CN108191524A - A kind of bioactivation organic calcium boron multielement nutrition liquid and preparation method thereof - Google Patents
A kind of bioactivation organic calcium boron multielement nutrition liquid and preparation method thereof Download PDFInfo
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- CN108191524A CN108191524A CN201810060290.7A CN201810060290A CN108191524A CN 108191524 A CN108191524 A CN 108191524A CN 201810060290 A CN201810060290 A CN 201810060290A CN 108191524 A CN108191524 A CN 108191524A
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- bioactivation
- nutrition liquid
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
- A01C21/005—Following a specific plan, e.g. pattern
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/02—Fertilisers containing other nitrates containing sodium or potassium nitrate
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
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Abstract
The invention discloses a kind of bioactivation organic calcium boron multielement nutrition liquid and preparation method thereof.Nutrient solution of the present invention is aided with nitrogen, potassium, potassium humate, potassium fulvate, amino acid and various trace elements based on calcium lactate and boric acid, according to plant physiology principle and nutrient balance principle.The bioactivation organic calcium boron multielement nutrition liquid energy of the present invention is effectively increased the thickness of plant cell membrane and improves its melt water ability, ensure the unimpeded and quick transport capacity of plant nutrient channel, the small fallen leaves of the Huang so as to prevent plant early stage improve percentage of fertile fruit, prevention fruit drop, increase fruit density and hardness, reducing day burning and vapour burns;The toughness of cell wall, which can effectively be enhanced, to be enhanced pericarp elasticity, reduces dehiscent fruit and disease pest harm;Increase yield, improving quality, improve fruit keeping quality, Shelf-life.
Description
Technical field
The present invention relates to a kind of bioactivation organic calcium boron multielement nutrition liquid and preparation method thereof, suitable for green plants,
Particularly there is good upgrading synergistic effect to economy class crops such as gourd, fruit and vegetable, fruit tree, grain and cotton oils and flowers and plants forests, belong to
In agricultural economy class technical field of crop cultivation.
Background technology
Present soil texture has occurred that serious change with the extension and being continuously increased for amount of fertilizer application time
Change, acidification, hardened, salination, virusization etc., prevent in some that plant should absorb in soil trace element from and
When obtain supplement and lead to malnutritive and yellow, fallen leaves shedding, dehiscent fruit, root-rot and easy infection disease.Because of long-term a large amount of useizations
Fertilizer, although calcium content is very high in soil, with PO of the long-term accumulation in soil4 -3And SO4 -2Reaction generation stone powder respectively
Last Ca3(PO4)2And CaSO4And be cured, and no organized enzyme deactivates that it causes it that cannot be absorbed and utilized by plant, therefore plant
Extremely calcium deficiency.
Calcium is one of main component for forming plant cell wall and cell membrane, is had in terms of the structure and function for maintaining film
Important function.Calcium is also the auxiliary of amylase, phosphatidase, arginine kinase and adenosine triphosphate acid kinase when carrying out enzymatic reaction
Factor.In recent years the albumen of a kind of calcic found in plant claims calmodulin.Calcium and ring-type possessed by calmodulin are more
After peptide chain combination, the latter can be made to be activated, so as to promote the activity of enzyme.NAD kinases in plant, ATP enzyme, precisely due to
The calmodulin of activation is combined into complex and enhances the activity of enzyme, so as to play promotion plant metabolism.Calcium is planted with pulse family
The formation of object root nodule also has certain relationship.In general, dicotyledon is more than monocotyledon to the requirement of calcium(Cereal), and
The melons and fruits such as tomato, soybean, cucumber, greengrocery crop belong to the dicotyledon of happiness calcium more, their demands to calcium trophic level
Several times even tens times are higher by than Cereal.
During plant calcium deficiency(Often also easy boron deficiency), the apex of root becomes brown, and branch, leaf excessive growth quality soften, young sprout
Dysmaturity, resistance is poor and easily catches an illness.For fruit tree, the accumulation of fruit sugar will be influenced, fruit powder is few, and fragrance is light, and
Easy fruit drop, the hardness of fruit and density are low, and intolerant to storage and transportation, shelf life is short.For grain, cotton and oil crops, easily lodge, seed
Not full, yield and quality can be all greatly affected, and for gourd, fruit and vegetable, be not only very good eating but also intolerant to putting and transport.China
Southern rainwater is more, and table soil calcium carbonate is easily leached, be mostly acid soil thus often calcium deficiency, for this purpose, the frequent liming of people
With neutralize its acidity and increase it is calcareous to promote the absorption of the decomposition of organic matter and nitrogen in soil, conducive to the numerous of edaphon
It grows.But things turn out contrary to one's wishes, and the validity of the micronutrient elements such as boron, zinc can be but reduced using excessive lime and causes soil plate
Knot.Therefore calcium plays many coordinative roles in plant, but the characteristic of calcium determines it in plant again
Mobility is poor, and it is far from being enough only to provide calcium by soil, and most of calcium in soil is cured and cannot be absorbed profit
With so to be supplemented in time by foliage-spray calcium boron.
It is well known that fruit tree needs a large amount of nutrient in period, once shortage or nutrient imbalance will result in nutrition
Bad, immunity degradation is not only easy to be encroached on by various germs and fall ill, and decline fruit quality, and the coming year can also subtract
Production.For example, nutrient imbalance after apple tree calcium deficiency, causes yellow leaflet to fall long since, it is left the small red apple of a tree, without quotient
Product are worth;Leaf becomes smaller, is thinning, crimping after grape calcium deficiency, and fruit is not of uniform size, and easy dehiscent fruit;After Kiwi berry calcium deficiency, leaf hair
Huang becomes smaller, and without texture, fruit easily softens, shedding, without shelf life, loses commodity value;After citrus calcium deficiency, leaf is small
And thin, no texture of feeling like jelly, fruit size are uneven;Dehiscent fruit phenomenon just often occurs for growth period after pomegranate calcium deficiency, finally loses quotient
Product are worth;It easily falls leaves after walnut calcium deficiency shedding;The crops such as grain, cotton and oil are also the same, and due to calcium deficiency, leaf is thin and small, causes
Bar carefully easily lodges, fringe is small, fruit is not full, low output and poor quality.It is such, differ and lift.
The existing leaf surface calcareous fertilizer overwhelming majority is formulated with the inorganic salts of calcium on the market, is not that poor compatibility is exactly
Absorption rate is too low, falls flat.
Invention content
An object of the present invention is to provide a kind of synergetic bioactivation organic calcium boron multielement nutrition suitable for plant
Liquid, not only makes calcium ion be absorbed and used by plants completely, and make at the shortcomings that existing leaf surface calcareous fertilizer is overcome to be difficult to be absorbed by plants
Synergistic effect occurs for calcium ion and other nutritional ingredients, and fertilizer efficiency is made to be more than the simple adduction of each active ingredient.
Another object of the present invention is to provide the preparation method of above-mentioned bioactivation organic calcium boron multielement nutrition liquid.
Third purpose of the present invention is to provide the application method of above-mentioned bioactivation organic calcium boron multielement nutrition liquid.
To achieve the above object, the present invention provides a kind of bioactivation organic calcium boron multielement nutrition liquid of synergetic(With
Under also become " collaboration calcium ").The bioactivation organic calcium boron multielement nutrition liquid of the present invention is according to plant physiology principle and battalion
It supports balance principle to be formulated, including main nutrient, light peptide enzyme cocktail, trace element, stabilizer and conditioner, by each component
Soluble in water, each component and content are:
Main nutrient:
Calcium lactate C6H10CaO6•5H2O 6-100 g/l
H3BO33-30 g/l
8-80 g/l of peptide urea
1-20 g/l of humic acid potassium
1-20 g/l of potassium fulvate
6-100 g/l of amino acid
KCl or KNO31-20 g/l
Light peptide enzyme cocktail:
Methylene blue 1-10ppm
Alanine 1-10ppm
Sodium salicylate 1-10ppm
Sodium sulfite 1-10ppm
Trace element:
Fe2+ + Mn2+ + Cu2+ + Zn2+ + Si4+1-10 g/l
Stabilizer:
1-10 g/l of xanthans
1-10 g/l of antifoaming agent
Conditioner:
HAc 1-10 g/l.
Bioactivation organic calcium boron multielement nutrition liquid of the present invention is preferably formulated as follows:
Main nutrient:
Calcium lactate C6H10CaO6•5H2O 6-80 g/l
H3BO33-20 g/l
8-50 g/l of peptide urea
1-15 g/l of humic acid potassium
1-15 g/l of potassium fulvate
6-60 g/l of amino acid
KCl or KNO31-15 g/l
Light peptide enzyme cocktail:
Methylene blue 3-10ppm
Alanine 3-10ppm
Sodium salicylate 3-10ppm
Sodium sulfite 3-10ppm
Trace element:
Fe2+ + Mn2+ + Cu2+ + Zn2+ + Si4+3-10 g/l
Stabilizer:
3-10 g/l of xanthans
1-6 g/l of antifoaming agent
Conditioner:
HAc 1-8 g/l.
Bioactivation organic calcium boron multielement nutrition liquid of the present invention more preferably formula is as follows:
Main nutrient:
Calcium lactate C6H10CaO6•5H2O 6-50 g/l
H3BO33-15 g/l
8-40 g/l of peptide urea
1-10 g/l of humic acid potassium
1-10 g/l of potassium fulvate
6-50 g/l of amino acid
KCl or KNO31-10 g/l
Light peptide enzyme cocktail:
Methylene blue 3-8ppm
Alanine 3-8ppm
Sodium salicylate 3-8ppm
Sodium sulfite 3-8ppm
Trace element:
Fe2+ + Mn2++ Cu2+ + Zn2+ + Si4+3-8 g/l
Stabilizer:
3-8 g/l of xanthans
1-6 g/l of antifoaming agent
Conditioner:
HAc 1-8 g/l.
The potassium fulvate is fulvic acid to be prepared, and be further made by biofermentation using animal slag body as raw material
Potassium fulvate.The product is by Gen Liduo biotech inc public offering.
The trace element is Fe2+、Mn2+、Cu2+And Zn2+Soluble-salt or its EDTA complex compound, weight ratio be
Fe:Mn:Cu:Zn =1:(0.3~0.7):(0.3~0.7):(0.8~1.2).
The preparation method of above-mentioned bioactivation organic calcium boron multielement nutrition liquid, includes the following steps:
(1)Under stiring, according to quantity calcium lactate C6H10CaO6•5H2O、H3BO3, peptide urea, trace element be dissolved in normal-temperature water;
(2)Under stiring, according to quantity amino acid, potassium humate, potassium fulvate, KCl or KNO3It is dissolved in normal-temperature water;
(3)Under stiring, mixing step(1)With(2)Solution, and xanthans, light peptide enzyme cocktail and HAc are added in, add in antifoaming agent
It stirs evenly.
Above-mentioned bioactivation organic calcium boron multielement nutrition liquid to plant upgrading synergy, improve anti pathologic immunity power, enhancing cold-resistant,
Bioactivation organic calcium boron multielement nutrition liquid when specifically used, is diluted with water 400-600 times by the application in drought resisting, resistance
Foliage-spray afterwards;Plant spire first time spraying concentration is 600 times of dilutions, and other 400-500 times of phenological periods, which dilute, to be sprayed,
The interval time sprayed twice is 10-20 days, can be with the non-alkaline combined use of pesticides without phosphate radical, sulfate radical.
Points for attention:(1)This product should before fruit tree blooms or Post flowering use, full-bloom stage is forbidden to use, and is sprayed twice
Must not be spaced less than 10 days.(2)It should avoid spraying under high temperature and strong sunlight, in the morning 10:30 former or afternoons 3:30(Visually work as
When temperature depending on)Later spraying effect is more preferably.(3)Spraying concentration≤0.05%, avoid with Basic pesticides and phosphorous acid group,
The other materials of sulfate radical are used with.
The present invention bioactivation organic calcium boron multielement nutrition liquid be suitable for almost all plants, particularly gourd, fruit and vegetable,
The economy class crop such as grain, cotton and oil and flowers and plants, forest.The bioactivation organic calcium boron multielement nutrition liquid of the present invention is in light peptide enzyme cocktail
Excitation promote under, maximum synergistic effect has been played between active organic calcium boron and other nutrients, it is good using rear effect
It is good, remarkable in economical benefits.
Advantages of the present invention and good effect:(1)The bioactivation organic calcium boron multielement nutrition liquid of the present invention, with calcium lactate
Based on boric acid, it is yellow rotten that nitrogen, potassium, potassium humate, bioprotein are aided with according to plant physiology principle and nutrient balance principle
Sour potassium and amino acid and various trace elements.(2)The bioactivation organic calcium boron multielement nutrition liquid advantage of the present invention is to prepare
Simple process is reliable, and without big energy consumption, the three wastes are not generated during production and use, free from environmental pollution, good and cheap, peace
Overall height is imitated.(3)The bioactivation organic calcium boron multielement nutrition liquid of the present invention has the characteristics that:Plant cell membrane can be effectively increased
Thickness and improve its melt water ability, ensure the unimpeded and quick transport capacity of plant nutrient channel, it is early so as to prevent plant
The small fallen leaves of Huang of phase improve percentage of fertile fruit, prevention fruit drop, increase fruit density and hardness, reducing that day burns and vapour burns;It can be effective
Enhancing the toughness of cell wall enhances pericarp elasticity, reduces dehiscent fruit and disease pest harm;Increase yield, improving quality, improve fruit
Keeping quality, Shelf-life.(4)Plant leaf surface respiratory intensity is reduced, plant Ye Bamboo hairs is reduced and consumes, improves photosynthetic work
With efficiency and stress resistance of plant(Resistant to lodging, drought resisting, cold-resistant), lag the leaves time make its be the coming year bud differentiation manufacture
More nutrition.(5)The bioactivation organic calcium boron multielement nutrition liquid of the present invention is by 1-3, multi items(Including melon fruit and vegetable
Dish, fruit tree, grain, cotton and oil and flowers and plants forest etc.), it is mostly regional(Hebei, Shandong, Shaanxi and Sichuan etc.)Field trial research, experience
The test of a variety of weather conditions, it was demonstrated that have the positive effect that:Green, light was turned by Huang in average 5-7 days using rear plant leaf
With efficient, leaf good luster, hypertrophy have texture for cooperation;Via plant immunity(Diseases and insect pests resistance)It improves, resistance enhancing carries
Matter synergistic effect is good, and Social benefit and economic benefit is notable.
Specific embodiment
Embodiment 1:
Toxicology test is carried out according to national standard GB15193.3-94.The bioactivation organic calcium boron multielement nutrition liquid of the present invention, warp
Cross toxicology test, LD50>10000mg/kg belongs to low toxicity;The tested crop of fruits and vegetables also passes through toxicology LD50>20000mg/kg is tried
It is nontoxic to test.
Environmental science designing institute of Shaanxi Province influences environment in " bioactivation organic calcium boron multielement nutrition liquid " preparation process
Preliminary analysis is as follows:
1. through being investigated to said preparation experiment with preparation process, said preparation preparation process sheerly compounds;
2. preparation process three-waste free discharge, because said preparation sheerly compounds, therefore preparation process is generated without waste water, exhaust gas, solid waste;
3. the small white mouse toxicological experiment carried out according to health and epidemic prevention station of Shaanxi Province to " bioactivation organic calcium boron multielement nutrition liquid "
As a result, LD50>10000mg/kg compares GBl5670-1995《Agriculture chemical registration toxicology test method》The acute oral of middle pesticide
Toxicity grading standard, said preparation and its raw material category low toxicity level;
4. through being investigated to main agricultural Organic Chemicals used, belong in the degradable organic substance of nature, be not easy to be formed
Residual;
By more than preliminary analysis, apparent environmental pollution will not be brought in said preparation preparation process.
Embodiment 2
Above-mentioned trace element is provided by its soluble compatible salt, and weight part ratio is about Fe:Mn:Cu:Zn =1.0: 0.5:
0.5: 1.0。
It is formulated the preparation method of L1:
The preparation method of bioactivation organic calcium boron multielement nutrition formula of liquid L1:(1)Under stiring, according to quantity calcium lactate
C6H10CaO6•5H2O、H3BO3, peptide urea, trace element be dissolved in 500ml normal-temperature waters;(2)Under stiring, according to quantity amino
Acid, potassium humate, potassium fulvate, KCl or KNO3It is dissolved in 200ml normal-temperature waters;(3)Under stiring, mixing step(1)With(2)
Solution, and xanthans, light peptide enzyme cocktail and HAc are added in, it adds in antifoaming agent and stirs evenly, it is quantitative to 1 liter.
Preparation method and the formula L1 preparation methods for being formulated L2 are identical in technique, and only the amount of each ingredient is different.
Application method:By bioactivation organic calcium boron multielement nutrition liquid add 400-600 times of soft water dilute after foliage-spray i.e.
It can.Plant spire first time spraying concentration is 600 times of dilutions, and other 400-500 times of phenological periods, which dilute, to be sprayed, between spraying twice
It it is 10-20 days every the time.Labour can be saved with the non-alkaline combined use of pesticides without phosphate radical, sulfate radical.
Embodiment 3
By taking apple, Kiwi berry, grape, citrus, pomegranate and corn as an example, bioactivation organic calcium boron multielement nutrition liquid proving ground
It is located at Hebei province Wei County(Grape, pears), Hubei Province Gongan County(Citrus), surveillance in Xunyi County of Shaanxi Province(Apple), Zhouzhi County and Mei County(Mi
Monkey peach and corn)With Xi'an Lintong District(Pomegranate), show to work well by the experimental study of 1-3.Main result is shown in Table
2。
Points for attention:(1)This product should before fruit tree blooms or Post flowering use, full-bloom stage is forbidden to use, and is sprayed twice
Must not be spaced less than 10 days.(2)It should avoid spraying under high temperature and strong sunlight, in the morning 10:30 former or afternoons 3:30(Visually work as
When temperature depending on)Later spraying effect is more preferably.(3)Spraying concentration≤0.05%, avoid with Basic pesticides and phosphorous acid group,
The other materials of sulfate radical are used with.
Embodiment 4
Remarks:A is the organic Ca and B nutrition liquid of bioactivation;B is Buddhist nun's card calcium of U.S.'s production;C is compareed for clear water.It sprays and ties twice
Fruit.
Embodiment 5
L1 is to be formulated in embodiment 2.Place:Binhai County Bin Huai towns.
Embodiment 6
L2 is to be formulated in embodiment 2.Place:Binhai County Bin Huai towns.
Claims (8)
1. a kind of bioactivation organic calcium boron multielement nutrition liquid, it is characterised in that contain main nutrient, light peptide enzyme cocktail, micro member
Element, stabilizer and conditioner, each component is soluble in water, and each component and content are:
Main nutrient:
Calcium lactate C6H10CaO6•5H2O 6-100 g/l
H3BO33-30 g/l
8-80 g/l of peptide urea
1-20 g/l of humic acid potassium
1-20 g/l of potassium fulvate
6-100 g/l of amino acid
KCl or KNO31-20 g/l
Light peptide enzyme cocktail:
Methylene blue 1-10ppm
Alanine 1-10ppm
Sodium salicylate 1-10ppm
Sodium sulfite 1-10ppm
Trace element:
Fe2+ + Mn2+ + Cu2+ + Zn2+1-10 g/l
Stabilizer:
1-10 g/l of xanthans
1-10 g/l of antifoaming agent
Conditioner:
HAc 1-10 g/l.
2. bioactivation organic calcium boron multielement nutrition liquid according to claim 1, it is characterised in that:
Main nutrient:
Calcium lactate C6H10CaO6•5H2O 6-80 g/l
H3BO33-20 g/l
8-50 g/l of peptide urea
1-15 g/l of humic acid potassium
1-15 g/l of potassium fulvate
6-60 g/l of amino acid
KCl or KNO31-15 g/l
Light peptide enzyme cocktail:
Methylene blue 3-10ppm
Alanine 3-10ppm
Sodium salicylate 3-10ppm
Sodium sulfite 3-10ppm
Trace element:
Fe2++Mn2++Cu2++Zn2+3-10 g/l
Stabilizer:
3-10 g/l of xanthans
1-6 g/l of antifoaming agent
Conditioner:
HAc 1-8 g/l.
3. bioactivation organic calcium boron multielement nutrition liquid according to claim 2, it is characterised in that:
Main nutrient:
Calcium lactate C6H10CaO6•5H2O 6-50 g/l
H3BO33-15 g/l
8-40 g/l of peptide urea
1-10 g/l of humic acid potassium
1-10 g/l of potassium fulvate
6-50 g/l of amino acid
KCl or KNO31-10 g/l
Light peptide enzyme cocktail:
Methylene blue 3-8ppm
Alanine 3-8ppm
Sodium salicylate 3-8ppm
Sodium sulfite 3-8ppm
Trace element:
Fe2+ + Mn2+ + Cu2+ + Zn2+3-8 g/l
Stabilizer:
3-8 g/l of xanthans
1-6 g/l of antifoaming agent
Conditioner:
HAc 1-8 g/l.
4. the bioactivation organic calcium boron multielement nutrition liquid according to claim 1-3 is one of arbitrary, it is characterised in that:It is described
Potassium fulvate is fulvic acid to be prepared, and potassium fulvate is further made by biofermentation using animal slag body as raw material.
5. bioactivation organic calcium boron multielement nutrition liquid according to claim 4, it is characterised in that:Trace element is Fe2+、
Mn2+、Cu2+And Zn2+Soluble-salt or its EDTA complex compound, weight ratio Fe:Mn:Cu:Zn =1:(0.3~0.7):
(0.3~0.7):(0.8~1.2).
6. the preparation method of bioactivation organic calcium boron multielement nutrition liquid described in claim 1, it is characterised in that including following
Step:
(1)Under stiring, according to quantity calcium lactate C6H10CaO65H2O、H3BO3, peptide urea, trace element be dissolved in normal-temperature water;
(2)Under stiring, according to quantity amino acid, potassium humate, potassium fulvate, KCl or KNO3It is dissolved in normal-temperature water;
(3)Under stiring, mixing step(1)With(2)Solution, and xanthans, light peptide enzyme cocktail and HAc are added in, add in antifoaming agent
It stirs evenly.
7. bioactivation organic calcium boron multielement nutrition liquid described in claim 1 to plant upgrading synergy, improve anti pathologic immunity power,
Enhance the application in cold-resistant, drought resisting, resistance.
8. the application method of bioactivation organic calcium boron multielement nutrition liquid described in claim 1, it is characterised in that biology is living
Change foliage-spray after organic calcium boron multielement nutrition liquid is diluted with water 400-600 times;Plant spire first time spraying concentration is
600 times dilution, other 400-500 times of phenological periods, which dilute, to be sprayed, the interval time sprayed twice be 10-20 days, can with it is not phosphorous
The non-alkaline combined use of pesticides of acid group, sulfate radical.
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CN109608279A (en) * | 2018-12-11 | 2019-04-12 | 山东博华高效生态农业科技有限公司 | A kind of sweetened special fertilizer of tomato and its application method |
CN110054526A (en) * | 2019-04-27 | 2019-07-26 | 根力多生物科技股份有限公司 | A kind of bioactivation organic multicomponent crops seed dressing agent and its preparation method and application |
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