CN108558544A - A kind of aquatic amino acid phosphorus calcareous fertilisers - Google Patents

A kind of aquatic amino acid phosphorus calcareous fertilisers Download PDF

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Publication number
CN108558544A
CN108558544A CN201810649772.6A CN201810649772A CN108558544A CN 108558544 A CN108558544 A CN 108558544A CN 201810649772 A CN201810649772 A CN 201810649772A CN 108558544 A CN108558544 A CN 108558544A
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CN
China
Prior art keywords
amino acid
aquatic
water
calcareous fertilisers
fermentation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810649772.6A
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Chinese (zh)
Inventor
张�杰
张晓梦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dangshan County Luyuan Ecological Fertilizer Co Ltd
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Dangshan County Luyuan Ecological Fertilizer Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dangshan County Luyuan Ecological Fertilizer Co Ltd filed Critical Dangshan County Luyuan Ecological Fertilizer Co Ltd
Priority to CN201810649772.6A priority Critical patent/CN108558544A/en
Publication of CN108558544A publication Critical patent/CN108558544A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00Culture of aquatic animals
    • A01K61/50Culture of aquatic animals of shellfish
    • A01K61/59Culture of aquatic animals of shellfish of crustaceans, e.g. lobsters or shrimps
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

Abstract

The invention discloses a kind of aquatic amino acid phosphorus calcareous fertilisers, and the amino acid zymotic fluid of parts by weight 35~45% and the calcium monohydrogen phosphate of parts by weight 55~65% are sufficiently mixed, and obtain water-soluble phosphorus >=17%, water-soluble calcium >=8%, amino acid >=17%, the mixture of total nitrogen >=12%.The present invention combines calcium monohydrogen phosphate by amino acid zymotic fluid, water-soluble phosphorus content is greatly improved, the added value of calcium monohydrogen phosphate is directly improved into 2 times or more, while meeting the needs of nitrogen, water-soluble calcium and amino acid can also be provided, the combination that aquatic products fertilizer is become to aquatic products fertilizer and aquatic feeds considerably reduces the cost at aquaculture family, is particularly suitable for the cultivation of shrimp crab.

Description

A kind of aquatic amino acid phosphorus calcareous fertilisers
Technical field
The present invention relates to a kind of aquatic fertilizer more particularly to a kind of aquatic amino acid phosphorus calcareous fertilisers.
Background technology
It uses organic fertilizer and chemical fertilizer for pond extra-nutrition substance in aquaculture, cultivates planktonic organism, to be foster The aquatic livestock grown provides natural bait, and this method can significantly improve the productivity in pond, and obtain the effect of increasing both production and income Fruit.Urea is generally used to provide nitrogen in aquatic fertilizer, the chemical fertilizer such as ammonium hydrogen carbonate or calcium superphosphate provide phosphorus, are unfavorable for aquatic environment Holding, easily cause the generation of pond burst disease.Additionally generally existing utilization rate of fertilizer is low, turn water after lead to environment The problems such as single fertilizer leads to water body microelement deficiencies, output of aquatic products and quality decline is used for a long time in body eutrophication.
Calcium monohydrogen phosphate is divided into fertilizer grade and feed grade, and the standard of calcium hydrophosphate fodder is higher than fertilizer grade, feed grade phosphoric acid Hydrogen calcium is applied in feed processing as phosphorus, the calcium monohydrogen phosphate of calcium complement agent.Due to phosphorus in phosphorus calcium ratio therein and animal skeleton Calcium can be all dissolved in animal hydrochloric acid in gastric juice than closest, and calcium hydrophosphate fodder is generally acknowledged best both at home and abroad at present One of feed mineral additive.Calcium hydrophosphate fodder includes 3 types, wherein I types total phosphorus content in GB/T 22549-2008 It is required that >=16.5%, Chinese holly Soluble phosphorus >=14%, without water-soluble phosphorus, II type total phosphorus content >=19%, Chinese holly Soluble phosphorus >=16%, water-soluble phosphorus >=8%, Type III total phosphorus content >=21%, Chinese holly Soluble phosphorus >=18%, water-soluble phosphorus >=10%.Since Chinese holly Soluble phosphorus is not soluble in water, directly it is applied to It can cause largely to waste in aquatic products.
In addition water-soluble calcium, the amino acid etc. needed in aquaculture, is typically provided by aquatic feeds, and existing aquatic products is used Fertilizer is difficult to provide, and if necessary to all provide, needs the mixing of various raw materials, virtually increases the price of fertilizer, but Fertilizer can be used as and provide the effect of feed by not realizing.
Invention content
In order to solve the problems, such as current techniques, the purpose of the present invention is to provide a kind of aquatic amino acid phosphorus calcium Fertilizer.
In order to achieve the above objectives, the technology used in the present invention means are:A kind of aquatic amino acid phosphorus calcareous fertilisers, by weight The amino acid zymotic fluid and the calcium monohydrogen phosphate of parts by weight 55~65% of part 35~45% are sufficiently mixed, and obtain water-soluble phosphorus >=17%, water-soluble Calcium >=8%, amino acid >=17%, the mixture of total nitrogen >=12%.
Further, the amino acid zymotic fluid refers to:It is pre- through being saccharified using soy meal and cornstarch as fermentation raw material Processing, obtained saccharified liquid are prepared with strain liquid mixed fermentation.
Further, the saccharification, which pre-processes, refers to:After soy meal and cornstarch are mixed, carbohydrase, sugar is added Change 30~70h of time, 30~35 DEG C of temperature, wherein shared parts by weight are:Soy meal 30~70, cornstarch 30~70, saccharification Enzyme 1~7, deionized water 40~80;The soy meal and cornstarch cross 80 mesh sieve.
Further, the preparation method of the strain liquid is:Brevibacterium flavum is through test tube, triangular flask, one cubic metre of hair Fermentation tank three-level expands culture, using the tryptone containing 4%NaCl+soya bean peptone agar+soya bean juice culture medium, fermentation temperature 20~ It 25 DEG C, is controlled in 60~80h per level-one fermentation time.
Further, the saccharified liquid refers to strain liquid mixed fermentation:Strain liquid, setting temperature are added into saccharified liquid 20~25 DEG C of degree, ferment 60~80h, wherein volume ratio, saccharified liquid 90~95%, strain liquid 5~10%.Bacterial strain in the strain liquid Content is 500,000,000/ml.
The beneficial effects of the present invention are:Calcium monohydrogen phosphate is combined by amino acid zymotic fluid, is greatly improved water-soluble The added value of calcium monohydrogen phosphate is directly improved 2 times or more, while meeting the needs of nitrogen by phosphorus content, moreover it is possible to be provided water-soluble Aquatic products fertilizer is become the combination of aquatic products fertilizer and aquatic feeds by calcium and amino acid, considerably reduce aquaculture family at This, is particularly suitable for the cultivation of shrimp crab.
Specific implementation mode
Present disclosure is further elaborated below by embodiment.
A kind of aquatic amino acid phosphorus calcareous fertilisers, by the amino acid zymotic fluid of parts by weight 35~45% and parts by weight 55~65% Calcium monohydrogen phosphate is sufficiently mixed, and obtains water-soluble phosphorus >=17%, water-soluble calcium >=8%, amino acid >=17%, the mixture of total nitrogen >=12%.
Amino acid zymotic fluid is 100% with calcium monohydrogen phosphate mixed proportion, and the ratio of amino acid zymotic fluid and calcium monohydrogen phosphate cannot The upper limit beyond above range or lower limit.When the amount of amino acid zymotic fluid is less than 35%, after being mixed with calcium monohydrogen phosphate, water is examined Although Soluble phosphorus is improved with content in original calcium monohydrogen phosphate, but change less, and the content of amino acid and nitrogen provides not enough. When the content of amino acid zymotic fluid is more than 45%, causes the offer raw material of calcium monohydrogen phosphate that cannot meet, water-soluble phosphorus, water can be caused The content of molten calcium declines, meanwhile, in the case where considering cost, the price of calcium monohydrogen phosphate is low, and the price of amino acid zymotic fluid Height, to reach an optimal value, the usage amount of calcium monohydrogen phosphate is the bigger the better more than the value of amino acid zymotic fluid, but needs full Sufficient mentioned component requirement.
The mixture that amino acid zymotic fluid obtains after being mixed in proportion with calcium monohydrogen phosphate is powdery, can be directly granulated.
The amino acid zymotic fluid refers to:Using soy meal and cornstarch as fermentation raw material, pre-processes, obtain through saccharification Saccharified liquid and strain liquid mixed fermentation prepare.
The saccharification pre-processes:After soy meal and cornstarch are mixed, addition carbohydrase, saccharificatinn period 30~ 70h, 30~35 DEG C of temperature, wherein shared parts by weight are:Soy meal 30~70, cornstarch 30~70, carbohydrase 1~7, go from Sub- water 40~80;The soy meal and cornstarch cross 80 mesh sieve.
The preparation method of the strain liquid is:Brevibacterium flavum expands through test tube, triangular flask, one cubic metre of fermentation tank three-level Culture, using the tryptone containing 4%NaCl+soya bean peptone agar+soya bean juice culture medium, 20~25 DEG C of fermentation temperature is sent out per level-one The ferment time controls in 60~80h.
The saccharified liquid refers to strain liquid mixed fermentation:It is added strain liquid into saccharified liquid, 20~25 DEG C of set temperature, Ferment 60~80h, wherein volume ratio, saccharified liquid 90~95%, strain liquid 5~10%.In the strain liquid bacterial strain content be 500,000,000/ ml。
The present invention combines calcium monohydrogen phosphate by amino acid zymotic fluid, and water-soluble phosphorus content is greatly improved, directly by phosphorus The added value of sour hydrogen calcium improves 2 times or more, while meeting the needs of nitrogen, moreover it is possible to water-soluble calcium and amino acid is provided, by water Production fertilizer becomes the combination of aquatic products fertilizer and aquatic feeds, considerably reduces the cost at aquaculture family, is particularly suitable for shrimp crab Cultivation.
Application embodiment is only intended to illustrate that technical characteristic disclosed in the present application, those skilled in the art pass through simple Carried out change is replaced, the range that the application is protected is still fallen within.

Claims (6)

1. a kind of aquatic amino acid phosphorus calcareous fertilisers, it is characterised in that:By the amino acid zymotic fluid and parts by weight of parts by weight 35~45% 55~65% calcium monohydrogen phosphate is sufficiently mixed, and obtains water-soluble phosphorus >=17%, water-soluble calcium >=8%, amino acid >=17%, total nitrogen >=12% Mixture.
2. aquatic amino acid phosphorus calcareous fertilisers according to claim 1, it is characterised in that:The amino acid zymotic fluid refers to: Using soy meal and cornstarch as fermentation raw material, pre-processed through saccharification, obtained saccharified liquid is prepared with strain liquid mixed fermentation.
3. aquatic amino acid phosphorus calcareous fertilisers according to claim 2, it is characterised in that:The saccharification pre-processes:It will After soy meal and cornstarch mixing, carbohydrase, 30~70h of saccharificatinn period, 30~35 DEG C of temperature, wherein shared parts by weight is added For:Soy meal 30~70, cornstarch 30~70, carbohydrase 1~7, deionized water 40~80;The soy meal and cornstarch Cross 80 mesh sieve.
4. aquatic amino acid phosphorus calcareous fertilisers according to claim 2, it is characterised in that:The preparation method of the strain liquid It is:Brevibacterium flavum is through test tube, triangular flask, and one cubic metre of fermentation tank three-level expands culture, using the tryptone containing 4%NaCl+ Soya bean peptone agar+soya bean juice culture medium, 20~25 DEG C of fermentation temperature are controlled per level-one fermentation time in 60~80h.
5. aquatic amino acid phosphorus calcareous fertilisers according to claim 2, it is characterised in that:The saccharified liquid is mixed with strain liquid Fermentation refers to:Strain liquid is added into saccharified liquid, 20~25 DEG C of set temperature, ferment 60~80h, wherein volume ratio, saccharified liquid 90~95%, strain liquid 5~10%.
6. aquatic amino acid phosphorus calcareous fertilisers according to claim 5, it is characterised in that:Bacterial strain content is in the strain liquid 500000000/ml.
CN201810649772.6A 2018-06-22 2018-06-22 A kind of aquatic amino acid phosphorus calcareous fertilisers Pending CN108558544A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810649772.6A CN108558544A (en) 2018-06-22 2018-06-22 A kind of aquatic amino acid phosphorus calcareous fertilisers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102351574A (en) * 2011-09-16 2012-02-15 浙江大学 Method for preparing amino acid calcium fertilizer by using coenzyme Q10 fermentation liquor
CN102765986A (en) * 2012-06-29 2012-11-07 安徽蒙特尔肥业有限公司 Organic calcium phosphate fertilizer and preparation method thereof
CN102816001A (en) * 2012-08-21 2012-12-12 武汉市洪山吕墩氨基酸厂 Special amino acid fertilizer solution for aquaculture and preparation method thereof
CN103351200A (en) * 2013-07-16 2013-10-16 吴锦华 Marine organism calcium magnesium fertilizer
CN104397325A (en) * 2014-11-24 2015-03-11 河南恒瑞源实业有限公司 Preparation method for livestock fattening feed containing eucommia ulmoides fine powder
CN104726510A (en) * 2013-12-24 2015-06-24 中粮生物化学(安徽)股份有限公司 Method for preparing lysine through fermenting
CN104788207A (en) * 2015-04-22 2015-07-22 天津贾立明蚯蚓养殖有限公司 Earthworm amino acid secondary nutrient fertilizer prepared through chelated method and preparation method thereof
CN105399465A (en) * 2015-11-05 2016-03-16 湖北大学 Calcium hydrate polypeptide fish guano as well as preparation method and application thereof
CN108164325A (en) * 2017-12-26 2018-06-15 深圳地天国际生物工程科技有限公司 It is a kind of for the rich water agent of aquaculture and its preparation process

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102351574A (en) * 2011-09-16 2012-02-15 浙江大学 Method for preparing amino acid calcium fertilizer by using coenzyme Q10 fermentation liquor
CN102765986A (en) * 2012-06-29 2012-11-07 安徽蒙特尔肥业有限公司 Organic calcium phosphate fertilizer and preparation method thereof
CN102816001A (en) * 2012-08-21 2012-12-12 武汉市洪山吕墩氨基酸厂 Special amino acid fertilizer solution for aquaculture and preparation method thereof
CN103351200A (en) * 2013-07-16 2013-10-16 吴锦华 Marine organism calcium magnesium fertilizer
CN104726510A (en) * 2013-12-24 2015-06-24 中粮生物化学(安徽)股份有限公司 Method for preparing lysine through fermenting
CN104397325A (en) * 2014-11-24 2015-03-11 河南恒瑞源实业有限公司 Preparation method for livestock fattening feed containing eucommia ulmoides fine powder
CN104788207A (en) * 2015-04-22 2015-07-22 天津贾立明蚯蚓养殖有限公司 Earthworm amino acid secondary nutrient fertilizer prepared through chelated method and preparation method thereof
CN105399465A (en) * 2015-11-05 2016-03-16 湖北大学 Calcium hydrate polypeptide fish guano as well as preparation method and application thereof
CN108164325A (en) * 2017-12-26 2018-06-15 深圳地天国际生物工程科技有限公司 It is a kind of for the rich water agent of aquaculture and its preparation process

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Application publication date: 20180921

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