CN108191514A - A kind of acid soil specific complex punching fertilising - Google Patents
A kind of acid soil specific complex punching fertilising Download PDFInfo
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- CN108191514A CN108191514A CN201711363011.6A CN201711363011A CN108191514A CN 108191514 A CN108191514 A CN 108191514A CN 201711363011 A CN201711363011 A CN 201711363011A CN 108191514 A CN108191514 A CN 108191514A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a kind of punchings of acid soil specific complex to apply fertilizer, and belongs to agrochemical technical field.The acid soil specific complex punching fertilising that the present invention develops includes urea, dopamine, Bacillus pasteurii bacterium solution, make lotion by oneself, inorganic salts, additive, carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid, the decomposed liquid of poultry dung and water, in configuration process, first by urea, dopamine, make lotion by oneself, inorganic salts and water are stirred, sequentially add carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung, and adjust pH, continue after being stirred, sterilizing, must sterilize mixed liquor, after Bacillus pasteurii bacterium solution and additive are stirred, it adds in sterilizing mixed liquor, and it is passed through argon gas into sterilizing mixed liquor, discharging, it rushes and applies fertilizer up to acid soil specific complex.Acid soil specific complex punching fertilising of the present invention can effectively improve nutritional ingredient and utilization rate of active components, and plant products is promoted to increase, improve fruit quality.
Description
Technical field
The invention discloses a kind of punchings of acid soil specific complex to apply fertilizer, and belongs to agrochemical technical field.
Background technology
With the increase of cultivated area, the organic fertilizer on plant producing region and periphery has been unable to meet the demand of agriculture and forestry fast development,
To solve the problems, such as that organic fertilizer source is insufficient, most peasant households ensure yield by application fertilizer.Punching fertilising is called liquid fertilizer, is
A kind of fertilizing type, i.e., the quick-acting chemical fertilizer of solid it is soluble in water and by water band fertilizer in a manner of apply people's soil.It is combined by rich water,
The nutrient of the required solubility of plant is penetrated into soil, is absorbed by crop root, and not only water-saving, province's fertilizer saves artificial shield
Canal, fertilising labour substantially reduce goods and materials and cost of labor, and mitigate the generation of pest and disease damage and the use of pesticide, are conducive to vegetable
Dish No-harmful apple orchard.Since the fertilizer efficiency of punching fertilising is come soon, 25d can take effect after general punching, show the change of leaf color and plant height
Change significantly, therefore, punching fertilising have developed rapidly in recent years, is widely adopted on vegetables and other industrial crops.
But since the fertilising of most of blindnesses, excessive fertilization phenomenon are more universal, tradition punching fertilising inferior quality causes
It is most after the problems such as thin out taste of fruit and storage property variation occur is serious, and conventional instant chemical fertilizer is manured into soil
It is lost by rain drop erosion, utilization rate is low, and the loss of fertilizer is not only economic loss, and cause to ecological environment
Significant damage.Therefore, controlled capability fertilizer has Releasing nutrient rate slow compared with common fertilizer, discharges as a kind of novel fertilizer
Speed and the features such as nutrient speed is consistent needed for plant growth, it is more suitable for plant growth.For punching is applied fertilizer, reach controlled release
Effect, it is promoted with using having good facilitation effect, therefore, tradition is rushed system of fertilization it is standby propose it is higher will
It asks, the comprehensive performance of punching fertilising could be improved.
Therefore, how to improve tradition punching fertilising nutritional ingredient utilization rate it is low, plant products increasing action is smaller, product quality
The shortcomings that poor, rushes fertilising with acquisition more high combination property, is that it is promoted with applied to broader field, meeting industrial raw
Production demand urgent problem to be solved.
Invention content
The present invention solves the technical problem of：It is low that nutritional ingredient utilization rate of applying fertilizer is rushed for tradition, plant products, which increase, to be made
With the shortcomings that smaller, product quality is poor, a kind of acid soil specific complex punching fertilising is provided.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of acid soil specific complex punching fertilising, is made of the raw material of following parts by weight：
20~30 parts of urea
3~5 parts of dopamine
10~18 parts of Bacillus pasteurii bacterium solution
Make 10~20 parts of lotion by oneself
8~10 parts of inorganic salts
4~6 parts of additive
10~15 parts of carbomer liquid
10~15 parts of chitosan liquid
4~8 parts of kitchen garbage zymotic fluid
4~8 parts of the decomposed liquid of poultry dung
100~200 parts of water
The acid soil specific complex rushes the preparation process applied fertilizer：
（1）It is formed by raw material and weighs each component；
（2）First urea, dopamine, self-control lotion, inorganic salts and water are stirred, sequentially add carbomer liquid, chitosan
Liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung, continue after being stirred, and sterilizing obtains sterilizing mixed liquor；
（3）It after Bacillus pasteurii bacterium solution and additive are stirred, adds in sterilizing mixed liquor, and into sterilizing mixed liquor
Argon gas is passed through, discharges to rush to get acid soil specific complex and apply fertilizer.
The Bacillus pasteurii bacterium solution configuration process is：It is 1 in mass ratio：400~1：500 by Bacillus pasteurii and
Water mixes, and adds the grape juice of water quality 1~3%, is stirred, obtains Bacillus pasteurii bacterium solution.
It is described self-control emulsion preparation process be：It will（N- amidino groups）Dodecylacrylamide presses matter with polyethylene glycol phosphate
Measure ratio 4：1~6：1 mixing, and add in the paracide of 0.1~0.3 times of polyethylene glycol phosphate quality and polyethylene glycol phosphate
The ferrocene that 0.1~0.2 times of quality after being stirred to react, adds（N- amidino groups）3~5 times of dodecylacrylamide quality
Water is stirred, derived from lotion processed.
The inorganic salts are configured by the raw material of following parts by weight：14~18 parts of potassium dihydrogen phosphates, 10~15 parts
Magnesium sulfate, 2~4 parts of cerous nitrates.
It is 1 in mass ratio by glycerine and diethanol that the additive, which is,：1~3：1 is configured.
The carbomer liquid configuration process is：It is 1 in mass ratio by carbomer and water：10~1：After 20 mixing, ammonia is added dropwise
Water adjusts pH to 6.5~6.7, then through ultrasonic disperse, obtains carbomer liquid.
The chitosan liquid configuration process is：It is 1 in mass ratio by chitosan and water：10~1：It is quiet after 15 are stirred
Swelling is put, adds the chitosan enzyme of chitosan mass 4~6%, after constant temperature stirring digests, enzyme deactivation obtains chitosan liquid.
The kitchen garbage zymotic fluid preparation process is：It is 1 in mass ratio by kitchen garbage, water and biogas slurry：1：1 mixing
Afterwards, constant temperature stirring 24~36h of anaerobic fermentation, centrifuges, and collects upper liquid, obtains kitchen garbage zymotic fluid.
The decomposed liquid preparation process of poultry dung is：Count in parts by weight, take successively 20~50 parts of chicken manures, 8~10 parts
Birds droppings, 20~50 parts of duck excrements, 10~15 parts of water after being stirred, are stacked 7~10 days in being protected from light ventilation, obtain stack retting material, then will
Stack retting material and water are 1 in mass ratio：5~1：10 is steaming mixed, and filtering obtains the decomposed liquid of poultry dung.
The beneficial effects of the invention are as follows：
（1）Technical solution of the present invention is one of active ingredient by using urea and Bacillus pasteurii bacterium solution, is using process
In, Bacillus pasteurii can decompose urea, and generate ammonium ion and carbanion, and first, ammonium ion can conduct
Nitrogen source is directly absorbed by plant root, and carbanion can be combined with hydrogen ion in acid soil, and generates carbonic acid, and carbon
Acid is unstable, and after daylight soil is heated, decomposable asymmetric choice net, which generates water and carbon dioxide, hydrionic consumption, can play adjusting
The effect of soil pH value, and water can be supplied directly to plant utilization, and carbon dioxide is discharged from soil, so as to abundant soil hole
Gap structure, is conducive to air and moisture penetration enters soil, so as to improve plant root respiration, strengthens root in soil
The quick absorption of active ingredient, and be conducive to the growth of root, plant is avoided due to above ground portion and under ground portion nutrient imbalance
There is the phenomenon that " top-heavy ", so as to reduce plant lodging, improve yield, and after carbon dioxide release, Plant Light can be used as
The required raw material of cooperation, further increases plant products；
（2）Technical solution of the present invention makes lotion by oneself to provide emulsification system by addition, in preparation process, the sky of inner emulsion
Most of active ingredient can be coated on cavity inside and form imitated vesicle structure by chamber, be existed so as to be conducive to each active ingredient in product
It permeates and is distributed in soil, and the presence of imitated vesicle structure can effectively avoid beneficiating ingredient and is lost in without plant absorption, improve battalion
The utilization rate formed point, in addition, after use, as plant root respiration generates carbon dioxide and Bacillus pasteurii
The carbon dioxide generated after decomposing urea increases so that amidine group can be acted on carbon dioxide in self-control lotion and band powers on
Lotus, since the repulsive interaction between like charges causes inner emulsion cavity system to expand, so as to increase vesica grain size, wall
Thickness reduces, final capsules rupture and be released internal cladding active ingredient, and the carry out rate of this process, with plant roots
The metabolic power of power and Bacillus pasteurii of portion's respiration is proportionate, and therefore, can be metabolized with plant growth
Vigorous degree and realize controlled release, further improve the utilization rate of active ingredient.
Specific embodiment
It is 1 in mass ratio：400~1：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, are stirred with glass bar
After mixing 10~15min of mixing, the grape juice of water quality 1~3% is added, continues to be stirred 10~20min, obtains Pasteur's gemma
Bacillus bacterium solution；It will（N- amidino groups）Dodecylacrylamide and polyethylene glycol phosphate in mass ratio 4：1~6：1 mixing pours into three
Mouth flask, and the paracide of 0.1~0.3 times of polyethylene glycol phosphate quality and polyethylene glycol phosphoric acid are added in into three-necked flask
The ferrocene that 0.1~0.2 times of ester quality, then three-necked flask immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature for 40~
45 DEG C, under the conditions of rotating speed is 400~600r/min, constant temperature is stirred to react 4~6h, under constant temperature stirring, is burnt to three mouthfuls
It is added in bottle（N- amidino groups）The water that 3~5 times of dodecylacrylamide quality continues to be stirred 10~20min, derived from system breast
Liquid；It is 1 in mass ratio by carbomer and water：10~1：20 are stirred, and mass fraction is added dropwise as 10~15% ammonium hydroxide, adjust
PH to 6.5~6.7, then at supersonic frequency under the conditions of 45~50kHz, 45~60min of ultrasonic disperse obtains carbomer liquid；By shell
Glycan and water are 1 in mass ratio：10~1：15 mixing are poured into No. 2 beakers, after being stirred 5~10min with glass bar, in room
4~6h of swelling is stood under the conditions of temperature, then the chitosan enzyme of chitosan mass 4~6% is added in into No. 2 beakers, and by No. 2 beakers
It moves into digital display to test the speed constant temperature blender with magnetic force, is 32~35 DEG C in temperature, under the conditions of rotating speed is 400~500r/min, constant temperature stirs
2~4h of enzymolysis is mixed, under the conditions of temperature is 85~95 DEG C, keeps the temperature 10~15min of enzyme deactivation, discharging obtains chitosan liquid；By quality
Than being 1：1：Kitchen garbage, water and biogas slurry are mixed and are poured into fermentation tank by 1, in temperature be 35~40 DEG C, rotating speed for 180~
Under the conditions of 200r/min, constant temperature stirring 24~36h of anaerobic fermentation, then material in fermentation tank is transferred to centrifuge, it is in rotating speed
Under the conditions of 12000~15000r/min, 10~15min is centrifuged, upper liquid is collected, obtains kitchen garbage zymotic fluid；By weight
Number meter, takes 20~50 parts of chicken manures, 8~10 parts of birds droppings, 20~50 parts of duck excrements successively, 10~15 parts of water, with blender with 300~
After 400r/min rotating speeds are stirred 20~30min, are stacked 7~10 days in being protected from light ventilation, obtain stack retting material, then by stack retting material and
Water is 1 in mass ratio：5~1：10 mixing are poured into iron pan, and 30~45min of boiling is heated under the conditions of being 95~98 DEG C in temperature,
It filters while hot, obtains poultry dung corrosive liquid；It counts in parts by weight, takes 20~30 parts of urea successively, 3~5 parts of dopamines, 10~18
Part Bacillus pasteurii bacterium solution, 10~20 parts of self-control lotions, 8~10 parts of inorganic salts, 4~6 parts of additives, 10~15 parts of carbomers
Liquid, 10~15 parts of chitosan liquid, 4~8 portions of kitchen garbage zymotic fluids, 4~8 parts of decomposed liquid of poultry dung, 100~200 parts of water, first
Urea, dopamine, self-control lotion, inorganic salts and water are poured into batch mixer, in rotating speed under the conditions of 300~500r/min, to stir
After mixing 30~45min of mixing, then carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid and poultry dung are added in into batch mixer
Decomposed liquid continues to be stirred 45~60min, then material in batch mixer is transferred to autoclave with 600~800r/min rotating speeds, warp
10~20min of pasteurization obtains sterilizing mixed liquor；Bacillus pasteurii bacterium solution and additive are stirred 10 with glass bar~
After 20min, add in gained sterilizing mixed liquor, and argon gas is passed through with 30~50mL/min rates into sterilizing mixed liquor, continue
After being passed through 1~2h, discharge to rush to get acid soil specific complex and apply fertilizer.The inorganic salts are by the raw material of following parts by weight
It is configured：14~18 parts of potassium dihydrogen phosphates, 10~15 parts of magnesium sulfate, 2~4 parts of cerous nitrates.The additive be by glycerine and
Diethanol is 1 in mass ratio：1~3：1 is configured.
Example 1
It is 1 in mass ratio：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, and 15min is stirred with glass bar
Afterwards, the grape juice of water quality 3% is added, continues to be stirred 20min, obtains Bacillus pasteurii bacterium solution；It will（N- amidino groups）12
Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 6：Three-necked flask is poured into 1 mixing, and adds in and gather into three-necked flask
The paracide of 0.3 times of ethylene glycol phosphate quality and the ferrocene of 0.2 times of polyethylene glycol phosphate quality, then by three-necked flask
It moving into digital display to test the speed constant temperature blender with magnetic force, is 45 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 6h,
Under constant temperature stirring, added in into three-necked flask（N- amidino groups）The water that 5 times of dodecylacrylamide quality continues to stir
Mixing 20min is mixed, derived from lotion processed；It is 1 in mass ratio by carbomer and water：20 are stirred, and it is 15% that mass fraction, which is added dropwise,
Ammonium hydroxide adjusts pH to 6.7, then at supersonic frequency under the conditions of 50kHz, ultrasonic disperse 60min obtains carbomer liquid；By chitosan
It is 1 in mass ratio with water：15 mixing are poured into No. 2 beakers, after being stirred 10min with glass bar, in standing under room temperature
6h is swollen, then the chitosan enzyme of chitosan mass 6% is added in into No. 2 beakers, and No. 2 beakers are moved into digital displays and are tested the speed constant temperature magnetic
Power blender is 35 DEG C in temperature, and under the conditions of rotating speed is 500r/min, constant temperature stirring enzymolysis 4h, is 95 DEG C of conditions then at temperature
Under, enzyme deactivation 15min is kept the temperature, discharging obtains chitosan liquid；It is 1 in mass ratio：1：The mixing of kitchen garbage, water and biogas slurry is poured into hair by 1
In fermentation tank, in temperature be 40 DEG C, under the conditions of rotating speed is 200r/min, constant temperature stirring anaerobic fermentation 36h, then by material in fermentation tank
Centrifuge is transferred to, in rotating speed under the conditions of 15000r/min, to centrifuge 15min, upper liquid is collected, obtains kitchen garbage fermentation
Liquid；It counts in parts by weight, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 parts of duck excrements successively, 15 parts of water are turned with blender with 400r/min
It after speed is stirred 30min, is stacked 10 days in being protected from light ventilation, obtains stack retting material, then by stack retting material and water be 1 in mass ratio：10
Mixing is poured into iron pan, is heated boiling 45min under the conditions of being 98 DEG C in temperature, is filtered while hot, obtain poultry dung corrosive liquid；By weight
Number meter is measured, takes 30 parts of urea successively, 5 parts of dopamines, 18 parts of Bacillus pasteurii bacterium solutions, 20 parts of self-control lotions, 10 parts inorganic
Salt, 6 parts of additives, 15 parts of carbomer liquid, 15 parts of chitosan liquid, 8 portions of kitchen garbage zymotic fluids, 8 parts of decomposed liquid of poultry dung,
200 parts of water first pour into urea, dopamine, self-control lotion, inorganic salts and water in batch mixer, in rotating speed be 500r/min conditions
Under, after being stirred 45min, then carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid and poultry dung are added in into batch mixer
Decomposed liquid continues to be stirred 60min, then material in batch mixer is transferred to autoclave with 800r/min rotating speeds, through pasteurization
20min obtains sterilizing mixed liquor；After Bacillus pasteurii bacterium solution and additive are stirred 20min with glass bar, gained is added in
In sterilizing mixed liquor, and argon gas is passed through with 50mL/min rates into sterilizing mixed liquor, after being continually fed into 2h, discharged to get acid
Property the punching fertilising of soil specific complex.The inorganic salts are to form 18 parts of potassium dihydrogen phosphates by the raw material configuration of following parts by weight,
15 parts of magnesium sulfate, 4 parts of cerous nitrates.It is 3 in mass ratio by glycerine and diethanol that the additive, which is,：1 is configured.
Example 2
It is 1 in mass ratio：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, and 15min is stirred with glass bar
Afterwards, the grape juice of water quality 3% is added, continues to be stirred 20min, obtains Bacillus pasteurii bacterium solution；It will（N- amidino groups）12
Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 6：Three-necked flask is poured into 1 mixing, and adds in and gather into three-necked flask
The paracide of 0.3 times of ethylene glycol phosphate quality and the ferrocene of 0.2 times of polyethylene glycol phosphate quality, then by three-necked flask
It moving into digital display to test the speed constant temperature blender with magnetic force, is 45 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 6h,
Under constant temperature stirring, added in into three-necked flask（N- amidino groups）The water that 5 times of dodecylacrylamide quality continues to stir
Mixing 20min is mixed, derived from lotion processed；It is 1 in mass ratio by carbomer and water：20 are stirred, and it is 15% that mass fraction, which is added dropwise,
Ammonium hydroxide adjusts pH to 6.7, then at supersonic frequency under the conditions of 50kHz, ultrasonic disperse 60min obtains carbomer liquid；By chitosan
It is 1 in mass ratio with water：15 mixing are poured into No. 2 beakers, after being stirred 10min with glass bar, in standing under room temperature
6h is swollen, then the chitosan enzyme of chitosan mass 6% is added in into No. 2 beakers, and No. 2 beakers are moved into digital displays and are tested the speed constant temperature magnetic
Power blender is 35 DEG C in temperature, and under the conditions of rotating speed is 500r/min, constant temperature stirring enzymolysis 4h, is 95 DEG C of conditions then at temperature
Under, enzyme deactivation 15min is kept the temperature, discharging obtains chitosan liquid；It is 1 in mass ratio：1：The mixing of kitchen garbage, water and biogas slurry is poured into hair by 1
In fermentation tank, in temperature be 40 DEG C, under the conditions of rotating speed is 200r/min, constant temperature stirring anaerobic fermentation 36h, then by material in fermentation tank
Centrifuge is transferred to, in rotating speed under the conditions of 15000r/min, to centrifuge 15min, upper liquid is collected, obtains kitchen garbage fermentation
Liquid；It counts in parts by weight, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 parts of duck excrements successively, 15 parts of water are turned with blender with 400r/min
It after speed is stirred 30min, is stacked 10 days in being protected from light ventilation, obtains stack retting material, then by stack retting material and water be 1 in mass ratio：10
Mixing is poured into iron pan, is heated boiling 45min under the conditions of being 98 DEG C in temperature, is filtered while hot, obtain poultry dung corrosive liquid；By weight
Number meter is measured, takes 5 parts of dopamines, 18 parts of Bacillus pasteurii bacterium solutions, 20 parts of self-control lotions, 10 parts of inorganic salts, 6 parts of additions successively
Agent, 15 parts of carbomer liquid, 15 parts of chitosan liquid, 8 portions of kitchen garbage zymotic fluids, 8 parts of decomposed liquid of poultry dung, 200 parts of water first will
Dopamine, self-control lotion, inorganic salts and water are poured into batch mixer, in rotating speed under the conditions of 500r/min, to be stirred 45min
Afterwards, carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung are added in then into batch mixer, continue with
800r/min rotating speeds are stirred 60min, then material in batch mixer is transferred to autoclave, through pasteurization 20min, must sterilize mixed
Close liquid；After Bacillus pasteurii bacterium solution and additive are stirred 20min with glass bar, add in gained sterilizing mixed liquor,
And argon gas is passed through with 50mL/min rates into sterilizing mixed liquor, after being continually fed into 2h, discharge to get acid soil specific complex
Punching fertilising.The inorganic salts are to be configured to form 18 parts of potassium dihydrogen phosphates by the raw material of following parts by weight, 15 parts of magnesium sulfate, 4 parts
Cerous nitrate.It is 3 in mass ratio by glycerine and diethanol that the additive, which is,：1 is configured.
Example 3
It is 1 in mass ratio：500 pour into saccharomycete and water mixing in No. 1 beaker, after being stirred 15min with glass bar, then add
Enter the grape juice of water quality 3%, continue to be stirred 20min, obtain saccharomycete bacterium solution；It will（N- amidino groups）Dodecylacrylamide
With polyethylene glycol phosphate in mass ratio 6：Three-necked flask is poured into 1 mixing, and polyethylene glycol phosphate is added in into three-necked flask
The paracide and the ferrocene of 0.2 times of polyethylene glycol phosphate quality that 0.3 times of quality, then three-necked flask immigration digital display is tested the speed
Constant temperature blender with magnetic force is 45 DEG C in temperature, and under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 6h, is stirred then at constant temperature
Under state, added in into three-necked flask（N- amidino groups）The water that 5 times of dodecylacrylamide quality continues to be stirred 20min,
Derived from lotion processed；It is 1 in mass ratio by carbomer and water：20 are stirred, and mass fraction is added dropwise as 15% ammonium hydroxide, adjust pH
To 6.7, then at supersonic frequency under the conditions of 50kHz, ultrasonic disperse 60min obtains carbomer liquid；By chitosan and water in mass ratio
It is 1：15 mixing are poured into No. 2 beakers, after being stirred 10min with glass bar, in standing swelling 6h under room temperature, then to 2
It adds in the chitosan enzyme of chitosan mass 6% in number beaker, and No. 2 beakers is moved into digital displays and are tested the speed constant temperature blender with magnetic force, Yu Wen
It is 35 DEG C to spend, and under the conditions of rotating speed is 500r/min, constant temperature stirring enzymolysis 4h under the conditions of temperature is 95 DEG C, keeps the temperature enzyme deactivation
15min, discharging, obtains chitosan liquid；It is 1 in mass ratio：1：1 pours into the mixing of kitchen garbage, water and biogas slurry in fermentation tank, Yu Wen
It is 40 DEG C to spend, under the conditions of rotating speed is 200r/min, constant temperature stirring anaerobic fermentation 36h, then material in fermentation tank is transferred to centrifuge,
In rotating speed under the conditions of 15000r/min, to centrifuge 15min, upper liquid is collected, obtains kitchen garbage zymotic fluid；In parts by weight
Meter, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 parts of duck excrements, 15 parts of water are stirred with blender with 400r/min rotating speeds successively
It after 30min, is stacked 10 days in being protected from light ventilation, obtains stack retting material, then by stack retting material and water be 1 in mass ratio：Iron is poured into 10 mixing
In pot, boiling 45min is heated under the conditions of being 98 DEG C in temperature, filters while hot, obtains poultry dung corrosive liquid；It counts in parts by weight,
Take 30 parts of urea successively, 5 parts of dopamines, 18 parts of saccharomycete bacterium solutions, 20 parts of self-control lotions, 10 parts of inorganic salts, 6 parts of additives, 15
Part carbomer liquid, 15 parts of chitosan liquid, 8 portions of kitchen garbage zymotic fluids, 8 parts of decomposed liquid of poultry dung, 200 parts of water, first by urea,
Dopamine, self-control lotion, inorganic salts and water are poured into batch mixer, in rotating speed under the conditions of 500r/min, to be stirred 45min
Afterwards, carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung are added in then into batch mixer, continue with
800r/min rotating speeds are stirred 60min, then material in batch mixer is transferred to autoclave, through pasteurization 20min, must sterilize mixed
Close liquid；After saccharomycete bacterium solution and additive are stirred 20min with glass bar, add in gained sterilizing mixed liquor, and to going out
Argon gas is passed through with 50mL/min rates in bacterium mixed liquor, after being continually fed into 2h, discharges and is applied to get the punching of acid soil specific complex
Fertilizer.The inorganic salts are to form 18 parts of potassium dihydrogen phosphates, 15 parts of magnesium sulfate, 4 parts of nitric acid by the raw material configuration of following parts by weight
Cerium.It is 3 in mass ratio by glycerine and diethanol that the additive, which is,：1 is configured.
Example 4
It is 1 in mass ratio：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, and 15min is stirred with glass bar
Afterwards, the grape juice of water quality 3% is added, continues to be stirred 20min, obtains Bacillus pasteurii bacterium solution；By water and dodecyl
Benzene sulfonic acid sodium salt in mass ratio 100：7 mixing derive from lotion processed in beaker, stirring 20min；It is in mass ratio by carbomer and water
1：20 are stirred, and mass fraction is added dropwise as 15% ammonium hydroxide, adjust pH to 6.7, then at supersonic frequency under the conditions of 50kHz, to surpass
Sound disperses 60min, obtains carbomer liquid；It is 1 in mass ratio by chitosan and water：15 mixing are poured into No. 2 beakers, are stirred with glass bar
After mixing mixing 10min, 6h is swollen in standing under room temperature, then the chitosan enzyme of chitosan mass 6% is added in into No. 2 beakers,
And No. 2 beakers are moved into digital displays and are tested the speed constant temperature blender with magnetic force, in temperature be 35 DEG C, under the conditions of rotating speed is 500r/min, constant temperature
Stirring enzymolysis 4h under the conditions of temperature is 95 DEG C, keeps the temperature enzyme deactivation 15min, and discharging obtains chitosan liquid；It is 1 in mass ratio：1：1
Kitchen garbage, water and biogas slurry are mixed and poured into fermentation tank, is 40 DEG C in temperature, under the conditions of rotating speed is 200r/min, constant temperature stirs
Anaerobic fermentation 36h is mixed, then material in fermentation tank is transferred to centrifuge, in rotating speed under the conditions of 15000r/min, to centrifuge
15min collects upper liquid, obtains kitchen garbage zymotic fluid；It counts in parts by weight, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 portions of ducks successively
Excrement, 15 parts of water after being stirred 30min with blender with 400r/min rotating speeds, are stacked 10 days in being protected from light ventilation, obtain stack retting
Material, then by stack retting material and water be 1 in mass ratio：10 mixing are poured into iron pan, and boiling is heated under the conditions of being 98 DEG C in temperature
45min is filtered while hot, obtains poultry dung corrosive liquid；It counts in parts by weight, takes 30 parts of urea successively, 5 parts of dopamines, 18 parts bars
Family name's bacillus bacterium solution, 20 parts of self-control lotions, 10 parts of inorganic salts, 6 parts of additives, 15 parts of carbomer liquid, 15 parts of chitosan liquid, 8
Portion kitchen garbage zymotic fluid, 8 parts of decomposed liquid of poultry dung, 200 parts of water, first by urea, dopamine, self-control lotion, inorganic salts and
Water is poured into batch mixer, in rotating speed under the conditions of 500r/min, after being stirred 45min, then to add in carbomer into batch mixer
Liquid, chitosan liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung, continue to be stirred 60min with 800r/min rotating speeds, then
Material in batch mixer is transferred to autoclave, through pasteurization 20min, obtains sterilizing mixed liquor；By Bacillus pasteurii bacterium solution and add
After agent is added to be stirred 20min with glass bar, add in gained sterilizing mixed liquor, and into sterilizing mixed liquor with 50mL/min speed
Rate is passed through argon gas, after being continually fed into 2h, discharges to rush to get acid soil specific complex and apply fertilizer.The inorganic salts are by following heavy
The raw material configuration for measuring number forms 18 parts of potassium dihydrogen phosphates, 15 parts of magnesium sulfate, 4 parts of cerous nitrates.The additive be by glycerine and
Diethanol is 3 in mass ratio：1 is configured.
Example 5
It is 1 in mass ratio：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, and 15min is stirred with glass bar
Afterwards, the grape juice of water quality 3% is added, continues to be stirred 20min, obtains Bacillus pasteurii bacterium solution；It will（N- amidino groups）12
Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 6：Three-necked flask is poured into 1 mixing, and adds in and gather into three-necked flask
The paracide of 0.3 times of ethylene glycol phosphate quality and the ferrocene of 0.2 times of polyethylene glycol phosphate quality, then by three-necked flask
It moving into digital display to test the speed constant temperature blender with magnetic force, is 45 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 6h,
Under constant temperature stirring, added in into three-necked flask（N- amidino groups）The water that 5 times of dodecylacrylamide quality continues to stir
Mixing 20min is mixed, derived from lotion processed；It is 1 in mass ratio by carbomer and water：20 are stirred, and it is 15% that mass fraction, which is added dropwise,
Ammonium hydroxide adjusts pH to 6.7, then at supersonic frequency under the conditions of 50kHz, ultrasonic disperse 60min obtains carbomer liquid；By chitosan
It is 1 in mass ratio with water：15 mixing are poured into No. 2 beakers, after being stirred 10min with glass bar, in standing under room temperature
6h is swollen, then the chitosan enzyme of chitosan mass 6% is added in into No. 2 beakers, and No. 2 beakers are moved into digital displays and are tested the speed constant temperature magnetic
Power blender is 35 DEG C in temperature, and under the conditions of rotating speed is 500r/min, constant temperature stirring enzymolysis 4h, is 95 DEG C of conditions then at temperature
Under, enzyme deactivation 15min is kept the temperature, discharging obtains chitosan liquid；It is 1 in mass ratio：1：The mixing of kitchen garbage, water and biogas slurry is poured into hair by 1
In fermentation tank, in temperature be 40 DEG C, under the conditions of rotating speed is 200r/min, constant temperature stirring anaerobic fermentation 36h, then by material in fermentation tank
Centrifuge is transferred to, in rotating speed under the conditions of 15000r/min, to centrifuge 15min, upper liquid is collected, obtains kitchen garbage fermentation
Liquid；It counts in parts by weight, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 parts of duck excrements successively, 15 parts of water are turned with blender with 400r/min
It after speed is stirred 30min, is stacked 10 days in being protected from light ventilation, obtains stack retting material, then by stack retting material and water be 1 in mass ratio：10
Mixing is poured into iron pan, is heated boiling 45min under the conditions of being 98 DEG C in temperature, is filtered while hot, obtain poultry dung corrosive liquid；By weight
Number meter is measured, takes 30 parts of urea successively, 5 parts of dopamines, 18 parts of Bacillus pasteurii bacterium solutions, 20 parts of self-control lotions, 10 parts inorganic
Salt, 15 parts of carbomer liquid, 15 parts of chitosan liquid, 8 portions of kitchen garbage zymotic fluids, 8 parts of decomposed liquid of poultry dung, 200 parts of water first will
Urea, dopamine, self-control lotion, inorganic salts and water are poured into batch mixer, in rotating speed under the conditions of 500r/min, to be stirred
After 45min, then carbomer liquid, chitosan liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung are added in into batch mixer, continued
60min is stirred, then material in batch mixer is transferred to autoclave with 800r/min rotating speeds, through pasteurization 20min, must be sterilized
Mixed liquor；Bacillus pasteurii bacterium solution is added in gained sterilizing mixed liquor, and into sterilizing mixed liquor with 50mL/min rates
Argon gas is passed through, after being continually fed into 2h, discharges to rush to get acid soil specific complex and apply fertilizer.The inorganic salts are by following weight
The raw material configuration of number forms 18 parts of potassium dihydrogen phosphates, 15 parts of magnesium sulfate, 4 parts of cerous nitrates.
Example 6
It is 1 in mass ratio：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, and 15min is stirred with glass bar
Afterwards, the grape juice of water quality 3% is added, continues to be stirred 20min, obtains Bacillus pasteurii bacterium solution；It will（N- amidino groups）12
Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 6：Three-necked flask is poured into 1 mixing, and adds in and gather into three-necked flask
The paracide of 0.3 times of ethylene glycol phosphate quality and the ferrocene of 0.2 times of polyethylene glycol phosphate quality, then by three-necked flask
It moving into digital display to test the speed constant temperature blender with magnetic force, is 45 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 6h,
Under constant temperature stirring, added in into three-necked flask（N- amidino groups）The water that 5 times of dodecylacrylamide quality continues to stir
Mixing 20min is mixed, derived from lotion processed；It is 1 in mass ratio by chitosan and water：15 mixing are poured into No. 2 beakers, are stirred with glass bar
After mixing mixing 10min, 6h is swollen in standing under room temperature, then the chitosan enzyme of chitosan mass 6% is added in into No. 2 beakers,
And No. 2 beakers are moved into digital displays and are tested the speed constant temperature blender with magnetic force, in temperature be 35 DEG C, under the conditions of rotating speed is 500r/min, constant temperature
Stirring enzymolysis 4h under the conditions of temperature is 95 DEG C, keeps the temperature enzyme deactivation 15min, and discharging obtains chitosan liquid；It is 1 in mass ratio：1：1
Kitchen garbage, water and biogas slurry are mixed and poured into fermentation tank, is 40 DEG C in temperature, under the conditions of rotating speed is 200r/min, constant temperature stirs
Anaerobic fermentation 36h is mixed, then material in fermentation tank is transferred to centrifuge, in rotating speed under the conditions of 15000r/min, to centrifuge
15min collects upper liquid, obtains kitchen garbage zymotic fluid；It counts in parts by weight, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 portions of ducks successively
Excrement, 15 parts of water after being stirred 30min with blender with 400r/min rotating speeds, are stacked 10 days in being protected from light ventilation, obtain stack retting
Material, then by stack retting material and water be 1 in mass ratio：10 mixing are poured into iron pan, and boiling is heated under the conditions of being 98 DEG C in temperature
45min is filtered while hot, obtains poultry dung corrosive liquid；It counts in parts by weight, takes 30 parts of urea successively, 5 parts of dopamines, 18 parts bars
Family name's bacillus bacterium solution, 20 parts of self-control lotions, 10 parts of inorganic salts, 6 parts of additives, 15 parts of chitosan liquid, 8 parts of kitchen garbage fermentations
Liquid, 8 parts of decomposed liquid of poultry dung, 200 parts of water first pour into urea, dopamine, self-control lotion, inorganic salts and water in batch mixer,
In rotating speed under the conditions of 500r/min, after being stirred 45min, then to add in chitosan liquid, kitchen garbage fermentation into batch mixer
Liquid and the decomposed liquid of poultry dung continue to be stirred 60min, then material in batch mixer is transferred to sterilizing with 800r/min rotating speeds
Pot, through pasteurization 20min, obtains sterilizing mixed liquor；Bacillus pasteurii bacterium solution and additive are stirred with glass bar
After 20min, add in gained sterilizing mixed liquor, and argon gas is passed through with 50mL/min rates into sterilizing mixed liquor, be continually fed into
After 2h, discharge to rush to get acid soil specific complex and apply fertilizer.The inorganic salts are configured by the raw material of following parts by weight
18 parts of potassium dihydrogen phosphates, 15 parts of magnesium sulfate, 4 parts of cerous nitrates.It is 3 in mass ratio by glycerine and diethanol that the additive, which is,：1 matches
It puts.
Example 7
It is 1 in mass ratio：500 pour into Bacillus pasteurii and water mixing in No. 1 beaker, and 15min is stirred with glass bar
Afterwards, the grape juice of water quality 3% is added, continues to be stirred 20min, obtains Bacillus pasteurii bacterium solution；It will（N- amidino groups）12
Alkyl acrylamide and polyethylene glycol phosphate in mass ratio 6：Three-necked flask is poured into 1 mixing, and adds in and gather into three-necked flask
The paracide of 0.3 times of ethylene glycol phosphate quality and the ferrocene of 0.2 times of polyethylene glycol phosphate quality, then by three-necked flask
It moving into digital display to test the speed constant temperature blender with magnetic force, is 45 DEG C in temperature, under the conditions of rotating speed is 600r/min, constant temperature is stirred to react 6h,
Under constant temperature stirring, added in into three-necked flask（N- amidino groups）The water that 5 times of dodecylacrylamide quality continues to stir
Mixing 20min is mixed, derived from lotion processed；It is 1 in mass ratio by carbomer and water：20 are stirred, and it is 15% that mass fraction, which is added dropwise,
Ammonium hydroxide adjusts pH to 6.7, then at supersonic frequency under the conditions of 50kHz, ultrasonic disperse 60min obtains carbomer liquid；In mass ratio
It is 1：1：1 by kitchen garbage, water and biogas slurry mix pour into fermentation tank, in temperature be 40 DEG C, rotating speed be 200r/min under the conditions of,
Constant temperature stirs anaerobic fermentation 36h, then material in fermentation tank is transferred to centrifuge, in rotating speed under the conditions of 15000r/min, to centrifuge
15min is detached, upper liquid is collected, obtains kitchen garbage zymotic fluid；It counts in parts by weight, takes 50 parts of chicken manures, 10 parts of birds droppings, 50 successively
Part duck excrement, 15 parts of water after being stirred 30min with blender with 400r/min rotating speeds, are stacked 10 days in being protected from light ventilation, obtain heap
It macerates material, then by stack retting material and water is 1 in mass ratio：10 mixing are poured into iron pan, and boiling is heated under the conditions of being 98 DEG C in temperature
45min is filtered while hot, obtains poultry dung corrosive liquid；It counts in parts by weight, takes 30 parts of urea successively, 5 parts of dopamines, 18 parts bars
Family name's bacillus bacterium solution, 20 parts of self-control lotions, 10 parts of inorganic salts, 6 parts of additives, 15 parts of carbomer liquid, 8 parts of kitchen garbage fermentations
Liquid, 8 parts of decomposed liquid of poultry dung, 200 parts of water first pour into urea, dopamine, self-control lotion, inorganic salts and water in batch mixer,
In rotating speed under the conditions of 500r/min, after being stirred 45min, then to add in carbomer liquid, kitchen garbage fermentation into batch mixer
Liquid and the decomposed liquid of poultry dung continue to be stirred 60min, then material in batch mixer is transferred to sterilizing with 800r/min rotating speeds
Pot, through pasteurization 20min, obtains sterilizing mixed liquor；Bacillus pasteurii bacterium solution and additive are stirred with glass bar
After 20min, add in gained sterilizing mixed liquor, and argon gas is passed through with 50mL/min rates into sterilizing mixed liquor, be continually fed into
After 2h, discharge to rush to get acid soil specific complex and apply fertilizer.The inorganic salts are configured by the raw material of following parts by weight
18 parts of potassium dihydrogen phosphates, 15 parts of magnesium sulfate, 4 parts of cerous nitrates.It is 3 in mass ratio by glycerine and diethanol that the additive, which is,：1 matches
It puts.
Comparative example：Fertilising is rushed in the production of Xuzhou agricultural science and technology Co., Ltd.
By the gained of example 1 to 7 rush fertilising and comparative example product carries out performance detection, specific detection method is as follows：
Fertilization effect：During test specimen is added to watermelon growing, carry out the fertilizer efficiency of the different test specimens of comparison.It is dense to dilute test specimen punching fertilising
400 times of degree, Seedling Stage, climing phase, fruit growth peak period dosage is drawn to be respectively 75,150,225kg/hm2, made by the way of trickle irrigation
With.Experiment sets 4 processing, is 1. 3 Seedling Stage, drawing climing phase and fruit growth peak period uses respectively；2. Seedling Stage, fruit growth
2 uses of peak period；3. draw 2 climing phase, fruit growth peak period uses.The plot area 160m each handled2, it is repeated 3 times, at random
Arrangement.10 plants are taken, investigates fertility condition, calculates average value.Watermelon Fruit is detected using portable diffusing reflection near-infrared analyzer
Core Site Determination center sugar content, at melon pulp measure side sugar amount, 10 samples is taken to measure respectively, calculate average value.
Specific testing result is as shown in table 1：
Table 1
By 1 testing result of table it is found that acid soil specific complex punching fertilising prepared by technical solution of the present invention can effectively improve
The utilization rate of nutritional ingredient and active ingredient promotes the increase of plant products, and fruit quality is also much improved,
It has broad prospects in the development of agrochemical industry.
Claims (9)
1. a kind of acid soil specific complex punching fertilising, which is characterized in that be made of the raw material of following parts by weight：
20~30 parts of urea
3~5 parts of dopamine
10~18 parts of Bacillus pasteurii bacterium solution
Make 10~20 parts of lotion by oneself
8~10 parts of inorganic salts
4~6 parts of additive
10~15 parts of carbomer liquid
10~15 parts of chitosan liquid
4~8 parts of kitchen garbage zymotic fluid
4~8 parts of the decomposed liquid of poultry dung
100~200 parts of water
The acid soil specific complex rushes the preparation process applied fertilizer：
（1）It is formed by raw material and weighs each component；
（2）First urea, dopamine, self-control lotion, inorganic salts and water are stirred, sequentially add carbomer liquid, chitosan
Liquid, kitchen garbage zymotic fluid and the decomposed liquid of poultry dung, continue after being stirred, and sterilizing obtains sterilizing mixed liquor；
（3）It after Bacillus pasteurii bacterium solution and additive are stirred, adds in sterilizing mixed liquor, and into sterilizing mixed liquor
Argon gas is passed through, discharges to rush to get acid soil specific complex and apply fertilizer.
2. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：Pasteur's gemma bar
Bacterium bacterium solution configuration process is：It is 1 in mass ratio：400~1：500 mix Bacillus pasteurii and water, add water quality 1~
3% grape juice, is stirred, and obtains Bacillus pasteurii bacterium solution.
3. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The self-control lotion system
It is for process：It will（N- amidino groups）Dodecylacrylamide and polyethylene glycol phosphate in mass ratio 4：1~6：1 mixing, and add
Enter the paracide of 0.1~0.3 times of polyethylene glycol phosphate quality and two cyclopentadienyls of 0.1~0.2 times of polyethylene glycol phosphate quality
Iron after being stirred to react, adds（N- amidino groups）The water that 3~5 times of dodecylacrylamide quality, is stirred, derived from system breast
Liquid.
4. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The inorganic salts be by
The raw material of following parts by weight is configured：14~18 parts of potassium dihydrogen phosphates, 10~15 parts of magnesium sulfate, 2~4 parts of cerous nitrates.
5. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The additive be by
Glycerine and diethanol are 1 in mass ratio：1~3：1 is configured.
6. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The carbomer liquid is matched
The process of putting is：It is 1 in mass ratio by carbomer and water：10~1：After 20 mixing, ammonium hydroxide is added dropwise and adjusts pH to 6.5~6.7, then pass through
Ultrasonic disperse obtains carbomer liquid.
7. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The chitosan liquid is matched
The process of putting is：It is 1 in mass ratio by chitosan and water：10~1：After 15 are stirred, swelling is stood, adds chitosan mass
4~6% chitosan enzyme, after constant temperature stirring digests, enzyme deactivation obtains chitosan liquid.
8. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The kitchen garbage hair
Zymotic fluid preparation process is：It is 1 in mass ratio by kitchen garbage, water and biogas slurry：1：After 1 mixing, constant temperature stirring anaerobic fermentation 24~
36h is centrifuged, and is collected upper liquid, is obtained kitchen garbage zymotic fluid.
9. a kind of acid soil specific complex punching fertilising according to claim 1, it is characterised in that：The poultry dung is rotten
Ripe liquid preparation process is：It counts in parts by weight, takes 20~50 parts of chicken manures, 8~10 parts of birds droppings, 20~50 parts of duck excrements successively, 10~
15 parts of water after being stirred, are stacked 7~10 days in being protected from light ventilation, obtain stack retting material, then by stack retting material and water are 1 in mass ratio：
5~1：10 is steaming mixed, and filtering obtains the decomposed liquid of poultry dung.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108977390A (en) * | 2018-08-10 | 2018-12-11 | 长沙昱旻信息科技有限公司 | A kind of pH responsive type bacillus subtilis microbial agent |
| CN109022326A (en) * | 2018-08-28 | 2018-12-18 | 云南大学 | One plant of production urea bacterium and its application |
| CN109054841A (en) * | 2018-08-10 | 2018-12-21 | 长沙昱旻信息科技有限公司 | A kind of pH responsive type agricultural microbial inoculum |
| CN109042638A (en) * | 2018-08-08 | 2018-12-21 | 长沙昱旻信息科技有限公司 | A kind of controlled release bacillus subtilis microbial agent |
| CN109836278A (en) * | 2019-03-14 | 2019-06-04 | 苏州鱼得水电气科技有限公司 | A kind of biologic compound fertilizer and its processing technology made of graphene oxide |
| CN111849496A (en) * | 2019-05-23 | 2020-10-30 | 史玉成 | Preparation method of multifunctional acid soil microbial improver |
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2017
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109042638A (en) * | 2018-08-08 | 2018-12-21 | 长沙昱旻信息科技有限公司 | A kind of controlled release bacillus subtilis microbial agent |
| CN108977390A (en) * | 2018-08-10 | 2018-12-11 | 长沙昱旻信息科技有限公司 | A kind of pH responsive type bacillus subtilis microbial agent |
| CN109054841A (en) * | 2018-08-10 | 2018-12-21 | 长沙昱旻信息科技有限公司 | A kind of pH responsive type agricultural microbial inoculum |
| CN108977390B (en) * | 2018-08-10 | 2020-11-20 | 河北丰农有机肥制造有限公司 | PH-sensitive bacillus subtilis microbial inoculum |
| CN109022326A (en) * | 2018-08-28 | 2018-12-18 | 云南大学 | One plant of production urea bacterium and its application |
| CN109836278A (en) * | 2019-03-14 | 2019-06-04 | 苏州鱼得水电气科技有限公司 | A kind of biologic compound fertilizer and its processing technology made of graphene oxide |
| CN111849496A (en) * | 2019-05-23 | 2020-10-30 | 史玉成 | Preparation method of multifunctional acid soil microbial improver |
| CN111849497A (en) * | 2019-05-23 | 2020-10-30 | 史玉成 | Preparation method of multifunctional acid soil microbial improver |
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