CN108294012A - A kind of bactericidal composition - Google Patents
A kind of bactericidal composition Download PDFInfo
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- CN108294012A CN108294012A CN201710023159.9A CN201710023159A CN108294012A CN 108294012 A CN108294012 A CN 108294012A CN 201710023159 A CN201710023159 A CN 201710023159A CN 108294012 A CN108294012 A CN 108294012A
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- bacterium amine
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- azoles bacterium
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
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Abstract
A kind of bactericidal composition, contain active components A and active constituent B, wherein, active components A is fluorine indenes azoles bacterium amine, active constituent B is selected from difenoconazole, Tebuconazole, propiconazole, hexaconazole, prothioconazoles, fluorine bacterium azoles, penconazole, tetraconazole, Flusilazole, tricyclazole, one or more of glyoxalin, and the weight ratio of active components A and active constituent B are 1:60~60:1, composite bactericide of the present invention can be configured to the conventional formulations such as suspending agent, aqueous emulsion, suspension emulsion, microcapsule suspending agent, suspension seed-coating agent, wettable powder, water dispersible granules, granule, dispersible oil-suspending agent.The present invention is higher to most of diseases controls in various crop, and bactericidal effect is notable, wide sterilization spectrum, has apparent synergistic effect.
Description
Technical field
The invention belongs to technical field of pesticide, are related to a kind of bactericidal composition of fluorine-containing indenes azoles bacterium amine.
Background technology
Fluorine indenes azoles bacterium amine chemical name：3- difluoromethyls-N- (the fluoro- 2,3- dihydros -1,1,3- trimethyls -1H- indenes -4- of 7-
Base) -1- methyl-1 H- pyrazole-4-carboxamides, belong to wide spectrum SDHI series bactericidal agents, fungicidal spectrum covers all thifluzamides and Lu Na
Gloomy fungicidal spectrum, in addition to Rhizoctonia solani special efficacy, all to anthrax, rust, early blight, powdery mildew, leaf mold, false smut preventive effect
Very well.It will be high than Lu Nasen, green prince wife's activity especially in terms of powdery mildew.Structural formula is as follows：
Difenoconazole, Tebuconazole, propiconazole, hexaconazole, prothioconazoles, fluorine bacterium azoles, penconazole, tetraconazole, fluorine silicon
Azoles, tricyclazole, glyoxalin belong to triazole bactericidal agent, mainly by influencing sterols biosynthesis, make somatic cells film work(
It can be destroyed, reach inhibition growth of pathogenic bacteria.Triazole bactericidal agent has efficient, wide spectrum, low-residual, lasting period length, interior suction
The features such as property is strong has both protection, treats, roots out and fumigation action.
Difenoconazole (difenoconazole) is that safety is relatively high in triazole bactericidal agent, is widely used in fruit
The crops such as tree, vegetables effectively prevent scab, anthrachose of grape, white rot, spot defoliation, powdery mildew, brown spot, rust, item rust
Disease, head blight etc..
Tebuconazole (tebuconazole) is a kind of efficient, wide spectrum, absorbability triazole type sterilization pesticide, has protection, controls
It treats, root out three zones, wide sterilization spectrum, lasting period are long, are used as seed treatment and foliar spray.
Propiconazole (propiconazole) is a kind of absorbability triazole bactericidal agent with protection and therapeutic effect, can
It is absorbed by root, stem, leaf portion, and can soon be conducted upwards in plant strain body, prevent sac fungus, basidiomycetes and Fungi Imperfecti cause
Disease, especially to take-all, powdery mildew, rust, root rot, sigatoka has preferable control effect.
Hexaconazole (hexaconazole) is sterol demethylation inhibitors, to fungi especially Basidiomycota and sac fungus
Disease caused by door has the protection and therapeutic effect of broad spectrum activity, destroys and prevent the cell membrane important composition ingredient ergot steroid of germ
The biosynthesis of alcohol causes cell membrane that cannot be formed, and keeps germ dead.The medicine can effectively prevent sac fungus, basidiomycetes and partly know
Microbial disease, especially to disease caused by basidiomycetes and sac fungus such as powdery mildew, rust, scab, brown spot, anthrax
Disease, banded sclerotial blight, false smut etc. have preferable preventive and therapeutic action.
Prothioconazoles (prothioconazole) are the triazole type wide-spectrum bactericide of Bayer exploitation, the mechanism of action and feature
It is the precursor-lanosterol i.e. demethylation inhibitors for inhibiting sterol in fungi.The medicine not only has good systemic activity, excellent
Different protection treats and roots out activity and the lasting period is long.Show prothioconazoles to crop not by a large amount of field control effectiveness test
Only good safety, preventing disease theraping effect is good, and has production-increasing function.
Fluorine bacterium azoles (triflumizole) are ergosterol demethylation inhibitors, have and prevent, treat, root out effect,
Systemic action conductibility is good, anti-rain drop erosion, can anti-various crop disease, be suitable for the powdery mildews such as wheat, fruit tree, vegetables, rust
The prevention of disease, peach brown rot.
Penconazole (penconazole) is a kind of absorbability triazole bactericidal agent having both protection, treatment and eradicant action, is steroid
Alcohol demethylation inhibitors, can be by tissue resorptions such as root of the crop, stem, leaves, and conduct upwards, through toxicity measurement and field efficacy
Test result shows there is a preferable control effect to many plant diseases, to crop safety under recommended dose, has no poisoning.
Tetraconazole (tetraconazole) belongs to second generation triazole bactericidal agent, fluorine-containing, bactericidal activity in molecular structure
Than 2-3 times that is the first generation, wide sterilization spectrum, efficient, lasting period are up to 4-6 weeks, have protection and therapeutic effect, and have well
Uptake and translocation performance.Suitable for crop cereal crop such as wheat, barley, oat, rye etc., fruit tree such as banana, grape, pears, apple
Fruit etc., vegetables are for example melon, beet, ornamental plant etc..Erysiphe, Puccinia, beak genuss, Pyrenophora and shell can be prevented
Needle spore belong to microbial disease for example wheat powdery mildew, loose smut of wheat, wheat rust, the bunt of wheat, wheat yinghu disease,
Barley leaf blotch, loose smut of barley, barley banded sclerotial blight, maize head smut, head smut of sorghum, melon and fruit powdery mildew, banana
Leaf spot, alternaria leaf spot of apple, pear scab and uncinula necator etc..Both can cauline leaf process, can also make seed treatment use.
Flusilazole (flusilazole) is a kind of absorbability triazole bactericidal agent having both protection and therapeutic effect, can be pressed down
Sterol demethylation processed, for preventing Ascomycetes, Basidiomycetes and Fungi Imperfecti fungi, such as venturia inaequalis, Powdery Mildew,
The wheat nuclear cavity bacteria of Cereal, Septoria bacterium, snag shell bacterium etc., the various pathogens on Guignardia and sweet tea Lay, peanut tikka
Disease, it is efficient to sclerotinia sclerotiorum.The biosynthesis for destroying and preventing ergosterol, causes cell membrane that cannot be formed, keeps germ dead
It dies.It is effective to disease caused by sac fungus, basidiomycetes and Fungi Imperfecti, there is special efficacy to pear scab.
Tricyclazole (tricyclazole) is a kind of protective fungicide with stronger absorbability, can be each by rice rapidly
Site absorption, the lasting period is long, efficacy stability, and dosage is low and anti-rain drop erosion, prevents rice blast bactericide specially, bactericidal effect
Mechanism be mainly inhibit attachment spore melanin formation, to inhibit spore germination and attachment spore formed, prevent germ invade people and
Reduce the generation of magnaporthe grisea spore.
Glyoxalin (imibenconazole) is a kind of absorbability wide-spectrum bactericide having both protection and therapeutic effect, effect
Mechanism and the biosynthesis that feature main function mechanism is the cell membrane important composition ingredient ergosterol for destroying and preventing germ,
To destroy the formation of cell membrane, cause germ dead, after being sprayed onto on crop in energy rapid osmotic to plant, resistance to rainwater punching
Brush.Controlling object can effectively prevent disease such as peach caused by sac fungus, basidiomycetes and Fungi Imperfecti, Japanese apricot, mandarin tree shot hole,
Pear scab, scab of apple, lures disease, powdery mildew, zonate spot, grapevine anthracnose, watermelon, muskmelon, tobacco, rose, day at rust
Originally thatch, Powdery Mildew of Grand Myrtle, the cercospora brown spot of peanut, tea anthracnose, black spot, lawn rust etc. are defended.Especially to citrus scab,
Grapevine anthracnose, pear scab have significant control effect.
Since various regions pesticide abuse causes resistance increasing, the lasting raising of the dosage of pesticide.However larger dose
Pesticide abuse causes to make havoc of environment, does not also play due effect well.Pass through our a large amount of field medicines
Effect experiment finds that the mixed generation that can be very good delaying drug resistance of pesticide improves drug effect, to reduce the usage amount of pesticide.
Invention content
The object of the present invention is to provide one kind having synergistic function, safety and environmental protection, improves drug effect, reduction labour cost
Bactericidal composition.
Above-mentioned bactericidal composition, active components A be fluorine indenes azoles bacterium amine, active constituent B be selected from difenoconazole, Tebuconazole,
One kind in propiconazole, hexaconazole, prothioconazoles, fluorine bacterium azoles, penconazole, tetraconazole, Flusilazole, tricyclazole, glyoxalin or
Person is several, and the weight ratio of active components A and active constituent B are 1：60~60：1, active components A is preferred heavy with active constituent B's
Amount is than being 1：20~20：1.
Using bactericidal composition of the present invention, it is equipped with auxiliary agent known to a person skilled in the art, in the art
Dosage form according to the present invention is made in method well known to technical staff：Suspending agent, suspension emulsion, microcapsule suspending agent, hangs aqueous emulsion
Floating seed coat agent, wettable powder, water dispersible granules, granule, dispersible oil-suspending agent.
Above-mentioned bactericidal composition has the characteristics that：1. fluorine indenes azoles bacterium amine belongs to novel environment friendly fungicide, bactericidal effect is strong,
Triazole bactericidal agent is wide-spectrum bactericide, has significant bactericidal effect, two kinds of fungicide mode of action tools to plurality of plant diseases
There is complementarity, the two is compounded, there is good synergistic effect；2. the occupation mode diversification of preparation, can also may be used with blade spraying
With pouring root, seed dressing etc.；3. two kinds of ingredients are without apparent cross resistance, active ingredient is novel, and the mode of action is unique.
Specific implementation mode
It is active using indoor biological for verification active components A and the synergistic effect after active constituent B compoundings in the present invention
With two methods of field control effectiveness test, the two kinds of test methods used are described individually below.Wherein, active constituent
A is fluorine indenes azoles bacterium amine, and active constituent B is difenoconazole, Tebuconazole, propiconazole, hexaconazole, prothioconazoles, fluorine bacterium azoles, penta bacterium
Azoles, tetraconazole, Flusilazole, tricyclazole, glyoxalin.
Experiment one：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and difenoconazole compounding.The subjects of indoor biometrics are
Soybean rust germ.Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates each medicament to pathogen
EC50, compare the virulence and bacteriostasis of different agents.
The co-toxicity of mixture preparation is indicated using the co-toxicity coefficient method of Sun Yunpei：
The mixture preparation theoretical toxicity index TTI=∑s (pharmaceutically active ingredient of the toxicity index ATI of certain medicine × in mixture
Percentage).
Co-toxicity coefficient CTC is synergistic effect when being more than 120, is antagonism when being less than 80, is when between 80~120
Addition.
1 fluorine indenes azoles bacterium amine of table is with difenoconazole different ratio to the measurement result of soybean rust germ co-toxicity coefficient
As can be seen from Table 1, when fluorine indenes azoles bacterium amine and difenoconazole compound in varing proportions, the total poison of complex preparation
Coefficient (CTC) is all higher than 120, there is the synergistic effect of different proportion to the prevention of soybean rust, when fluorine indenes azoles bacterium amine and phenylate
Methyl cyclic-azole is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 136, and synergistic effect is more notable.
Experiment two：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and Tebuconazole compounding, subjects are rice sheath blight disease germ.
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
2 fluorine indenes azoles bacterium amine of table is with Tebuconazole different ratio to the measurement result of rice sheath blight disease germ co-toxicity coefficient
As can be seen from Table 2, when fluorine indenes azoles bacterium amine and Tebuconazole compound in varing proportions, the co-toxicity coefficient of complex preparation
(CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of rice sheath blight disease, when fluorine indenes azoles bacterium amine and Tebuconazole
1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 135, and synergistic effect is more notable.
Experiment three：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and propiconazole compound, subjects are sigatoka germ,
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
3 fluorine indenes azoles bacterium amine of table is with propiconazole different ratio to the measurement result of sigatoka germ co-toxicity coefficient
As can be seen from Table 3, when fluorine indenes azoles bacterium amine and propiconazole compound in varing proportions, the co-toxicity coefficient of complex preparation
(CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of sigatoka, when fluorine indenes azoles bacterium amine and propiconazole
1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 132, and synergistic effect is more notable.
Experiment four：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and hexaconazole compounding, subjects are rice sheath blight disease germ.
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
4 fluorine indenes azoles bacterium amine of table is with hexaconazole different ratio to the measurement result of rice sheath blight disease germ co-toxicity coefficient
As can be seen from Table 4, when fluorine indenes azoles bacterium amine and hexaconazole compound in varing proportions, the co-toxicity coefficient of complex preparation
(CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of rice sheath blight disease, when fluorine indenes azoles bacterium amine and hexaconazole
1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 135, and synergistic effect is more notable.
Experiment five：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and prothioconazoles compounding, subjects are wheat powdery mildew disease
Bacterium.Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, than less
With the virulence and bacteriostasis of medicament.
5 fluorine indenes azoles bacterium amine of table is with prothioconazoles different ratio to the measurement result of wheat powdery mildew germ co-toxicity coefficient
As can be seen from Table 5, when fluorine indenes azoles bacterium amine and prothioconazoles compound in varing proportions, the total poison system of complex preparation
Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of wheat powdery mildew, when fluorine indenes azoles bacterium amine and rosickyite
Bacterium azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 132, and synergistic effect is more notable.
Experiment six：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and fluorine bacterium azoles compounding, subjects are cucumber powdery mildew bacteria.
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
6 fluorine indenes azoles bacterium amine of table is with fluorine bacterium azoles different ratio to the measurement result of cucumber powdery mildew bacteria co-toxicity coefficient
As can be seen from Table 6, when fluorine indenes azoles bacterium amine and fluorine bacterium azoles compound in varing proportions, the co-toxicity coefficient of complex preparation
(CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of powdery mildew of cucumber, wherein fluorine indenes azoles bacterium amine and fluorine bacterium
The proportioning of azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 133, and synergistic effect is more notable.
Experiment seven：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and penconazole compounding, subjects are uncinula necator germ.
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
7 fluorine indenes azoles bacterium amine of table is with penconazole different ratio to the measurement result of uncinula necator germ co-toxicity coefficient
As can be seen from Table 7, when fluorine indenes azoles bacterium amine and penconazole compound in varing proportions, the co-toxicity coefficient of complex preparation
(CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of uncinula necator, wherein fluorine indenes azoles bacterium amine and fluorine bacterium
The proportioning of azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 135, and synergistic effect is more notable.
Experiment eight：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and tetraconazole compounding, subjects are powdery mildew of strawberry disease
Bacterium, reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, than less
With the virulence and bacteriostasis of medicament.
8 fluorine indenes azoles bacterium amine of table is with tetraconazole different ratio to the measurement result of powdery mildew of strawberry germ co-toxicity coefficient
As can be seen from Table 8, when fluorine indenes azoles bacterium amine and tetraconazole compound in varing proportions, the total poison system of complex preparation
Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of powdery mildew of strawberry, wherein fluorine indenes azoles bacterium amine and four
The proportioning of fluorine ether azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 136, and synergistic effect is more notable.
Experiment nine：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and Flusilazole compounding, subjects are cucumber powdery mildew bacteria,
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
9 fluorine indenes azoles bacterium amine of table is with Flusilazole different ratio to the measurement result of cucumber powdery mildew bacteria co-toxicity coefficient
As can be seen from Table 9, when fluorine indenes azoles bacterium amine and Flusilazole compound in varing proportions, the co-toxicity coefficient of complex preparation
(CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of powdery mildew of cucumber, wherein fluorine indenes azoles bacterium amine and fluorine silicon
The proportioning of azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 131, and synergistic effect is more notable.
Experiment ten：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and tricyclazole compounding, subjects are rice Pyricularia grisea.
Reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates EC of each medicament to pathogen50, more different medicines
The virulence and bacteriostasis of agent.
10 fluorine indenes azoles bacterium amine of table is with tricyclazole different ratio to the measurement result of rice Pyricularia grisea co-toxicity coefficient
As can be seen from Table 10, when fluorine indenes azoles bacterium amine and tricyclazole compound in varing proportions, the total poison system of complex preparation
Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of rice blast, wherein fluorine indenes azoles bacterium amine and three
The proportioning of ring azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 135, and synergistic effect is more notable.
Test 11：The indoor biometrics experiment of fluorine indenes azoles bacterium amine and glyoxalin compounding, subjects are that subjects are pears
Scab germ, reference《Farm-chemical indoor determination test rule fungicide》It carries out, calculates each medicament to pathogen
EC50, compare the virulence and bacteriostasis of different agents.
11 fluorine indenes azoles bacterium amine of table is with glyoxalin different ratio to the measurement result of pear scab germ co-toxicity coefficient
As can be seen from Table 11, when fluorine indenes azoles bacterium amine and glyoxalin compound in varing proportions, the total poison system of complex preparation
Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of pear scab, wherein fluorine indenes azoles bacterium amine and imines
The proportioning of azoles is 1：20~20：When 1, co-toxicity coefficient (CTC) is all higher than 131, and synergistic effect is more notable.
It can be seen that after fluorine indenes azoles bacterium amine is compounded with triazole bactericidal agent by the above raw test, drug effect is
It improves, there is good synergistic effect after the two compounding.
It being further illustrated the present invention below by specific embodiment, the following examples are not limitations of the present invention,
Only further supplement.Percentage is weight percentage in formula, and used active compound and auxiliary agent are that other producers provide.
Embodiment 1 (22% fluorine indenes azoles bacterium amine difenoconazole suspending agent)
Embodiment 2 (20% fluorine indenes azoles bacterium amine difenoconazole water dispersible granule)
Embodiment 3 (30.5% fluorine indenes azoles bacterium amine difenoconazole suspending seed-dressing agent)
Embodiment 4 (21% fluorine indenes azoles bacterium amine tebuconazole aqueous emulsion)
Embodiment 5 (18% fluorine indenes azoles bacterium amine tebuconazole suspension concentrates)
Embodiment 6 (20% fluorine indenes azoles bacterium amine tebuconazole water dispersible granule)
Embodiment 7 (32% fluorine indenes azoles bacterium amine propiconazole suspension seed-coating agent)
Embodiment 8 (22% fluorine indenes azoles bacterium amine propiconazole microcapsule suspension seed-coating agent)
Embodiment 9 (41% fluorine indenes azoles bacterium amine propiconazole suspension seed-coating agent)
Embodiment 10 (31% fluorine indenes azoles bacterium amine diniconazole water dispersible granule)
Embodiment 11 (18% fluorine indenes azoles bacterium amine hexaconazole suspending agent)
Embodiment 12 (30% fluorine indenes azoles bacterium amine hexaconazole suspending agent)
Embodiment 13 (30% fluorine indenes azoles bacterium amine prothioconazoles water dispersible granules)
Embodiment 14 (32% fluorine indenes azoles bacterium amine prothioconazoles suspending agent)
Embodiment 15 (42% fluorine indenes azoles bacterium amine prothioconazoles suspension emulsion)
Embodiment 16 (51% fluorine indenes azoles bacterium amine triflumizole wettable powder)
Embodiment 17 (15% fluorine indenes azoles bacterium amine triflumizole wettable powder)
Embodiment 18 (52% fluorine indenes azoles bacterium amine triflumizole water dispersant)
Embodiment 19 (15% fluorine indenes azoles bacterium amine penconazole suspending agent)
Embodiment 20 (30.5% fluorine indenes azoles bacterium amine penconazole water dispersible granules)
Embodiment 21 (30% fluorine indenes azoles bacterium amine penconazole aqueous emulsion)
Embodiment 22 (10% fluorine indenes azoles bacterium amine tetraconazole aqueous emulsion)
Embodiment 23 (22% fluorine indenes azoles bacterium amine tetraconazole suspending agent)
Embodiment 24 (12% fluorine indenes azoles bacterium amine tetraconazole aqueous emulsion)
Embodiment 25 (33% fluorine indenes azoles bacterium amine Flusilazole suspending agent)
Embodiment 26 (21% fluorine indenes azoles bacterium amine Flusilazole aqueous emulsion)
Embodiment 27 (35% fluorine indenes azoles bacterium amine flusilazole water dispersible granule)
Embodiment 28 (the 18% dispersible oil-suspending agent of fluorine indenes azoles bacterium amine Flusilazole)
Embodiment 29 (22% fluorine indenes azoles bacterium amine tricyclazole wettable powder)
Embodiment 30 (31% fluorine indenes azoles bacterium amine tricyclazole water dispersible granule)
Embodiment 31 (17% fluorine indenes azoles bacterium amine tricyclazole suspending agent)
Embodiment 32 (41% fluorine indenes azoles bacterium amine tricyclazole suspension emulsion)
Embodiment 33 (24% fluorine indenes azoles bacterium amine glyoxalin wettable powder)
Embodiment 34 (15% fluorine indenes azoles bacterium amine glyoxalin wettable powder)
Select above example to carry out field trial, verification complex preparation to the control effect of crop, while by with work
Property ingredient A and active constituent B single doses carry out Contrast on effect, the synergistic effect of preparation after verification compounding.Comparison medicament includes：5%
Fluorine indenes azoles bacterium amine suspending agent (dosage form English name：SC), 10% difenoconazole water dispersible granule (dosage form English name：WDG)、
50% tebuconazole water dispersible granule (dosage form English name：WDG), 25% propiconazole emulsifiable concentrate (dosage form English name：EC), 40% oneself
Azoles alcohol suspending agent (dosage form English name：SC), 20% prothioconazoles missible oil (dosage form English name：EC), 30% fluorine bacterium azoles are wettable
Property pulvis (dosage form English name：WP), 10% penconazole missible oil (dosage form English name：EC), 4% tetraconazole aqueous emulsion (agent
Type English name：EW), 10% Flusilazole aqueous emulsion (dosage form English name：EW), 75% tricyclazole wettable powder (dosage form English
Literary fame claims：WP), 15% glyoxalin wettable powder (dosage form English name：WP).
Test 12：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and the field medicine of different agents prevention soybean rust
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
The test result of 12 fluorine indenes azoles bacterium amine of table and active constituent B complex preparations and different agents prevention soybean rust
It is seen from the above data that 7 days preventive effects to soybean rust are more than 83% after medicine for complex preparation, after medicine
14 days preventive effects to soybean rust compare single dose, have good synergistic effect after compounding, extend holding effect more than 87%
It is phase, more longlasting to the control effect of soybean rust.
Test 13：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention rice sheath blight disease field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
13 fluorine indenes azoles bacterium amine of table and active constituent B complex preparations and the test result of different agents prevention rice sheath blight disease
It is seen from the above data that 7 days preventive effects to rice sheath blight disease are more than 84% after medicine for complex preparation, in medicine
14 days preventive effects to rice sheath blight disease compare single dose, have good synergistic effect after compounding, extend and hold more than 89% afterwards
It is the effect phase, more longlasting to the control effect of rice sheath blight disease.
Test 14：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention sigatoka field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
14 fluorine indenes azoles bacterium amine of table and active constituent B complex preparations and the test result of different agents prevention sigatoka
It is seen from the above data that 7 days preventive effects to sigatoka are more than 84% after medicine for complex preparation, in medicine
14 days preventive effects to sigatoka compare single dose, have good synergistic effect after compounding, extend and hold more than 89% afterwards
It is the effect phase, more longlasting to the control effect of sigatoka.
Test 15：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention wheat powdery mildew field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
15 fluorine indenes azoles bacterium amine of table prevents wheat powdery mildew test result with active constituent B complex preparations and different agents
It is seen from the above data that 7 days preventive effects to wheat powdery mildew are more than 84% after medicine for complex preparation, in medicine
14 days preventive effects to wheat powdery mildew compare single dose, have good synergistic effect after compounding, extend and hold more than 89% afterwards
It is the effect phase, more longlasting to the control effect of wheat powdery mildew.
Test 16：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention powdery mildew of cucumber field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
16 fluorine indenes azoles bacterium amine of table prevents powdery mildew of cucumber test result with active constituent B complex preparations and different agents
It is seen from the above data that 7 days preventive effects to powdery mildew of cucumber are more than 83% after medicine for complex preparation, in medicine
14 days preventive effects to powdery mildew of cucumber compare single dose, have good synergistic effect after compounding, extend and hold more than 88% afterwards
It is the effect phase, more longlasting to the control effect of powdery mildew of cucumber.
Test 17：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention uncinula necator field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
17 fluorine indenes azoles bacterium amine of table prevents uncinula necator test result with active constituent B complex preparations and different agents
It is seen from the above data that 7 days preventive effects to uncinula necator are more than 84% after medicine for complex preparation, in medicine
14 days preventive effects to uncinula necator compare single dose, have good synergistic effect after compounding, extend and hold more than 88% afterwards
It is the effect phase, more longlasting to the control effect of uncinula necator.
Test 18：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention powdery mildew of strawberry field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
18 fluorine indenes azoles bacterium amine of table prevents powdery mildew of strawberry test result with active constituent B complex preparations and different agents
It is seen from the above data that 7 days preventive effects to powdery mildew of strawberry are more than 84% after medicine for complex preparation, in medicine
14 days preventive effects to powdery mildew of strawberry compare single dose, have good synergistic effect after compounding, extend and hold more than 88% afterwards
It is the effect phase, more longlasting to the control effect of powdery mildew of strawberry.
Test 19：Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention rice blast field medicine
Effect experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
19 fluorine indenes azoles bacterium amine of table prevents rice blast test result with active constituent B complex preparations and different agents
It is seen from the above data that 7 days preventive effects to rice blast are more than 85% after medicine for complex preparation, in medicine
14 days preventive effects to rice blast compare single dose, have good synergistic effect after compounding, extend and hold more than 89% afterwards
It is the effect phase, more longlasting to the control effect of rice blast.
Test 20：Fluorine indenes azoles bacterium amine prevents pear scab field efficacy with active constituent B complex preparations and different agents
Experiment, reference《Field control effectiveness test criterion》Carry out field control effectiveness test and evaluating drug effect.
Computational methods：According to Disease investigation data, the disease index and control effect of each processing are calculated.
20 fluorine indenes azoles bacterium amine of table prevents pear scab test result with active constituent B complex preparations and different agents
It is seen from the above data that 7 days preventive effects to pear scab are more than 85% after medicine for complex preparation, after medicine
14 days preventive effects to pear scab compare single dose, have good synergistic effect after compounding, extend holding effect more than 90%
It is phase, more longlasting to the control effect of pear scab.
In conclusion complex preparation can be very good to improve the synergistic effect of product, drug resistance is delayed, can apply
Controlling disease in crops improves drug effect, extends the lasting period, reduces cost, mitigate the amount of labour of peasant, there is very high practicality
Property.The present invention, can between technical characteristic described in different technologies scheme under the premise of can implement and unobvious violate the present invention
Other technologies scheme is formed to carry out arbitrary form combination.The above specific implementation mode and embodiment are carried out to the present invention
Detailed description, but not the scope of the present invention is defined, it modifies and replaces in the principle without departing from claim
It changes, is within the scope of protection of the invention interior.
Claims (4)
1. a kind of bactericidal composition, it is characterised in that：Containing active components A and active constituent B, the active components A is fluorine indenes
Azoles bacterium amine, active constituent B are selected from difenoconazole, Tebuconazole, propiconazole, hexaconazole, prothioconazoles, fluorine bacterium azoles, penconazole, four
The weight ratio of one or more of fluorine ether azoles, Flusilazole, tricyclazole, glyoxalin, active components A and active constituent B are 1：60
~60：1.
2. bactericidal composition according to claim 1, it is characterised in that：The preferred weight of active components A and active constituent B
Than being 1：20~20：1.
3. bactericidal composition according to claim 1, it is characterised in that：Suspending agent, water are made by active constituent and auxiliary material
Emulsion, suspension emulsion, microcapsule suspending agent, suspension seed-coating agent, wettable powder, water dispersible granules, granule, dispersible oil suspend
Agent.
4. bactericidal composition according to claim 1, for preventing powdery mildew, downy mildew, scab, leaf spot, rice blast
Disease, banded sclerotial blight, rust, late blight, brown spot, damping-off, sclerotiniose, anthracnose, moire disease, full rot, rot disease, spot are fallen
Leaf disease, gray mold, head blight etc..
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108576009A (en) * | 2018-07-06 | 2018-09-28 | 广东中迅农科股份有限公司 | Bactericidal composition |
| WO2020121347A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Concentrated suspension containing fluindapyr and use thereof as fungicide in crop plants |
| WO2020121345A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Oil dispersion containing fluindapyr and use thereof as fungicide in crop plants |
| WO2020121346A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Suspoemulsion containing fluindapyr and use thereof as fungicide in crop plants |
| CN114467956A (en) * | 2022-02-23 | 2022-05-13 | 青岛奥迪斯生物科技有限公司 | Pesticide composition containing indoxacarb and application thereof |
| CN115669669A (en) * | 2022-11-17 | 2023-02-03 | 江苏七洲绿色化工股份有限公司 | Composition containing indoxacarb and tebuconazole as well as preparation method and application thereof |
| WO2023180909A1 (en) * | 2022-03-22 | 2023-09-28 | Upl Limited | An agrochemical composition |
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| CN104602523A (en) * | 2012-06-15 | 2015-05-06 | I-F产品协作基金会 | Synergistic compositions for the protection of agrarian crops and the use thereof |
| GB2521255A (en) * | 2013-10-22 | 2015-06-17 | Syngenta Participations Ag | Method of combating corynespora |
| CN104981162A (en) * | 2012-11-30 | 2015-10-14 | 拜耳作物科学股份公司 | Ternary fungicidal mixtures |
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| CN104602523A (en) * | 2012-06-15 | 2015-05-06 | I-F产品协作基金会 | Synergistic compositions for the protection of agrarian crops and the use thereof |
| CN104981162A (en) * | 2012-11-30 | 2015-10-14 | 拜耳作物科学股份公司 | Ternary fungicidal mixtures |
| GB2521255A (en) * | 2013-10-22 | 2015-06-17 | Syngenta Participations Ag | Method of combating corynespora |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108576009A (en) * | 2018-07-06 | 2018-09-28 | 广东中迅农科股份有限公司 | Bactericidal composition |
| WO2020121347A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Concentrated suspension containing fluindapyr and use thereof as fungicide in crop plants |
| WO2020121345A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Oil dispersion containing fluindapyr and use thereof as fungicide in crop plants |
| WO2020121346A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Suspoemulsion containing fluindapyr and use thereof as fungicide in crop plants |
| CN114467956A (en) * | 2022-02-23 | 2022-05-13 | 青岛奥迪斯生物科技有限公司 | Pesticide composition containing indoxacarb and application thereof |
| WO2023180909A1 (en) * | 2022-03-22 | 2023-09-28 | Upl Limited | An agrochemical composition |
| CN115669669A (en) * | 2022-11-17 | 2023-02-03 | 江苏七洲绿色化工股份有限公司 | Composition containing indoxacarb and tebuconazole as well as preparation method and application thereof |
| CN115669669B (en) * | 2022-11-17 | 2024-04-23 | 江苏七洲绿色化工股份有限公司 | Composition containing penconazole and tebuconazole and preparation method and application thereof |
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Application publication date: 20180720 |