CN108456469A - Agricultural machinery sealing wax and preparation method thereof - Google Patents
Agricultural machinery sealing wax and preparation method thereof Download PDFInfo
- Publication number
- CN108456469A CN108456469A CN201810036352.0A CN201810036352A CN108456469A CN 108456469 A CN108456469 A CN 108456469A CN 201810036352 A CN201810036352 A CN 201810036352A CN 108456469 A CN108456469 A CN 108456469A
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- China
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- parts
- agricultural machinery
- water
- sealing wax
- machinery sealing
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- Granted
Links
- 239000012173 sealing wax Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920003180 amino resin Polymers 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 15
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 14
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 10
- 239000000080 wetting agent Substances 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 6
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical group CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 239000006184 cosolvent Substances 0.000 claims description 4
- 229960002887 deanol Drugs 0.000 claims description 4
- 239000012972 dimethylethanolamine Substances 0.000 claims description 4
- 230000007613 environmental effect Effects 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 15
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 7
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000002242 deionisation method Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229920003148 Eudragit® E polymer Polymers 0.000 description 2
- NEDGUIRITORSKL-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;2-(dimethylamino)ethyl 2-methylprop-2-enoate;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.CCCCOC(=O)C(C)=C.CN(C)CCOC(=O)C(C)=C NEDGUIRITORSKL-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 241000219122 Cucurbita Species 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 239000000159 acid neutralizing agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000009318 large scale farming Methods 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Abstract
The invention discloses a kind of agricultural machinery sealing waxes and preparation method thereof, belong to paint field, and formula is as follows count by weight percentage：Water-base resin：40 60 parts of water-based acrylic resin, 10 15 parts of water-compatible amino resin；Auxiliary agent：10 20 parts of environmentally friendly solvent, 15 parts of neutralizer, 0.2 0.4 parts of antifoaming agent, 0.2 0.5 parts of levelling agent, 0.3 0.6 parts of substrate wetting agents, 40 60 parts of deionized water.Using preparation method provided by the invention, a kind of environmentally friendly, compact in paint film stable and uniform agricultural machinery sealing wax can be prepared, solves the problems, such as existing agricultural machinery paint.
Description
Technical field
The invention belongs to technical field of coatings more particularly to a kind of agricultural machinery sealing wax and preparation method thereof.
Background technology
China is used as grain big country, the use of farm implements to have long history, and in today's society, agricultural realizes the modern times
Change, large-scale Farming and harvesting have large-scale farm machinery, this is the embodiment of social progress, but traditional agricultural machinery
There is no being substituted under the tide of mechanization, because traditional agricultural machinery is easy to use, flexible, it is convenient for carrying, in grain-production
It is essential, and with the present improvement of people's living standards, agricultural machinery is applied to gardens gardening, gourd, fruit and vegetable, flowers kind
The numerous areas such as plant, people plant a little satisfactions and become a kind of fashion from the vegetables of household in a little flowers and plants of Around the house kind,
It allows people's more love life, gets close to nature, enjoy health.So modern agricultural machinery goes back quilt in addition to maintain traditional use function
The label of culture is sticked, object of the good agricultural machinery even as collection is also particularly important so for its appearance.Agriculture
The appearance of machine depends greatly on the coating on its surface, this just proposes strict requirements, mesh to the coating in the field
Preceding coating common problem is：
(1) existing with painting based on solvent type, it needs to solve the problems, such as that pollution is big, unsafe；
(2) there are apparent gaps with solvent based product for the appearance properties such as richness of existing water paint product；
(3) the dip-coating effect of existing water paint product is difficult to coordinate blistering and increase the balance of coating thickness, that is, works as coating
When viscosity is low, it is not likely to produce blistering, but paint film is very thin, cannot met the requirements, vice versa；
(4) existing water paint product throwing slot rear stability has to be hoisted.
Invention content
Technical problem to be solved by the invention is to provide it is a kind of environmental protection, compact in paint film stable and uniform agricultural machinery sealing wax,
It can solve the problems, such as existing agricultural machinery paint.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of agricultural machinery sealing wax, formula is by weight
Percentage calculation is as follows：Water-base resin：40-60 parts of water-based acrylic resin, 10-15 parts of water-compatible amino resin；Auxiliary agent：Environmental protection is molten
10-20 parts of agent, 0.2-0.4 parts of antifoaming agent, 0.2-0.5 parts of levelling agent, 0.3-0.6 parts of substrate wetting agents, is gone 1-5 parts of neutralizer
40-60 parts of ionized water.
Further, the water-based acrylic resin is Eudragit E A1621A.
Further, the water-compatible amino resin is Amino resin 5717W, one kind in cyanogen spy 303 or two
Kind.
Further, the environmentally friendly cosolvent is two or three in ethylene glycol, propylene glycol monomethyl ether, alcohol.
Further, the neutralizer is one or both of dimethylethanolamine, AMP-95.
Further, used additives are made in the defoaming that used additives TEGO-902w, BYK are made in the deaeration that the antifoaming agent is TEGO
Two kinds of mixtures of BYK-024.
Further, the levelling agent is one or both of BYK-331, TEGO-4100.
Further, the substrate wetting agents are one or both of BASF-3322, TEGO-270.
It is using agricultural machinery advantageous effect caused by sealing wax provided by the present invention：
(1) water-base resin system is selected, VOC≤80g/L, smell is very low, more environmentally-friendly；
(2) different types of antifoaming agent is selected to be compounded, balance blistering solves system air bubble problem, with asking for film thickness
Topic improves film effect；
(3) suitable environmentally friendly solvent compounding is selected, the stability that coating stores in dip-coating paint bath is improved；
(4) water-based acrylic resin and water-compatible amino resin high-temperature cross-linking are selected, compact in paint film degree is improved, is improved plentiful
Degree.
The present invention also provides a kind of preparation methods of agricultural machinery sealing wax, can prepare above-mentioned agricultural machinery sealing wax, step is such as
Under：
Water-based acrylic resin is added in stock pot according to the raw material proportioning, adds environmentally friendly solvent by step a,
It is stirred 2-3 minutes with the speed of 450-500r/min.
Step b is added neutralizer and adjusts pH value, with the speed of 450-500r/min while stirring according to the raw material proportioning
Degree stirring 2-3 minutes.
Step c, according to the raw material proportioning, with the speed of 450-500r/min while stirring by amino resins, antifoaming agent,
Moistening flatting agent, deionized water are sequentially added into, and are stirred 10-15 minutes with the speed of 1100-1200r/min.
Specific implementation mode
The present invention will be further described in detail with reference to the specific embodiments.
A kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, formula is count by weight percentage such as
Under：Water-base resin：40-60 parts of water-based acrylic resin, 10-15 parts of water-compatible amino resin；Auxiliary agent：10-20 parts of environmentally friendly solvent, in
With 1-5 parts of agent, 0.2-0.4 parts of antifoaming agent, 0.2-0.5 parts of levelling agent, 0.3-0.6 parts of substrate wetting agents, deionized water 40-60
Part.
Sealing wax provided in an embodiment of the present invention selects water soluble acrylic acid dispersion and water-compatible amino resin, passes through 120 DEG C
High-temperature baking crosslinking curing obtains the water-based stoving paint coating of high glaze, high-decoration, wherein the water paint VOC prepared≤
80g/L, smell is very low, prevents pollution environment；It selects different types of antifoaming agent to be compounded, solves system air bubble problem；
Suitable environmentally friendly solvent compounding is selected, storage stability is improved, improves film effect.
Compared with traditional solvent based coating, water paint has price low, safe to use, saves resource and the energy, subtracts
The advantages that few environmental pollution and public hazards, thus have become the Main way of current development coatings industry.Water soluble acrylic acid olefine resin
Coating is with fastest developing speed, pollution-free coating that kind is most in water paint.
Further, described aqueous as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention
Acrylic resin is the Eudragit E A1621A of three wood of Jiangsu.
Further, as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, the water
Property amino resins be one or both of the Amino resin 5717W of the wood of Jiangsu three, cyanogen spy 303.
Further, as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, the environmental protection
Cosolvent is two or three in ethylene glycol, propylene glycol monomethyl ether, alcohol.Suitable environmentally friendly solvent compounding is selected, storage is improved
Stability improves film effect.Propylene glycol belongs to dihydric alcohol ether solvent, toxicity of the propylene glycol to human body with glycol ether
Less than gylcol ether product, belong to less toxic ethers.Propylene glycol monomethyl ether has faint ether taste, but does not have strong and stimulating smell, makes it
Purposes is more safe extensively.Since existing ether has hydroxyl in its molecular structure again, thus its solubility property is very excellent, again
There is the features such as suitable rate of volatilization and reactivity and obtains wide application.Ethylene glycol is miscible in ethyl alcohol, ether etc., surely
It is qualitative good, it is colourless, odorless, it can be used as solvent.
Further, as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, the neutralization
Agent is one or both of dimethylethanolamine, AMP-95.Dimethylethanolamine is used for ion exchange resin, is used as water solubility
Coating cosolvent；AMP-95 (2-amino-2-methyl-1-propanol), AMP-95 chemical name 2- amino-2-methyls -1-
Propyl alcohol, structural formula are (CH3) 2C (NH2) CH2OH, are a kind of multifunction amine auxiliary agents, and the pH value for adjusting lotion adhesive is very stable,
The effect for also moistening, disperseing.AMP-95 is beneficial to manufacture, storage, transport, using and the coating such as final film forming all make
With each stage in period.Meanwhile there is outstanding base strength, efficient pigment dispersion and enhanced scrubbing resistance
Property.Compared to some other organic bases, the stability of AMP-95 is good, is not easy xanthochromia, while small toxicity, belongs to the tune of environment-friendly type
Save agent.
Further, as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, the defoaming
The defoaming that used additives TEGO-902w, BYK are made in the deaeration that agent is TEGO acts on auxiliary agent B two kinds of mixtures of YK-024.Select inhomogeneity
The antifoaming agent of type is compounded, and system air bubble problem is solved.
Further, as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, the levelling
Agent is one or both of BYK-331, TEGO-4100.
Further, as a kind of specific implementation mode of agricultural machinery sealing wax provided in an embodiment of the present invention, the base
Material wetting agent is one or both of BASF-3322, TEGO-270.
Below by specific embodiment, the agricultural machinery sealing wax of offer is further illustrated the present invention, it should be noted that real
It applies specific numerical value in example to be intended to be merely illustrative of the present, should not be construed as limiting the invention.
Embodiment 1
Formula is as follows count by weight percentage：Water-base resin：40 parts of water-based acrylic resin, water-compatible amino resin 10
Part；Auxiliary agent：10 parts of environmentally friendly solvent, 1 part of neutralizer, 0.2 part of antifoaming agent, 0.2 part of levelling agent, 0.3 part of substrate wetting agents, deionization
40 parts of water.
Embodiment 2
Formula is as follows count by weight percentage：Water-base resin：60 parts of water-based acrylic resin, water-compatible amino resin 15
Part；Auxiliary agent：20 parts of environmentally friendly solvent, 5 parts of neutralizer, 0.4 part of antifoaming agent, 0.5 part of levelling agent, 0.6 part of substrate wetting agents, deionization
60 parts of water.
Embodiment 3
Formula is as follows count by weight percentage：Water-base resin：50 parts of water-based acrylic resin, water-compatible amino resin 12
Part；Auxiliary agent：15 parts of environmentally friendly solvent, 3 parts of neutralizer, 0.3 part of antifoaming agent, 0.4 part of levelling agent, 0.5 part of substrate wetting agents, deionization
50 parts of water.
The present invention also provides a kind of preparation method of agricultural machinery sealing wax, preparation process is as follows：
Water-based acrylic resin is added in stock pot according to the raw material proportioning, adds environmentally friendly solvent by step a,
It is stirred 2-3 minutes with the speed of 450-500r/min.
Step b is added neutralizer and adjusts pH value, with the speed of 450-500r/min while stirring according to the raw material proportioning
Degree stirring 2-3 minutes.
Step c, according to the raw material proportioning, with the speed of 450-500r/min while stirring by amino resins, antifoaming agent,
Moistening flatting agent, deionized water are sequentially added into, and are stirred 10-15 minutes with the speed of 1100-1200r/min.
Table 1 is the embodiment of the present invention test result：
Table 1
Technical solution provided by the invention is described in detail above, using specific case to the present invention in the present invention
Embodiment be expounded, the explanation of above example is only intended to help understand the present invention, it is noted that for this skill
For the technical staff in art field, without departing from the principle of the present invention, can also several improvement be carried out to the present invention, these
Improvement is also fallen within the protection scope of the claims of the present invention.
Claims (9)
1. a kind of agricultural machinery sealing wax, which is characterized in that formula is as follows count by weight percentage：Water-base resin：Water soluble acrylic acid
40-60 parts of resin, 10-15 parts of water-compatible amino resin；Auxiliary agent：10-20 parts of environmentally friendly solvent, 1-5 parts of neutralizer, antifoaming agent 0.2-
0.4 part, 0.2-0.5 parts of levelling agent, 0.3-0.6 parts of substrate wetting agents, 40-60 parts of deionized water.
2. agricultural machinery sealing wax according to claim 1, which is characterized in that the water-based acrylic resin is acrylic resin
EA1621A。
3. agricultural machinery sealing wax according to claim 1, which is characterized in that the water-compatible amino resin is methyl-etherified amino
One or both of resin 5717W, cyanogen spy 303.
4. agricultural machinery sealing wax according to claim 1, which is characterized in that the environmental protection cosolvent is ethylene glycol, propylene glycol
Two or three in methyl ether, alcohol.
5. agricultural machinery sealing wax according to claim 1, which is characterized in that the neutralizer is dimethylethanolamine, AMP-
One or both of 95.
6. agricultural machinery sealing wax according to claim 1, which is characterized in that the antifoaming agent is that used additives are made in the deaeration of TEGO
The defoaming of TEGO-902w, BYK act on auxiliary agent B two kinds of mixtures of YK-024.
7. agricultural machinery sealing wax according to claim 1, which is characterized in that the levelling agent is BYK-331, TEGO-4100
One or both of.
8. agricultural machinery sealing wax according to claim 1, which is characterized in that the substrate wetting agents be BASF-3322,
One or both of TEGO-270.
9. a kind of preparation method of agricultural machinery sealing wax, which is characterized in that
Water-based acrylic resin is added in stock pot according to the raw material proportioning, adds environmentally friendly solvent by step a, with
The speed of 450-500r/min stirs 2-3 minutes.
Step b is added neutralizer and adjusts pH value, stirred with the speed of 450-500r/min while stirring according to the raw material proportioning
It mixes 2-3 minutes.
Step c, according to the raw material proportioning, with the speed of 450-500r/min while stirring by amino resins, antifoaming agent, wetting
Levelling agent, deionized water are sequentially added into, and are stirred 10-15 minutes with the speed of 1100-1200r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810036352.0A CN108456469B (en) | 2018-01-15 | 2018-01-15 | Water paint for agricultural machinery and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810036352.0A CN108456469B (en) | 2018-01-15 | 2018-01-15 | Water paint for agricultural machinery and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108456469A true CN108456469A (en) | 2018-08-28 |
| CN108456469B CN108456469B (en) | 2024-02-09 |
Family
ID=63220889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810036352.0A Active CN108456469B (en) | 2018-01-15 | 2018-01-15 | Water paint for agricultural machinery and preparation method thereof |
Country Status (1)
| Country | Link |
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|---|---|---|---|---|
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-
2018
- 2018-01-15 CN CN201810036352.0A patent/CN108456469B/en active Active
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| Publication number | Publication date |
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| CN108456469B (en) | 2024-02-09 |
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