CN108149472A - 一种环保型纺织浆料 - Google Patents

一种环保型纺织浆料 Download PDF

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CN108149472A
CN108149472A CN201611105049.9A CN201611105049A CN108149472A CN 108149472 A CN108149472 A CN 108149472A CN 201611105049 A CN201611105049 A CN 201611105049A CN 108149472 A CN108149472 A CN 108149472A
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parts
sizing agent
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spinning sizing
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高朝飞
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Manchester Easy Textile Co Ltd Fuquan
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Manchester Easy Textile Co Ltd Fuquan
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymerisation Methods In General (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

一种环保型纺织浆料，以重量份计，包括以下组分：壳聚糖3‑9份，抗皱剂2‑8份、顺丁烯二酸酐15‑20份，双丙烯酸丁二酯2‑6份，膨润土0.5‑1.5份，水性共聚醚酯2‑6份，乙酰化二淀粉磷酸脂5‑12份，丙烯酰胺5‑15份，丙烯酸丁酯4‑9份，醋酸乙烯酯2‑6份，引发剂1‑2份，催化剂0.8‑1.5份，氯化钙2‑6份，去离子水5‑10份、变性淀粉5‑10份。壳聚糖和变性淀粉的加入可以有效膨化和疏松织物纤维，提高织物的上浆率，膨润土的加入，可以大大提高浆膜的强度和韧性；本发明通过合理控制浆料各组分的含量和制备工艺条件，制备得到的纺织浆料粘度稳定，具有优异的化学稳定性和热稳定性，易于上浆与退浆，浆液废水易于处理，浆膜性能和上浆性能好，吸湿再粘性低，绿色环保，避免环境污染。

Description

一种环保型纺织浆料
技术领域
本发明涉及纺织技术领域，具体涉及一种环保型纺织浆料。
背景技术
随着国民经济的不断发展，现代人对于纺织破品的要求越来越高，对使用的体验也提出了更加严苛的要求，纺织浆料使纱条表面被覆一层光滑、耐磨、柔韧且有一定强度的浆膜，使得纱条整体更为紧固，降低纱条表面的摩擦系数，同时使得部分浆液渗入纱线内部，增加纤维之间的粘附力，提高纱线的抗拉强度，以适应纺织制造过程中的大张力、中打纬，减少断头提高效率。目前浆料主要有三大类：淀粉(包括变性淀粉)、聚乙烯醇(PVA)、丙烯酸类(包括酸盐类、酰胺类、酯类)，正在研制开发的还有水分散性聚酯浆料。然而，在生产浆料、使用浆料、退浆过程中，不可避免要对环境造成污染，而且已成为纺织行业较大的污染源之一。淀粉用于经纱上浆历史悠久，因为淀粉是一种再生植物，资源丰富来源广，价格低廉，对亲水性纤维（如棉麻、粘胶纤维）具有良好的粘附性能，因此在三大类浆料中用量最多，可利用对淀粉改性，使其提高浆膜柔韧性、粘着性、渗透性、耐磨性，可降解，不会对环境、人体造成有害影响。
发明内容
本发明的目的在于提供一种环保型纺织浆料，该纺织浆料具有良好的成膜性和渗透性，不仅能减少污染，而且制备工艺简单，是一种环境友好型的工业产品。
本发明的技术方案：一种环保型纺织浆料，以重量份计，包括以下组分：壳聚糖3-9份，抗皱剂2-8份、顺丁烯二酸酐15-20份， 双丙烯酸丁二酯2-6份，膨润土0.5-1.5份， 水性共聚醚酯2-6份，乙酰化二淀粉磷酸脂5-12份， 丙烯酰胺5-15份，丙烯酸丁酯4-9份， 醋酸乙烯酯2-6份，引发剂1-2份， 催化剂0.8-1.5份，氯化钙2-6份，去离子水5-10份、变性淀粉5-10份。
前述环保型纺织浆料，以重量份计，包括以下组分：壳聚糖4-8份，抗皱剂3-7份、顺丁烯二酸酐17-19份， 双丙烯酸丁二酯3-5份，膨润土0.7-1.2份， 水性共聚醚酯3-5份，乙酰化二淀粉磷酸脂7-10份， 丙烯酰胺10-13份，丙烯酸丁酯5-8份， 醋酸乙烯酯3-5份，引发剂1.2-1.6份， 催化剂1-1.3份，氯化钙3-5份，去离子水6-9份、变性淀粉6-9份。
前述环保型纺织浆料，以重量份计，包括以下组分：壳聚糖7份，抗皱剂5份、顺丁烯二酸酐18份， 双丙烯酸丁二酯3-5份，膨润土1份， 水性共聚醚酯4份，乙酰化二淀粉磷酸脂8份， 丙烯酰胺12份，丙烯酸丁酯7份， 醋酸乙烯酯4份，引发剂1.5份， 催化剂1.2份，氯化钙4份，去离子水7份、变性淀粉8份。
与现有技术相比，壳聚糖和变性淀粉的加入可以有效膨化和疏松织物纤维，提高织物的上浆率，膨润土的加入，可以大大提高浆膜的强度和韧性；本发明通过合理控制浆料各组分的含量和制备工艺条件，制备得到的纺织浆料粘度稳定，具有优异的化学稳定性和热稳定性，易于上浆与退浆，浆液废水易于处理，浆膜性能和上浆性能好，吸湿再粘性低，绿色环保，避免环境污染。
具体实施方式
实施例1
一种环保型纺织浆料，以重量份计，包括以下组分：壳聚糖3份，抗皱剂2份、顺丁烯二酸酐15份， 双丙烯酸丁二酯2份，膨润土0.5份， 水性共聚醚酯2份，乙酰化二淀粉磷酸脂5份，丙烯酰胺5份，丙烯酸丁酯4份， 醋酸乙烯酯2份，引发剂1份， 催化剂0.8份，氯化钙2份，去离子水5份、变性淀粉5份。
实施例2
一种环保型纺织浆料，以重量份计，包括以下组分：壳聚糖7份，抗皱剂5份、顺丁烯二酸酐18份， 双丙烯酸丁二酯3-5份，膨润土1份， 水性共聚醚酯4份，乙酰化二淀粉磷酸脂8份，丙烯酰胺12份，丙烯酸丁酯7份， 醋酸乙烯酯4份，引发剂1.5份， 催化剂1.2份，氯化钙4份，去离子水7份、变性淀粉8份。
实施例3
一种环保型纺织浆料，以重量份计，包括以下组分：壳聚糖9份，抗皱剂8份、顺丁烯二酸酐20份， 双丙烯酸丁二酯6份，膨润土1.5份， 水性共聚醚酯6份，乙酰化二淀粉磷酸脂12份， 丙烯酰胺15份，丙烯酸丁酯9份， 醋酸乙烯酯6份，引发剂2份， 催化剂1.5份，氯化钙6份，去离子水10份、变性淀粉10份。

Claims (3)

1. 一种环保型纺织浆料，其特征在于，以重量份计，包括以下组分：壳聚糖3-9份，抗皱剂2-8份、顺丁烯二酸酐15-20份， 双丙烯酸丁二酯2-6份，膨润土0.5-1.5份， 水性共聚醚酯2-6份，乙酰化二淀粉磷酸脂5-12份， 丙烯酰胺5-15份，丙烯酸丁酯4-9份， 醋酸乙烯酯2-6份，引发剂1-2份， 催化剂0.8-1.5份，氯化钙2-6份，去离子水5-10份、变性淀粉5-10份。
2.根据权利要求1所述的环保型纺织浆料，其特征在于，以重量份计，包括以下组分：壳聚糖4-8份，抗皱剂3-7份、顺丁烯二酸酐17-19份， 双丙烯酸丁二酯3-5份，膨润土0.7-1.2份， 水性共聚醚酯3-5份，乙酰化二淀粉磷酸脂7-10份， 丙烯酰胺10-13份，丙烯酸丁酯5-8份， 醋酸乙烯酯3-5份，引发剂1.2-1.6份， 催化剂1-1.3份，氯化钙3-5份，去离子水6-9份、变性淀粉6-9份。
3.根据权利要求1所述的环保型纺织浆料，其特征在于，以重量份计，包括以下组分：壳聚糖7份，抗皱剂5份、顺丁烯二酸酐18份， 双丙烯酸丁二酯3-5份，膨润土1份， 水性共聚醚酯4份，乙酰化二淀粉磷酸脂8份， 丙烯酰胺12份，丙烯酸丁酯7份， 醋酸乙烯酯4份，引发剂1.5份， 催化剂1.2份，氯化钙4份，去离子水7份、变性淀粉8份。
CN201611105049.9A 2016-12-05 2016-12-05 一种环保型纺织浆料 Pending CN108149472A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110438808A (zh) * 2019-07-10 2019-11-12 南通缘喜纺织品有限公司 一种环保型纺织浆料及其制备方法
CN111335037A (zh) * 2020-04-03 2020-06-26 荆门市诺维英新材料科技有限公司 一种环保型纺织浆料及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110438808A (zh) * 2019-07-10 2019-11-12 南通缘喜纺织品有限公司 一种环保型纺织浆料及其制备方法
CN111335037A (zh) * 2020-04-03 2020-06-26 荆门市诺维英新材料科技有限公司 一种环保型纺织浆料及其制备方法

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Application publication date: 20180612