per the total seedling number of cell and sugarcane Snout moth's larva, which is caused harm, causes withered heart seedling number, calculates withered heart rate and control effect.
(4) calculation formula:Withered heart rate=withered heart seedling number/total seedling number * 100%.Control effect=(check plot withered heart rate-it applies Medicine area withered heart rate)/check plot withered heart rate * 100%.
(5) test result is shown in Table 2.
The field control effectiveness test statistical form of 2 fluorobenzene insect amide of table, phoxim and its mixed agent prevention sugarcane moth borer
Can be obtained from the test data table of table 2, test group 1#, test group 2# sugarcane withered heart rate be respectively 4.28% and 5.98%, hence it is evident that less than the withered heart rate of control group 1#, control group 2#, test group 1#, test group 2# also show sugarcane borer control effect Higher than control group 1#, control group 2#, illustrate the rational mixture of fluorobenzene insect amide and phoxim, synergy is notable, can greatly improve pair The control effect of sugarcane moth borer advantageously reduces the dosage of each single dose, reduces drug cost, can control the danger of sugarcane moth borer Evil, there is good application value.

Claims (3)

1. a kind of granular pesticide of prevention sugarcane moth borer, which is characterized in that active ingredient is by fluorobenzene insect amide and phoxim group At the weight ratio of fluorobenzene insect amide and phoxim is 1:1-10.
2. granular pesticide according to claim 1, which is characterized in that fluorobenzene insect amide and the weight ratio of phoxim are 1: 5 or 1:8.
3. granular pesticide according to claim 1 or 2, which is characterized in that fluorobenzene insect amide is in granular pesticide Weight percent is 0.2-2.0%, and weight percent of the phoxim in granular pesticide is 0.4-5.0%.
CN201810611564.7A 2018-06-14 2018-06-14 A kind of granular pesticide of prevention sugarcane moth borer Pending CN108605977A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102626077A (en) * 2012-04-01 2012-08-08 广西田园生化股份有限公司 Ultra-low-volume liquid containing flubendiamide
CN104692944A (en) * 2015-03-14 2015-06-10 武鸣县红鹰肥业有限公司 Special organic-inorganic compound fertilizer for sugarcane and preparation method of special organic-inorganic compound fertilizer
CN104970013A (en) * 2015-07-30 2015-10-14 广东省湛江市甘丰农药厂 Controlled-release pesticide granules and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102626077A (en) * 2012-04-01 2012-08-08 广西田园生化股份有限公司 Ultra-low-volume liquid containing flubendiamide
CN104692944A (en) * 2015-03-14 2015-06-10 武鸣县红鹰肥业有限公司 Special organic-inorganic compound fertilizer for sugarcane and preparation method of special organic-inorganic compound fertilizer
CN104970013A (en) * 2015-07-30 2015-10-14 广东省湛江市甘丰农药厂 Controlled-release pesticide granules and preparation method thereof

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Application publication date: 20181002