CN108589303A - 一种水性涂层用阻燃树脂整理剂及其制备方法 - Google Patents
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Abstract
本发明公开了一种水性涂层用阻燃树脂整理剂及其制备方法。整理剂包括水性树脂、水性阻燃剂、水性树脂增稠剂、水性填料、水性分散剂、水性架桥剂和水。本发明采用水作为整个产品体系的溶剂，不使用有机溶剂，减少VOC的排放，同时在加工过程中不需要进行溶剂的收集和回收，同时使用磷氮系环保阻燃剂，不含卤素，符合环保方向。
Description
技术领域
本发明涉及一种水性涂层用阻燃树脂整理剂及其制备方法，属于水性涂层技术领域。
背景技术
在汽车内饰工业中，阻燃要求一直是产品的重点，针对纺织品用于汽车内饰件，主要的材料种类是涤纶面料，但涤纶面料的氧指数（LOI）是23.5%,属于可燃性面料，涤纶面料后续通过染色或功能性加工后会更加易于燃烧，同时涤纶面料的耐磨耗性及尺寸安定性也需要增强，所以需要使用同时具有阻燃，耐磨耗和增加尺寸安定性的产品，目前汽车内饰面料的加工工艺是通过不同工艺分别增强阻燃，耐磨耗和尺寸安定性。工序比较冗长，并且效果稳定性不够好，在实际工业应用中对生产工厂的工艺稳定性要求高。
发明内容
为了克服现有技术的不足，本发明提供了一种水性涂层用阻燃树脂整理剂及其制备方法。
本发明是通过以下技术方案来实现的：
一种水性涂层用阻燃树脂整理剂，包括水性树脂、水性阻燃剂、水性树脂增稠剂、水性填料、水性分散剂、水性架桥剂和水。
所述的一种水性涂层用阻燃树脂整理剂，所述各原料的重量份数分别为：水性树脂30-50份、水性阻燃剂10-20份、水性树脂增稠剂1-2份、水性填料1-2份、水性分散剂1-2份、水性架桥剂3-5份和水30-50份。
所述的一种水性涂层用阻燃树脂整理剂，所述水性树脂为聚酯类聚氨酯或聚醚型聚氨酯中的一种或几种。
所述的一种水性涂层用阻燃树脂整理剂，所述水性阻燃剂为改性聚磷酸铵、环状磷酸酯或季戊四醇磷酸酯乳液中的一种或几种。
所述的一种水性涂层用阻燃树脂整理剂，所述水性树脂增稠剂为碱溶涨类增稠剂或聚氨酯缔合型增稠剂。
所述的一种水性涂层用阻燃树脂整理剂，所述水性填料为纳米级二氧化钛金红石型。
所述的一种水性涂层用阻燃树脂整理剂，所述水性分散剂为纤维素醚或木质素磺化物。
所述的一种水性涂层用阻燃树脂整理剂，所述水性架桥剂为封闭型异氰酸酯架桥剂或封闭氮丙啶类架桥剂。
所述的一种水性涂层用阻燃树脂整理剂的制备方法，在反应釜中加入水和水性分散剂，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入水性阻燃剂持续搅拌，再投入水性树脂，搅拌均匀后调整体系pH值，加入水性树脂增稠剂调整粘度，最后投入水性架桥剂，搅拌均匀。
水性分散剂，可以均匀分散水性填料和水性阻燃剂，不易产生结块和沉淀；调整体系pH值可以使增稠更容易，同时体系也更稳定。
本发明所达到的有益效果：
本发明采用水作为整个产品体系的溶剂，不使用有机溶剂，减少VOC的排放，同时在加工过程中不需要进行溶剂的收集和回收，同时使用磷氮系环保阻燃剂，不含卤素，符合环保方向。
本发明的外观为乳白色粘稠状；粘度（mPa.s）为9000-12000，固含为45-55%。
本发明的整理剂能够改善汽车内饰用涤纶材料的阻燃性能，耐磨耗性能和尺寸安定性，减少了以往的多道工序，提高了工艺的稳定性。
具体实施方式
下面对本发明作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
一种水性涂层用阻燃树脂整理剂，所述各原料的重量份数分别为：聚酯类聚氨酯40份、改性聚磷酸铵5份、环状磷酸酯10份、碱溶涨类增稠剂2份、纳米级二氧化钛金红石型1份、纤维素醚1.5份、封闭型异氰酸酯架桥剂4份和水36.5份。
按照比例，在反应釜中加入水和纤维素醚，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入改性聚磷酸铵和环状磷酸酯持续搅拌，再投入聚酯类聚氨酯，搅拌均匀后调整体系pH值为6-8，加入碱溶涨类增稠剂调整粘度，最后投入封闭型异氰酸酯架桥剂，搅拌均匀。
一种水性涂层用阻燃树脂整理剂的使用方法，将涤纶平织面料进行退浆前处理后，将水性涂层用阻燃树脂整理剂涂覆到面料上，涂覆量为40g/m2，在130℃的条件下烘干2min），最后在65℃ 的条件下定型 1min。
实施例2
一种水性涂层用阻燃树脂整理剂，所述各原料的重量份数分别为：聚醚类聚氨酯50份、改性聚磷酸铵5份、环状磷酸酯5份、碱溶涨类增稠剂2份、纳米级二氧化钛金红石型1份、木质素磺化物1.5份、封闭氮丙啶类架桥剂4份和水30份。
按照比例，在反应釜中加入水和木质素磺化物，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入改性聚磷酸铵和环状磷酸酯持续搅拌，再投入聚醚类聚氨酯，搅拌均匀后调整体系pH值，加入碱溶涨类增稠剂调整粘度，最后投入封闭氮丙啶类架桥剂，搅拌均匀。
一种水性涂层用阻燃树脂整理剂的使用方法，将涤纶平织面料进行退浆前处理后，将水性涂层用阻燃树脂整理剂涂覆到面料上，涂覆量为40g/m2，在130℃的条件下烘干2min），最后在65℃ 的条件下定型 1min。
实施例3
一种水性涂层用阻燃树脂整理剂，所述各原料的重量份数分别为：聚酯类聚氨酯15份、聚醚类聚氨酯15份、环状磷酸酯10份、季戊四醇磷酸酯乳液10份、聚氨酯缔合型增稠剂2份、纳米级二氧化钛金红石型1份、纤维素醚1.5份、封闭型异氰酸酯架桥剂3份和水50份。
按照比例，在反应釜中加入水和纤维素醚，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入环状磷酸酯和季戊四醇磷酸酯乳液持续搅拌，再投入聚酯类聚氨酯和聚醚类聚氨酯，搅拌均匀后调整体系pH值，加入聚氨酯缔合型增稠剂调整粘度，最后投入封闭型异氰酸酯架桥剂，搅拌均匀。
一种水性涂层用阻燃树脂整理剂的使用方法，将涤纶平织面料进行退浆前处理后，将水性涂层用阻燃树脂整理剂涂覆到面料上，涂覆量为40g/m2，在130℃的条件下烘干2min），最后在65℃ 的条件下定型 1min。
实施例4
一种水性涂层用阻燃树脂整理剂，所述各原料的重量份数分别为：聚酯类聚氨酯20份、聚醚类聚氨酯15份、改性聚磷酸铵10份、季戊四醇磷酸酯乳液10份、聚氨酯缔合型增稠剂2份、纳米级二氧化钛金红石型2份、木质素磺化物2份、封闭氮丙啶类架桥剂3份和水37份。
按照比例，在反应釜中加入水和木质素磺化物，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入改性聚磷酸铵和季戊四醇磷酸酯乳液持续搅拌，再投入聚酯类聚氨酯和聚醚类聚氨酯，搅拌均匀后调整体系pH值，加入聚氨酯缔合型增稠剂调整粘度，最后投入封闭氮丙啶类架桥剂，搅拌均匀。
一种水性涂层用阻燃树脂整理剂的使用方法，将涤纶平织面料进行退浆前处理后，将水性涂层用阻燃树脂整理剂涂覆到面料上，涂覆量为40g/m2，在130℃的条件下烘干2min），最后在65℃ 的条件下定型 1min。
实施例5
一种水性涂层用阻燃树脂整理剂，所述各原料的重量份数分别为：聚酯类聚氨酯15份、聚醚类聚氨酯20份、改性聚磷酸铵5份、环状磷酸酯5份、季戊四醇磷酸酯乳液10份、聚氨酯缔合型增稠剂1份、纳米级二氧化钛金红石型1份、纤维素醚0.5份、木质素磺化物0.5份、封闭型异氰酸酯架桥剂5份和水37.5份。
按照比例，在反应釜中加入水、纤维素醚和木质素磺化物，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入改性聚磷酸铵、环状磷酸酯和季戊四醇磷酸酯乳液持续搅拌，再投入聚酯类聚氨酯和聚醚类聚氨酯，搅拌均匀后调整体系pH值，加入聚氨酯缔合型增稠剂调整粘度，最后投入封闭型异氰酸酯架桥剂，搅拌均匀。
一种水性涂层用阻燃树脂整理剂的使用方法，将涤纶平织面料进行退浆前处理后，将水性涂层用阻燃树脂整理剂涂覆到面料上，涂覆量为40g/m2，在130℃的条件下烘干2min），最后在65℃ 的条件下定型 1min。
对比例1
与实施例5一致，只是缺少阻燃剂。
对比例2
与实施例5一致，只是缺少分散剂。
各实施例和对比例进行稳定性试验和阻燃性试验，采用阻燃标准GB/T 8410,结果见下表。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变形，这些改进和变形也应视为本发明的保护范围。
Claims (9)
1.一种水性涂层用阻燃树脂整理剂，其特征是，包括水性树脂、水性阻燃剂、水性树脂增稠剂、水性填料、水性分散剂、水性架桥剂和水。
2.根据权利要求1所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述各原料的重量份数分别为：水性树脂30-50份、水性阻燃剂10-20份、水性树脂增稠剂1-2份、水性填料1-2份、水性分散剂1-2份、水性架桥剂3-5份和水30-50份。
3.根据权利要求2所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述水性树脂为聚酯类聚氨酯或聚醚型聚氨酯中的一种或几种。
4.根据权利要求2所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述水性阻燃剂为改性聚磷酸铵、环状磷酸酯或季戊四醇磷酸酯乳液中的一种或几种。
5.根据权利要求2所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述水性树脂增稠剂为碱溶涨类增稠剂或聚氨酯缔合型增稠剂。
6.根据权利要求2所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述水性填料为纳米级二氧化钛金红石型。
7.根据权利要求2所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述水性分散剂为纤维素醚或木质素磺化物。
8.根据权利要求2所述的一种水性涂层用阻燃树脂整理剂，其特征是，所述水性架桥剂为封闭型异氰酸酯架桥剂或封闭氮丙啶类架桥剂。
9.根据以上任一权利要求所述的一种水性涂层用阻燃树脂整理剂的制备方法，其特征是，在反应釜中加入水和水性分散剂，投入纳米级二氧化钛金红石型，高速搅拌，搅拌均匀后投入水性阻燃剂持续搅拌，再投入水性树脂，搅拌均匀后调整体系pH值，加入水性树脂增稠剂调整粘度，最后投入水性架桥剂，搅拌均匀。
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