CN108193497B - 一种纺织品浴中防皱剂 - Google Patents

一种纺织品浴中防皱剂 Download PDF

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CN108193497B
CN108193497B CN201810022664.6A CN201810022664A CN108193497B CN 108193497 B CN108193497 B CN 108193497B CN 201810022664 A CN201810022664 A CN 201810022664A CN 108193497 B CN108193497 B CN 108193497B
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王国林
章�宁
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Zhejiang Lianhui New Material Co ltd
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Abstract

本发明涉及一种纺织品浴中防皱剂，按质量分数计包括：非离子聚丙烯酰胺3‑9％、非离子渗透剂2‑8％、葡萄糖酸钠2‑6％、磷酸酯1‑5％、聚乙二醇2‑3％、山梨酸钾0.2‑0.4％、余量为水。该纺织品浴中防皱剂能够改善织物的柔软度，减少织物在湿加工过程中的擦伤或褶皱。

Description

一种纺织品浴中防皱剂
技术领域
本发明涉及纺织助剂领域，具体涉及一种纺织品浴中防皱剂。
背景技术
织物在前处理、染色绳状加工中由于机械张力的影响，动摩擦系数很大，容易产生折皱，鸡爪印等瑕疵。为了改善织物在湿加工过程中的运行状态，减少织物在湿加工过程中的擦伤或条痕，因此开发一款原料常见易得，工艺简单方便且适用性较广的抗皱剂是染整行业的一致要求。
目前市场上的抗皱剂种类繁多，但实际使用中限制性较多，稠度太高会造成布运行不顺，太稀则造成作用不大。市场上有些产品渗透性较差会使布面染色水洗造成块状花，对产品品质造成较大影响，或者布面手感较差，对后续工序造成影响。
发明内容
本发明的目的在于针对现有技术的不足，提供一种纺织品浴中防皱剂，改善织物的柔软度，减少织物在湿加工过程中的擦伤或褶皱。
本发明所提供的技术方案为：
一种纺织品浴中防皱剂，按质量分数计包括：
Figure BDA0001544065760000011
Figure BDA0001544065760000021
上述技术方案中，采用非离子聚丙烯酰胺作为滑动剂，在布的表面形成保护膜，使得织物在染色时顺滑、柔软，如果分子量太小纺织面料的表面就不能形成有效的覆盖，效果不好。这就需要采用分子量较高的非离子聚丙烯酰胺，而且防皱剂中更希望提高聚丙烯酰胺的用量，但是高分子非离子聚丙用量增大后防皱剂流动度会变差，影响使用性能。因此复配使用葡萄糖酸钠提高防皱剂的整体流动性，使纺织品清洗简单，节约用水，减少布面云花。非离子渗透剂的添加主要是为了降低表面张力，进而提高染料的上染率，避免纺织品表面因抗皱剂的存在影响整体渗透性。
作为优选，所述非离子聚丙烯酰胺的分子量为1300万、1600万或1700万。
作为优选，所述非离子渗透剂为脂肪醇聚氧乙烯醚。
作为优选，所述脂肪醇聚氧乙烯醚包括JFC-1或JFC-2。
作为优选，所述磷酸酯包括异构十三醇醚(6)磷酸酯或异构十三醇磷酸酯。上述的磷酸酯具有优良的抗静电性、平滑性、柔软性，可显著提高纤维的吸湿性，能较好的调整纤维之间的动摩擦系数。
作为优选，所述聚乙二醇为PEG-200或PEG400。本发明中主要是利用其较好的增溶性、粘度调节性、柔软性、抗静电性。
作为优选，所述纺织品浴中防皱剂按质量分数计包括：
Figure BDA0001544065760000022
Figure BDA0001544065760000031
进一步优选，所述纺织品浴中防皱剂按质量分数计包括：
Figure BDA0001544065760000032
同现有技术相比，本发明的有益效果体现在：
(1)本发明所提供的浴中防皱剂能够改善织物的柔软度，减少织物在湿加工过程中的擦伤或褶皱。
(2)本发明所提供的浴中防皱剂粘度合适，应用广泛。
(3)本发明所提供的浴中防皱剂使织物在低浴比状态下加工时操作更加容易、品质更好，并在不同温度(20-135℃)及酸碱中发挥作用。
具体实施方式
实施例1
浴中防皱剂，按质量分数计包括：
Figure BDA0001544065760000033
Figure BDA0001544065760000041
复配工艺如下：
(1)取总工艺量水的70％，边升温，边匀速缓慢加入聚丙烯酰胺，慢慢升温至80-90℃，待聚丙烯酰胺，完全开稀后，降温备用。
(2)取工艺量水的30％，依次加入非离子渗透剂、磷酸酯、聚乙二醇。
(3)最后将两体系合并搅匀后，加入葡萄糖酸钠与山梨酸钾。
实施例2
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000042
实施例3
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000043
Figure BDA0001544065760000051
实施例4
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000052
实施例5
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000053
Figure BDA0001544065760000061
实施例6
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000062
实施例7
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000063
对比例1
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000071
对比例2
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000072
对比例3
浴中防皱剂，复配工艺同实施例1，按质量分数计包括：
Figure BDA0001544065760000073
Figure BDA0001544065760000081
对比例4
传统抗皱剂，按以下质量分数进行复配：
聚丙烯酰胺分子量300-500万 25％
水 75％
性能测试
(1)染色方法：
采用喷射染机和常规的NR罗马织物的染色工艺对一批NR罗马织物进行染色，40℃下加入匀染剂、抗皱剂等助剂，染料，保温10min，以2℃/min的速度升温至98-105℃，保温30min，以2.5℃/min的速度降温至60℃，排液，其中抗皱剂分别使用实施例1-7所制备的抗皱剂和对比例1-4制备的抗皱剂。
(2)测试方法：
1、流动度：1g/L水抗皱剂溶液取100ML，用0.5mm孔径分液漏斗，滴加计时。
2、布面直观性，平整度：专业人士分组感官评分，分成四个等级，其中1-差；2-稍次；3-较平整；4-平整。
3、滑爽、柔软性手感：专业人士分组触摸评分，分成五个等级，其中1-无手感；2-轻微滑爽柔软；3-有一些滑爽柔软；4较滑爽柔软；5-超级滑爽柔软。
4、耐洗性，参照AATCC-135标准。
5、亲水性和毛效：参照GB/T21655.1-2008。
6、抗静电性能，参照FZ/T01042-1996标准执行。
(3)织物的各项性能比较
表1为实施例1-7的各项性能比较
Figure BDA0001544065760000091
表2为对比例1-4的各项性能比较
Figure BDA0001544065760000092
根据表1-2可以看出，本发明的浴中抗皱剂优点非常明显，特别是实施例1布面直观性，平整度高，烘干后布面柔软度、滑度优于同类产品，流动度高，容易清洗干净节约用水，减少布面云花，加快染色升降温，提高了生产效益。

Claims (6)

1.一种纺织品浴中防皱剂，其特征在于，按质量分数计包括：
Figure FDA0002400621270000011
所述非离子聚丙烯酰胺的分子量为1300万、1600万或1700万。
2.根据权利要求1所述的纺织品浴中防皱剂，其特征在于，所述非离子渗透剂为脂肪醇聚氧乙烯醚。
3.根据权利要求2所述的纺织品浴中防皱剂，其特征在于，所述脂肪醇聚氧乙烯醚包括JFC-1或JFC-2。
4.根据权利要求1所述的纺织品浴中防皱剂，其特征在于，所述磷酸酯包括异构十三醇醚(6)磷酸酯或异构十三醇磷酸酯。
5.根据权利要求1所述的纺织品浴中防皱剂，其特征在于，所述聚乙二醇为PEG-200或PEG400。
6.根据权利要求1所述的纺织品浴中防皱剂，其特征在于，按质量分数计包括：
Figure FDA0002400621270000012
Figure FDA0002400621270000021
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CN1963012A (zh) * 2006-12-05 2007-05-16 东华大学 一种防皱整理保护剂及用其对织物进行防皱整理的方法
CN103321050A (zh) * 2013-06-07 2013-09-25 张家港市德宝化工有限公司 用于聚酯纤维的浴中抗皱剂及其制备方法
CN104294587A (zh) * 2014-10-20 2015-01-21 苏州庄爵服饰有限公司 用于棉布的防皱树脂整理剂
CN106637949A (zh) * 2016-11-01 2017-05-10 桐乡市濮院毛针织技术服务中心 一种锦纶染色用抗皱剂

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Publication number Priority date Publication date Assignee Title
CN1648326A (zh) * 2004-11-01 2005-08-03 上海市印染技术研究所 纺织品浴中抗皱剂
CN1924183A (zh) * 2006-09-20 2007-03-07 东华大学 一种防皱整理强力保护剂
CN1963012A (zh) * 2006-12-05 2007-05-16 东华大学 一种防皱整理保护剂及用其对织物进行防皱整理的方法
CN103321050A (zh) * 2013-06-07 2013-09-25 张家港市德宝化工有限公司 用于聚酯纤维的浴中抗皱剂及其制备方法
CN104294587A (zh) * 2014-10-20 2015-01-21 苏州庄爵服饰有限公司 用于棉布的防皱树脂整理剂
CN106637949A (zh) * 2016-11-01 2017-05-10 桐乡市濮院毛针织技术服务中心 一种锦纶染色用抗皱剂

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