CN1876737A - Gold brocade coating material - Google Patents
Gold brocade coating material Download PDFInfo
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- CN1876737A CN1876737A CN 200610091191 CN200610091191A CN1876737A CN 1876737 A CN1876737 A CN 1876737A CN 200610091191 CN200610091191 CN 200610091191 CN 200610091191 A CN200610091191 A CN 200610091191A CN 1876737 A CN1876737 A CN 1876737A
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Abstract
The invention relates the gold brocade coating, belonging to building textured paint field. The raw materials comprises clarity ala emulsion, mica titanium pearl essence, film former lipidol-12, dispersing agent polycarboxylate, defoaming agent NXZ and thickening agent acrylic acid series polycarboxylic acids. The coating has good environmental protection, ageing resistance and water resistance. The gold brocade coating can be used to finish wall.
Description
Technical field
The invention belongs to the architectural decorative coating technical field, relate in particular to a kind of water-soluble wall coating for building with gold brocade effect.
Background technology
China's inner wall decoration mainly is to take material as the leading factor with metope emulsion paint and wallpaper at present.Wallpaper compares with the metope emulsion paint that to have a color magnificent, the pattern salient feature, but the seam of wallpaper is easy to crack, and not environmental protection, cost height, non-anti-pollution, how to improve the prescription and the production technique of metope emulsion paint, obtaining decorating the design that exactly likes wallpaper, to demonstrate various artistic effect, is the problem that present decorative paint those skilled in the art press for solution.
On August 11st, 1999, disclosed Chinese patent application CN98124400.9 provided a kind of mercerized brocade like fluctuation color coatings, it is by polyvinyl alcohol, water, hydrochloric acid, methyl-prop diluted acid formicester, formaldehyde, urea, caustic soda etc., through heating up, dissolving, transfer pH value, add and convert reaction, cooling, dissolving, reinforced, stirring forms, it is characterized in that it is the mercerized brocade like fluctuation color coatings that is prepared by following weight (kg) proportion raw material: polyvinyl alcohol 10.00, water 75.00-90.00, hydrochloric acid 0.95, methyl-prop diluted acid formicester 0.06-0.10, formaldehyde 3.70, urea 1.00, caustic soda 0.3-0.40.Mercerising slime flux, honorable as unreal as metope behind this coatings decoration such as the damask.This decorative paint is not in order to hide the particular color of mica titanium nacreous material, raw materials such as polyvinyl alcohol have been adopted, not only scrub performance is poor but based on the coating of this raw material, quality and environmental protection aspect all do not reach the specification of quality of national regulation yet, the deepening of can fading of pattern that coating showed after after a while and color loses original decorative effect.
Summary of the invention
The purpose of this invention is to provide the gold brocade coating material of a kind of multilayer illusion-colour that can embody pearlescence and good color developing, this coating has more the feature of environmental protection, water tolerance and ageing resistance.
The technical solution adopted in the present invention is as follows:
A kind of gold brocade coating material is characterized in that this coating comprises following raw material composition: nanometer transparent pure-acrylic emulsion, mica titanium perlatolic powder, film coalescence aid alcohol ester-12, polycarboxylate type dispersion agent, defoamer NXZ and acrylic acid series polyocarboxy acid type thickening material.
This gold brocade coating material is made up of following materials of weight proportions:
Nanometer transparent pure-acrylic emulsion 30～50 female titanium pearlescences 5～15
Film coalescence aid alcohol ester-12 1.0～2.5 polycarboxylate type dispersion agent 0.3～0.9
Defoamer NXZ 0.4～1.2 acrylic acid series polyocarboxy acid type thickening material 0.2～0.8
Isothiazolinone sanitas 0.05～0.15 frostproofer propylene glycol 0.8～1.8
Deionized water 30～45
Described nanometer transparent pure-acrylic emulsion is to be that raw material carries out the commercially available nano level emulsion that copolymerization obtains with methacrylic ester and acrylate, and the solid content of this pure-acrylic emulsion is 30%～45%.
Described nanometer transparent pure-acrylic emulsion is pure third microemulsion of KD-1 type of Wuhan University Of Technology's development.
Described polycarboxylate type dispersion agent can be selected from dispersion agent DA-01, dispersion agent DA-5016 or dispersion agent DA-40.
Described defoamer NXZ can be selected from fat hydrocarbon defoamer NXZ, metallic soap type defoamer SN-Defamer NXZ or universal defoamer Foamaster NXZ.
Described acrylic acid series polyocarboxy acid type thickening material is thickening material AT-06.
The fineness of described mica titanium perlatolic powder is 800～1200 orders.
The preparation technology of this gold brocade coating material is characterized in that the preparation technology of this coating is as follows:
In deionized water, drop into polycarboxylate type dispersion agent, defoamer NXZ, isothiazolinone sanitas and frostproofer propylene glycol, under 200～300 rev/mins stirring velocity, mix, add the mica titanium perlatolic powder then, high-speed stirring is made the pearly pigment slurry under 600～800 rev/mins condition; Reduce rotating speed to 200～300 rev/min, add the nanometer transparent pure-acrylic emulsion and mix, slowly add film coalescence aid alcohol ester-12 and fully mix; Filter back standing and reacting under vacuum condition, obtain this gold brocade coating material.
The nanometer transparent pure-acrylic emulsion is to be raw material with methacrylic ester and acrylate, carries out the nano level emulsion that copolymerization obtains under certain condition, and the solid content of this pure-acrylic emulsion is 30%～45%.Multiple these nanometer transparent pure-acrylic emulsion commodity are arranged on the market.Adopt the special surface promoting agent KD-1 of the homemade Gemini of belonging to type to be used for the polymerization of pure third microemulsion as Wuhan University Of Technology, the result shows, only need just can obtain pure third microemulsion of transparent nano level of higher solids content, and keep fine latex median size 29nm～39nm with 1.44%～2.15% single anion type emulsifying agent KD-1.Than conventional pure-acrylic emulsion, particle diameter is little, and minimum film-forming temperature (MFT) decreases, and second-order transition temperature increases.This nanometer transparent pure-acrylic emulsion is compared with traditional PVA acetal adhesive solution simultaneously, has more environmental protection, water-fast and ageing resistance, and it is also more convenient to construct.
The mica titanium perlatolic powder covers the sandwich platelet that metal oxide is formed outward by the natural mica thin slice.Dependence is to ray refraction, and form and aspect and gloss are created in transmission, and this pearlescence has high refractive index and good transparency, makes it create the effect identical with natural peral gloss in transparent medium.
The chemical name of film coalescence aid alcohol ester-12 is 2,2,4-trimethylammonium-1, and the 3-pentanediol mono isobutyrate, it can improve the film forming properties of emulsion paint, reduces the minimum film-forming temperature of emulsion paint, improves the scrub resistance of emulsion paint, improves the emulsion paint color developing.In emulsion paint, use this product, can be lowered into film temperature effectively, improve the paint film scrub resistance, improve the pigment homogeneity, have good color developing, improve paint film adhesion, reduce Alligatoring, peel off.The not hydrolysis in general alkaline medium of this film coalescence aid has good preservation stability.Under the mal-condition lower in temperature, that humidity is bigger, still have film forming properties preferably.Therefore, in emulsion paint, use this product in right amount, can improve the performance of product effectively.
Polycarboxylate type dispersion agent can effectively carry out homodisperse with pearlescence, and the improvement system is to the wettability of pigment, shorten milling time, stable pigments dispersion system, prevent pigment flocculation, reduce loose colour, tendency such as grow dim.DA is a kind of dispersion agent that is widely used in water-borne coatings, is the polymer aqueous solution of polycarboxylate type, and it has splendid molecular weight and the molecular weight distribution that is rather narrow, and is in the emulsion paint manufacturing processed, fine with the consistency of whole coating system.Select for use the DA dispersion agent can obtain best system lacquer viscosity.After adding the DA dispersion agent, can improve the mud jacking efficient of coating, effectively suppress returning of color stuffing and slightly reach the viscosity knock-on that face is filled out slurry, thereby improve the stability in storage of coating.The dispersion agent that the present invention uses can be dispersion agent DA-01, dispersion agent DA-5016 or the dispersion agent DA-40 in the dispersion agent of commercial goods.
Acrylic acid series polyocarboxy acid type thickening material AT-06 can give moderate levelling of coating system and sagging performance, has excellent compatibility with various Emulsion Adhesives, thickening efficiency height, good rheological property.Storage and stability in use through the latex after its thickening are all good, and can satisfy the requirement of the multiple form of construction work course of processing.
The isothiazolinone sanitas is the high-performance anticorrosion and bactericidal agent by Rhom and Hass's Development and Production, it is applicable to emulsion paint, all kinds of water-borne coatings, emulsion polymerization, also can be used for suppressing bacterium and fungi growing at production and memory print printing ink and other moisture organic products.To phenylpropyl alcohol, vinegar third, pure third and other multipolymer fabulous preservative efficacy is arranged, and fabulous compatible conformability is arranged with organic and inorganics composition in these products.The isothiazolinone sanitas to phenylpropyl alcohol, vinegar third, pure third and other multipolymer fabulous preservative efficacy is arranged, and fabulous compatible conformability is arranged with organic and inorganics composition in these products.Isothiazolinone sanitas used in the present invention can be that the trade name that Rhom and Hass produces is the sanitas of Kathon LXE, also can be the sanitas LXE that Shenzhen Haichuan Company is produced.
The production technique of this gold brocade coating material is easy, only need earlier dispersion agent, defoamer, sanitas and frostproofer and aqueous solvent to be mixed, once add pearlescence, nanometer transparent pure-acrylic emulsion, film forming pearl auxiliary agent and thickening material then, under certain stirring velocity, mix, static placement certain hour (being generally 24 hours) under vacuum condition can obtain at last.
The present invention adopts the reasonably combined of nanometer transparent pure-acrylic emulsion and various auxiliary agents, more can embody the multilayer illusion-colour of pearlescence and good color developing, and have not in the effect that can observe different color with angle, its manufacture craft is easy, has more favorable environment protection energy, water tolerance and ageing resistance.This gold brocade coating material can be used for the fitting-up of all-environment indoor wall.
Embodiment
The present invention is further elaborated below in conjunction with embodiment.
Embodiment 1 presses each feed composition that column weight amount proportioning is got this gold brocade coating material:
(Wuhan University Of Technology makes nanometer transparent pure-acrylic emulsion KD-1,) 40kg, Shantou, Guangdong Longhua company produces mica titanium perlatolic powder (fineness 800 orders) 10kg, film coalescence aid alcohol ester-12 (Jilin Petrochemical company product) 1.7kg, Beijing Orient acrylic chemical company produces polycarboxylate type dispersion agent DA-01 0.6kg, the defoamer NXZ0.8kg that Shenzhen Haichuan Company is produced, Beijing Orient acrylic chemical company produces acrylic acid series polyocarboxy acid type thickening material AT-06 0.5kg, the sanitas LXE 0.09kg that Shenzhen Haichuan Company is produced, Yanshan Petrochemical is produced frostproofer propylene glycol 1.3kg, deionized water 40kg.
Earlier deionized water is poured in the dispersion machine, begun to stir, stirring velocity is controlled to be 200～300 rev/mins, is sequentially added into dispersion agent, defoamer, sanitas and frostproofer and mixes about 15 minutes; Add the mica titanium perlatolic powder again, adjusting rotating speed stirred under 600～800 rev/mins condition 10～20 minutes, make the pearly pigment slurry, rotating speed is reduced to 200～300 rev/mins again, add the transparent pure-acrylic emulsion of nanometer, stir and mixed in 5～10 minutes, slowly add thickening material, add back restir 5～10 minutes fully to evenly in the thread mode.Filter mixed solution with vibratory screening apparatus, vacuum sealed package, static placement makes its reaction obtain this gold brocade coating material finished product after 24 hours.
This gold brocade coating material finished product is carried out every index detect, and contrast with standard GB 18582-2001, testing conditions is a temperature: 23 ± 2 ℃, humidity 50 ± 5% detects data and sees Table 1.
Every detection data of table 1 coating of the present invention and GB contrast information slip
| Test event | Unit | GB is limited the quantity of | Test result | |
| Volatile organic compounds (VOC) | g/L | ≤200 | 53 | |
| Free formaldehyde | g/kg | ≤0.1 | 0.019 | |
| Heavy metal | Dissoluble lead | mg/kg | ≤90 | 4.63 |
| Soluble cadmium | mg/kg | ≤75 | 1.36 | |
| Soluble chromium | mg/kg | ≤60 | 2.12 | |
| Soluble mercury | mg/kg | ≤60 | 0.47 | |
As can be seen from the above table, every performance index of gold brocade coating material provided by the invention all are better than the national standard of limits of harmful substances in the indoor hardware fitting interior wall coating.Simultaneously this gold brocade coating material is applied to the decoration that whitewashes of indoor wall, its every detected result sees Table 2.Coating after whitewashing can show the pearly-lustre color of mica titanium perlatolic powder completely, and because ray refraction can be observed different colors from different angles, decorative effect is good.
Whitewashing and the application performance test data of table 2 coating of the present invention
| Test event | Technical requirements | Test result | ||
| Premium grads | Acceptable end product | Salable product | ||
| Condition in container | No lump is uniform state after the stirring | By | ||
| Application property | It is accessible to brush two roads | By | ||
| Low-temperature stability | Never degenerate | By | ||
| Time of drying (surface drying) | ≤2h | 35min | ||
| Appearance of film | Normally | By | ||
| Contrast ratio (white and light color) | ≥0.95 | ≥0.93 | ≥0.90 | 0.96 |
| Alkali resistance (24h) | No abnormal | By | ||
| Anti-whitewashing property, inferior | ≥1000 | ≥500 | ≥200 | 10000 times, no abnormal |
Embodiment 2 presses each marketable material component that column weight amount proportioning is got this gold brocade coating material:
(Wuhan University Of Technology makes nanometer transparent pure-acrylic emulsion KD-1,) 30kg, Shantou, Guangdong Longhua company produces mica titanium perlatolic powder (fineness 1000 orders) 15kg, film coalescence aid alcohol ester-12 (Jilin Petrochemical company product) 1.0kg, Beijing Orient acrylic chemical company produces polycarboxylate type dispersion agent DA-5016 0.9kg, metallic soap type defoamer SN-Defamer NXZ 0.4kg, Beijing Orient acrylic chemical company produces acrylic acid series polyocarboxy acid type thickening material AT-06 0.8kg, U.S. Rhom and Hass produces sanitas Kathon LXE 0.05kg, Yanshan Petrochemical is produced frostproofer propylene glycol 1.8kg, deionized water 45kg.
Earlier deionized water is poured in the dispersion machine, begun to stir, stirring velocity is controlled to be 200～300 rev/mins, is sequentially added into dispersion agent, defoamer, sanitas and frostproofer and mixes about 15 minutes; Add the mica titanium perlatolic powder again, adjusting rotating speed stirred 20 minutes under 600～800 rev/mins condition, make the pearly pigment slurry, rotating speed is reduced to 200～300 rev/mins again, add the transparent pure-acrylic emulsion of nanometer, stir and mixed in 10 minutes, slowly add thickening material, add back restir 5～10 minutes fully to evenly in the thread mode.Filter mixed solution with vibratory screening apparatus, vacuum sealed package, static placement makes its reaction obtain this gold brocade coating material finished product after 24 hours.
Embodiment 3 presses each marketable material component that column weight amount proportioning is got this gold brocade coating material:
(Wuhan University Of Technology makes nanometer transparent pure-acrylic emulsion KD-1,) 50kg, Shantou, Guangdong Longhua company produces mica titanium perlatolic powder (fineness 1200 orders) 5kg, film coalescence aid alcohol ester-12 2.5kg, Beijing Orient acrylic chemical company produces polycarboxylate type dispersion agent DA-40 0.3kg, universal defoamer FoamasterNXZ 1.2kg, Beijing Orient acrylic chemical company produces acrylic acid series polyocarboxy acid type thickening material AT-060.2kg, U.S. Rhom and Hass produces sanitas Kathon LXE 0.15kg, Yanshan Petrochemical is produced frostproofer propylene glycol 0.8kg, deionized water 30kg.
Earlier deionized water is poured in the dispersion machine, begun to stir, stirring velocity is controlled to be 200～300 rev/mins, is sequentially added into dispersion agent, defoamer, sanitas and frostproofer and mixes about 15 minutes; Add the mica titanium perlatolic powder again, adjusting rotating speed stirred 20 minutes under 600～800 rev/mins condition, make the pearly pigment slurry, rotating speed is reduced to 200～300 rev/mins again, add the transparent pure-acrylic emulsion of nanometer, stir and mixed in 10 minutes, slowly add thickening material, add back restir 5～10 minutes fully to evenly in the thread mode.Filter mixed solution with vibratory screening apparatus, vacuum sealed package, static placement makes its reaction obtain this gold brocade coating material finished product after 24 hours.
Claims (9)
1. a gold brocade coating material is characterized in that this coating comprises following raw material composition: nanometer transparent pure-acrylic emulsion, mica titanium perlatolic powder, film coalescence aid alcohol ester-12, polycarboxylate type dispersion agent, defoamer NXZ and acrylic acid series polyocarboxy acid type thickening material.
2. gold brocade coating material according to claim 1 is characterized in that this coating is made up of following materials of weight proportions:
Nanometer transparent pure-acrylic emulsion 30～50 removes female titanium pearlescence 5～15
Film coalescence aid alcohol ester-12 1.0～2.5 polycarboxylate type dispersion agent 0.3～0.9
Defoamer NXZ 0.4～1.2 acrylic acid series polyocarboxy acid type thickening material 0.2～0.8
Isothiazolinone sanitas 0.05～0.15 frostproofer propylene glycol 0.8～1.8
Deionized water 30～45.
3. gold brocade coating material according to claim 1 is characterized in that described nanometer transparent pure-acrylic emulsion is is that raw material carries out the commercially available nano level emulsion that copolymerization obtains with methacrylic ester and acrylate, and the solid content of this pure-acrylic emulsion is 30%～45%.
4. gold brocade coating material according to claim 1 is characterized in that described nanometer transparent pure-acrylic emulsion is pure third microemulsion of KD-1 type of Wuhan University Of Technology's development.
5. gold brocade coating material according to claim 1 is characterized in that described polycarboxylate type dispersion agent can be selected from dispersion agent DA-01, dispersion agent DA-5016 or dispersion agent DA-40.
6. gold brocade coating material according to claim 1 is characterized in that described defoamer NXZ can be selected from fat hydrocarbon defoamer NXZ, metallic soap type defoamer SN-Defamer NXZ or universal defoamer Foamaster NXZ.
7. gold brocade coating material according to claim 1 is characterized in that described acrylic acid series polyocarboxy acid type thickening material is thickening material AT-06.
8. gold brocade coating material according to claim 1, the fineness that it is characterized in that described mica titanium perlatolic powder is 800～1200 orders.
9. the preparation technology of claim 1 or 2 described gold brocade coating materials is characterized in that the preparation technology of this coating is as follows:
In deionized water, drop into polycarboxylate type dispersion agent, defoamer NXZ, isothiazolinone sanitas and frostproofer propylene glycol, under 200～300 rev/mins stirring velocity, mix, add the mica titanium perlatolic powder then, high-speed stirring is made the pearly pigment slurry under 600～800 rev/mins condition; Reduce rotating speed to 200～300 rev/min, add the nanometer transparent pure-acrylic emulsion and mix, slowly add film coalescence aid alcohol ester-12 and fully mix; Filter back standing and reacting under vacuum condition, obtain this gold brocade coating material.
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| CN 200610091191 CN1876737A (en) | 2006-07-06 | 2006-07-06 | Gold brocade coating material |
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| CN 200610091191 CN1876737A (en) | 2006-07-06 | 2006-07-06 | Gold brocade coating material |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560352A (en) * | 2009-05-31 | 2009-10-21 | 铜陵市绿冉环保涂料有限责任公司 | Color cement tile water based paint |
| CN103696284A (en) * | 2013-12-23 | 2014-04-02 | 苏州大学 | Special pearlescent paste for Suzhou embroideries as well as preparation method and application of special pearlescent paste |
| CN104073099A (en) * | 2013-03-27 | 2014-10-01 | 高建平 | Finish coating |
| CN105440857A (en) * | 2015-12-31 | 2016-03-30 | 重庆发顺化工有限责任公司 | Cloud wire coating and processing method thereof |
| CN108384289A (en) * | 2018-01-23 | 2018-08-10 | 浙江博星化工涂料有限公司 | A kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect |
| CN109161268A (en) * | 2018-08-22 | 2019-01-08 | 富思特新材料科技发展股份有限公司 | A kind of interior wall water-based metal low luster coating and preparation method thereof of decomposable formaldehyde |
| CN109439105A (en) * | 2017-08-30 | 2019-03-08 | 罗雪洁 | A kind of anti-aging water paint for internal walls of environmental protection |
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2006
- 2006-07-06 CN CN 200610091191 patent/CN1876737A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560352A (en) * | 2009-05-31 | 2009-10-21 | 铜陵市绿冉环保涂料有限责任公司 | Color cement tile water based paint |
| CN104073099A (en) * | 2013-03-27 | 2014-10-01 | 高建平 | Finish coating |
| CN103696284A (en) * | 2013-12-23 | 2014-04-02 | 苏州大学 | Special pearlescent paste for Suzhou embroideries as well as preparation method and application of special pearlescent paste |
| CN105440857A (en) * | 2015-12-31 | 2016-03-30 | 重庆发顺化工有限责任公司 | Cloud wire coating and processing method thereof |
| CN109439105A (en) * | 2017-08-30 | 2019-03-08 | 罗雪洁 | A kind of anti-aging water paint for internal walls of environmental protection |
| CN108384289A (en) * | 2018-01-23 | 2018-08-10 | 浙江博星化工涂料有限公司 | A kind of coating and preparation method thereof of imitative yellow mud bar crackle metope effect |
| CN109161268A (en) * | 2018-08-22 | 2019-01-08 | 富思特新材料科技发展股份有限公司 | A kind of interior wall water-based metal low luster coating and preparation method thereof of decomposable formaldehyde |
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