CN108404903A - 链烷烃转化成烯烃的方法和其中使用的催化剂 - Google Patents

链烷烃转化成烯烃的方法和其中使用的催化剂 Download PDF

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CN108404903A
CN108404903A CN201810205533.1A CN201810205533A CN108404903A CN 108404903 A CN108404903 A CN 108404903A CN 201810205533 A CN201810205533 A CN 201810205533A CN 108404903 A CN108404903 A CN 108404903A
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catalyst
weight
temperature
bed
zeolite
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孔吉·苏里耶
武蒂贴·贾里瓦差拉
布鲁帕尼亚·莱克恩加姆
阿努瓦·农卡姆翁
克萨达·素蒂乌姆蓬
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SCG Chemicals PCL
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
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    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
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    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J38/00—Regeneration or reactivation of catalysts, in general
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J38/00—Regeneration or reactivation of catalysts, in general
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    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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CN201810205533.1A 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂 Pending CN108404903A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13162080.9 2013-04-03
EP13162080.9A EP2786978B1 (en) 2013-04-03 2013-04-03 Process for converting paraffin to olefin and catalyst for use therein
CN201480018621.0A CN105102407B (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂

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CN201480018621.0A Expired - Fee Related CN105102407B (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂

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US (2) US10329219B2 (enExample)
EP (2) EP2975013A1 (enExample)
JP (2) JP6289607B2 (enExample)
KR (1) KR20150139870A (enExample)
CN (2) CN108404903A (enExample)
SG (1) SG11201508020XA (enExample)
TW (2) TWI629255B (enExample)
WO (1) WO2014163590A1 (enExample)

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EP2975013A1 (en) * 2013-04-03 2016-01-20 Scg Chemicals Co. Ltd. Catalyst for converting paraffin to olefin
EP3000800A1 (en) * 2014-09-23 2016-03-30 Borealis AG An endothermic gas phase catalytic dehydrogenation process
US10131594B2 (en) * 2014-10-28 2018-11-20 SMG Co., Ltd Metathesis catalyst on mixed metal oxide-zeolite support and process for use thereof
EP3050621A1 (en) * 2015-01-30 2016-08-03 Terramark Markencreation GmbH Metathesis catalyst and process for producing olefin
EP3238819B1 (en) * 2015-03-20 2020-11-04 SMH Co., Ltd. Process for olefin metathesis
WO2017003014A1 (ko) * 2015-06-30 2017-01-05 한국화학연구원 환원가스 전처리 후 연속 반응-재생 및 유동식 올레핀 제조방법
US10221110B2 (en) * 2016-12-08 2019-03-05 Evonik Degussa Gmbh Dehydrogenation of olefin-rich hydrocarbon mixtures
WO2018108544A1 (en) * 2016-12-13 2018-06-21 SMH Co., Ltd. Hydrocarbon conversion catalyst system
PL3335790T3 (pl) * 2016-12-13 2021-10-25 SMH Co., Ltd. Sposób konwersji wsadu węglowodorowego zawierającego nasycony związek węglowodorowy w produkty olefinowe
ES2797802T3 (es) * 2016-12-13 2020-12-03 Smh Co Ltd Catalizador para la conversión de una alimentación de hidrocarburos que comprende un compuesto de hidrocarburo saturado en productos olefínicos
KR101971085B1 (ko) * 2016-12-30 2019-04-22 에스케이가스 주식회사 올레핀 제조용 촉매 및 이를 이용한 연속 반응-재생 올레핀 제조방법
KR102179574B1 (ko) * 2017-06-07 2020-11-16 에스케이가스 주식회사 환원 전처리를 포함하는 올레핀 제조 방법
JP7032512B2 (ja) 2017-07-18 2022-03-08 ルーマス テクノロジー エルエルシー オレフィン製造のための一体化された熱分解・脱水素プロセス
CN109833903A (zh) * 2017-11-29 2019-06-04 中国科学院大连化学物理研究所 一种低碳烷烃无氧脱氢制烯烃催化剂及其制备和应用
MX2020013186A (es) * 2018-07-05 2021-02-26 Dow Global Technologies Llc Procesamiento quimico que usa hidrogeno que contiene combustible complementario para el procesamiento de catalizadores.
EP3806971B1 (en) * 2018-07-20 2023-12-06 SCG Chemicals Co., Ltd. Process for the separation of ethylbenzene from other c8 aromatic compounds
JP7467475B2 (ja) * 2018-12-26 2024-04-15 ピーティーティー グローバル ケミカル パブリック カンパニー リミテッド Ｃ４－ｃ７炭化水素から軽質オレフィンを製造するための触媒
JP6802311B2 (ja) * 2019-03-26 2020-12-16 エスエムエイチ カンパニー，リミテッド 混合金属酸化物−ゼオライト担体上のメタセシス触媒およびそれを使用するためのプロセス

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