CN108264347A - 一种耐磨氧化锆陶瓷 - Google Patents
一种耐磨氧化锆陶瓷 Download PDFInfo
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- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 239000000919 ceramic Substances 0.000 title claims abstract description 49
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 35
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 22
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 21
- 238000002360 preparation method Methods 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 12
- 239000007767 bonding agent Substances 0.000 claims abstract description 11
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 11
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 11
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 11
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims abstract description 10
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims abstract description 10
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 9
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 3
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- 238000005245 sintering Methods 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910002804 graphite Inorganic materials 0.000 claims description 8
- 239000010439 graphite Substances 0.000 claims description 8
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000010431 corundum Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- -1 methyl glycol fatty acid ester Chemical class 0.000 claims description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910052586 apatite Inorganic materials 0.000 claims 1
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 6
- 238000007254 oxidation reaction Methods 0.000 abstract description 6
- 238000005452 bending Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000035939 shock Effects 0.000 abstract description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
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- FIKFOOMAUXPBJM-UHFFFAOYSA-N hepta-2,5-dienediamide Chemical class NC(=O)C=CCC=CC(N)=O FIKFOOMAUXPBJM-UHFFFAOYSA-N 0.000 abstract 1
- 229910010293 ceramic material Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
本发明公开了一种耐磨氧化锆陶瓷,涉及氧化锆技术领域。所述的耐磨氧化锆陶瓷包括以下重量份计的原料:氧化锆45‑55份、氧化钡8‑12份、氧化铈6‑10份、氧化锌2‑4份、氧化钴10‑12份、羟基磷灰石12‑16份、N,N’‑亚甲基双丙烯酰胺5‑8份、表面活性剂10‑15份、氧化石墨烯1.5‑4份、抗菌剂2‑5份、粘接剂3‑5份。制备过程中加入氧化钡颗粒,使氧化锆晶格变形,提高氧化锆的再结晶能力,提高氧化锆陶瓷的硬度,增强耐磨性能。且由于加入了抗菌剂,可以使得到的造粒粉具有抗菌效能,本发明使用石墨烯做添加剂,增强氧化锆陶瓷的抗热震性,提高氧化锆陶瓷在高温下的抗弯强度、断裂韧性。
Description
技术领域
本发明涉及一种耐磨氧化锆陶瓷,具体为氧化锆技术领域。
背景技术
作为新型高技术陶瓷,氧化锆陶瓷具有高强度、高断裂韧性、高硬度以及优异的隔热性能以及耐高温性能等属性,被广泛的应用于结构陶瓷和功能陶瓷领域。另外,氧化锆没有磁性、不导电、不生锈、耐磨,其在生物医学器械领域和道具、工具领域中也应用很广。近来,部分稳定氧化锆 (TZP) 可以通过粉末冶金方法,制备避磁的手表表壳、耐腐的表件和其 它仪器零件。除了上述的应用,TZP 还广泛地应用于装饰、生活、医学、压电陶瓷、传感器陶瓷等领域。
氧化锆陶瓷,具有熔点和沸点高、硬度大、耐磨损、耐高温、耐腐蚀,常温下为绝缘体、高温下则具有导电性等优良性质,被广泛应用于结构陶瓷和功能性陶瓷领域。相对于普通陶瓷,氧化锆陶瓷的密度、抗弯强度、断裂韧性、硬度和耐磨性更大,但抗热震性差。抗热震性代表着陶瓷材料抵抗温度变化能力的大小,也是陶瓷材料热学性能以及力学性能相对各种受热条件时一个全面的反映。氧化锆陶瓷经常在高温下使用,在高温下没有高韧性的特点,会导致其抗弯强度、断裂韧性、硬度和耐磨性下降。因此在高温和低温使用时性能的差异严重制约氧化锆陶瓷的发展。
陶瓷材料虽然有许多优越的特性,如高温力学性能、抗化学侵蚀性能、电绝缘性、较高的硬度和耐磨性等。但由于其结构决定了陶瓷材料缺乏像金属那样在受力状态下发生滑移引起塑性变形能力,容易产生缺陷,存在裂纹,且易于导致高度的应力集中,因而决定了陶瓷材料脆性的本质。因此改善陶瓷材料的脆性是陶瓷学家长期关注的问题,纯净的氧化锆是白色固体,含有杂质时会显现灰色或淡黄色,添加显色剂还可显示各种其它颜色。纯氧化锆的分子量为 123.22,理论密度是 5.89g/cm3,熔点为 2715℃。通 常含有少量的氧化铪,难以分离,但是对氧化锆的性能没有明显的影响。氧化锆有三种晶体形态:单斜、四方、立方晶相。常温下氧化锆只以单斜相出现,加热到 1100℃左右转变为四 方相,加热到更高温度会转化为立方相。由于在单斜相向四方相转变的时候会产生较大的体积变化,冷却的时候又会向相反的方向发生较大的体积变化,容易造成产品的开裂,限制了纯氧化锆在高温领域的应用,且其耐磨性能一般。
发明内容
本发明的目的在于提供一种耐磨性能良好的氧化锆陶瓷,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案一种耐磨氧化锆陶瓷包括以下重量份计的原料:氧化锆45-55份、氧化钡 8-12份、氧化铈 6-10份、氧化锌2- 4份、氧化钴10- 12份、羟基磷灰石 12-16份、N,N’- 亚甲基双丙烯酰胺 5-8份、表面活性剂 10-15 份、氧化石墨烯1.5-4份、抗菌剂2-5份、粘接剂3-5份。
进一步优选,所述的耐磨氧化锆陶瓷包括以下重量份计的原料 :氧化锆48份、氧化钡 10份、氧化铈 8份、氧化锌3份、氧化钴11份、羟基磷灰石15份、N,N’- 亚甲基双丙烯酰胺 6份、表面活性剂 12份、氧化石墨烯3份、抗菌剂3份、粘接剂4份。
作为优选,所述的表面活性剂为质量比为1:1:1:1的单硬脂酸甘油酯、失水山梨醇倍半油酸酯、丙二醇脂肪酸酯、琥珀酸二辛酯磺酸钠的混合物。
一种耐磨氧化锆陶瓷的制备方法为:步骤一、氧化石墨烯的制备,将氧化石墨,放入去离子水溶液中,制得溶液,其中氧化石墨与去离子水溶液的质量比为1:2,将溶液采用超声分散1h,制得氧化石墨烯分散溶液,将氧化石墨烯分散溶液用高速离心机离心10min,得到较稳定的氧化石墨烯胶状悬浮溶液;
步骤二、将步骤一制备的氧化石墨烯胶状悬浮溶液与氧化锆、氧化钡、氧化铈、氧化锌、氧化钴、羟基磷灰石、N,N’- 亚甲基双丙烯酰胺、表面活性剂、氧化石墨烯、抗菌剂、粘接剂混合均匀得到混合物,将混合物经一次真空脱泡后注入模具中,加热固化成型,脱模干燥后干燥得到干坯;
步骤三、排胶及烧结:将坯体置入箱式炉中,在温度 200-500℃排胶 36-48小时,将排胶后的坯体摆放于刚玉坩埚中,经 1500 ~ 1650℃烧结,得到氧化锆陶瓷。
与现有技术相比,本发明的有益效果是:制备过程中加入氧化钡颗粒,使氧化锆晶格变形,提高氧化锆的再结晶能力,提高氧化锆陶瓷的硬度,增强耐磨性能。且由于加入了抗菌剂,可以使得到的造粒粉具有抗菌效能,本发明使用石墨烯做添加剂,利用石墨烯在高温下仍具有高硬度和高强度,其强度和硬度不随温度变化而改变的独特性质,将石墨烯添加入氧化锆陶瓷中,以增强氧化锆陶瓷的抗热震性,提高氧化锆陶瓷在高温下的抗弯强度、断裂韧性、硬度和耐磨性。
附图说明
图1为本发明实施例与对比例性能测试比较图。
具体实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1
一种耐磨氧化锆陶瓷的制备:步骤一、氧化石墨烯的制备,将重量份数为1.5份的氧化石墨,放入去离子水溶液中,制得溶液,其中氧化石墨与去离子水溶液的质量比为1:2,将溶液采用超声分散1.2h,制得氧化石墨烯分散溶液,将氧化石墨烯分散溶液用高速离心机离心8min,得到较稳定的氧化石墨烯胶状悬浮溶液;
步骤二、将步骤一制备的氧化石墨烯胶状悬浮溶液与重量份数为氧化锆45份、氧化钡8份、氧化铈 6份、氧化锌2份、氧化钴10份、羟基磷灰石 12份、N,N’- 亚甲基双丙烯酰胺 5份、表面活性剂 10 份、抗菌剂2份、粘接剂3份混合均匀得到混合物,将混合物经一次真空脱泡后注入模具中,加热固化成型,脱模干燥后干燥得到干坯 ;
步骤三、排胶及烧结:将坯体置入箱式炉中,在温度 500℃排胶 24小时,将排胶后的坯体摆放于刚玉坩埚中,经 1580℃烧结,得到氧化锆陶瓷。
实施例2
一种耐磨氧化锆陶瓷的制备:步骤一、氧化石墨烯的制备,将重量份数为3份的氧化石墨,放入去离子水溶液中,制得溶液,其中氧化石墨与去离子水溶液的质量比为1:2,将溶液采用超声分散1h,制得氧化石墨烯分散溶液,将氧化石墨烯分散溶液用高速离心机离心10min,得到较稳定的氧化石墨烯胶状悬浮溶液;
步骤二、将步骤一制备的氧化石墨烯胶状悬浮溶液与重量份数为氧化锆48份、氧化钡10份、氧化铈 8份、氧化锌3份、氧化钴11份、羟基磷灰石15份、N,N’- 亚甲基双丙烯酰胺 6份、表面活性剂 12份、抗菌剂3份、粘接剂4份混合均匀得到混合物,将混合物经一次真空脱泡后注入模具中,加热固化成型,脱模干燥后干燥得到干坯;
步骤三、 排胶及烧结:将坯体置入箱式炉中,在温度 450℃排胶 36小时,将排胶后的坯体摆放于刚玉坩埚中,经 1600℃烧结,得到氧化锆陶瓷制品。
实施例3
一种耐磨氧化锆陶瓷的制备:步骤一、氧化石墨烯的制备,将重量份数为4份的氧化石墨,放入去离子水溶液中,制得溶液,其中氧化石墨与去离子水溶液的质量比为1:2,将溶液采用超声分散1h,制得氧化石墨烯分散溶液,将氧化石墨烯分散溶液用高速离心机离心10min,得到较稳定的氧化石墨烯胶状悬浮溶液;
步骤二、将步骤一制备的氧化石墨烯胶状悬浮溶液与重量份数为氧化锆55份、氧化钡12份、氧化铈 10份、氧化锌 4份、氧化钴 12份、羟基磷灰石 16份、N,N’- 亚甲基双丙烯酰胺 8份、表面活性剂15 份、抗菌剂5份、粘接剂5份混合均匀得到混合物,将混合物经一次真空脱泡后注入模具中,加热固化成型,脱模干燥后干燥得到干坯;
步骤三、排胶及烧结:将坯体置入箱式炉中,在温度 450℃排胶 36小时,将排胶后的坯体摆放于刚玉坩埚中,经 1600℃烧结,得到氧化锆陶瓷。
对比例
氧化锆陶瓷的制备:将氧化锆48份、氧化铈 8份、氧化锌3份、氧化钴11份、羟基磷灰石15份、N,N’- 亚甲基双丙烯酰胺 6份、表面活性剂 12份、抗菌剂3份、粘接剂4份混合均匀得到混合物,将混合物经一次真空脱泡后注入模具中,加热固化成型,脱模干燥后干燥得到干坯 ;
将坯体置入箱式炉中,在温度 450℃排胶 36小时,将排胶后的坯体摆放于刚玉坩埚中,经 1600℃烧结,得到氧化锆陶瓷。
将实施例1-3和对比例中制备的氧化锆陶瓷进行性能测试,测试结果如图1所示,参照图1,实施例1-3中制备的氧化锆陶瓷硬度较高,耐磨性能良好。
尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (4)
1.一种耐磨氧化锆陶瓷,其特征在于:所述的耐磨氧化锆陶瓷包括以下重量份计的原料:氧化锆45-55份、氧化钡 8-12份、氧化铈 6-10份、氧化锌2- 4份、氧化钴10- 12份、羟基磷灰石 12-16份、N,N’- 亚甲基双丙烯酰胺 5-8份、表面活性剂 10-15 份、氧化石墨烯1.5-4份、抗菌剂2-5份、粘接剂3-5份。
2.根据权利要求1所述的一种耐磨氧化锆陶瓷,其特征在于:所述的耐磨氧化锆陶瓷包括以下重量份计的原料 :氧化锆48份、氧化钡 10份、氧化铈 8份、氧化锌3份、氧化钴11份、羟基磷灰石15份、N,N’- 亚甲基双丙烯酰胺 6份、表面活性剂 12份、氧化石墨烯3份、抗菌剂3份、粘接剂4份。
3.根据权利要求1所述的一种耐磨氧化锆陶瓷,其特征在于:所述的表面活性剂为质量比为1:1:1:1的单硬脂酸甘油酯、失水山梨醇倍半油酸酯、丙二醇脂肪酸酯、琥珀酸二辛酯磺酸钠的混合物。
4.根据权利要求1所述的一种耐磨氧化锆陶瓷,其特征在于所述的耐磨氧化锆陶瓷的制备方法为:步骤一、氧化石墨烯的制备,将氧化石墨,放入去离子水溶液中,制得溶液,其中氧化石墨与去离子水溶液的质量比为1:2,将溶液采用超声分散1h,制得氧化石墨烯分散溶液,将氧化石墨烯分散溶液用高速离心机离心10min,得到较稳定的氧化石墨烯胶状悬浮溶液;
步骤二、将步骤一制备的氧化石墨烯胶状悬浮溶液与氧化锆、氧化钡、氧化铈、氧化锌、氧化钴、羟基磷灰石、N,N’- 亚甲基双丙烯酰胺、表面活性剂、氧化石墨烯、抗菌剂、粘接剂混合均匀得到混合物,将混合物经一次真空脱泡后注入模具中,加热固化成型,脱模干燥后干燥得到干坯;
步骤三、排胶及烧结:将坯体置入箱式炉中,在温度 200-500℃排胶 36-48小时,将排胶后的坯体摆放于刚玉坩埚中,经 1500 ~ 1650℃烧结,得到氧化锆陶瓷。
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