CN102037975A - Sterilization composition containing triticonazole and triazole - Google Patents
Sterilization composition containing triticonazole and triazole Download PDFInfo
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- CN102037975A CN102037975A CN2011100082883A CN201110008288A CN102037975A CN 102037975 A CN102037975 A CN 102037975A CN 2011100082883 A CN2011100082883 A CN 2011100082883A CN 201110008288 A CN201110008288 A CN 201110008288A CN 102037975 A CN102037975 A CN 102037975A
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Abstract
The invention discloses a sterilization composition containing triticonazole and triazole, comprising synergistic effective quantity of triticonazole and any one triazole fungicide of triazolone, tebuconazole, hexaconazole, cyproconazole, triadimenol, flutriafol and diniconazole, wherein the ratio of parts by weight of the two active components is (80:1)-(1:80). The sterilization composition disclosed by the invention at least contains one surfactant, thus being convenient for the active components to disperse in water when in application. The sterilization composition disclosed by the invention has protection, treatment and eradication activities, can be applied to multiple crops such as wheat, rice, vegetables, fruit trees and the like, and can control plant diseases caused by pathogenic bacteria of ascomycotina, basidiomycolina and deuteromycotina.
Description
Technical field
The invention belongs to the disinfectant use in agriculture field, relate to a kind of preparation and application that contains the bactericidal composition of triticonazole.
Background technology
Triticonazole (triticonazole) is the triazole bactericidal agent by Beyer Co., Ltd's exploitation, molecular formula: C
17H
20ClN
3O, chemical name: (±)-(E)-5-(4-benzyl chloride thiazolinyl)-2,2-dimethyl-1-(1H-1,2,4-triazol-1-yl methyl) cyclopentanol.
Structural formula:
Triticonazole is a C-14 demethylation enzyme inhibitor in the sterol biosynthesis.Controlling object: cereal crop, legume, fruit diseases, disease that sickle spore (mould) genus, Puccinia, wheat class nuclear cavity Pseudomonas, Ustilago, Tilletia, Erysiphe, circle nuclear cavity bacteria, Septoria, Ramularia etc. cause such as powdery mildew, rust, apple scab, net blotch etc.
The agent of triticonazole list is used for a long time, and disease is developed immunity to drugs, and causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.And that the active ingredient of the different mechanisms of action is carried out is composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.
Summary of the invention
The objective of the invention is to propose a kind of generation or delaying drug resistance speed that can prevent disease drug resistance, the bactericidal composition that contains triticonazole that use cost is low, preventive effect is good.
The inventor is by a large amount of indoor biometricses and field control effectiveness test, finds the use that is mixed within the specific limits of triticonazole and triazole bactericidal agent unexpectedly, and diseases such as the powdery mildew of cereal crop, rust, smut, glume blight are had good synergistic effect.Further experiment finds, the use that is mixed within the specific limits of triticonazole and triazole bactericidal agent also has good preventive effect to the spot defoliation of vegetables and fruit tree, anthracnose, powdery mildew, scab, leaf spot, net blotch etc.And the composite of triticonazole and triazole bactericidal agent at home and abroad do not see openly as yet.
The bactericidal composition that the present invention proposes contains two kinds of active components of A, B.
Active component A is selected from following any one triazole bactericidal agent: triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, alkene azoles alcohol, Triadimenol.
Common feature is to contain hydroxyl (ketone group), substituted-phenyl and 1,2 on the main chain, 4-triazole group compound on the triazole bactericidal agent chemical constitution.This class medicament is except that to the oomycetes non-activity in the Mastigomycotina, and the pathogen of Ascomycotina, Basidiomycotina and Deuteromycotina is all had activity, and its mechanism of action is damaged somatic cells film function for to influence the sterols biosynthesis.
Described triazolone (triadimefon), molecular formula are C
14H
16ClN
3O
2, chemical name: 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-α-butanone.Be a kind of efficient, low toxicity, low-residual, the lasting period is long, interior absorption is strong triazole bactericidal agent.After the each several part of plant absorption, can in plant corpus, conduct.Rust and powdery mildew are had prevention, effect such as root out, treat, fumigate.All effective to the disease of various crop such as corn circle pinta, wheat class moire disease, wheat leaf rot, pineapple black rot, maize head smut etc.The bactericidal mechanism principle of triazolone mainly is to suppress the biosynthesis of thalline ergosterol, thereby the growth, the growth of mycelia and the formation of spore that suppress or disturb thalline to adhere to spore and haustorium.
Described own azoles alcohol (hexaconazole), molecular formula are C
14H
17Cl
2X
3O, chemical name: (RS)-2-(2,4 dichloro benzene base)-1-(1H-1,2,4-triazol-1-yl)-oneself-2-alcohol.
Described Tebuconazole (tebuconazole), molecular formula are C
16H
22ON
3Cl, chemical name: (RS)-and 1-is right-chlorphenyl-4, and 4-dimethyl-3 (1H-1,2,4-triazol-1-yl methyl) amylalcohol.Tebuconazole is the wide spectrum triazole bactericidal agent, and consumption is low, can be applicable to the seed treatment of wheat, to the various cause of diseases that seed carries, is adsorbed on epidermis or seed inside all equally effectively, is particularly useful for the control of smut.
Described Flutriafol (flutriafol), molecular formula are C16H13F2N30, chemical name: α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol.Flutriafol has interior absorption, conducts in plant corpus, and disease is had protection and therapeutic action.Can prevent and treat the cereal crop powdery mildew, Helminthosporium, Puccinia, shell pin Pseudomonas pathogen also can be cooked seed treatment, prevents and treats soil-borne disease and seed-borne disease.The cereal powdery mildew there is special efficacy.
Described alkene azoles alcohol (diniconazole), molecular formula are C
15H
17Cl
2N
3O, chemical name: (E)-(RS)-and 1-(2,4 dichloro benzene base)-4,4-dimethyl-2-(1,2, the 4-triazol-1-yl)-1-amylene-3-alcohol.Triazole bactericidal agent suppresses 14 α-demethylation effect in the ergosterol biosynthesis of fungi, cause that ergosterol lacks, and causes fungal cell membrane undesired, final fungi death, and the lasting period is permanent.To people and animals, useful insect, Environmental security.
Described Triadimenol (triadimenol), molecular formula are C
14H
18ClN
3O
2, chemical name: 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4 triazoles-1 base) butyl-2-alcohol.Mainly be that to suppress ergosterol synthetic, thus suppress and disturb thalline adhere to growing of spore and haustorium.
Described cyproconazole (Cyproconazole), molecular formula: C
15H
18ClN
3O, chemical name: 2-(4-chlorphenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl) fourth-2-alcohol.Be sterol demethylation inhibitor, have prevention and therapeutic action.All effective to the Erysiphales on cereal crop, coffee, beet, fruit tree and the grape, Uredinales, the mould genus of genus spore, Rhynchosporium spp, Septoria, Venturia bacterium.Use with other bactericide, can fine cereal eye spot disease, leaf spot and the net blotch of preventing and treating.The control wheat rust lasting period was 4～6 weeks, and preventing and treating powdery mildew was 3～4 weeks.Cereal, fruit tree and grape powdery mildew, peanut, beet tops pinta, apple snow mildew and peanut white rot.
Active component B is a triticonazole.
The ratio of weight and number of A, two kinds of active components of B is 80: 1～1: 80, and preferred ratio of weight and number is 40: 1～1: 40, and preferred ratio of weight and number is: 20: 1～1: 20.
The described bactericidal composition that contains triticonazole is characterized in that: the ratio of weight and number of active component triazolone and triticonazole is 10: 1～1: 10, and further preferred ratio of weight and number is 5: 1～1: 5.
The described bactericidal composition that contains triticonazole is characterized in that: the own azoles alcohol of active component is 10: 1～1: 10 with the ratio of weight and number of triticonazole, and further preferred ratio of weight and number is 5: 1～1: 5.
The described bactericidal composition that contains triticonazole is characterized in that: the ratio of weight and number of active component Tebuconazole and triticonazole is 10: 1～1: 10, and further preferred ratio of weight and number is 5: 1～1: 5.
The described bactericidal composition that contains triticonazole is characterized in that: the ratio of weight and number of active component cyproconazole and triticonazole is 10: 1～1: 10, and further preferred ratio of weight and number is 5: 1～1: 5.
The described bactericidal composition that contains triticonazole is characterized in that: the ratio of weight and number of active component Flutriafol and triticonazole is 10: 1～1: 10, and further preferred ratio of weight and number is 5: 1～1: 5.
The described bactericidal composition that contains triticonazole is characterized in that: active component alkene azoles alcohol is 10: 1～1: 10 with the ratio of weight and number of triticonazole, and further preferred ratio of weight and number is 5: 1～1: 5.
The described bactericidal composition that contains triticonazole is characterized in that: the ratio of weight and number of active component Triadimenol and triticonazole is 10: 1～1: 10, and further preferred ratio of weight and number is 5: 1～1: 5.
Amount of application when the content of active component depends on independent use in the present composition also depends on the mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, and the while is also relevant with the target fungi.Usually active weight percentage is 1～90% of a gross weight in the composition, and preferable is 10%～80%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of bactericidal composition of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, emulsifier or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by common processing method preparation known in those skilled in the art, be about to active substance and after liquid flux or solid carrier mix, add in surfactant such as dispersant, stabilizing agent, wetting agent, binding agent, the defoamer etc. one or more again.
Bactericidal composition of the present invention can be processed into acceptable any one formulation on any agricultural chemicals on demand, and the wherein excellent formulation of selecting is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, seed treatment.
When making wetting powder, composition comprises following constituent content: active components A 1～80%, triticonazole 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～90%.
Active components A, triticonazole, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into wetting powder product of the present invention.
When making water dispersible granules, composition comprises following constituent content: active components A 1～80%, triticonazole 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～90%.
Active components A, triticonazole, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes water dispersible granules product of the present invention.
Comprise following constituent content when composition is made suspending agent: active components A 1～40%, triticonazole 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add active components A, triticonazole, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes suspending agent product of the present invention.
Comprise following constituent content when composition is made aqueous emulsion: active components A 1～40%, triticonazole 1～40%, solvent 1～30%, emulsifier 1～15%, co-emulsifier 0～8%, antifreeze 0～10%, thickener 0.1～2%, defoamer 0.01～2%, deionized water are supplied surplus.
Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content when composition is made microemulsion: active components A 1～40%, triticonazole 1～40%, solvent 1～30%, emulsifier 3～20%, co-emulsifier 0～12%, antifreeze 0～10%, thickener 0.1～2%, defoamer 0.01～2%, stabilizing agent 0～4%, deionized water is supplied surplus.
Former medicine of active components A and the former medicine of triticonazole are dissolved in the homogenizer that solvent and cosolvent are housed; Mix strongly after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that above-mentioned solution is housed and homogenize, obtain the as clear as crystal microemulsion product of the present invention of outward appearance at last.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, glucose, the aluminium chloride.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from one or more among alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, phenethyl phenol polyethenoxy ether, 506#, 600#, 700#, NP-10 phosphate, OP-10 phosphate, castor oil polyoxyethylene ether, sorbester p17, Tween 80, the 602#;
Described co-emulsifier is one or more in butanols, isobutanol, dodecanol-1, tetradecanol-1, the octadecanol-1;
Described solvent is selected from one or more in toluene, dimethylbenzene, methyl alcohol, ethanol, acetone, ether, cyclohexanone, vegetable oil, dimethyl formamide, acetonitrile, polyethylene glycol, pyrrolidones, the solvent N-chain alkyl pyrrolidones;
Described preservative is selected from one or more in formaldehyde, sodium salicylate, Sodium Benzoate, isothiazolinone, the dichlorophen;
Described kind of clothing film forming agent is selected from: one or more in polyvinyl alcohol, polyvinyl acetate, carboxymethyl cellulose, gum Arabic, gelatin, xanthans, the starch;
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Microbicide compositions of the present invention has protection concurrently, treats and roots out activity, for example can be used for various crop: wheat, paddy rice, vegetables, fruit tree etc., the microbial plant disease of cause of disease of control capsule bacterium subphylum, Basidiomycotina and Deuteromycotina.Anthracnose, leaf spot, powdery mildew, rust, smut, banded sclerotial blight, rice blast etc. there is special efficacy.
Composition of the present invention has following advantage:
(1) said composition shows significant synergistic effect in certain ratio range, has both improved protection effect, has reduced mu dosage and cost, has enlarged fungicidal spectrum again;
(2) since in the said composition each active component do not have the problem of cross resistance, so the application of said composition can reach and delay drug-fast generation of pathogen and development, the result of use that helps to prolong this medicament reduces pesticide resistance and produces probability;
(3) improved safety, being mixed will be lower to the influence of environment, safer.
Embodiment
To further instruction of the present invention, the percentage among the embodiment is ratio of weight and number below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Implementation of an application example one: Toxicity Determination
Active components A (A be selected from triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, alkene azoles alcohol, the Triadimenol a kind of) is composite to target germ Toxicity Determination with triticonazole
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament the target germ.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active components A (triazole bactericidal agent triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, alkene azoles alcohol, Triadimenol) and triticonazole shared ratio in composition;
A is a kind of in triazole bactericidal agent triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, alkene azoles alcohol, the Triadimenol;
B is a triticonazole.
It is as shown in the table for result of the test:
Toxicity test result one
Table 1 triazolone, triticonazole and composite toxicity test analysis of results table thereof to alternaria leaf spot of apple
As shown in Table 1, triazolone, triticonazole are to the EC of alternaria leaf spot of apple
50Be respectively 1.86mg/L and 1.45mg/L.Triazolone and triticonazole were mixed in the scope at 80: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Toxicity test result two
The own azoles alcohol of table 2, triticonazole and composite toxicity test analysis of results table thereof to rice sheath blight disease
As shown in Table 2, own azoles alcohol, triticonazole are to the EC of rice sheath blight disease
50Be respectively 0.39mg/L and 1.61mg/L.Own azoles alcohol is mixed in the scope at 80: 1～1: 80 with triticonazole and all shows obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Toxicity test result three
Table 3 cyproconazole, triticonazole and composite toxicity test analysis of results table thereof to ring rot of apple
As shown in Table 3, cyproconazole, triticonazole are to the EC of ring rot of apple
50Be respectively 1.77mg/L and 1.86mg/L.Cyproconazole and triticonazole were mixed in the scope at 80: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Toxicity test result four
Table 4 Flutriafol, triticonazole and composite toxicity test analysis of results table thereof to powdery mildew of cucumber
As shown in Table 4, Flutriafol, triticonazole are to the EC of powdery mildew of cucumber
50Be respectively 1.64mg/L and 1.78mg/L.Flutriafol and triticonazole were mixed in the scope at 80: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Toxicity test result five
Table 5 alkene azoles alcohol, triticonazole and composite toxicity test analysis of results table thereof to pear scab
As shown in Table 5, alkene azoles alcohol, triticonazole are to the EC of pear scab
50Be respectively 1.06mg/L and 1.59mg/L.Alkene azoles alcohol is mixed in the scope at 80: 1～1: 80 with triticonazole and all shows obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Toxicity test result six
Table 6 Triadimenol, triticonazole and composite toxicity test analysis of results table thereof to barley powdery mildew
As shown in Table 6, Triadimenol, triticonazole are to the EC of barley powdery mildew
50Be respectively 1.78mg/L and 1.69mg/L.Triadimenol and triticonazole were mixed in the scope at 80: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Toxicity test result seven
Table 7 Tebuconazole, triticonazole and composite toxicity test analysis of results table thereof to rice blast
As shown in Table 7, Tebuconazole, triticonazole are to the EC of rice blast
50Be respectively 1.35mg/L and 1.65mg/L.Tebuconazole and triticonazole were mixed in the scope at 80: 1～1: 80 and all show obvious synergistic effect.Wherein, both mixed synergies in 20: 1～1: 20 scope are comparatively desirable, and mixed synergies is particularly outstanding in 10: 1～1: 10 scope.
Implementation of an application example two: field control effectiveness test
Embodiment 180% triazolone triticonazole wetting powder is prevented and treated the wheat rust test of pesticide effectiveness
Triazolone 60%, triticonazole 20%, the phonetic formaldehyde condensation products sulphate 4% of alkylphenol-polyethenoxy, lauryl sodium sulfate 5%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 80% triazolone triticonazole wetting powder.This proportioning is by 40 gram/mus dilution spraying, and in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively in 7 days, 14 days after the last dispenser and calculates preventive effect.Prevent and treat the wheat rust effect in 7 days, 14 days behind the medicine and be respectively 90.8%, 96.3%, 20% triazolone missible oil and 25% triticonazole wetting powder are according to same quadrat method, use by 95 gram/mus and the dilution of 80 gram/mus respectively, 14 days preventive effects are respectively 69.5% and 72.8% behind the medicine.
In the present embodiment triazolone replaceable be a kind of in Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, alkene azoles alcohol, the Triadimenol, thereby form new embodiment.
Embodiment 260% Tebuconazole triticonazole water dispersible granules is prevented and treated the ring rot of apple test of pesticide effectiveness
Tebuconazole 20%, triticonazole 40%, alkyl benzene sulfonate calcium salt 4%, neopelex 2%, wetting and penetrating agent F 3%, bentonite add to 100%, the mixed 60% Tebuconazole triticonazole water dispersible granules that gets.This proportioning is by 4000 times of dilution sprayings, and in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 3 times, investigates disease index respectively in 7 days, 14 days after the last dispenser and calculates preventive effect.Prevent and treat the ring rot of apple effect in 7 days, 14 days behind the medicine and be respectively 91.6%, 96.8%, 80% tebuconazole water dispersible granule and 25% triticonazole wetting powder are according to same quadrat method, dilute 5000 times and 900 times of spraying uses respectively, 14 days preventive effects are respectively 72.6% and 70.3% behind the medicine.
In the present embodiment Tebuconazole replaceable be a kind of in triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, the alkene azoles alcohol, thereby form new embodiment.
The embodiment 340% Flutriafol triticonazole suspending agent control wheat powdery mildew test of pesticide effectiveness
Flutriafol 10%, triticonazole 30%, polycarboxylate 4%, sodium lignin sulfonate 3%, DBSA 4%, silicone oil 0.1%, polyvinyl alcohol 2%, deionized water adds to 100%, the mixed 40% Flutriafol triticonazole suspending agent that gets.This proportioning is by 45 gram/mus dilution spraying, and in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively in 7 days, 14 days after the last dispenser and calculates preventive effect.7 days, 14 days control wheat powdery mildew drug effects really are respectively 91.6%, 96.4% behind the medicine, 50% Flutriafol wetting powder and 25% triticonazole wetting powder are according to same quadrat method, use by 15 gram/mus and 75 gram/mus dilution spraying respectively, 14 days preventive effects are respectively 67.5% and 72.8% behind the medicine.
In the present embodiment Flutriafol replaceable be a kind of in triazolone, Tebuconazole, own azoles alcohol, cyproconazole, alkene azoles alcohol, the Triadimenol, thereby form new embodiment.
Embodiment 445% own azoles alcohol triticonazole suspension emulsion is prevented and treated the rice sheath blight disease test of pesticide effectiveness
Own azoles alcohol 5%, triticonazole 40%, lignosulfonates 2%, polycarboxylate 3%, neopelex 4%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, isobutanol 4%, xanthans 1%, ethylene glycol 4%, deionized water add to 100%, the mixed 45% own azoles alcohol triticonazole suspension emulsion that gets.This proportioning is by 25 gram/mus dilution spraying, and in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively in 7 days, 14 days after the last dispenser and calculates preventive effect.Prevent and treat the rice sheath blight disease drug effect in 7 days, 14 days behind the medicine and really be respectively 91.3%, 96.5%, 10% hexaconazole suspending agent and 25% triticonazole wetting powder are according to same quadrat method, use by 50 gram/mus and the dilution of 80 gram/mus respectively, 14 days preventive effects are respectively 73.7% and 71.5% behind the medicine.
In the present embodiment own azoles alcohol replaceable be a kind of in triazolone, Tebuconazole, cyproconazole, Flutriafol, alkene azoles alcohol, the Triadimenol, thereby form new embodiment.
Embodiment 536% cyproconazole triticonazole aqueous emulsion is prevented and treated the sigatoka test of pesticide effectiveness
Cyproconazole 18%, triticonazole 18%, alkylbenzenesulfonate 4%, alkylphenol polyoxyethylene 5%, C3-C6 alcohol 7%, propane diols 4%, polyvinyl alcohol 1%, silicone oil 0.4%, deionized water supplies 100%, the mixed 36% cyproconazole triticonazole aqueous emulsion that gets.This proportioning is by 2000 times of dilution sprayings, and in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 3 times, investigates disease index respectively in 7 days, 14 days after the last dispenser and calculates preventive effect.Prevent and treat the sigatoka effect in 7 days, 14 days behind the medicine and be respectively 91.4%, 96.2%, 40% cyproconazole wetting powder and 25% triticonazole wetting powder are according to same quadrat method, by 1500 times and 800 times of dilution uses, 14 days preventive effects are respectively 71.5% and 72.1% behind the medicine respectively.
In the present embodiment cyproconazole replaceable be a kind of in triazolone, Tebuconazole, own azoles alcohol, Flutriafol, alkene azoles alcohol, the Triadimenol, thereby form new embodiment.
Embodiment 645% alkene azoles alcohol triticonazole microemulsion is prevented and treated the pear scab test of pesticide effectiveness
Alkene azoles alcohol 15%, triticonazole 30%, alkylphenol polyoxyethylene phosphate 3%, castor oil polyoxyethylene ether 5%, butanols 3%, gelatin 2%, polyvinyl alcohol 3%, silicone oil 0.2%, deionized water supplies 100%, the mixed 45% alkene azoles alcohol triticonazole microemulsion that gets.This proportioning is by 3500 times of dilution sprayings, and in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 3 times, investigates disease index respectively in 7 days, 14 days after the last dispenser and calculates preventive effect.Prevent and treat the pear scab effect in 7 days, 14 days behind the medicine and be respectively 91.3%, 96.2%, 12.5% alkene azoles alcohol missible oil and 25% triticonazole wetting powder are according to same quadrat method, dilute 1000 times and 800 times of uses respectively, 14 days preventive effects are respectively 69.3% and 68.5% behind the medicine.
In the present embodiment alkene azoles alcohol replaceable be a kind of in triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, the Triadimenol, thereby form new embodiment.
Embodiment 710% Triadimenol triticonazole seed treatment is prevented and treated the big smut test of pesticide effectiveness
Triadimenol 5%, triticonazole 5%, polycarboxylate 4%, sodium alkyl benzene sulfonate 3%, sodium lignin sulfonate 3%, carboxymethyl cellulose 3%, xanthans 2%, salicylate 2%, deionized water adds to 100%, the mixed 10% Triadimenol triticonazole seed treatment that gets.This proportioning is pressed 30g/100kg seed seed dressing, in closed container, seed dressing was mixed 1 minute with the seed jolting, with planting seed to the experimental field, and laggard pedestrian worker's irrigation in one day.After planting 28 days calculate preventive effect is 100%, does not observe and infects.Contrast medicament 25% Triadimenol seed dressing and 28% triticonazole seed dressing calculated preventive effect and are respectively 83.4%, 85.2% by using with quadrat method in after planting 28 days.
In the present embodiment Triadimenol replaceable be a kind of in triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, the alkene azoles alcohol, thereby form new embodiment.
The ratio of A, two kinds of active components of B can be adjusted in 80: 1～1: 80 synergy scope in the foregoing description, thereby forms new embodiment.
Claims (5)
1. bactericidal composition that contains triticonazole and triazole type is characterized in that: the ratio of weight and number of two kinds of active component A and B is 80: 1～1: 80.Described active component A is selected from a kind of in triazolone, Tebuconazole, own azoles alcohol, cyproconazole, Flutriafol, alkene azoles alcohol, the Triadimenol, and active component B is selected from triticonazole.
2. the bactericidal composition that contains triticonazole according to claim 1 is characterized in that: the ratio of weight and number of two kinds of active component A and B is 20: 1～1: 20.
3. according to the described bactericidal composition that contains triticonazole of claim 2, it is characterized in that:
The own azoles alcohol of active component is 10: 1～1: 10 with the ratio of weight and number of triticonazole;
The ratio of weight and number of active component Tebuconazole and triticonazole is 10: 1～1: 10;
The ratio of weight and number of active component cyproconazole and triticonazole is 10: 1～1: 10;
The ratio of weight and number of active component Flutriafol and triticonazole is 10: 1～1: 10;
Active component alkene azoles alcohol is 10: 1～1: 10 with the ratio of weight and number of triticonazole;
The ratio of weight and number of active component Triadimenol and triticonazole is 10: 1～1: 10;
The ratio of weight and number of active component triazolone and triticonazole is 10: 1～1: 10.
4. the bactericidal composition that contains triticonazole according to claim 1 is characterized in that: the weight percentage of active component is 5%～85% of a gross weight in the composition.
5. the bactericidal composition that contains triticonazole according to claim 4 is characterized in that: the weight percentage of active component is 10%～80% of a gross weight in the composition.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102659468A (en) * | 2012-04-23 | 2012-09-12 | 赵国彬 | Bactericide containing triazoles |
| CN104285966A (en) * | 2014-10-15 | 2015-01-21 | 济南凯因生物科技有限公司 | Bactericidal composition for preventing and treating peanut powdery mildew |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057157A (en) * | 1990-06-13 | 1991-12-25 | 罗纳-普朗克农业化学公司 | Be used for the processing method of fungicide of blade and the composition of used fungicide |
| CN101637157A (en) * | 2008-07-30 | 2010-02-03 | 中国中化集团公司 | Fungicide composition |
| WO2010103065A1 (en) * | 2009-03-11 | 2010-09-16 | Basf Se | Fungicidal compositions and their use |
-
2011
- 2011-01-14 CN CN2011100082883A patent/CN102037975A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057157A (en) * | 1990-06-13 | 1991-12-25 | 罗纳-普朗克农业化学公司 | Be used for the processing method of fungicide of blade and the composition of used fungicide |
| CN101637157A (en) * | 2008-07-30 | 2010-02-03 | 中国中化集团公司 | Fungicide composition |
| WO2010103065A1 (en) * | 2009-03-11 | 2010-09-16 | Basf Se | Fungicidal compositions and their use |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102659468A (en) * | 2012-04-23 | 2012-09-12 | 赵国彬 | Bactericide containing triazoles |
| CN104285966A (en) * | 2014-10-15 | 2015-01-21 | 济南凯因生物科技有限公司 | Bactericidal composition for preventing and treating peanut powdery mildew |
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Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Applicant after: Shaanxi Meibang Pesticide Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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Application publication date: 20110504 |