CN108238818B - Method for manufacturing multi-layer color splashing ceramic - Google Patents
Method for manufacturing multi-layer color splashing ceramic Download PDFInfo
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- CN108238818B CN108238818B CN201810055789.9A CN201810055789A CN108238818B CN 108238818 B CN108238818 B CN 108238818B CN 201810055789 A CN201810055789 A CN 201810055789A CN 108238818 B CN108238818 B CN 108238818B
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/87—Ceramics
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5048—Phosphates
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention relates to a method for manufacturing multi-layer color splashing ceramic, which is characterized in that one or more ceramic pigments are respectively prepared into water-based slurry and oil-based slurry, the water-based slurry is used as one or more beams, the oil-based slurry is used as the other one or more beams, and splashing is carried out on a ceramic blank from different angles to form random mixing of the water-based slurry and the oil-based slurry, the texture definition of a color splashing pattern is improved by utilizing the immiscible property of the water-based slurry and the oil-based slurry, and the separation of an upper layer and a lower layer is gradually generated in the flowing process by utilizing the density difference of the water-based slurry and the oil-based slurry, so that the color splashing pattern has multi-layer stereoscopic impression. The color splashing ceramic product has smooth and bright surface after being fired, unique decorative pattern style, random and changeable style, smoothness, naturalness, rich texture and inspiration, rich decorative effect and accurate meaning expression, thereby having wide market prospect.
Description
Technical Field
The invention belongs to the field of decoration and manufacture of ceramic products, and particularly relates to a method for manufacturing multilayer color splashing ceramic, which is particularly suitable for manufacturing porcelain bottles, porcelain plates and other ceramic artistic works with different shapes.
Background
The splash-colored ceramic art is a means of decorating texture changes caused by flowing of ceramic colored drawing pigments and oil materials. The splash color is used as one of the ceramic decoration techniques, and a set of rich modern ceramic painting art expression techniques is formed through continuous development in exploration, inheritance, reference and innovation on the basis of the traditional Chinese painting art.
The color splash painting method has 4 ways on ceramic decoration, one is a pink color ink splash painting method, and the pink color is created by combining raw materials and oil materials (camphor oil, turpentine oil and frankincense oil). The second method is a new color splash-ink painting method, which only combines foreign materials and oil materials to create a splash-color painting. Thirdly, the underglaze color glaze splashing painting method is used for preparing a transparent glaze layer on the pattern formed by the natural flowing of the pigment splashing. Fourthly, the method of painting by splashing color for the comprehensive decoration of the glaze and the glaze, namely, firstly painting a blank and then splashing color on the porcelain.
Because the color splashing decoration technique has strong expressive force and rich colors, the oil produces a special natural texture effect and has the wonderful change generated by the high-temperature colored glaze, so that the decoration picture is more typical and more lifelike. The color splashing raw materials mainly comprise ceramic pigments and oil materials, wherein the used oil materials are as follows: mastic oil, camphor oil, turpentine oil, kerosene, butyl acetate, dimethylbenzene and various thin materials. The mastic oil is viscous and not easy to volatilize, and can be used as a binder of a pigment. The oleum Camphora and oleum Terebinthinae have higher volatility than oleum Terebinthinae, and can be used for diluting colorant and performing skill. For example, in patent application No. cn201410748875.x, a pigment is prepared from mastic oil, camphor oil, kerosene and alcohol, the mastic is sprayed on the surface of a clay body, a flowing liquid is added to make the sprayed pigment flow on the clay body in a desired direction, a beautiful picture is displayed, the whole picture is painted by eyes, finally a bluish white transparent glaze is sprayed, and the ceramic is fired at a high temperature of about 1300 ℃ to form an underglaze color-sprayed painting product with a natural decoration effect. However, the pattern formed by the method can only be single-layer and has no stereoscopic effect.
In the actual creation process, due to the difference of the porosity (water absorption) and the shape of the blank, the proportion of the pigment and the oil is difficult to control, and the oil is less, the picture is too dry and too astringent, and the effect of flowing texture is not achieved. The oil is too much and is easy to accumulate or flow too fast, and the oil is easy to seep out to dirty the picture. If the flow of the splashing color materials cannot be easily controlled, the artistic effect of the splashing color painting is inevitably influenced. The method adopted in patent application cn201410748875.x is to prepare an underglaze color-splashing high-temperature pigment, sprinkle the color-splashing high-temperature pigment on the surface of the clay body, and then use a flowing liquid to make the pigment flow to form a flowing picture, so that the sprinkled color flows on the clay body in a required direction. Obviously, the texture formed by the method has the effect of later-stage decoration, the pattern is unnatural, and the natural beauty and natural and even feeling of the splash color art are pursued.
Disclosure of Invention
The invention aims to provide a method for manufacturing multi-layer color splashing ceramic with unique decorative pattern style, random and changeable style, smoothness, naturalness and strong stereoscopic impression.
In order to solve the technical problems, the technical scheme of the invention is as follows: a manufacturing method of multi-layer color splashing ceramic is characterized by comprising the following steps:
the method comprises the following steps: preparation of aqueous slurries
The formula comprises the following components in percentage by weight: 10-30% of ceramic pigment, 0.5-1% of dispersant I, 1-10% of viscosity regulator and 59-88.5% of water, wherein the ceramic pigment, the dispersant I and the water are rapidly and uniformly stirred according to a certain proportion, and then the viscosity regulator with a certain proportion is gradually added to obtain aqueous slurry with stable suspension and viscosity of 10-200 mPa & s;
step two: preparation of oily slurry
The formula comprises the following components in percentage by weight: 15-35% of ceramic pigment, 0.5-1.5% of dispersant II, 1-10% of cosolvent and 53.5-83.5% of oily solvent, and after the ceramic pigment, the dispersant II, the cosolvent and the oily solvent are rapidly and uniformly stirred according to a certain proportion, oily slurry with stable suspension viscosity of 20-500 mPa & s is obtained;
step three: splash color
Respectively filling the water-based slurry with various colors into containers with proper volumes, respectively filling the oil-based slurry with various colors into other containers, collecting the containers filled with the water-based slurry and the containers filled with the oil-based slurry according to a certain mass ratio, and spraying the slurry by manual splashing or pressure driving, and simultaneously, controlling the slurry by manual or mechanical arm to splash onto the ceramic blank at an angle of 30-90 degrees, so that the water-based slurry and the oil-based slurry are randomly mixed on the ceramic blank to form a pattern with multi-level and three-dimensional sense;
step four: firing
And (4) drying the pattern obtained in the third step, and directly placing the dried pattern into a kiln for firing or placing the dried pattern into the kiln for firing after applying a layer of transparent glaze on the surface of the pattern, so as to obtain the multilayer splashing ceramic.
The ceramic pigment in the first step is a medium-temperature or high-temperature ceramic pigment commonly used in the industry; the first dispersing agent is one of sodium polyacrylate, ammonium polyacrylate, cactus water, sodium metaphosphate and sodium tripolyphosphate; the viscosity regulator is one of carboxymethyl cellulose, methyl cellulose, polyvinyl alcohol, hydroxypropyl methyl cellulose, gelatin and polyethylene glycol.
The ceramic pigment in the second step is a medium-temperature or high-temperature ceramic pigment commonly used in the industry; the second dispersant is one of span series dispersants, acrylic acid-acrylate copolymer, styrene-acrylic acid copolymer, maleic acid-acrylic acid copolymer, WL21-17000 and WL 21-17240; the cosolvent is one of ethanol, amyl alcohol, isooctanol and tween series;
the oily solvent in the second step can be one or more of engine oil, diesel oil, kerosene, xylene, cyclohexane, olive oil, camphor oil, frankincense oil, ethyl acetate, turpentine oil and castor oil, and when the oily solvent is a mixture of two or more of the two, the viscosity of the mixed oily solvent is adjusted to 1-400 mPa & s by adjusting the weight percentage of the oily solvent in each step.
The mass ratio of the aqueous slurry to the oily slurry in the third step is 1: 1 to 3.
The firing temperature in the fourth step is 1150-1350 ℃.
The invention has the following beneficial effects:
(1) the method for blending the aqueous slurry and the oily slurry is adopted, so that the aqueous slurry and the oily slurry are randomly mixed, the texture definition of the color splashing pattern is improved by using the immiscible property of the aqueous slurry and the oily slurry, and the separation of an upper layer and a lower layer is gradually generated in the flowing process by using the density difference of the aqueous slurry and the oily slurry, so that the color splashing pattern has a multi-level stereoscopic impression, and the showing force of the pattern is increased.
(2) The water-based slurry is easy to permeate into the ceramic body, the specific gravity of the water-based slurry is high, the water-based slurry is easy to be positioned at the bottom of the slurry of the water-based slurry and the ceramic body after wetting, and the ceramic body prevents the oil-based slurry from permeating, so that the oil-based slurry can flow on the surface of the water-based slurry more easily, abundant and changeable textures are generated, and unnatural feeling caused by follow-up artificial guidance is avoided.
(3) The water-based slurry can be easily infiltrated into the ceramic body, so that the combination of the color splashing pattern and the ceramic body is enhanced, and the problem that the color splashing pattern is not firmly combined with the ceramic body and is peeled off due to uneven thickness can be effectively avoided.
Detailed Description
To further illustrate the technical means and effects of the present invention adopted to achieve the predetermined objects, the following detailed description will be given to the specific implementation, method, steps, features and effects of the manufacturing method of multi-layered color-splashing ceramic according to the present invention with reference to the preferred embodiments as follows:
the first embodiment is as follows:
250g of cobalt blue pigment, 7.5g of sodium tripolyphosphate and 700g of water are subjected to rapid ball milling for 20min, then 42.5g of carboxymethyl cellulose is added, ball milling is carried out for 10min again to obtain blue aqueous slurry, the viscosity of the slurry is 120 mPa.s, and 1000g of the aqueous slurry is put into a container 1.
Mixing 200g praseodymium yellow material, 7.5g WL21-17000, 80g isooctanol, 400g 20g#Engine oil 312.5g kerosene was subjected to rapid ball milling for 20min to obtain yellow oily slurry having a viscosity of 98mPa · s, and 1000g of the slurry was charged into the vessel 2.
250g of zirconium-iron red material, 10g of WL21-17240, 100g of ethanol, 350g of diesel oil and 292.5g of camphor oil are subjected to rapid ball milling for 20min to obtain red oily slurry, the viscosity of the slurry is 450 mPas, 1000g of the slurry is taken out and put into a container 3.
Pouring slurry in the containers 1-3 to a flat ceramic blank at an angle of 30 degrees after the slurry is collected, allowing the slurry to freely flow to form a color-pouring pattern, spreading the slurry to the ceramic blank, horizontally placing, naturally drying, calcining at 1200 ℃, and preserving heat for 20min to obtain a color-pouring ceramic product.
Example two:
150g of cobalt blue pigment, 9g of ammonium polyacrylate and 761g of water are quickly ball-milled for 20min, then 80g of polyvinyl alcohol is added, ball-milling is carried out for 10min, blue water-based slurry is obtained, the viscosity of the slurry is 30 mPa.s, and 1000g of the slurry is put into a container 1.
300g of zirconium-iron red material, 5g of water and 675g of water are subjected to rapid ball milling for 20min, then 20g of gelatin is added, ball milling is carried out for 10min, red water-based slurry is obtained, the viscosity of the slurry is 180 mPa.s, and 1000g of the slurry is put into a container 2.
300g of praseodymium yellow pigment, 15g of maleic acid-acrylic acid copolymer, 20g of amyl alcohol, 400g of frankincense oil and 265g of turpentine are subjected to rapid ball milling for 20min to obtain yellow oily slurry, the viscosity of the slurry is 150 mPas, and 1000g of the slurry is loaded into a container 3.
250g of titanium white pigment, 10g of styrene-acrylic acid copolymer, 100g of isooctanol, 350g of xylene, 190g of ethyl acetate and 100g of kerosene are subjected to rapid ball milling for 20min to obtain white oily slurry, the viscosity of the slurry is 400 mPas, 1000g of the slurry is taken out and put into a container 4.
Respectively installing the slurry in the containers 1-4 on a mechanical arm, arranging the mechanical arm in a manner that the centers of the circular disks are symmetrically distributed, placing the water-based slurry and the oil-based slurry at intervals, simultaneously flushing the slurry to the edge of the open disk-shaped ceramic blank at an angle of 75 degrees under pneumatic pressure to enable the slurry to freely flow to form a splash-color pattern, after the ceramic blank is fully paved with the slurry, horizontally placing the slurry, naturally drying the slurry, spraying a layer of transparent glaze, calcining the slurry at 1290 ℃, and preserving the heat for 20min to obtain a splash-color ceramic product.
Claims (2)
1. A manufacturing method of multi-layer color splashing ceramic is characterized by comprising the following steps:
the method comprises the following steps: preparation of aqueous slurries
The formula comprises the following components in percentage by weight: 10-30% of ceramic pigment, 0.5-1% of dispersant I, 1-10% of viscosity regulator and 59-88.5% of water, wherein the ceramic pigment, the dispersant I and the water are rapidly and uniformly stirred according to a certain proportion, and then the viscosity regulator with a certain proportion is gradually added to obtain aqueous slurry with stable suspension and viscosity of 10-200 mPa & s;
step two: preparation of oily slurry
The formula comprises the following components in percentage by weight: 15-35% of ceramic pigment, 0.5-1.5% of dispersant II, 1-10% of cosolvent and 53.5-83.5% of oily solvent, and after the ceramic pigment, the dispersant II, the cosolvent and the oily solvent are rapidly and uniformly stirred according to a certain proportion, oily slurry with stable suspension viscosity of 20-500 mPas is obtained;
step three: splash color
Respectively filling the water-based slurry with various colors into containers, respectively filling the oil-based slurry with various colors into other containers, collecting the containers filled with the water-based slurry and the containers filled with the oil-based slurry according to a certain proportion, manually splashing or driving the containers filled with the oil-based slurry to spray the slurry by pressure, and simultaneously manually or mechanically controlling the slurry to splash onto the ceramic blank at an angle of 30-90 degrees so that the water-based slurry and the oil-based slurry are randomly mixed on the ceramic blank to form a pattern with multi-level three-dimensional effect;
step four: firing
Drying the pattern obtained in the third step, directly placing the dried pattern into a kiln for burning or placing the dried pattern into the kiln for burning after applying a layer of transparent glaze on the surface of the pattern to obtain multi-layer splashing ceramic;
the ceramic pigment in the first step is a medium-temperature or high-temperature ceramic pigment commonly used in the industry; the first dispersant is one of sodium polyacrylate, ammonium polyacrylate, sodium metaphosphate and sodium tripolyphosphate; the viscosity regulator is one of carboxymethyl cellulose, methyl cellulose, polyvinyl alcohol, hydroxypropyl methyl cellulose, gelatin and polyethylene glycol;
the ceramic pigment in the second step is a medium-temperature or high-temperature ceramic pigment commonly used in the industry; the second dispersant is one of span series dispersants, acrylic acid-acrylate copolymer, styrene-acrylic acid copolymer and maleic acid-acrylic acid copolymer; the cosolvent is one of ethanol, amyl alcohol, isooctanol and tween series;
the oily solvent in the second step is one or more of engine oil, diesel oil, kerosene, olive oil, camphor oil, frankincense oil and turpentine oil, and when two or more oily solvents are mixed, the viscosity of the mixed oily solvent is 1-400 mPa & s by adjusting the weight percentage of the oily solvent in each step;
the volume ratio of the aqueous slurry to the oily slurry in the third step is 1: 1 to 3.
2. The method of manufacturing according to claim 1, wherein: and the calcining temperature in the step four is 1150-1350 ℃, and the heat preservation time is 20 min.
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| CN201810055789.9A CN108238818B (en) | 2018-01-20 | 2018-01-20 | Method for manufacturing multi-layer color splashing ceramic |
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| CN108238818B true CN108238818B (en) | 2020-09-29 |
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| CN109305795B (en) * | 2018-10-08 | 2021-10-29 | 景德镇陶瓷大学 | Kaolin porcelain body and application method thereof |
| CN109732759B (en) * | 2019-03-11 | 2023-03-28 | 岑传论 | Ice and snow painting process for ceramic |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1250760A (en) * | 1998-10-13 | 2000-04-19 | 李延声 | Technology for making blue and white porcelain |
| WO2011103378A1 (en) * | 2010-02-18 | 2011-08-25 | Videojet Technologies Inc. | Wetness indicating ink compositions |
| CN103483010A (en) * | 2013-09-05 | 2014-01-01 | 湖南新世纪陶瓷有限公司 | Manufacturing technique of stereoscopic underglaze multicolor ceramic |
| CN103963547A (en) * | 2014-05-09 | 2014-08-06 | 操驰 | Ceramic boneless painting and manufacturing method thereof |
| CN104478494A (en) * | 2014-12-10 | 2015-04-01 | 胡昭军 | Method for preparing underglaze splash-color ceramic |
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- 2018-01-20 CN CN201810055789.9A patent/CN108238818B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1250760A (en) * | 1998-10-13 | 2000-04-19 | 李延声 | Technology for making blue and white porcelain |
| WO2011103378A1 (en) * | 2010-02-18 | 2011-08-25 | Videojet Technologies Inc. | Wetness indicating ink compositions |
| CN103483010A (en) * | 2013-09-05 | 2014-01-01 | 湖南新世纪陶瓷有限公司 | Manufacturing technique of stereoscopic underglaze multicolor ceramic |
| CN103963547A (en) * | 2014-05-09 | 2014-08-06 | 操驰 | Ceramic boneless painting and manufacturing method thereof |
| CN104478494A (en) * | 2014-12-10 | 2015-04-01 | 胡昭军 | Method for preparing underglaze splash-color ceramic |
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