CN108298501A - 化学氧化水制备氧气的CuO/过硫酸盐氧化剂 - Google Patents
化学氧化水制备氧气的CuO/过硫酸盐氧化剂 Download PDFInfo
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910001868 water Inorganic materials 0.000 title claims abstract description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000001301 oxygen Substances 0.000 title claims abstract description 22
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 22
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 17
- 230000003647 oxidation Effects 0.000 title claims abstract description 16
- 239000000126 substance Substances 0.000 title claims abstract description 11
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 6
- 239000000243 solution Substances 0.000 claims abstract description 22
- 239000010949 copper Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000007800 oxidant agent Substances 0.000 claims abstract description 10
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- 239000002086 nanomaterial Substances 0.000 claims abstract description 9
- 239000012670 alkaline solution Substances 0.000 claims abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 51
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 12
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 12
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims description 8
- 229910052927 chalcanthite Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 5
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 claims description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
- 229910002567 K2S2O8 Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- 229910002476 CuII Inorganic materials 0.000 claims 1
- 229910004882 Na2S2O8 Inorganic materials 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 claims 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims 1
- 235000019394 potassium persulphate Nutrition 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 14
- 238000006555 catalytic reaction Methods 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 5
- 230000002194 synthesizing effect Effects 0.000 abstract description 4
- 239000012716 precipitator Substances 0.000 abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 238000003756 stirring Methods 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 238000010792 warming Methods 0.000 description 8
- 239000003643 water by type Substances 0.000 description 8
- 238000001556 precipitation Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 235000011054 acetic acid Nutrition 0.000 description 4
- 150000001243 acetic acids Chemical class 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000001027 hydrothermal synthesis Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 210000000720 eyelash Anatomy 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0203—Preparation of oxygen from inorganic compounds
- C01B13/0207—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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- B01J37/08—Heat treatment
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
- B01J37/344—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
- B01J37/346—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy of microwave energy
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Abstract
本发明涉及以微纳结构氧化铜(CuO)为化学催化水氧化催化剂,在溶有氧化剂的碱性溶液中可形成化学氧化水制备氧气的CuO/过硫酸盐氧化剂。其制备方法如下述步骤:以不同铜盐为铜源,通过溶液热沉淀法、微波合成法和高温焙烧法合成微纳结构CuO,在有氧化剂过硫酸盐的碱性溶液中,可以催化氧化水产生氧气。
Description
技术领域
本发明用以不同铜盐为铜源,通过溶液热沉淀法、微波合成法和高温焙烧法合成微纳结构的CuO,在溶有氧化剂的碱性溶液中,具有良好的催化性能,可与过硫酸盐一起,形成化学氧化水制备氧气的CuO/过硫酸盐氧化剂。
背景技术
当今世界,能源问题和环境问题备受关注。研发新型可持续无污染能源已迫在眉睫。在这些能源中,氢(H2)燃料引起科研工作者的极大兴趣。水的全分解 (2H2O→2H2+O2)引起了科研工作者的极大兴趣。催化水氧化主要为光催化、电催化和化学催化。而化学催化水氧化反应是三者中最方便易行的方法,仅需要催化剂和电子牺牲氧化剂。早期的化学催化水氧化催化剂主要是铱和钌的氧化物,但其高昂的价格限制了它们的商业应用,故研究者将研究对象转向了含量相对丰富且价格较低的过渡金属。近年来,钴、锰、镍、铁等的化合物被证明可以作为化学催化水氧化的催化剂。本发明以不同铜盐为铜源,通过溶液热沉淀法、微波合成法和高温焙烧法合成微纳结构的CuO,在溶有氧化剂的碱性溶液中,具有良好的催化性能,可与过硫酸盐一起,形成化学氧化水制备氧气的CuO/过硫酸盐氧化剂。
发明内容
本实验提供用不同铜盐为铜源,通过溶液热沉淀法、微波合成法和高温焙烧法合成微纳结构CuO,分散在溶有氧化剂的碱性溶液中,制备氧气。操作步骤如下:
(1)醋酸铜 (Cu(CH3COO)2·H2O)、硫酸铜 (CuSO4·5H2O) 、硝酸铜 (Cu(NO3)2·3H2O)、氯化铜(CuCl2·2H2O)分别与氢氧化钠 (NaOH)、氢氧化钾 (KOH) 和浓氨水反应,在水溶液中生成微纳结构的CuO。(2)醋酸铜 (Cu(CH3COO)2·H2O)、硫酸铜 (CuSO4·5H2O) 、硝酸铜(Cu(NO3)2·3H2O) 、氯化铜(CuCl2·2H2O)分别与氢氧化钠 (NaOH)、氢氧化钾 (KOH) 和浓氨水反应,在微波反应器中生成微纳结构的CuO。(3)醋酸铜 (Cu(CH3COO)2·H2O)、硫酸铜(CuSO4·5H2O) 、硝酸铜 (Cu(NO3)2·3H2O) 、氯化铜(CuCl2·2H2O)在马弗炉中高温焙烧生成微纳结构的CuO。(4)将制备的CuO (1-20mg) 分散在溶有一定量的氧化剂(1-200mg)的碱性溶液(pH值为10-14)中,碱性溶液的体积为10-100 mL。
附图说明
图1为本发明第1实施例制备的CuO的扫描电镜图。
图2为本发明第1实施例制备的CuO 的 X-射线粉末衍射图。
图3为本发明第1实施例制备的以CuO为催化剂,以过硫酸钠为氧化剂的产氧动力学图。
具体实施方式
通过具体的实施例对本发明进行进一步详细描述:
实施例1:CuO的制备: 0.50 g Cu(CH3COO)2·H2O溶解在300 mL 去离子水中,磁力搅拌,待Cu(CH3COO)2·H2O 全部溶解,加1 mL冰乙酸,搅拌至澄清溶液,加入0.8 g NaOH,100oC 回流30min,出现棕黑色沉淀。离心,棕黑色沉淀用去离子水洗3次,60 oC真空干燥12 h。5mg CuO 分散在10 mL pH为 13的NaOH 溶液中,加入10mg Na2S2O8,制备氧气。
实施例2:CuO的制备: 1.20 g CuSO4·5H2O 溶解在300 mL 去离子水中,磁力搅拌,待CuSO4·5H2O全部溶解,加1 mL冰乙酸,搅拌至澄清溶液,加入1.0 g KOH,100 oC 回流1h,出现棕黑色沉淀。离心,棕黑色沉淀用去离子水洗3次,60 oC真空干燥24 h。1mg CuO分散在10 mL pH为 10的氨水溶液中,加入1 mg KHSO5·0.5KHSO4·0.5K2SO4,制备氧气。
实施例3:CuO的制备: 1.20 g Cu(NO3)2·3H2O 溶解在300 mL 去离子水中,磁力搅拌,待Cu(NO3)2·3H2O 全部溶解,加1 mL冰乙酸,搅拌至澄清溶液,加入5 mL浓氨水,100oC 回流30min,出现棕黑色沉淀。离心,棕黑色沉淀用去离子水洗3次,60 oC真空干燥12 h。20 mg CuO 分散在100 mL pH为 14的KOH 溶液中,加入200 mg K2S2O8,制备氧气。
实施例4:CuO的制备: 3.60 g CuCl2·2H2O 溶解在300 mL 去离子水中,磁力搅拌,待CuCl2·2H2O 全部溶解,加1 mL冰乙酸,搅拌至澄清溶液,加入0.8 g NaOH,100 oC 回流60min,蓝色成电变为棕黑色沉淀。离心,去离子水洗3次得棕黑色粉末,80 oC真空干燥12h。5mg CuO 分散在50 mL pH为 11的 NaOH 溶液中,加入80 mg Na2S2O8,制备氧气。
实施例5:CuO的制备: 2.50 g Cu(CH3COO)2·H2O溶于98 mL去离子水中,加入2 ml乙二醇(EG),搅拌30 min后,加入60 ml溶解有10.00 g的NaOH溶液,继续搅拌1 h。上述的蓝色混合物进行微波水热反应,在120 oC下保温15 min,然后由空气压缩机冷却30 min。待冷却至室温后,产物用水和乙醇洗涤,在80℃干燥12 h。5mg CuO 分散在10 mL pH为 13的NaOH 溶液中,加入10mg Na2S2O8,制备氧气。
实施例6:CuO的制备: 1.20 g CuSO4·5H2O溶于98 mL去离子水中,加入2 ml 乙二醇(EG),搅拌30 min后,加入60 ml溶解有5.00 g的KOH溶液,继续搅拌1 h。上述的蓝色混合物进行微波水热反应,在120 oC下保温15 min,然后由空气压缩机冷却30 min。待冷却至室温后,产物用水和乙醇洗涤,在60℃干燥24 h。1mg CuO分散在10 mL pH为 10的氨水溶液中,加入1 mg KHSO5·0.5KHSO4·0.5K2SO4,制备氧气。
实施例7:CuO的制备: 2.50 g Cu(NO3)2·3H2O溶于98 mL去离子水中,加入2 ml乙二醇(EG),搅拌30 min后,加入5 mL浓氨水,继续搅拌1 h。上述的蓝色混合物进行微波水热反应,在140 oC下保温15 min,然后由空气压缩机冷却30 min。待冷却至室温后,产物用水和乙醇洗涤,在80℃干燥12 h。20 mg CuO 分散在100 mL pH为 14的KOH 溶液中,加入200 mg K2S2O8,制备氧气。
实施例8:CuO的制备: 5.00 g CuCl2·2H2O溶于98 mL去离子水中,加入2 ml 乙二醇(EG),搅拌30 min后,加入60 ml溶解有10.00 g的NaOH溶液,继续搅拌1 h。上述的蓝色混合物进行微波水热反应,在120 oC下保温30 min,然后由空气压缩机冷却30 min。待冷却至室温后,产物用水和乙醇洗涤,在80℃干燥12 h。5mg CuO 分散在50 mL pH为 11的NaOH 溶液中,加入80 mg Na2S2O8,制备氧气。
实施例9:CuO的制备: 2.00 g Cu(CH3COO)2·H2O研磨后在马弗炉中程序升温焙烧。先升温至150oC,再此温度下保持2 h后再次升温至400oC,在此温度下保持4 h。5mg CuO分散在10 mL pH为 13的NaOH 溶液中,加入10mg Na2S2O8,制备氧气。
实施例10:CuO的制备: 4.00 g CuSO4·5H2O研磨后在马弗炉中程序升温焙烧。先升温至150oC,再次温度下保持2 h后再次升温至700oC,在此温度下保持4 h。1mg CuO 溶解在50 mL NaOH 溶液中,加入20 mg KHSO5·0.5KHSO4·0.5K2SO4,间隔1 h测氧气浓度。1mgCuO分散在10 mL pH为 10的氨水溶液中,加入1 mg KHSO5·0.5KHSO4·0.5K2SO4,制备氧气。
实施例11:CuO的制备: 2.00 g Cu(NO3)2·3H2O研磨后在马弗炉中程序升温焙烧。先升温至130oC,再此温度下保持2 h后再次升温至450 oC,在此温度下保持4 h。20 mg CuO分散在100 mL pH为 14的KOH 溶液中,加入200 mg K2S2O8,制备氧气。
实施例12:CuO的制备: 2.00 g CuCl2·2H2O研磨后在马弗炉中程序升温焙烧。先升温至150oC,再此温度下保持2 h后再次升温至900 oC,在此温度下保持5 h。5mg CuO 分散在50 mL pH为 11的NaOH 溶液中,加入80 mg Na2S2O8,制备氧气。
Claims (3)
1.以不同铜盐为铜源,不同方法合成的微纳结构氧化铜 (CuO),在溶有氧化剂的碱性溶液中,具有良好的催化性能,可形成化学氧化水制备氧气的CuO/过硫酸盐氧化剂。
2.根据权利要求1 所述,其特征在于:以醋酸铜 (Cu(CH3COO)2·H2O)、硝酸铜 (Cu(NO3)2·3H2O) 、硫酸铜 (CuSO4·5H2O) 、氯化铜(CuCl2·2H2O)为CuII提供体,氢氧化钠(NaOH)、氢氧化钾 (KOH)和浓氨水为碱性溶液的提供试剂,CuO的使用量为1-20mg,碱性溶液的pH值为10-14。
3.根据权利要求1 所述,其特征在于:过一硫酸钾 (KHSO5·0.5KHSO4·0.5K2SO4) 、过硫酸钠 (Na2S2O8)、过硫酸钾 (K2S2O8)为氧化剂,使用量为1-200mg。
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