CN108384289A - A kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect - Google Patents

A kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect Download PDF

Info

Publication number
CN108384289A
CN108384289A CN201810062775.XA CN201810062775A CN108384289A CN 108384289 A CN108384289 A CN 108384289A CN 201810062775 A CN201810062775 A CN 201810062775A CN 108384289 A CN108384289 A CN 108384289A
Authority
CN
China
Prior art keywords
coating
yellow mud
mud bar
crackle
imitative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810062775.XA
Other languages
Chinese (zh)
Other versions
CN108384289B (en
Inventor
王君瑞
唐植贤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Boxing Chemical & Paint Co Ltd
Original Assignee
Zhejiang Boxing Chemical & Paint Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Boxing Chemical & Paint Co Ltd filed Critical Zhejiang Boxing Chemical & Paint Co Ltd
Priority to CN201810062775.XA priority Critical patent/CN108384289B/en
Publication of CN108384289A publication Critical patent/CN108384289A/en
Application granted granted Critical
Publication of CN108384289B publication Critical patent/CN108384289B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention belongs to paint fields, more particularly, to a kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect.The present invention utilizes the natural materials such as yellow mud bar, straw, quartz sand, pre-gelatinized tapioca starch, xanthans, it is prepared for a kind of coating of imitative yellow mud bar crackle metope effect, the coating is environmentally protective, easily batch scrape, application property is good, natural to the strong adhesive force of base material, crackle clean mark, it can be widely applied to the covering with paint of metope inside and outside leisure farm, foot bath city, amusement club etc., product has the function of breathing damping, fire protection flame retarding, the noise abatement of drop sound, insulation etc., and market prospects are fine.

Description

A kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect
Technical field
The invention belongs to paint field, the coating more particularly, to a kind of imitative yellow mud bar crackle metope effect and its preparation side Method.
Background technology
Crackle metope effect coating is most original, most simple, most warm pleasant construction material, other in mountain villa in recent years The inner-outer wall in the places such as villa, hot pot city, market is more and more widely used in covering with paint, lacquer, colour wash, etc., and gives return to primitive age field Honourable and wireless reverie triggers the feeling that people calls to mind past sufferings and thinks over the good times.But current crackle metope effect coating many on the market all exist The phenomenon that poor adhesive force, intensity are low, water resistance is bad, application property is difficult, crack effect is uneven, crack shape is unnatural influences Crackle metope effect coating is in further genralrlization application on the market.
Invention content
It is an object of the present invention to be directed to the deficiencies in the prior art, a kind of imitative yellow mud bar crackle metope effect is provided The coating of fruit.
For this purpose, the above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of coating of imitative yellow mud bar crackle metope effect, which is characterized in that the imitative yellow mud bar crackle metope effect Coating includes:
Remaining gathers together enough mass percent as 100% with water.
In order to obtain further technique effect, the present invention can also use technical solution further below:
Preferably, the self-crosslinking pure-acrylic emulsion is formed by acrylic ester monomer and acrylic acid copolymer.
Preferably, solid part of the self-crosslinking pure-acrylic emulsion is 47~49%wt.
Preferably, the yellow mud bar is the yellow clay that main component is aluminium oxide and iron oxide.
Preferably, the preservative is isothiazolinone and its derivative.
Preferably, the quartz sand be 10~20 mesh, 20~40 mesh and one kind in 120~180 mesh natural siliceous sands or Several combination of person.
Preferably, the crackle agent is the one or several kinds in superfine alumina silicate, zinc stearate and aerosil Combination.
Preferably, the thickener is that association type alkali swollen thickener, polyurethane thickener and sodium carboxymethylcellulose increase One or several kinds of combinations in thick dose.
Another object of the present invention is, for the deficiencies in the prior art, provides a kind of imitative yellow mud bar and splits The preparation method of the coating of line metope effect.
For this purpose, the above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of preparation method of the coating of imitative yellow mud bar crackle metope effect, the preparation method provide foregoing imitative The coating of yellow mud bar crackle metope effect, and prepare in accordance with the following steps:
Water is put into painting cylinder, pre-gelatinized tapioca starch, xanthans and preservative is added in airborne dust formula under stirring, and With 1500~2000rpm/min, 15~20min of high speed dispersion, it is made fully to be dissolved into uniform, transparent glue, yellow mud is added Bar, quartz sand and straw be mixed evenly, self-crosslinking pure-acrylic emulsion and crackle agent is then added with 1500~2000rpm/ Min high speed dispersions are eventually adding thickener adjustment viscosity to uniform.
The present invention is prepared for one kind using natural materials such as yellow mud bar, straw, quartz sand, pre-gelatinized tapioca starch, xanthans The coating of imitative yellow mud bar crackle metope effect, the coating is environmentally protective, easily batch scrape, application property is good, to the strong adhesive force of base material, Crackle clean mark is naturally, can be widely applied to the covering with paint of metope inside and outside leisure farm, foot bath city, amusement club etc., product tool There are functions, the market prospects such as breathing damping, fire protection flame retarding, the noise abatement of drop sound, insulation fine.
Specific implementation mode
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
Composition:
Water is first put into painting cylinder, airborne dust formula is added pre-gelatinized tapioca starch, xanthans and preservative and exists under stirring 15~20min of high speed dispersion under 1800 rpm/min makes it fully be dissolved into uniform, transparent glue, and yellow mud bar, quartz is added Sand, straw are mixed evenly, and self-crosslinking pure-acrylic emulsion, crackle agent is added and high speed dispersion is uniform at 1800rpm/min. Then thickener is added and adjusts viscosity, is packed after qualified.
Embodiment 2
Composition:
The preparation method of the coating of imitative yellow mud bar crackle metope effect in embodiment 2 and the preparation method in embodiment 1 It is identical.
Embodiment 3
Composition:
The preparation method of the coating of imitative yellow mud bar crackle metope effect in embodiment 3 and the preparation method in embodiment 1 It is identical.
The obtained imitative yellow mud bar crackle metope effect coating of the embodiment of the present invention 1 to 3 is split with certain brand on the market Line metope effect coating is compared, and test result is as follows for coating property shown in table:
By the above test result it can be found that the coating of imitative yellow mud bar crackle metope effect provided by the present invention is with good Good workability, the adhesion strength performance under standard state and after immersion show it is excellent, it is resistance under 96h water resistance tests Water effect is fabulous, and the performance under the test of 48h alkali resistances is excellent, and its appearance of film crackle clear and natural is uniform, therefore, this The coating for inventing the imitative yellow mud bar crackle metope effect provided can be widely applied to leisure farm, foot bath city, amusement club etc. The covering with paint of inside and outside metope, product have the function of breathing damping, fire protection flame retarding, the noise abatement of drop sound, insulation etc., and market prospects are very It is good.
Above-mentioned specific implementation mode is used for illustrating the present invention, is merely a preferred embodiment of the present invention, rather than to this Invention limited, in the protection domain of spirit and claims of the present invention, to the present invention make any modification, etc. With replacement, improvement etc., protection scope of the present invention is both fallen within.

Claims (9)

1. a kind of coating of imitative yellow mud bar crackle metope effect, which is characterized in that the painting of the imitative yellow mud bar crackle metope effect Material includes:
Remaining gathers together enough mass percent as 100% with water.
2. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 1, which is characterized in that the self-crosslinking Pure-acrylic emulsion is formed by acrylic ester monomer and acrylic acid copolymer.
3. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 2, which is characterized in that the self-crosslinking Solid part of pure-acrylic emulsion is 47~49%wt.
4. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 1, which is characterized in that the yellow mud bar For the yellow clay that main component is aluminium oxide and iron oxide.
5. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 1, which is characterized in that the preservative For isothiazolinone and its derivative.
6. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 1, which is characterized in that the quartz sand For one or several kinds of combinations in 10~20 mesh, 20~40 mesh and 120~180 mesh natural siliceous sands.
7. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 1, which is characterized in that the crackle agent For one or several kinds of combinations in superfine alumina silicate, zinc stearate and aerosil.
8. a kind of coating of imitative yellow mud bar crackle metope effect according to claim 1, which is characterized in that the thickener For one or several kinds of groups in association type alkali swollen thickener, polyurethane thickener and sodium carboxymethyl cellulose thickener It closes.
9. a kind of preparation method of the coating of imitative yellow mud bar crackle metope effect, which is characterized in that the preparation method provides power Profit requires the coating of the imitative yellow mud bar crackle metope effect described in 1, and prepares in accordance with the following steps:
Water is put into painting cylinder, airborne dust formula addition pre-gelatinized tapioca starch, xanthans and preservative under stirring, and with 1500~2000rpm/min, 15~20min of high speed dispersion make it fully be dissolved into uniform, transparent glue, be added yellow mud bar, Quartz sand and straw are mixed evenly, and self-crosslinking pure-acrylic emulsion and crackle agent is then added with 1500~2000rpm/min high Speed is dispersed to uniformly, is eventually adding thickener adjustment viscosity.
CN201810062775.XA 2018-01-23 2018-01-23 Coating imitating yellow mud crack wall surface effect and preparation method thereof Active CN108384289B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810062775.XA CN108384289B (en) 2018-01-23 2018-01-23 Coating imitating yellow mud crack wall surface effect and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810062775.XA CN108384289B (en) 2018-01-23 2018-01-23 Coating imitating yellow mud crack wall surface effect and preparation method thereof

Publications (2)

Publication Number Publication Date
CN108384289A true CN108384289A (en) 2018-08-10
CN108384289B CN108384289B (en) 2020-10-09

Family

ID=63076333

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810062775.XA Active CN108384289B (en) 2018-01-23 2018-01-23 Coating imitating yellow mud crack wall surface effect and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108384289B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112662253A (en) * 2020-12-22 2021-04-16 夏宏炜 Novel retro natural mud paint and preparation method thereof
CN114015289A (en) * 2021-12-09 2022-02-08 温州市品达科装饰材料有限公司 Water-based crack paint, preparation method thereof and application method of crack paint

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1876737A (en) * 2006-07-06 2006-12-13 北京中化科城技术研究所 Gold brocade coating material
KR20070118356A (en) * 2006-06-12 2007-12-17 (주)알씨코리아 Color floor composition of inorganic for middle application
CN101175807A (en) * 2005-05-16 2008-05-07 卡吉尔公司 Cationic crosslinked starch containing compositions and use thereof
CN101319103A (en) * 2008-07-04 2008-12-10 大连市甘井子区飞龙达新型装饰材料厂 Negative ion putty powder
CN102558974A (en) * 2011-12-31 2012-07-11 佛山市南海万磊建筑涂料有限公司 Water-based crack sandstone paint and preparation method thereof
CN102584114A (en) * 2012-03-14 2012-07-18 沈阳顺风新城建筑材料有限公司 Tile-like sand wall-textured coating for exterior walls and preparation method thereof
CN102863859A (en) * 2012-09-18 2013-01-09 张立功 Energy-saving marble-imitating paint preparation method and product thereof
CN103011701A (en) * 2011-09-28 2013-04-03 比亚迪股份有限公司 Vitrified microbead insulating mortar and preparation method thereof
CN103113041A (en) * 2013-03-07 2013-05-22 富思特新材料科技发展股份有限公司 Natural rock coating imitating flame-treated flag stone and preparation method of natural rock coating
CN103351695A (en) * 2013-06-25 2013-10-16 天长市开林化工有限公司 Anti-cracking exterior wall putty
CN104761989A (en) * 2015-04-08 2015-07-08 佛山市南海万磊建筑涂料有限公司 Composite inorganic metal velvet coating and preparation method thereof
CN105985690A (en) * 2015-02-04 2016-10-05 天长市高新技术创业服务中心 Water-based crack paint
CN107573789A (en) * 2017-09-11 2018-01-12 宜昌市大棒科技有限公司 A kind of hazy and illusionary camouflage veneer coating and preparation method thereof

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101175807A (en) * 2005-05-16 2008-05-07 卡吉尔公司 Cationic crosslinked starch containing compositions and use thereof
KR20070118356A (en) * 2006-06-12 2007-12-17 (주)알씨코리아 Color floor composition of inorganic for middle application
CN1876737A (en) * 2006-07-06 2006-12-13 北京中化科城技术研究所 Gold brocade coating material
CN101319103A (en) * 2008-07-04 2008-12-10 大连市甘井子区飞龙达新型装饰材料厂 Negative ion putty powder
CN103011701A (en) * 2011-09-28 2013-04-03 比亚迪股份有限公司 Vitrified microbead insulating mortar and preparation method thereof
CN102558974A (en) * 2011-12-31 2012-07-11 佛山市南海万磊建筑涂料有限公司 Water-based crack sandstone paint and preparation method thereof
CN102584114A (en) * 2012-03-14 2012-07-18 沈阳顺风新城建筑材料有限公司 Tile-like sand wall-textured coating for exterior walls and preparation method thereof
CN102863859A (en) * 2012-09-18 2013-01-09 张立功 Energy-saving marble-imitating paint preparation method and product thereof
CN103113041A (en) * 2013-03-07 2013-05-22 富思特新材料科技发展股份有限公司 Natural rock coating imitating flame-treated flag stone and preparation method of natural rock coating
CN103351695A (en) * 2013-06-25 2013-10-16 天长市开林化工有限公司 Anti-cracking exterior wall putty
CN105985690A (en) * 2015-02-04 2016-10-05 天长市高新技术创业服务中心 Water-based crack paint
CN104761989A (en) * 2015-04-08 2015-07-08 佛山市南海万磊建筑涂料有限公司 Composite inorganic metal velvet coating and preparation method thereof
CN107573789A (en) * 2017-09-11 2018-01-12 宜昌市大棒科技有限公司 A kind of hazy and illusionary camouflage veneer coating and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112662253A (en) * 2020-12-22 2021-04-16 夏宏炜 Novel retro natural mud paint and preparation method thereof
CN114015289A (en) * 2021-12-09 2022-02-08 温州市品达科装饰材料有限公司 Water-based crack paint, preparation method thereof and application method of crack paint

Also Published As

Publication number Publication date
CN108384289B (en) 2020-10-09

Similar Documents

Publication Publication Date Title
CN108384289A (en) A kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect
CN106675149A (en) Double-component external wall heat-insulating putty having water resistance effect and preparation method thereof
CN104556822A (en) Environment-friendly interior wall coating composition
CN104690805A (en) High-strength environment-friendly composite board and preparation method thereof
CN103497560A (en) Formaldehyde-free putty paste for interior wall latex paint
CN105754398A (en) Environment-friendly waterproof anti-bacteria putty powder and preparing method thereof
CN108191307A (en) A kind of anti-dropout graphene lacquer and preparation method thereof
CN104017438A (en) Composite fire retardant coating
CN104861899A (en) Adhesive composition for plywood and preparation process of adhesive composition
CN103497564B (en) Dry powder latex paint water resistant putty powder
CN108485324A (en) A kind of moisture-proof diatom coating of powder
CN107312375A (en) A kind of energy-saving heat preserving powder of lacquer putty for use on and preparation method thereof
CN104293168A (en) VOC-free deodorization ultraviolet-curing coating for wood building material
CN106752595A (en) A kind of stone imitation material
CN107177249A (en) A kind of manufacture craft of novel fire resistant wall paint
CN104293180A (en) Protecting reinforcing solution for ancient colored paintings on unplastered wooden buildings, and preparation method and reinforcing protection method thereof
CN203247798U (en) Novel fireproof decorative sheet imitating stone veins
CN103045040B (en) A kind of natural sliver paint and preparation method
CN108929069A (en) A kind of self-cleaning lacquer and preparation method thereof
CN204825504U (en) It shifts printing base stock easily to be convenient for water of production, quality monitoring
CN108219542A (en) Aqueous forest negative oxygen ion lacquer and preparation method thereof
CN107868555A (en) A kind of hydrophobicity texture coating
CN107512871A (en) A kind of native annulus fidelity mineral varnish
CN105623393A (en) Aqueous environmental-protection decorative type fire-resistant paint and preparation method thereof
CN104927525A (en) Waterborne antifreezing paint

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Wang Junrui

Inventor after: Xu Yunli

Inventor after: Tang Zhixian

Inventor before: Wang Junrui

Inventor before: Tang Zhixian

CB03 Change of inventor or designer information
GR01 Patent grant
GR01 Patent grant