CN108358191A - 一种低缺陷石墨烯及其制备方法 - Google Patents
一种低缺陷石墨烯及其制备方法 Download PDFInfo
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- CN108358191A CN108358191A CN201810444553.4A CN201810444553A CN108358191A CN 108358191 A CN108358191 A CN 108358191A CN 201810444553 A CN201810444553 A CN 201810444553A CN 108358191 A CN108358191 A CN 108358191A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 217
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 197
- 230000007547 defect Effects 0.000 title claims abstract description 66
- 238000002360 preparation method Methods 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 claims description 36
- 239000003638 chemical reducing agent Substances 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- OBOXTJCIIVUZEN-UHFFFAOYSA-N [C].[O] Chemical group [C].[O] OBOXTJCIIVUZEN-UHFFFAOYSA-N 0.000 claims description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 12
- 239000010439 graphite Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 6
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 8
- 150000001721 carbon Chemical group 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 239000002667 nucleating agent Substances 0.000 description 21
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 7
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
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- 238000005229 chemical vapour deposition Methods 0.000 description 2
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- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
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- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
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- 239000003574 free electron Substances 0.000 description 1
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- -1 graphite Alkene Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 230000005693 optoelectronics Effects 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/22—Electronic properties
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Abstract
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109179387A (zh) * | 2018-11-16 | 2019-01-11 | 重庆大学 | 一种制备石墨烯的方法及其制得的石墨烯 |
CN109231190A (zh) * | 2018-11-02 | 2019-01-18 | 重庆大学 | 制备还原氧化石墨烯的方法及其制得的还原氧化石墨烯 |
CN110093058A (zh) * | 2019-05-21 | 2019-08-06 | 郑州新世纪材料基因组工程研究院有限公司 | 防腐涂料用低缺陷石墨烯组合物、浆料及其制备方法、防腐涂料 |
CN110482535A (zh) * | 2019-09-24 | 2019-11-22 | 大连海事大学 | 一种液相微波等离子体还原氧化石墨烯的方法及装置 |
CN110615970A (zh) * | 2019-09-16 | 2019-12-27 | 海安南京大学高新技术研究院 | 高品质石墨烯及其导热导电环氧树脂复合材料及其制备方法 |
CN113089371A (zh) * | 2021-04-14 | 2021-07-09 | 新乡医学院 | 一种还原氧化石墨烯纸及其制备方法 |
CN114590799A (zh) * | 2022-03-28 | 2022-06-07 | 南通第六元素材料科技有限公司 | 石墨烯制备方法、石墨烯粉体及产品 |
CN116239106A (zh) * | 2023-02-16 | 2023-06-09 | 广东轻工职业技术学院 | 一种微波辅助制备高导热还原氧化石墨烯气凝胶的方法 |
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CN102602925A (zh) * | 2012-04-13 | 2012-07-25 | 常州第六元素材料科技股份有限公司 | 一种高压还原制备石墨烯的方法 |
CN102951631A (zh) * | 2011-08-29 | 2013-03-06 | 海洋王照明科技股份有限公司 | 一种石墨烯的制备方法 |
CN103204499A (zh) * | 2013-04-24 | 2013-07-17 | 张家港市东大工业技术研究院 | 一种制备海绵状石墨烯的方法 |
CN104843689A (zh) * | 2015-04-22 | 2015-08-19 | 浙江大学 | 一种定位制备石墨烯薄膜的方法 |
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CN103204499A (zh) * | 2013-04-24 | 2013-07-17 | 张家港市东大工业技术研究院 | 一种制备海绵状石墨烯的方法 |
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CN106865529A (zh) * | 2017-03-30 | 2017-06-20 | 南开大学 | 一种触发方式的微波辅助高品质还原氧化石墨烯的制备方法 |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109231190A (zh) * | 2018-11-02 | 2019-01-18 | 重庆大学 | 制备还原氧化石墨烯的方法及其制得的还原氧化石墨烯 |
CN109179387A (zh) * | 2018-11-16 | 2019-01-11 | 重庆大学 | 一种制备石墨烯的方法及其制得的石墨烯 |
CN110093058A (zh) * | 2019-05-21 | 2019-08-06 | 郑州新世纪材料基因组工程研究院有限公司 | 防腐涂料用低缺陷石墨烯组合物、浆料及其制备方法、防腐涂料 |
CN110093058B (zh) * | 2019-05-21 | 2021-04-13 | 郑州新世纪材料基因组工程研究院有限公司 | 防腐涂料用低缺陷石墨烯组合物、浆料及其制备方法、防腐涂料 |
CN110615970A (zh) * | 2019-09-16 | 2019-12-27 | 海安南京大学高新技术研究院 | 高品质石墨烯及其导热导电环氧树脂复合材料及其制备方法 |
CN110482535A (zh) * | 2019-09-24 | 2019-11-22 | 大连海事大学 | 一种液相微波等离子体还原氧化石墨烯的方法及装置 |
CN110482535B (zh) * | 2019-09-24 | 2024-05-03 | 大连海事大学 | 一种液相微波等离子体还原氧化石墨烯的方法及装置 |
CN113089371A (zh) * | 2021-04-14 | 2021-07-09 | 新乡医学院 | 一种还原氧化石墨烯纸及其制备方法 |
CN114590799A (zh) * | 2022-03-28 | 2022-06-07 | 南通第六元素材料科技有限公司 | 石墨烯制备方法、石墨烯粉体及产品 |
CN114590799B (zh) * | 2022-03-28 | 2024-05-10 | 南通第六元素材料科技有限公司 | 石墨烯制备方法、石墨烯粉体及产品 |
CN116239106A (zh) * | 2023-02-16 | 2023-06-09 | 广东轻工职业技术学院 | 一种微波辅助制备高导热还原氧化石墨烯气凝胶的方法 |
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Effective date of registration: 20240315 Address after: Room A319, Building A, No. 901 Development Avenue, Economic and Technological Development Zone, Suqian City, Jiangsu Province, 223800- GYY00326 Patentee after: Guosheng Advanced Technology Innovation Park (Jiangsu) Co.,Ltd. Country or region after: China Address before: No.1-436, Zhongyuan Zhigu, intersection of Zhongyuan West Road and Feilong Road, Xingyang City, Zhengzhou City, Henan Province Patentee before: ZHENGZHOU NEW CENTURY MATERIAL GENOME ENGINEERING RESEARCH INSTITUTE CO.,LTD. Country or region before: China |