CN105754398A - Environment-friendly waterproof anti-bacteria putty powder and preparing method thereof - Google Patents
Environment-friendly waterproof anti-bacteria putty powder and preparing method thereof Download PDFInfo
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- CN105754398A CN105754398A CN201610259507.8A CN201610259507A CN105754398A CN 105754398 A CN105754398 A CN 105754398A CN 201610259507 A CN201610259507 A CN 201610259507A CN 105754398 A CN105754398 A CN 105754398A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
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Abstract
The invention discloses environment-friendly waterproof anti-bacteria putty powder and a preparing method thereof.The environment-friendly waterproof anti-bacteria putty powder is prepared from, by weight, 500 parts of ash-calcium, 500 parts of ground calcium carbonate, 4-10 parts of cellulose, 120-150 parts of pine and cypress ash, 80-90 parts of kanuma mud, 20-30 parts of egg shell powder, 15-20 parts of fumed silica, 25-35 parts of vermiculite power, 24-32 parts of redispersible latex powder, 50-70 parts of gellan gum, 55-75 parts of dry sphagna powder, 30-40 parts of ocentyl succinic anhydride starch ester, 16-20 parts of freeze thawing polyvinyl alcohol gelatin powder, 15-20 parts of sodium abietate, 20-40 parts of superfine silica powder, 8-12 parts of lentinus edodes powder, 1-3 parts of pigment and 60-70 parts of anti-bacteria powder.The environment-friendly waterproof anti-bacteria putty powder has extremely high water resistance and cohesiveness, and is safe, environmentally friendly and capable of resisting bacteria and improving environment quality.
Description
Technical field
The present invention relates to building material technical field.It is more particularly related to a kind of water-fast antibacterial powder of lacquer putty for use on of environmental protection and
Its preparation method.
Background technology
Before putty is paint class construction, a kind of surface packing material that construction surface is pre-processed, it is therefore intended that fill construction surface
Hole and correct the curve deviation of construction surface, for obtaining uniformly, smooth lacquer painting lays a solid foundation, it is desirable to putty possesses well
Adhesion strength and resistance to water, and require relatively low in other respects, such as reduce noxious gas emission, environmental protection aspect.
Along with the theory of the most progressive of society and environmental protection is strengthened, people are more likely to select environment protection type functional powder of lacquer putty for use on, the opposing party
Face is owing to inner wall of building and human contact's time are long, and the impact on health is big, therefore for having resistance to water, U.S.
The powder of lacquer putty for use on of the property seen, security and the feature of environmental protection has wide market prospects.
Summary of the invention
It is an object of the invention to solve at least the above, and the advantage that at least will be described later is provided.
It is a still further object of the present invention to provide a kind of water-fast antibacterial powder of lacquer putty for use on of environmental protection and preparation method thereof, the environmental protection of the present invention is resistance to
The antibacterial powder of lacquer putty for use on of water has extremely strong resistance to water and caking property, not only safety and environmental protection, moreover it is possible to play bacteriostasis, can improve
Environmental quality.
In order to realize according to object of the present invention and further advantage, it is provided that a kind of water-fast antibacterial powder of lacquer putty for use on of environmental protection, including
Following raw material in parts by weight: ash calcium 500 parts, powdered whiting 500 parts, cellulose 4-10 part, pine and cypress ash 120-150
Part, deer natural pond soil 80-90 part, egg-shell meal 20-30 part, gas-phase silica 15-20 part, vermiculite power 25-35 part, can divide again
Dissipate latex powder 24-32 part, gellan gum 50-70 part, solid carbon dioxide lichenin 55-75 part, starch octenyl succinate anhydride 30-40 part,
Freeze thawing polyvinyl alcohol rubber powder 16-20 part, sodium abietate 15-20 part, superfine silica gel powder 20-40 part, mushroom powder 8-12 part, face
Material 1-3 part and antibacterial powder 60-70 part；
The most antibacterial powder include in parts by weight following raw material composition: lophatherum gracile powder 20-30 part, wood vinegar powder 30-42 part,
Lemon grass meal 20-25 part, gardenia powder 3-5 part, spearmint powder 12-16 part, dandelion powder 12-16 part and marjoram powder 8-12
Part.
Preferably, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, the following raw material including in parts by weight: ash calcium 500 parts,
Powdered whiting 500 parts, cellulose 7 parts, pine and cypress ash 135 parts, 85 parts of deer natural pond soil, egg-shell meal 25 parts, gas phase hard charcoal
Black 18 parts, vermiculite power 30 parts, redispersable latex powder 28 parts, gellan gum 60 parts, solid carbon dioxide lichenin 65 parts, octenyl
Succinic acid starch ester 35 parts, freeze thawing polyvinyl alcohol rubber powder 18 parts, sodium abietate 18 parts, superfine silica gel powder 30 parts, mushroom powder
10 parts of pigment 2 parts and 65 parts of antibacterial powder.
Preferably, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described antibacterial powder includes following raw material composition in parts by weight:
25 parts of lophatherum gracile powder, wood 36 parts of vinegar powder, lemon grass meal 23 parts, gardenia powder 4 parts, 14 parts of spearmint powder, dandelion powder
14 parts and 10 parts of marjoram powder.
Preferably, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described cellulose is that hydroxypropyl methyl cellulose, carboxymethyl are fine
Dimension element, lignocellulosic and chitin fiber element form for 4:2:1:5 in mass ratio.
Preferably, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described pigment be Tea Green Pigment, gardenia blue, clover pigment and
Nostoc blue pigment is 3:2:1:1 composition according to mass ratio.
Preferably, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described pine and cypress ash is will the ash of residual after pine tree or cypress burning
Cinder use ball mill be crushed to 200-300 mesh prepare, described solid carbon dioxide lichenin be solid carbon dioxide tongue is cleaned after, use pulverizer pulverize
To 80-100 mesh, then with ball mill be crushed to 200-300 mesh prepare, described mushroom powder be mushroom mushroom handle crushed after being dried extremely
200-300 mesh prepares, and described egg-shell meal is to be crushed to 200-300 mesh after egg shell clean dry prepare.
Preferably, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described lophatherum gracile powder, lemon grass meal, spearmint powder, Pu Gong
English powder and marjoram powder are the most first used pulverizer powder respectively by lophatherum gracile, lemon grass (Cymbopogon citratus), spearmint, dandelion and marjoram
It is broken to 80-100 mesh, then it is prepared to be crushed to 200-300 mesh with ball mill.
On the basis of the above, present invention also offers the preparation method of the water-fast antibacterial powder of lacquer putty for use on of a kind of environmental protection, comprise the following steps:
Step one, by pine and cypress ash, deer natural pond soil, egg-shell meal, gas-phase silica, vermiculite power and the solid carbon dioxide lichenin of above-mentioned weight portion
Mix, obtain the first mixed powder；
Step 2, the redispersable latex powder by above-mentioned weight portion, gellan gum, starch octenyl succinate anhydride, the poly-second of freeze thawing
Enol rubber powder, sodium abietate, superfine silica gel powder and mushroom powder mix, and obtain the second mixed powder；
Step 3, grey calcium and the powdered whiting of above-mentioned weight portion are mixed, obtain the 3rd mixed powder；
Step 4, described first mixed powder, the second mixed powder and the 3rd mixed powder are mixed, obtain the 4th mixed powder, take
The 1/10 of described 4th mixed powder weight, mixes with the cellulose of above-mentioned weight portion, pigment and antibacterial powder, obtains the 5th and mixes
Close powder, the most again the 5th mixed powder is mixed with remaining 4th mixed powder, obtain the water-fast antibacterial powder of lacquer putty for use on of environmental protection.
The present invention at least includes following beneficial effect:
1) the water-fast antibacterial powder of lacquer putty for use on of the environmental protection of the present invention has the performances such as excellent resistance to water, scrub resistance, mildew-resistant, and viscous
Knotting strength is high, the most easy to crack, do not fall off, non-scale, not hollowing, on the basis of adding suitable pigment, the environmental protection of the present invention
Water-fast antibacterial powder of lacquer putty for use on is prone to coloring, in bright gay color, not fugitive color, can replace tradition putty and latex to a certain extent
Paint is for the decoration of building inner-outer wall；
2) pine and cypress ash, deer natural pond soil, vermiculite power and the mixing of solid carbon dioxide lichenin are had flight of colors and suction by the powder of lacquer putty for use on of the present invention
Attached performance, also has good plasticity, caking property, permeability, and its bonding be conducive between each raw material is shunk after drying
Rate is little, and will not produce be full of cracks, can improve the putty adhesive force to building wall, and the powder of lacquer putty for use on of the present invention also has necessarily
Sound-absorbing noise elimination function, deadening can be played to a certain extent；
3) egg-shell meal, gas-phase silica with ash calcium and powdered whiting mix, have strengthen powder of lacquer putty for use on water-resistant capacity with after
The ability of phase intensity, gas-phase silica has exquisiteness, absorption affinity is strong, wearability good, ageing-resistant feature；
4) gellan gum, freeze thawing polyvinyl alcohol rubber powder, superfine silica gel powder and mushroom powder have good instant capacity, excellent film forming
Property, stronger cementability and permeability, the adhesive force of powder of lacquer putty for use on can be improved, after effectively preventing putty construction, produce efflorescence, tortoise
Split and peel off；
5) antibacterial powder is by lophatherum gracile powder, wood vinegar powder, lemon grass meal, gardenia powder, spearmint powder, dandelion powder and marjoram
Powder with appropriate than composition, make powder of lacquer putty for use on have stronger biocidal property, and antibacterial good endurance, persistently, can resist mould, bacterium,
Saccharomycete etc., have make us body and mind loosen, the fragrance of pressure of releiving, it addition, wood vinegar powder also there is the effect except formaldehyde, right
Play environmental-protection function in domestic environment, be conducive to the most healthy.
Part is embodied by the further advantage of the present invention, target and feature by description below, and part also will be by the present invention
Research and practice and be understood by the person skilled in the art.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification
Word can be implemented according to this.
It should be noted that experimental technique described in following embodiment, if no special instructions, it is conventional method, described
Reagent and material, if no special instructions, the most commercially obtain.
Embodiment 1:
A kind of water-fast antibacterial powder of lacquer putty for use on of environmental protection, the following raw material including in parts by weight: ash calcium 500 parts, powdered whiting
500 parts, cellulose 4 parts, pine and cypress ash 120 parts, deer natural pond soil 80 parts, egg-shell meal 20 parts, gas-phase silica 15 parts,
Vermiculite power 25 parts, redispersable latex powder 24 parts, gellan gum 50 parts, solid carbon dioxide lichenin 55 parts, octenyl succinic acid starch
Ester 30 parts, freeze thawing polyvinyl alcohol rubber powder 16 parts, sodium abietate 15 parts, superfine silica gel powder 20 parts, mushroom powder 8 parts, pigment
1 part and 60 parts of antibacterial powder；
The most antibacterial powder includes that following raw material in parts by weight forms: 20 parts of lophatherum gracile powder, wood 30 parts of vinegar powder, lemon grass (Cymbopogon citratus)
20 parts of powder, gardenia powder 3 parts, 12 parts of spearmint powder, 12 parts of dandelion powder and 8 parts of marjoram powder.
Wherein, described pine and cypress ash is to use ball mill to be crushed to 200-300 mesh system in the ashes of residual after pine tree or cypress burning
, described solid carbon dioxide lichenin be solid carbon dioxide tongue is cleaned after, use pulverizer to be crushed to 80-100 mesh, then be crushed to ball mill
200-300 mesh prepares, and described mushroom powder is that mushroom mushroom handle crushed after being dried prepares to 200-300 mesh, and described egg-shell meal is chicken
It is crushed to 200-300 mesh after eggshell clean dry prepare.
Wherein, described lophatherum gracile powder, lemon grass meal, spearmint powder, dandelion powder and marjoram powder are respectively by lophatherum gracile, lemon
Lemon grass, spearmint, dandelion and marjoram the most first use pulverizer to be crushed to 80-100 mesh, then pulverize with ball mill
Prepare to 200-300 mesh.
The raw material of granular size after pulverizing except above-mentioned restriction, remaining raw material of the present invention is typically crushed to 100-200 mesh, it is possible to
With finely between 200-300 mesh.
On the basis of the above, present invention also offers the preparation method of the water-fast antibacterial powder of lacquer putty for use on of a kind of environmental protection, comprise the following steps:
Step one, by pine and cypress ash, deer natural pond soil, egg-shell meal, gas-phase silica, vermiculite power and the solid carbon dioxide lichenin of above-mentioned weight portion
Mix, obtain the first mixed powder；
Step 2, the redispersable latex powder by above-mentioned weight portion, gellan gum, starch octenyl succinate anhydride, the poly-second of freeze thawing
Enol rubber powder, sodium abietate, superfine silica gel powder and mushroom powder mix, and obtain the second mixed powder；
Step 3, grey calcium and the powdered whiting of above-mentioned weight portion are mixed, obtain the 3rd mixed powder；
Step 4, described first mixed powder, the second mixed powder and the 3rd mixed powder are mixed, obtain the 4th mixed powder, take
The 1/10 of described 4th mixed powder weight, mixes with the cellulose of above-mentioned weight portion, pigment and antibacterial powder, obtains the 5th and mixes
Close powder, the most again the 5th mixed powder is mixed with remaining 4th mixed powder, obtain the water-fast antibacterial powder of lacquer putty for use on of environmental protection.
Embodiment 2:
Described environmental protection is water-fast antibacterial powder of lacquer putty for use on, the following raw material including in parts by weight: ash calcium 500 parts, powdered whiting
500 parts, cellulose 7 parts, pine and cypress ash 135 parts, deer natural pond soil 85 parts, egg-shell meal 25 parts, gas-phase silica 18 parts,
Vermiculite power 30 parts, redispersable latex powder 28 parts, gellan gum 60 parts, solid carbon dioxide lichenin 65 parts, octenyl succinic acid starch
Ester 35 parts, freeze thawing polyvinyl alcohol rubber powder 18 parts, sodium abietate 18 parts, superfine silica gel powder 30 parts, 10 parts of pigment of mushroom powder
2 parts and 65 parts of antibacterial powder.
Described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described antibacterial powder includes following raw material composition in parts by weight: lophatherum gracile powder
25 parts, wood 36 parts of vinegar powder, lemon grass meal 23 parts, gardenia powder 4 parts, 14 parts of spearmint powder, 14 parts of dandelion powder and
10 parts of marjoram powder.
Wherein, described cellulose is hydroxypropyl methyl cellulose, carboxymethylcellulose calcium, lignocellulosic and chitin fiber element
Form for 4:2:1:5 in mass ratio.
The preparation method of the water-fast antibacterial powder of lacquer putty for use on of environmental protection of the present embodiment is with embodiment 1.
Embodiment 3:
A kind of water-fast antibacterial powder of lacquer putty for use on of environmental protection, the following raw material including in parts by weight: ash calcium 500 parts, powdered whiting
500 parts, cellulose 10 parts, pine and cypress ash 150 parts, deer natural pond soil 90 parts, egg-shell meal 30 parts, gas-phase silica 20 parts,
Vermiculite power 35 parts, redispersable latex powder 32 parts, gellan gum 70 parts, solid carbon dioxide lichenin 75 parts, octenyl succinic acid starch
Ester 40 parts, freeze thawing polyvinyl alcohol rubber powder 20 parts, sodium abietate 20 parts, superfine silica gel powder 40 parts, mushroom powder 12 parts, face
Expect 3 parts and 70 parts of antibacterial powder；
The most antibacterial powder includes that following raw material in parts by weight forms: 30 parts of lophatherum gracile powder, wood 42 parts of vinegar powder, lemon grass (Cymbopogon citratus)
25 parts of powder, gardenia powder 5 parts, 16 parts of spearmint powder, 16 parts of dandelion powder and 12 parts of marjoram powder.
Wherein, described cellulose is hydroxypropyl methyl cellulose, carboxymethylcellulose calcium, lignocellulosic and chitin fiber element
Form for 4:2:1:5 in mass ratio.
The preparation method of the water-fast antibacterial powder of lacquer putty for use on of environmental protection of the present embodiment is with embodiment 1.
Embodiment 4:
On the basis of embodiment 2, described environmental protection is water-fast antibacterial powder of lacquer putty for use on, described pigment be Tea Green Pigment, gardenia blue,
Clover pigment and nostoc blue pigment are 3:2:1:1 composition according to mass ratio.
Comparative example 1:
The advantage that the water-fast antibacterial powder of lacquer putty for use on of environmental protection of the present invention is described by comparative example 1.Wherein, control group be commercially available commonly
Powder of lacquer putty for use on, experimental group is the water-fast antibacterial powder of lacquer putty for use on of environmental protection of the embodiment of the present invention 2 preparation.In inspection project, condition in container,
Application property, bond strength, drying time, initial dry cracking resistance and resistance to water are with reference to JB/T 298-2010 " architecture indoor
With putty " (N-type) standard test, purifying formaldehyde rate is with reference to JC/T1074-2008 " function of purifying indoor air coating material
Purifying property " standard test, antibacterium performance and Anti-mildew capability are examined with reference to HG/T3950-2007 " antibiotic paint " standard
Test.Contrast and experiment is shown in Table 1.
Table 1
| Inspection project | Standard-required | Control group | Experimental group |
| Condition in container | Without caking, uniformly | Without caking, uniformly | Without caking, uniformly |
| Application property | Scratch accessible | Scratch accessible | Scratch accessible |
| Bond strength, MPa | >0.5 | 0.62 | 3.7 |
| Drying time (surface drying), h | ≤5 | 2.5 | 1.3 |
| Initial dry cracking resistance (6h) | Flawless | Flawless | Flawless |
| Resistance to water (96h) | Without exception | Slightly dry linting, bubble and cracking | Without exception |
| Purifying formaldehyde efficiency, % | ≥75 | 0 | 89.7 |
| Antibacterium performance, % | ≥99 | 43.75 | 99.98 |
| Anti-mildew capability | 0 grade | 2 grades | 0 grade |
Although embodiment of the present invention are disclosed as above, but it is not restricted in specification and embodiment listed fortune
With, it can be applied to various applicable the field of the invention completely, for those skilled in the art, and can be easily
Realizing other amendment, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention does not limit
In specific details with shown here as the embodiment with description.
Claims (8)
1. the water-fast antibacterial powder of lacquer putty for use on of environmental protection, it is characterised in that include following raw material in parts by weight: ash calcium 500
Part, powdered whiting 500 parts, cellulose 4-10 part, pine and cypress ash 120-150 part, deer natural pond soil 80-90 part, egg-shell meal
20-30 part, gas-phase silica 15-20 part, vermiculite power 25-35 part, redispersable latex powder 24-32 part, gellan gum 50-70
Part, solid carbon dioxide lichenin 55-75 part, starch octenyl succinate anhydride 30-40 part, freeze thawing polyvinyl alcohol rubber powder 16-20 part, pine
Fragrant acid sodium 15-20 part, superfine silica gel powder 20-40 part, mushroom powder 8-12 part, pigment 1-3 part and antibacterial powder 60-70 part；
The most antibacterial powder include in parts by weight following raw material composition: lophatherum gracile powder 20-30 part, wood vinegar powder 30-42 part,
Lemon grass meal 20-25 part, gardenia powder 3-5 part, spearmint powder 12-16 part, dandelion powder 12-16 part and marjoram powder 8-12
Part.
2. the water-fast antibacterial powder of lacquer putty for use on of environmental protection as claimed in claim 1, it is characterised in that include in parts by weight is as follows
Raw material: ash calcium 500 parts, powdered whiting 500 parts, cellulose 7 parts, pine and cypress ash 135 parts, deer natural pond soil 85 parts, egg
25 parts of shell powder, gas-phase silica 18 parts, vermiculite power 30 parts, redispersable latex powder 28 parts, gellan gum 60 parts, dry
65 parts of sphagna powder, starch octenyl succinate anhydride 35 parts, freeze thawing polyvinyl alcohol rubber powder 18 parts, sodium abietate 18 parts, micro-
30 parts of powder silica gel, 10 parts of pigment of mushroom powder 2 parts and 65 parts of antibacterial powder.
3. the water-fast antibacterial powder of lacquer putty for use on of environmental protection as claimed in claim 2, it is characterised in that described antibacterial powder includes with weight
Part meter following raw material composition: 25 parts of lophatherum gracile powder, wood 36 parts of vinegar powder, lemon grass meal 23 parts, gardenia powder 4 parts, stay
Blue face powder 14 parts, 14 parts of dandelion powder and 10 parts of marjoram powder.
4. the water-fast antibacterial powder of lacquer putty for use on of environmental protection as claimed in claim 3, it is characterised in that described cellulose is hydroxypropyl first
Base cellulose, carboxymethylcellulose calcium, lignocellulosic and chitin fiber element form for 4:2:1:5 in mass ratio.
5. the water-fast antibacterial powder of lacquer putty for use on of environmental protection as claimed in claim 1, it is characterised in that described pigment be Tea Green Pigment,
Gardenia blue, clover pigment and nostoc blue pigment are 3:2:1:1 composition according to mass ratio.
6. the water-fast antibacterial powder of lacquer putty for use on of environmental protection as claimed in claim 1, it is characterised in that described pine and cypress ash be by pine tree or
The ashes remained after cypress burning use ball mill to be crushed to 200-300 mesh and prepare, and described solid carbon dioxide lichenin is to be cleaned by solid carbon dioxide tongue
After, using pulverizer to be crushed to 80-100 mesh, then it is prepared to be crushed to 200-300 mesh with ball mill, described mushroom powder is mushroom
Mushroom handle crushed after being dried prepares to 200-300 mesh, and described egg-shell meal is to be crushed to 200-300 mesh system after egg shell clean dry
?.
7. the water-fast antibacterial powder of lacquer putty for use on of environmental protection as claimed in claim 1, it is characterised in that described lophatherum gracile powder, lemon grass (Cymbopogon citratus)
Powder, spearmint powder, dandelion powder and marjoram powder are done by lophatherum gracile, lemon grass (Cymbopogon citratus), spearmint, dandelion and marjoram respectively
First use pulverizer to be crushed to 80-100 mesh after dry, then it is prepared to be crushed to 200-300 mesh with ball mill.
8. the preparation method of the water-fast antibacterial powder of lacquer putty for use on of the environmental protection as described in arbitrary in claim 1-7, it is characterised in that
Comprise the following steps:
Step one, by pine and cypress ash, deer natural pond soil, egg-shell meal, gas-phase silica, vermiculite power and the solid carbon dioxide lichenin of above-mentioned weight portion
Mix, obtain the first mixed powder；
Step 2, the redispersable latex powder by above-mentioned weight portion, gellan gum, starch octenyl succinate anhydride, the poly-second of freeze thawing
Enol rubber powder, sodium abietate, superfine silica gel powder and mushroom powder mix, and obtain the second mixed powder；
Step 3, grey calcium and the powdered whiting of above-mentioned weight portion are mixed, obtain the 3rd mixed powder；
Step 4, described first mixed powder, the second mixed powder and the 3rd mixed powder are mixed, obtain the 4th mixed powder, take
The 1/10 of described 4th mixed powder weight, mixes with the cellulose of above-mentioned weight portion, pigment and antibacterial powder, obtains the 5th and mixes
Close powder, the most again the 5th mixed powder is mixed with remaining 4th mixed powder, obtain the water-fast antibacterial powder of lacquer putty for use on of environmental protection.
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| CN106147344A (en) * | 2016-08-19 | 2016-11-23 | 桂林市春晓环保科技有限公司 | A kind of novel green Internal wall water-fast putty powder and preparation and application thereof |
| CN106147349A (en) * | 2016-08-19 | 2016-11-23 | 桂林市春晓环保科技有限公司 | A kind of Novel environmental-friendputty putty powder and preparation and application thereof |
| CN106189462A (en) * | 2016-08-25 | 2016-12-07 | 仇颖超 | A kind of preparation method of Environmental-friendputty putty powder |
| CN106752251A (en) * | 2017-02-08 | 2017-05-31 | 上海为然环保科技有限公司 | A kind of environmentally friendly water-fast antibacterial mastic powder and preparation method thereof |
| CN107383981A (en) * | 2017-08-15 | 2017-11-24 | 长兴国锋塑料有限公司 | A kind of interior wall is incubated antibacterial powder of lacquer putty for use on and its construction method |
| CN107418283A (en) * | 2017-09-11 | 2017-12-01 | 浙江理工大学 | Environmental-friendputty putty powder that a kind of high-strength antibacterial is water-fast and preparation method thereof |
| CN107722707A (en) * | 2017-11-16 | 2018-02-23 | 桂林市晟博科技服务有限公司 | A kind of environmentally friendly water-proof putty powder and preparation method thereof |
| CN109161245A (en) * | 2017-04-13 | 2019-01-08 | 刘义辉 | A kind of inner wall surface water proof putty containing water resistant additive |
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