CN108367933B - 用于处理含锂材料的方法 - Google Patents

用于处理含锂材料的方法 Download PDF

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Publication number
CN108367933B
CN108367933B CN201680060790.XA CN201680060790A CN108367933B CN 108367933 B CN108367933 B CN 108367933B CN 201680060790 A CN201680060790 A CN 201680060790A CN 108367933 B CN108367933 B CN 108367933B
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lithium
aqueous composition
bipolar membrane
membrane electrolysis
compartment monopolar
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Chinese (zh)
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CN108367933A (zh
Inventor
珍-弗朗索瓦·马尼安
盖伊·布拉萨
尼古拉斯·拉罗什
盖理·皮尔斯
斯蒂芬·查尔斯·麦凯
米科拉斯·格拉德科瓦斯
彼得·西蒙斯
J·大卫·亨德尔斯
吉纳维芙·克莱顿
皮埃尔·布沙尔
贝尔坦·奥莱特
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Nemaska Lithium Inc
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Nemaska Lithium Inc
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/46—Apparatus therefor
    • B01D61/465—Apparatus therefor comprising the membrane sequence AB or BA, where B is a bipolar membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/46—Apparatus therefor
    • B01D61/466—Apparatus therefor comprising the membrane sequence BC or CB
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/58—Multistep processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/06—Sulfates; Sulfites
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/02—Roasting processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/007—Wet processes by acid leaching
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/14—Alkali metal compounds
    • C25B1/16—Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Health & Medical Sciences (AREA)
  • Urology & Nephrology (AREA)
  • Nanotechnology (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
CN201680060790.XA 2015-08-27 2016-08-26 用于处理含锂材料的方法 Active CN108367933B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562210977P 2015-08-27 2015-08-27
US62/210,977 2015-08-27
PCT/CA2016/051008 WO2017031595A1 (en) 2015-08-27 2016-08-26 Methods for treating lithium-containing materials

Publications (2)

Publication Number Publication Date
CN108367933A CN108367933A (zh) 2018-08-03
CN108367933B true CN108367933B (zh) 2020-10-09

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US (1) US10597305B2 (cg-RX-API-DMAC7.html)
EP (1) EP3341330B1 (cg-RX-API-DMAC7.html)
JP (1) JP7030049B2 (cg-RX-API-DMAC7.html)
KR (1) KR102559772B1 (cg-RX-API-DMAC7.html)
CN (1) CN108367933B (cg-RX-API-DMAC7.html)
AU (2) AU2016312997A1 (cg-RX-API-DMAC7.html)
CA (1) CA2996651C (cg-RX-API-DMAC7.html)
CL (1) CL2018000522A1 (cg-RX-API-DMAC7.html)
WO (1) WO2017031595A1 (cg-RX-API-DMAC7.html)

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PT2855735T (pt) 2012-05-30 2018-06-14 Nemaska Lithium Inc Processos de preparação de carbonato de lítio
ES2859556T3 (es) 2013-03-15 2021-10-04 Nemaska Lithium Inc Procesos para preparar hidróxido de litio
KR102132463B1 (ko) 2013-10-23 2020-08-06 네마스카 리튬 인코포레이션 리튬 카보네이트의 제조방법
CN106103806B (zh) 2014-02-24 2019-07-12 内玛斯卡锂业有限公司 处理含锂材料的方法
KR20180043792A (ko) 2015-08-28 2018-04-30 알베마를 코포레이션 리튬-함유 염수로부터 리튬 유가물을 회수하는 방법
CA2940509A1 (en) 2016-08-26 2018-02-26 Nemaska Lithium Inc. Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid
KR102400367B1 (ko) 2017-11-22 2022-05-23 네마스카 리튬 인코포레이션 다양한 금속의 하이드록사이드와 옥사이드 및 이들의 유도체를 제조하는 방법
KR101957706B1 (ko) * 2018-09-20 2019-03-13 한국지질자원연구원 리튬망간산화물로부터 리튬 회수 방법
CN109331663A (zh) * 2018-11-13 2019-02-15 北京廷润膜技术开发股份有限公司 双极性膜置换电渗析装置和采用双极性膜置换电渗析装置制备氢氧化锂的方法
KR102164661B1 (ko) 2018-12-06 2020-10-12 주식회사 에코프로이노베이션 리튬 정광으로부터 황산나트튬 혼합 배소에 의한 수산화리튬 제조방법
CA3195237C (en) 2018-12-21 2023-12-19 Mangrove Water Technologies Ltd Li recovery processes and onsite chemical production for li recovery processes
CA3141478A1 (en) 2019-05-22 2020-11-26 Nemaska Lithium Inc. Processes for preparing hydroxides and oxides of various metals and derivatives thereof
KR102325755B1 (ko) * 2019-12-20 2021-11-11 주식회사 포스코 리튬 화합물 제조방법
CN111235591B (zh) * 2020-03-04 2021-06-04 杭州科锐环境能源技术有限公司 一种由锂辉石硫酸浸出液制备单水氢氧化锂的方法
JP2022075619A (ja) * 2020-11-06 2022-05-18 出光興産株式会社 水酸化リチウムの製造方法
US20230406718A1 (en) * 2020-11-06 2023-12-21 Idemitsu Kosan Co.,Ltd. Method for producing lithium hydroxide
CN117043109A (zh) * 2021-03-25 2023-11-10 出光兴产株式会社 氢氧化锂的制造方法
MX2021012211A (es) * 2021-10-04 2023-04-05 Hot Spring Mining S A De C V Proceso de concentracion de litio y potasio a partir de arcillas provenientes de salares.
JP7100217B1 (ja) 2022-01-05 2022-07-12 Ｊｘ金属株式会社 リチウムイオン電池廃棄物の金属回収方法
JP7100211B1 (ja) 2022-01-05 2022-07-12 Ｊｘ金属株式会社 リチウムイオン電池廃棄物の金属回収方法
KR102873038B1 (ko) * 2022-12-16 2025-10-20 포스코홀딩스 주식회사 리튬 회수용 수세액 및 리튬 함유 폐액으로부터 리튬의 회수 방법
KR102648802B1 (ko) 2023-07-25 2024-03-18 주식회사 리켐텍 메카노케미스트리 및 알카리프리팅 공정을 이용하여 폐 탈황분진을 리튬 제조 공정에 활용하는 방법.

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