CN108357176A - 一种环保防水卷材及其制备方法 - Google Patents

一种环保防水卷材及其制备方法 Download PDF

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CN108357176A
CN108357176A CN201810072677.4A CN201810072677A CN108357176A CN 108357176 A CN108357176 A CN 108357176A CN 201810072677 A CN201810072677 A CN 201810072677A CN 108357176 A CN108357176 A CN 108357176A
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parts
layer
retardant
flame
coiled material
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马义才
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Fuhua Novel Material Co Ltd Of Section In Hefei
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Abstract

本发明公开了一种环保防水卷材及其制备方法,涉及防水卷材技术领域。本发明包括阻燃层、防水层、紫外线吸收层、硅胶层和帆布层。本发明通过设置阻燃层、防水层、紫外线吸收层、硅胶层和帆布层,使卷材能同时满足阻燃、防水、防紫外线和高强度,拓宽了卷材的应用范围。在阻燃层靠近防水层的一侧均设圆形凸起,紫外线吸收层的上下表面均设条形凸起,提高了层与层之间的结合牢度,防止在使用的过程中层与层之间分离,提高卷材的使用寿命。

Description

一种环保防水卷材及其制备方法
技术领域
本发明属于防水卷材技术领域,特别是涉及一种环保防水卷材及其制备方法。
背景技术
防水卷材主要是用于建筑墙体、屋面、以及隧道、公路、垃圾填埋场等处,起到抵御外界雨水、地下水渗漏的一种可卷曲成卷状的柔性建材产品,作为工程基础与建筑物之间无渗漏连接,是整个工程防水的第一道屏障,对整个工程起着至关重要的作用。
现有的防水卷材多为沥青防水材料、高聚物改性防水卷材,卷材多为单层或多层复合结构。有些卷材虽然防水性能很好但是阻燃性和防紫外线性能很差,有些具有阻燃性但是防水性和强度又很差,有些复合结构的卷材阻燃性、防水性、强度都很好但是复合层之间的牢度又不行。
如何提高防水卷材的综合性能是目前亟待解决的问题。
发明内容
本发明的目的在于提供一种环保防水卷材及其制备方法,通过设置阻燃层、防水层、紫外线吸收层、硅胶层和帆布层,在阻燃层的一侧均设有圆形凸起、紫外线吸收层的上下表面均设有条形凸起。解决了现有的防水卷材综合性能差的问题。
为解决上述技术问题,本发明是通过以下技术方案实现的:
本发明为一种环保防水卷材及其制备方法,包括
阻燃层、防水层、紫外线吸收层、硅胶层和帆布层;
所述阻燃层靠近所述防水层的一侧均设有圆形凸起,所述紫外线吸收层的上下表面均设有条形凸起。
进一步地,所述圆形凸起的表面设有凹槽。
进一步地,所述阻燃层包括以下成分:
聚丙烯 62份~80份
阻燃剂 10份~19份
分散剂 10份~15份
增韧剂 2份~15份
钛白粉 15份~20份
所述防水层为丁基橡胶自粘层,包括如下成分:
丁基橡胶 22份~30份
乙烯醋酸乙烯共聚物 4份~5.2份
偶联剂 0.3份~0.5份
增粘树脂 18份~25份
炭黑 11份~12份
轻质碳酸钙 6份~9份
防老剂 0.3份~0.5份
稳定剂 0.6份-0.8份;
所述紫外线吸收层成分如下:
PVC树脂 40份~75份
热稳定剂 0.5份~2份
增塑剂 15份~20份
紫外线吸收剂 0.01份~0.2份
空心玻璃微珠 20份~30份
轻质碳酸钙 10份~15份。
进一步地,所述阻燃剂是氢氧化镁;所述分散剂是硬脂酸单甘油酯;所述增韧剂为丁二烯橡胶,所述钛白粉为金红石型,所述偶联剂为乙烯基三甲氧基硅烷。
进一步地,所述阻燃层的厚度在1-2mm范围。
一种环保防水卷材的制备方法,包括如下步骤:
步骤一,制作阻燃层:先将聚丙烯、阻燃剂、分散剂、增韧剂、钛白粉加入高速捏合机中捏合3-5分钟;捏合后的物料经挤压机和压延机压制成一表面带有圆形凸起的阻燃层;
步骤二,制作防水层:先将丁基橡胶、乙烯醋酸乙烯共聚物、轻质碳酸钙、偶联剂放入高速开炼机中,在80℃~90℃下开炼5分钟得到丁基橡胶薄片;将丁基橡胶薄片、增粘树脂、炭黑、防老剂、稳定剂加入橡胶捏合机中,温度控制在80℃~100℃到膏状丁基橡胶备用;
步骤三,制作紫外线吸收层:先将PVC树脂、热稳定剂、增塑剂、放入捏合机中温度控制在100℃~130℃,捏合5~10分钟,之后加入紫外线吸收剂、轻质碳酸钙和空心玻璃微珠以相同的速度捏合,温度控制在160℃~180℃,捏合3~5分钟后依次进入挤出机、压延机制成上下表面均带有条形凸起的紫外线吸收层;
步骤四,将紫外线吸收层、硅胶层、将帆布层依次压合;
步骤五,将膏状丁基橡胶涂抹到紫外线吸收层的上表面;
步骤六,将阻燃层带有圆形凸起的一面贴合到丁基橡胶上得到最终的成品。
本发明具有以下有益效果:
本发明通过设置阻燃层、防水层、紫外线吸收层、硅胶层和帆布层,使卷材能同时满足阻燃、防水、防紫外线和高强度,拓宽了卷材的应用范围。在阻燃层靠近防水层的一侧均设圆形凸起,紫外线吸收层的上下表面均设条形凸起,提高了层与层之间的结合牢度,防止在使用的过程中层与层之间分离,提高卷材的使用寿命。
当然,实施本发明的任一产品并不一定需要同时达到以上所述的所有优点。
附图说明
为了更清楚地说明本发明实施例的技术方案,下面将对实施例描述所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。
图1为本发明具体实施例的结构示意图;
附图中,各标号所代表的部件列表如下:
1-阻燃层,2-防水层,3-紫外线吸收层,4-硅胶层,5-帆布层,101-圆形凸起,301-条形凸起。
具体实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。
在本发明的描述中,需要理解的是,术语“一侧”、“上”、“下”、“厚度”、“表面”、“中”等指示方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的组件或元件必须具有特定的方位,以特定的方位构造和操作,因此不能理解为对本发明的限制。
请参阅图1所示,本发明为一种环保防水卷材及其制备方法,包括
阻燃层1、防水层2、紫外线吸收层3、硅胶层4和帆布层;
阻燃层1靠近防水层2的一侧均设有圆形凸起101,如此,可以提高阻燃层1与防水层2的结合牢度。紫外线吸收层3的上下表面均设有条形凸起301,如此可以提高紫外线吸收层3与防水层2、硅胶层4的结合牢度。
其中,圆形凸起101的表面设有凹槽,如此,可以增大摩擦力,进一步提高阻燃层1与防水层2的结合牢度。
其中,阻燃层1包括以下成分:
聚丙烯 62份~80份
阻燃剂 10份~19份
分散剂 10份~15份
增韧剂 2份~15份
钛白粉 15份~20份
防水层2为丁基橡胶自粘层,包括如下成分:
丁基橡胶 22份~30份
乙烯醋酸乙烯共聚物 4份~5.2份
偶联剂 0.3份~0.5份
增粘树脂 18份~25份
炭黑 11份~12份
轻质碳酸钙 6份~9份
防老剂 0.3份~0.5份
稳定剂 0.6份-0.8份;
紫外线吸收层3成分如下:
PVC树脂 40份~75份
热稳定剂 0.5份~2份
增塑剂 15份~20份
紫外线吸收剂 0.01份~0.2份
空心玻璃微珠 20份~30份
轻质碳酸钙 10份~15份。
其中,阻燃剂是氢氧化镁;分散剂是硬脂酸单甘油酯;增韧剂为丁二烯橡胶,钛白粉为金红石型,偶联剂为乙烯基三甲氧基硅烷。
其中,阻燃层1的厚度在1-2mm范围。
具体实施时,增塑剂为二辛酯,阻燃层1的厚度在0.5-2mm,防水层2的厚度为阻燃层1的2倍,紫外线吸收层3的厚度与防水层2的厚度相同,硅胶层4的厚度为防水层2的2倍。阻燃层1不仅有阻燃的功能同时也具有一定的防水能力,紫外线吸收层3能够在卷材应用到墙体或屋面时提高卷材抗紫外线的能力提高卷材的使用寿命。
一种环保防水卷材的制备方法,包括如下步骤:
步骤一,制作阻燃层1:先将聚丙烯、阻燃剂、分散剂、增韧剂、钛白粉加入高速捏合机中捏合3-5分钟;捏合后的物料经挤压机和压延机压制成一表面带有圆形凸起101的阻燃层1;
步骤二,制作防水层2:先将丁基橡胶、乙烯醋酸乙烯共聚物、轻质碳酸钙、偶联剂放入高速开炼机中,在80℃~90℃下开炼5分钟得到丁基橡胶薄片;将丁基橡胶薄片、增粘树脂、炭黑、防老剂、稳定剂加入橡胶捏合机中,温度控制在80℃~100℃到膏状丁基橡胶备用;
步骤三,制作紫外线吸收层3:先将PVC树脂、热稳定剂、增塑剂、放入捏合机中温度控制在100℃~130℃,捏合5~10分钟,之后加入紫外线吸收剂、轻质碳酸钙和空心玻璃微珠以相同的速度捏合,温度控制在160℃~180℃,捏合3~5分钟后依次进入挤出机、压延机制成上下表面均带有条形凸起301的紫外线吸收层3;
步骤四,将紫外线吸收层3、硅胶层4、将帆布层依次压合;
步骤五,将膏状丁基橡胶涂抹到紫外线吸收层3的上表面;
步骤六,将阻燃层1带有圆形凸起101的一面贴合到丁基橡胶上得到最终的成品。
本实施例的一个具体应用为:第一步制作阻燃层1,取聚丙烯70份,氢氧化镁11份,硬脂酸单甘油酯10份,丁二烯橡胶5份,钛白粉16份加入高速捏合机中捏合3分钟,捏合后的物料经挤压机和压延机压制成一表面带有圆形凸起101的阻燃层1,为了增加摩擦力可在圆形凸起101的表面设置凹槽。第二步制作防水层2,取丁基橡胶22份、乙烯醋酸乙烯共聚物5份、轻质碳酸钙8份、乙烯基三甲氧基硅烷0.3份放入高速开炼机中,在80℃~90℃下开炼5分钟得到丁基橡胶薄片,将得到的全部丁基橡胶薄片放入橡胶捏合机中并加入增粘树脂19份、炭黑11份、防老剂0.3份、稳定剂0.6份并将温度控制在80℃~100℃到膏状丁基橡胶备用。第三步制作紫外线吸收层3:先将PVC树脂45份、热稳定剂1份、增塑剂16份、放入捏合机中温度控制在100℃~130℃,捏合6分钟,之后加入紫外线吸收剂0.05份、轻质碳酸钙11份和空心玻璃微珠20份以相同的速度捏合,温度控制在160℃~170℃,捏合4分钟后依次进入挤出机、压延机制成上下表面均带有条形凸起301的紫外线吸收层3。第四步将紫外线吸收层3、硅胶层4、将帆布层依次压合在一起,第五步将膏状丁基橡胶涂抹到紫外线吸收层3的上表面厚度大概1.5mm因紫外线吸收层3上表面有条形凸起301,提高了丁基橡与紫外线吸收层3的结合牢度,第六步将阻燃层1带有圆形凸起101的一面贴合到丁基橡胶上并施加一定的压力使阻燃层1与丁基橡胶、丁基橡胶与紫外线吸收层3彼此间紧密贴合,最后将复合好的卷材烘干打卷。
在本说明书的描述中,参考术语“一个实施例”、“示例”、“具体示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。
以上公开的本发明优选实施例只是用于帮助阐述本发明。优选实施例并没有详尽叙述所有的细节,也不限制该发明仅为所述的具体实施方式。显然,根据本说明书的内容,可作很多的修改和变化。本说明书选取并具体描述这些实施例,是为了更好地解释本发明的原理和实际应用,从而使所属技术领域技术人员能很好地理解和利用本发明。本发明仅受权利要求书及其全部范围和等效物的限制。

Claims (6)

1.一种环保防水卷材,其特征在于,自上而下由以下五层结构组成:
阻燃层(1)、防水层(2)、紫外线吸收层(3)、硅胶层(4)和帆布层(5);
所述阻燃层(1)靠近所述防水层(2)的一侧均设有圆形凸起(101),所述紫外线吸收层(3)的上下表面均设有条形凸起(301)。
2.根据权利要求1所述的一种环保防水卷材,其特征在于,所述圆形凸起(101)的表面设有凹槽。
3.根据权利要求1所述的一种环保防水卷材,其特征在于,
所述阻燃层(1)包括以下成分:
聚丙烯62份~80份
阻燃剂10份~19份
分散剂10份~15份
增韧剂2份~15份
钛白粉15份~20份
所述防水层(2)为丁基橡胶自粘层,包括如下成分:
丁基橡胶22份~30份
乙烯醋酸乙烯共聚物4份~5.2份
偶联剂0.3份~0.5份
增粘树脂18份~25份
炭黑11份~12份
轻质碳酸钙6份~9份
防老剂0.3份~0.5份
稳定剂0.6份-0.8份;
所述紫外线吸收层(3)成分如下:
PVC树脂40份~75份
热稳定剂0.5份~2份
增塑剂15份~20份
紫外线吸收剂0.01份~0.2份
空心玻璃微珠20份~30份
轻质碳酸钙10份~15份。
4.根据权利要求3所述的一种环保防水卷材,其特征在于,所述阻燃剂是氢氧化镁;所述分散剂是硬脂酸单甘油酯;所述增韧剂为丁二烯橡胶,所述钛白粉为金红石型,所述偶联剂为乙烯基三甲氧基硅烷。
5.根据权利要求1所述的一种环保防水卷材,其特征在于,所述阻燃层(1)的厚度在1-2mm范围。
6.如权利要求1-5所述的一种环保防水卷材的制备方法,其特征在于,包括如下步骤:
步骤一,制作阻燃层(1):先将聚丙烯、阻燃剂、分散剂、增韧剂、钛白粉加入高速捏合机中捏合3-5分钟;捏合后的物料经挤压机和压延机压制成一表面带有圆形凸起(101)的阻燃层(1);
步骤二,制作防水层(2):先将丁基橡胶、乙烯醋酸乙烯共聚物、轻质碳酸钙、偶联剂放入高速开炼机中,在80℃~90℃下开炼5分钟得到丁基橡胶薄片;将丁基橡胶薄片、增粘树脂、炭黑、防老剂、稳定剂加入橡胶捏合机中,温度控制在80℃~100℃到膏状丁基橡胶备用;
步骤三,制作紫外线吸收层(3):先将PVC树脂、热稳定剂、增塑剂、放入捏合机中温度控制在100℃~130℃,捏合5~10分钟,之后加入紫外线吸收剂、轻质碳酸钙和空心玻璃微珠以相同的速度捏合,温度控制在160℃~180℃,捏合3~5分钟后依次进入挤出机、压延机制成上下表面均带有条形凸起(301)的紫外线吸收层(3);
步骤四,将紫外线吸收层(3)、硅胶层(4)、将帆布层(5)依次压合;
步骤五,将膏状丁基橡胶涂抹到紫外线吸收层(3)的上表面;
步骤六,将阻燃层(1)带有圆形凸起(101)的一面贴合到丁基橡胶上得到最终的成品。
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Application publication date: 20180803