CN108508098B - 凝胶渗透色谱技术检测古马隆树脂中残油含量的方法 - Google Patents
凝胶渗透色谱技术检测古马隆树脂中残油含量的方法 Download PDFInfo
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- CN108508098B CN108508098B CN201611144674.4A CN201611144674A CN108508098B CN 108508098 B CN108508098 B CN 108508098B CN 201611144674 A CN201611144674 A CN 201611144674A CN 108508098 B CN108508098 B CN 108508098B
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- 238000005227 gel permeation chromatography Methods 0.000 title claims abstract description 29
- 238000005516 engineering process Methods 0.000 title claims abstract description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 12
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims abstract description 9
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 21
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- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 2
- LTEQMZWBSYACLV-UHFFFAOYSA-N Hexylbenzene Chemical compound CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
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- 238000012986 modification Methods 0.000 description 2
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
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- 239000008117 stearic acid Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/62—Detectors specially adapted therefor
- G01N30/74—Optical detectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
- B01J20/291—Gel sorbents
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- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
指标/牌号 | G-90 | G-100N | V-120 | V-120S | L-5 | L-20 |
外观 | 液状 | 液状 | ||||
色数 | 16以下 | 16以下 | 16以下 | 16以下 | 茶褐色 | 黑褐色 |
软化点(℃) | 90 | 100 | 120 | 120 | - | - |
粘度(Ps:25℃) | - | - | - | - | 5 | 20 |
羟值(KOH mg/g) | 25 | 25 | 30 | 30 | 50 | 67 |
酸值(KOH mg/g) | 1以下 | 1以下 | 1以下 | 1以下 | 1.0 | 1.3 |
比重(15/4) | 1.11 | 1.12 | 1.14 | 1.14 | 1.09 | 1.10 |
溴值(g/100g) | 9 | 11 | 6 | 7 | 48 | 55 |
Claims (5)
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CN201611144674.4A CN108508098B (zh) | 2017-02-27 | 2017-02-27 | 凝胶渗透色谱技术检测古马隆树脂中残油含量的方法 |
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CN108508098B true CN108508098B (zh) | 2020-08-14 |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001221786A (ja) * | 2000-02-07 | 2001-08-17 | Shin Etsu Chem Co Ltd | 塩化メチレン残存量の測定方法 |
JP2002168844A (ja) * | 2000-11-30 | 2002-06-14 | Hitachi Chemical Dupont Microsystems Ltd | ポリイミド前駆体樹脂膜の残存溶媒量測定方法及びこの方法によるベーク条件出し方法 |
CN101281176A (zh) * | 2008-05-16 | 2008-10-08 | 中国石油兰州石油化工公司 | 用凝胶渗透色谱分析c5加氢石油树脂相对分子量及分布的方法 |
CN102958979A (zh) * | 2011-02-04 | 2013-03-06 | 株式会社艾迪科 | 具有受阻胺骨架的化合物以及树脂组合物 |
CN103454355A (zh) * | 2013-08-28 | 2013-12-18 | 天津爱勒易医药材料有限公司 | 一种聚丙烯酸树脂乳胶液(肠溶型)产品中单体含量的分析检测方法 |
CN105044245A (zh) * | 2015-08-31 | 2015-11-11 | 山东蓝帆化工有限公司 | Pvc糊树脂残留有机物测定方法 |
CN105510508A (zh) * | 2016-02-15 | 2016-04-20 | 北京泛博科技有限责任公司 | 酚醛树脂中小分子残余物含量的检测方法 |
-
2017
- 2017-02-27 CN CN201611144674.4A patent/CN108508098B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001221786A (ja) * | 2000-02-07 | 2001-08-17 | Shin Etsu Chem Co Ltd | 塩化メチレン残存量の測定方法 |
JP2002168844A (ja) * | 2000-11-30 | 2002-06-14 | Hitachi Chemical Dupont Microsystems Ltd | ポリイミド前駆体樹脂膜の残存溶媒量測定方法及びこの方法によるベーク条件出し方法 |
CN101281176A (zh) * | 2008-05-16 | 2008-10-08 | 中国石油兰州石油化工公司 | 用凝胶渗透色谱分析c5加氢石油树脂相对分子量及分布的方法 |
CN102958979A (zh) * | 2011-02-04 | 2013-03-06 | 株式会社艾迪科 | 具有受阻胺骨架的化合物以及树脂组合物 |
CN103454355A (zh) * | 2013-08-28 | 2013-12-18 | 天津爱勒易医药材料有限公司 | 一种聚丙烯酸树脂乳胶液(肠溶型)产品中单体含量的分析检测方法 |
CN105044245A (zh) * | 2015-08-31 | 2015-11-11 | 山东蓝帆化工有限公司 | Pvc糊树脂残留有机物测定方法 |
CN105510508A (zh) * | 2016-02-15 | 2016-04-20 | 北京泛博科技有限责任公司 | 酚醛树脂中小分子残余物含量的检测方法 |
Non-Patent Citations (2)
Title |
---|
High Performance Liquid Chromatographic Determination of Residual Monomer Released from Heat-Cured Acrylic Resin.An In Vivo Study;Raghuwar D. Singh, MDS等;《Journal of Prosthodontics》;20130731;第22卷(第5期);358-361 * |
气相色谱法测定聚氯乙烯树脂中残留氯乙烯单体含量的改进;谷惠莉;《天津化工》;20120531;第26卷(第3期);47-48 * |
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Address after: Weisan Road Chemical Office Building, Baoshan District, Shanghai, 2004 Applicant after: Baowu Carbon Material Technology Co., Ltd. Address before: No. 3501 Tongji Road, Baoshan District, Shanghai 201900 Applicant before: Chemical Co., Ltd. of Baoshan Iron and Steel Group, Shanghai |
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CP01 | Change in the name or title of a patent holder |
Address after: Weisan Road Chemical Office Building, Baoshan District, Shanghai, 2004 Patentee after: Baowu Carbon Technology Co.,Ltd. Address before: Weisan Road Chemical Office Building, Baoshan District, Shanghai, 2004 Patentee before: BAOWU CARBON MATERIAL TECHNOLOGY Co.,Ltd. |
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