CN108385378A - 一种涤棉织物的抗菌整理方法 - Google Patents

一种涤棉织物的抗菌整理方法 Download PDF

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CN108385378A
CN108385378A CN201810298959.6A CN201810298959A CN108385378A CN 108385378 A CN108385378 A CN 108385378A CN 201810298959 A CN201810298959 A CN 201810298959A CN 108385378 A CN108385378 A CN 108385378A
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陈东进
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Dongguan Lianzhou Intellectual Property Operation and Management Co Ltd
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Abstract

本发明公开了一种涤棉织物的抗菌整理方法，包括以下步骤：首先制备月见草浓缩液，然后将其与叶蜡石粉末、去离子水混合在一定温度下进行反应，结束后冷却至室温，继续加入丙烯酸酯系单体、乳化剂，滴加引发剂，反应，反应结束后，继续加入氯化钙、琥珀酸二(2‑乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，干燥，最后在120℃下焙烘。该方法整理后的涤棉织物柔软性好，抗菌性能优异，力学性能佳。

Description

一种涤棉织物的抗菌整理方法
技术领域：
本发明涉及纺织品整理领域，具体的涉及一种涤棉织物的抗菌整理方法。
背景技术：
随着消费者对衣着的要求逐渐趋向多样化、多功能化，例如沙滩服、登山服等户外休闲服装面料市场的需求逐渐旺盛，但户外休闲服装面料对产品的阻燃和抗菌等功能性要求较高，常用工艺是对涤纶等化纤长丝面料进行涂层等后整理，制成抗菌性能优异的功能性面料。
但是目前市场上的抗菌功能性面料普遍存在力学性能差，且柔软舒适度不好，耐磨、耐擦洗性不好。
发明内容：
本发明的目的是提供一种涤棉织物的抗菌整理方法，该方法整理的织物柔软舒适，抗菌性能优异，且力学性能佳，抗冲击性能好，耐磨、耐洗性好。
为实现上述目的，本发明采用以下技术方案：
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，冷冻干燥，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理3-8h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理1-5h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至60-80℃，滴加引发剂，反应10-30min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，干燥，最后在120℃下焙烘。
作为上述技术方案的优选，步骤(1)中，所述冷冻干燥的条件为-15～-20℃，时间为10-20h。
作为上述技术方案的优选，步骤(2)中，所述叶蜡石粉末、月见草浓缩液的质量比为(3-6)：1。
作为上述技术方案的优选，步骤(2)中，所述丙烯酸酯系单体为丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯中的一种或多种混合。
作为上述技术方案的优选，步骤(2)中，所述乳化剂为阿拉伯胶。
作为上述技术方案的优选，步骤(2)中，所述引发剂为过硫酸钾。
作为上述技术方案的优选，整理液中各组分的用量以重量份计分别为：叶蜡石粉末3-6份、去离子水15-35份、月见草浓缩液1份、丙烯酸酯系单体10-20份、乳化剂1-2份、引发剂1-2份、氯化钙3-5份、琥珀酸二(2-乙基己酯)磺酸钠1-3份、二甲基硅油0.5-3份。
作为上述技术方案的优选，步骤(3)，处理时的料液比为1：(10-20)。
作为上述技术方案的优选，步骤(3)，所述干燥的条件为60-80℃，干燥30-60min。
本发明具有以下有益效果：
本发明首先以月见草为原料制得月见草浓缩液，其含有较高浓度的脂肪酸和亚麻酸以及良好的抑菌成分；然后本发明将叶蜡石粉和去离子水混合，并采用月见草浓缩液作为改性成分，在一定温度下进行改性，可有效改善叶蜡石在整理液中的分散性，最后加入丙烯酸系类单体、引发剂和乳化剂进行反应，制得的整理液稳定性好，与织物的润湿性能好；
本发明制得的整理液中以聚丙烯酸树脂为成膜物质，且其组分含有较多的活性基团，可有效渗入到织物纤维内部，与织物纤维结合，从而整理后的织物耐磨、耐擦洗性好，抗菌性能优异，力学性能佳。
具体实施方式：
为了更好地理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例1
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，-15～-20℃下冷冻干燥10h，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理3h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理1h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至60℃，滴加引发剂，反应10min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；整理液中各组分的用量以重量份计分别为：叶蜡石粉末3份、去离子水15份、月见草浓缩液1份、丙烯酸酯系单体10份、乳化剂1份、引发剂1份、氯化钙3份、琥珀酸二(2-乙基己酯)磺酸钠1份、二甲基硅油0.5份；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，料液比为1：10，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，60-80℃下干燥30min，最后在120℃下焙烘。
实施例2
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，-15～-20℃下冷冻干燥20h，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理8h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理5h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至80℃，滴加引发剂，反应30min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；整理液中各组分的用量以重量份计分别为：叶蜡石粉末6份、去离子水35份、月见草浓缩液1份、丙烯酸酯系单体20份、乳化剂2份、引发剂2份、氯化钙5份、琥珀酸二(2-乙基己酯)磺酸钠3份、二甲基硅油3份；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，料液比为1：20，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，60-80℃下干燥60min，最后在120℃下焙烘。
实施例3
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，-15～-20℃下冷冻干燥12h，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理4h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理2h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至65℃，滴加引发剂，反应10min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；整理液中各组分的用量以重量份计分别为：叶蜡石粉末4份、去离子水20份、月见草浓缩液1份、丙烯酸酯系单体12份、乳化剂1.2份、引发剂1份、氯化钙3.5份、琥珀酸二(2-乙基己酯)磺酸钠1份、二甲基硅油1份；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，料液比为1：12，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，60-80℃下干燥40min，最后在120℃下焙烘。
实施例4
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，-15～-20℃下冷冻干燥14h，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理5h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理3h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至65℃，滴加引发剂，反应20min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；整理液中各组分的用量以重量份计分别为：叶蜡石粉末4.5份、去离子水25份、月见草浓缩液1份、丙烯酸酯系单体15份、乳化剂1.5份、引发剂1.5份、氯化钙4份、琥珀酸二(2-乙基己酯)磺酸钠2份、二甲基硅油1.5份；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，料液比为1：14，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，60-80℃下干燥40min，最后在120℃下焙烘。
实施例5
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，-15～-20℃下冷冻干燥16h，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理6h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理4h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至70℃，滴加引发剂，反应20min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；整理液中各组分的用量以重量份计分别为：叶蜡石粉末5份、去离子水25份、月见草浓缩液1份、丙烯酸酯系单体16份、乳化剂1.6份、引发剂1.5份、氯化钙4份、琥珀酸二(2-乙基己酯)磺酸钠2份、二甲基硅油2份；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，料液比为1：16，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，60-80℃下干燥50min，最后在120℃下焙烘。
实施例6
一种涤棉织物的抗菌整理方法，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，-15～-20℃下冷冻干燥18h，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理7h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理4.5h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至70℃，滴加引发剂，反应30min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；整理液中各组分的用量以重量份计分别为：叶蜡石粉末5.5份、去离子水30份、月见草浓缩液1份、丙烯酸酯系单体18份、乳化剂1.8份、引发剂1.5份、氯化钙4.5份、琥珀酸二(2-乙基己酯)磺酸钠2份、二甲基硅油2.5份；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，料液比为1：18，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，60-80℃下干燥50min，最后在120℃下焙烘。
下面对上述整理后的涤棉织物进行性能测试。
抗菌性能测试按照AATCC100-2012标准。使用金黄色葡萄球菌作为革兰氏阳性菌，大肠杆菌作为革兰氏阴性菌。
断裂强力按照ISO 13934-I/1999标准进行测试。
测试结果如表1所示：
表1
从上述测试结果来看，本发明整理的涤棉织物具有优异的抗菌性能和力学性能，且耐洗性能好。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (9)

1.一种涤棉织物的抗菌整理方法，其特征在于，包括以下步骤：
(1)将月见草切碎，清洗干净，晒干，冷冻干燥，研磨，制得粉末；将粉末分散于乙醇中，40-50℃下搅拌处理3-8h，过滤，收集滤液，并对滤液进行浓缩处理，制得月见草浓缩液；
(2)将叶蜡石粉末和去离子水混合搅拌均匀转移至带有冷凝管的三口烧瓶中，然后加上述制得的月见草浓缩液，80-90℃下回流处理1-5h，然后冷却至室温，继续滴加丙烯酸酯系单体、乳化剂，缓慢升温至60-80℃，滴加引发剂，反应10-30min，反应结束后，继续加入氯化钙、琥珀酸二(2-乙基己酯)磺酸钠、二甲基硅油，搅拌混合均匀，制得整理液；
(3)将涤棉织物用去离子水清洗干净，然后将清洗后的涤棉织物浸泡在上述制得的整理液中，二浸二轧，轧余率70％，取出，常温静置30min，然后采用去离子水清洗干净，干燥，最后在120℃下焙烘。
2.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(1)中，所述冷冻干燥的条件为-15～-20℃，时间为10-20h。
3.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(2)中，所述叶蜡石粉末、月见草浓缩液的质量比为(3-6)：1。
4.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(2)中，所述丙烯酸酯系单体为丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯中的一种或多种混合。
5.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(2)中，所述乳化剂为阿拉伯胶。
6.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(2)中，所述引发剂为过硫酸钾。
7.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于，整理液中各组分的用量以重量份计分别为：叶蜡石粉末3-6份、去离子水15-35份、月见草浓缩液1份、丙烯酸酯系单体10-20份、乳化剂1-2份、引发剂1-2份、氯化钙3-5份、琥珀酸二(2-乙基己酯)磺酸钠1-3份、二甲基硅油0.5-3份。
8.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(3)，处理时的料液比为1：(10-20)。
9.如权利要求1所述的一种涤棉织物的抗菌整理方法，其特征在于：步骤(3)，所述干燥的条件为60-80℃，干燥30-60min。
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