CN108546426A - A kind of fiber marble lacquer and preparation method thereof - Google Patents
A kind of fiber marble lacquer and preparation method thereof Download PDFInfo
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- CN108546426A CN108546426A CN201810288136.5A CN201810288136A CN108546426A CN 108546426 A CN108546426 A CN 108546426A CN 201810288136 A CN201810288136 A CN 201810288136A CN 108546426 A CN108546426 A CN 108546426A
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- taken
- fiber
- bentonite
- added
- dispersion liquid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of fiber marble lacquers, it is made of the raw material of following weight parts：Silicone acrylic emulsion 110 120, hydroxyethyl cellulose 46, lauryl mercaptan 23, tributyl tin trichloride 0.1 0.3, Diacetone Acrylamide 0.8 1, glass fibre 57,2 mercaptobenzimidazoles 0.4 1, octyl epoxy stearate 24, bentonite 10 13, aluminum stearate 23, the present invention handles bentonite using cellulose, effectively improve bentonitic surface toughness, then pass through surface treatment, improve its surface-active, its dispersion compatibility between silicone acrylic emulsion is enhanced, to improve the uniform and stable property of finished product paint film.
Description
Technical field
The invention belongs to the fields of painting, and in particular to a kind of fiber marble lacquer and preparation method thereof.
Background technology
Marble lacquer is also known as parian paint, imitation marble paint etc., as people chase after the art of fitting-out work
It asks, also with lithotome, especially high quality natural stone resource is petered out, the artificial high Scagliola of colored drawing, milli
It is unquestionable to become in art coatings, most there are a kind of product marbles of application prospect compared with stone material, there is following spy
Point：（1）Easily construction：Compared with stone material, parian paint can be used for different types of metope, cylinder, top surface；（2）Protective：
As real stone material, waterproof is not influenced by environmental pollution；（3）Transport facility：It is lighter than Bartlit, it is easy transport；（4）
Color：Multiple color is available；（5）Expense：The price of product cheaper than natural marble 70%.The product main component is
Natural marble powder, and have marmorean effect.Because of this, the production of lacquer, parian paint has become and has built
Build the hot issue of furnishing fields.In recent years, stone-simulative paint face layer was in civil buildings exterior wall, interior decoration, Yi Jiyuan
Woods modeling stone field has been obtained for being widely applied, with serious, the elegant and harmonious feeling with back to nature；
However, the dispersion poor compatibility between the inorganic filler being added in commercially available marble lacquer and organic emulsion, is easily reduced paint
The uniform and stable property intensity of film, meanwhile, the toughness of commercially available film coated surface is relatively low, and abrasion resistance is poor.
Invention content
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of fiber marble lacquer and its preparations
Method.
To achieve the above object, the present invention uses following technical scheme：
A kind of fiber marble lacquer, it is made of the raw material of following weight parts：
It is silicone acrylic emulsion 110-120, hydroxyethyl cellulose 4-6, lauryl mercaptan 2-3, tributyl tin trichloride 0.1-0.3, double
Acetone acrylamide 0.8-1, glass fibre 5-7,2-mercaptobenzimidazole 0.4-1, octyl epoxy stearate 2-4, bentonite 10-
13, aluminum stearate 2-3.
A kind of preparation method of fiber marble lacquer, includes the following steps：
（1）Bentonite is taken, is calcined 1-2 hours at 700-750 DEG C, is cooled to room temperature, wears into fine powder, it is mixed with hydroxyethyl cellulose
It closes, is added in the deionized water of 3-4 times of mixture weight, it is 10-20 minutes ultrasonic, obtain bentonite dispersion liquid；
（2）Diacetone Acrylamide is taken, is added in the deionized water of 120-130 times of its weight, stirs evenly, it is molten to obtain amide
Liquid；
（3）2-mercaptobenzimidazole is taken, is added in the absolute ethyl alcohol of 5-7 times of its weight, stirs evenly, raising temperature is 60-
It 70 DEG C, is mixed with lauryl mercaptan, insulated and stirred 10-20 minutes obtains compound alcoholic solution；
（4）Glass fibre, aluminum stearate mixing are taken, insulated and stirred 15-20 minutes at 60-70 DEG C, it is molten to be added to above-mentioned amide
Liquid, it is 2-3 minutes ultrasonic, obtain fiber amide solution；
（5）Above-mentioned bentonite dispersion liquid, compound alcoholic solution, the mixing of fiber amide solution are taken, it is 10-20 minutes ultrasonic, it is distilled off
Ethyl alcohol obtains composite fibre dispersion liquid；
（6）Above-mentioned composite fibre dispersion liquid is taken, is mixed with remaining each raw material, 1000-1200 revs/min is stirred 1-2 hours to get institute
State fiber marble lacquer.
Advantages of the present invention：
The present invention by bentonite using cellulose handle, effectively improve bentonitic surface toughness, then by surface at
Reason, improves its surface-active, its dispersion compatibility between silicone acrylic emulsion is enhanced, to improve the uniform of finished product paint film
Stability.The coating surface intensity of the present invention is high, and impact resistance is strong, and comprehensive performance is superior.
Specific implementation mode
Embodiment 1
A kind of fiber marble lacquer, it is made of the raw material of following weight parts：
Silicone acrylic emulsion 110, hydroxyethyl cellulose 4, lauryl mercaptan 2, tributyl tin trichloride 0.1, Diacetone Acrylamide
0.8-1, glass fibre 5,2-mercaptobenzimidazole 0.4, octyl epoxy stearate 2, bentonite 10, aluminum stearate 2.
A kind of preparation method of fiber marble lacquer, includes the following steps：
（1）Bentonite is taken, is calcined 1 hour at 700 DEG C, is cooled to room temperature, wears into fine powder, mixed with hydroxyethyl cellulose, added
Enter into the deionized water of 3 times of mixture weight, ultrasound 10 minutes obtains bentonite dispersion liquid；
（2）Diacetone Acrylamide is taken, is added in the deionized water of 120 times of its weight, is stirred evenly, obtain amide solution；
（3）2-mercaptobenzimidazole is taken, is added in the absolute ethyl alcohol of 5 times of its weight, stirs evenly, it is 60 DEG C to increase temperature,
It is mixed with lauryl mercaptan, insulated and stirred 10 minutes obtains compound alcoholic solution；
（4）Glass fibre, aluminum stearate mixing, insulated and stirred 15 minutes at 60 DEG C is taken to be added to above-mentioned amide solution, ultrasound
2 minutes, obtain fiber amide solution；
（5）Take above-mentioned bentonite dispersion liquid, compound alcoholic solution, the mixing of fiber amide solution, ultrasound 10 minutes that second is distilled off
Alcohol obtains composite fibre dispersion liquid；
（6）Above-mentioned composite fibre dispersion liquid is taken, is mixed with remaining each raw material, 1000 revs/min are stirred 1 hour to get the fiber
Marble lacquer.
Embodiment 2
A kind of fiber marble lacquer, it is made of the raw material of following weight parts：
Silicone acrylic emulsion 120, hydroxyethyl cellulose 6, lauryl mercaptan 3, tributyl tin trichloride 0.3, Diacetone Acrylamide
1, glass fibre 7,2-mercaptobenzimidazole 1, octyl epoxy stearate 4, bentonite 13, aluminum stearate 3.
A kind of preparation method of fiber marble lacquer, include the following steps：
（1）Bentonite is taken, is calcined 2 hours at 750 DEG C, is cooled to room temperature, wears into fine powder, mixed with hydroxyethyl cellulose, added
Enter into the deionized water of 4 times of mixture weight, ultrasound 20 minutes obtains bentonite dispersion liquid；
（2）Diacetone Acrylamide is taken, is added in the deionized water of 130 times of its weight, is stirred evenly, obtain amide solution；
（3）2-mercaptobenzimidazole is taken, is added in the absolute ethyl alcohol of 7 times of its weight, stirs evenly, it is 70 DEG C to increase temperature,
It is mixed with lauryl mercaptan, insulated and stirred 20 minutes obtains compound alcoholic solution；
（4）Glass fibre, aluminum stearate mixing are taken, insulated and stirred 20 minutes at 70 DEG C are added to above-mentioned amide solution, surpass 3
Minute, obtain fiber amide solution；
（5）Take above-mentioned bentonite dispersion liquid, compound alcoholic solution, the mixing of fiber amide solution, ultrasound 20 minutes that second is distilled off
Alcohol obtains composite fibre dispersion liquid；
（6）Above-mentioned composite fibre dispersion liquid is taken, is mixed with remaining each raw material, 1200 revs/min are stirred 2 hours to get the fiber
Marble lacquer.
Claims (2)
1. a kind of fiber marble lacquer, which is characterized in that it is made of the raw material of following weight parts：
It is silicone acrylic emulsion 110-120, hydroxyethyl cellulose 4-6, lauryl mercaptan 2-3, tributyl tin trichloride 0.1-0.3, double
Acetone acrylamide 0.8-1, glass fibre 5-7,2-mercaptobenzimidazole 0.4-1, octyl epoxy stearate 2-4, bentonite 10-
13, aluminum stearate 2-3.
2. a kind of preparation method of fiber marble lacquer as described in claim 1, which is characterized in that include the following steps：
（1）Bentonite is taken, is calcined 1-2 hours at 700-750 DEG C, is cooled to room temperature, wears into fine powder, it is mixed with hydroxyethyl cellulose
It closes, is added in the deionized water of 3-4 times of mixture weight, it is 10-20 minutes ultrasonic, obtain bentonite dispersion liquid；
（2）Diacetone Acrylamide is taken, is added in the deionized water of 120-130 times of its weight, stirs evenly, it is molten to obtain amide
Liquid；
（3）2-mercaptobenzimidazole is taken, is added in the absolute ethyl alcohol of 5-7 times of its weight, stirs evenly, raising temperature is 60-
It 70 DEG C, is mixed with lauryl mercaptan, insulated and stirred 10-20 minutes obtains compound alcoholic solution；
（4）Glass fibre, aluminum stearate mixing are taken, insulated and stirred 15-20 minutes at 60-70 DEG C, it is molten to be added to above-mentioned amide
Liquid, it is 2-3 minutes ultrasonic, obtain fiber amide solution；
（5）Above-mentioned bentonite dispersion liquid, compound alcoholic solution, the mixing of fiber amide solution are taken, it is 10-20 minutes ultrasonic, it is distilled off
Ethyl alcohol obtains composite fibre dispersion liquid；
（6）Above-mentioned composite fibre dispersion liquid is taken, is mixed with remaining each raw material, 1000-1200 revs/min is stirred 1-2 hours to get institute
State fiber marble lacquer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810288136.5A CN108546426A (en) | 2018-04-03 | 2018-04-03 | A kind of fiber marble lacquer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810288136.5A CN108546426A (en) | 2018-04-03 | 2018-04-03 | A kind of fiber marble lacquer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108546426A true CN108546426A (en) | 2018-09-18 |
Family
ID=63513895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810288136.5A Withdrawn CN108546426A (en) | 2018-04-03 | 2018-04-03 | A kind of fiber marble lacquer and preparation method thereof |
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| Country | Link |
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| CN (1) | CN108546426A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114085581A (en) * | 2022-01-05 | 2022-02-25 | 广东嘉宝莉科技材料有限公司 | Silk color artistic coating and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740177A (en) * | 2013-12-06 | 2014-04-23 | 青岛益群漆业集团有限公司 | Development of super weather-proof marble coating rock slice paint |
| CN105219197A (en) * | 2015-11-04 | 2016-01-06 | 赵彬 | A kind of production formula of true mineral varnish and technique |
| CN105601166A (en) * | 2016-01-27 | 2016-05-25 | 广东施彩涂料有限公司 | Stone-like coating resisting temperature variation construction and preparation method thereof |
-
2018
- 2018-04-03 CN CN201810288136.5A patent/CN108546426A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740177A (en) * | 2013-12-06 | 2014-04-23 | 青岛益群漆业集团有限公司 | Development of super weather-proof marble coating rock slice paint |
| CN105219197A (en) * | 2015-11-04 | 2016-01-06 | 赵彬 | A kind of production formula of true mineral varnish and technique |
| CN105601166A (en) * | 2016-01-27 | 2016-05-25 | 广东施彩涂料有限公司 | Stone-like coating resisting temperature variation construction and preparation method thereof |
Non-Patent Citations (6)
| Title |
|---|
| 任责忠等: "《实用有机化学辞典》", 31 July 1997, 高等教育出版社 * |
| 徐思亭等: "《塑料材料与助剂》", 31 July 2007, 天津大学出版社 * |
| 汪多仁: "《合成树脂与工程塑料的生产技术》", 31 August 2001, 中国轻工业出版社 * |
| 程天恩等: "《防菌防霉剂手册》", 31 March 1993, 上海科学技术文献出版社 * |
| 韩哲文等: "《高分子科学教程（第二版）》", 28 February 2011, 华东理工大学出版社 * |
| 马世昌: "《化学物质辞典》", 30 April 1999, 陕西科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114085581A (en) * | 2022-01-05 | 2022-02-25 | 广东嘉宝莉科技材料有限公司 | Silk color artistic coating and preparation method and application thereof |
| CN114085581B (en) * | 2022-01-05 | 2022-09-09 | 广东嘉宝莉科技材料有限公司 | Silk color artistic coating and preparation method and application thereof |
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Application publication date: 20180918 |
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