CN108093633B - 共处理二氧化碳和硫化氢的方法 - Google Patents

共处理二氧化碳和硫化氢的方法 Download PDF

Info

Publication number
CN108093633B
CN108093633B CN201580080946.6A CN201580080946A CN108093633B CN 108093633 B CN108093633 B CN 108093633B CN 201580080946 A CN201580080946 A CN 201580080946A CN 108093633 B CN108093633 B CN 108093633B
Authority
CN
China
Prior art keywords
anode
cathode
electrolyte
gas stream
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201580080946.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN108093633A (zh
Inventor
斯塔马蒂奥斯·索恩蒂
阿尔贝托·L·巴列斯特罗斯
弗里茨·西米恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Arabian Oil Co
Original Assignee
Saudi Arabian Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Arabian Oil Co filed Critical Saudi Arabian Oil Co
Publication of CN108093633A publication Critical patent/CN108093633A/zh
Application granted granted Critical
Publication of CN108093633B publication Critical patent/CN108093633B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0637—Direct internal reforming at the anode of the fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Fuel Cell (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Inert Electrodes (AREA)
CN201580080946.6A 2015-04-16 2015-10-14 共处理二氧化碳和硫化氢的方法 Active CN108093633B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/688,578 2015-04-16
US14/688,578 US9951430B2 (en) 2015-04-16 2015-04-16 Methods for co-processing carbon dioxide and hydrogen sulfide
PCT/US2015/055492 WO2016167835A1 (en) 2015-04-16 2015-10-14 Methods for co-processing carbon dioxides and hydrogen sulfide

Publications (2)

Publication Number Publication Date
CN108093633A CN108093633A (zh) 2018-05-29
CN108093633B true CN108093633B (zh) 2021-07-27

Family

ID=54697637

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580080946.6A Active CN108093633B (zh) 2015-04-16 2015-10-14 共处理二氧化碳和硫化氢的方法

Country Status (8)

Country Link
US (1) US9951430B2 (https=)
EP (1) EP3283669B1 (https=)
JP (1) JP6728226B2 (https=)
KR (1) KR20180019526A (https=)
CN (1) CN108093633B (https=)
SA (1) SA517390159B1 (https=)
SG (1) SG11201708519QA (https=)
WO (1) WO2016167835A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106602086A (zh) * 2016-11-23 2017-04-26 北京化工大学 一种自支撑氧还原/析出双效氧电极催化剂及其制备方法
CN107881529B (zh) * 2017-10-27 2019-08-27 江苏大学 一种复合析氢电催化材料及制备方法
CN110607531A (zh) * 2018-06-14 2019-12-24 中国科学院大连化学物理研究所 一种含硫化氢和二氧化碳气体循环电化学转化处理方法及其装置
JP7162300B2 (ja) * 2018-10-29 2022-10-28 時空化学株式会社 電極触媒及びその製造方法
CN109860546B (zh) * 2019-01-10 2022-02-15 宁德新能源科技有限公司 正极材料和包含所述正极材料的电化学装置
KR20220030938A (ko) * 2019-06-27 2022-03-11 니폰 제온 가부시키가이샤 황화카르보닐의 제조 방법
CN112569754B (zh) * 2019-09-29 2022-07-01 中国科学技术大学苏州高等研究院 一种生物电化学反应装置及气体纯化方法
CN113351008A (zh) * 2020-03-04 2021-09-07 中国科学院生态环境研究中心 钙钛矿复合氧化物材料在低温羰基硫水解反应中的应用
CN111304672B (zh) * 2020-03-18 2022-03-29 大连理工大学 一种h型固定床二氧化碳还原电解池及应用
CA3168369A1 (en) * 2020-03-31 2021-10-07 Osaka Gas Co., Ltd. Reverse water-gas shift catalyst, electrolytic reaction system, hydrocarbon production system, and production method and use method therefor
CN112679293B (zh) * 2020-12-30 2025-12-05 中国科学院山西煤炭化学研究所 一种h2s和co2混合气制取甲烷的方法及装置
CN113463128B (zh) * 2021-05-21 2023-05-09 兰州大学 水分解催化剂及其制备方法和应用
US12018392B2 (en) 2022-01-03 2024-06-25 Saudi Arabian Oil Company Methods for producing syngas from H2S and CO2 in an electrochemical cell
US12597623B2 (en) * 2022-09-14 2026-04-07 Saudi Arabian Oil Company Generating power from recycled hydrocarbon gas

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3249522A (en) * 1965-02-23 1966-05-03 Socony Mobil Oil Co Inc Electrochemical oxidation of hydrogen sulfide
CN1906122A (zh) * 2003-12-26 2007-01-31 株式会社杰士汤浅 氢制造方法和用于该方法的氢制造装置
UA61556U (uk) * 2010-12-14 2011-07-25 Институт Биоорганической Химии И Нефтехимии Нан Украины Пристрій для сумісної утилізації сірководню і оксидів вуглецю
UA62880U (uk) * 2010-12-14 2011-09-26 Институт Биоорганической Химии И Нефтехимии Нан Украины Спосіб сумісної утилізації сірководню і оксидів вуглецю
CN103160849A (zh) * 2011-12-12 2013-06-19 清华大学 二氧化碳电化学还原转化利用的方法
CN104024478A (zh) * 2011-07-06 2014-09-03 液体光有限公司 二氧化碳捕集和转化成有机产物

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3409520A (en) 1965-09-23 1968-11-05 Mobil Oil Corp Removal of hydrogen sulfide from a hydrogen sulfide-hydrocarbon gas mixture by electrolysis
US4081337A (en) 1977-04-22 1978-03-28 Robert Spitzer Electrolytic production of hydrogen
JPS56146883A (en) * 1980-04-15 1981-11-14 Mitsui Eng & Shipbuild Co Ltd Recovering method for hydrogen
US4544461A (en) 1983-03-28 1985-10-01 Energy Conversion Devices, Inc. Hydrogen sulfide decomposition cell and catalytic materials therefor
US5140049A (en) 1985-10-25 1992-08-18 Exxon Research And Engineering Co. Method for producing olefins from H2 and CO2 using an iron carbide based catalyst
ES2034360T3 (es) * 1987-03-26 1993-04-01 Institute Of Gas Technology Empleo de combustible conteniendo azufre en pilas de combustible de carbonato fundido.
US4859292A (en) 1988-03-28 1989-08-22 The Texas A & M University System Method and apparatus for H2 S electrolysis
US5019227A (en) 1989-11-09 1991-05-28 The Texas A&M University System Electrochemical method for producing hydrogen and sulfur
JP3259020B2 (ja) 1991-08-21 2002-02-18 智行 乾 酸化物系触媒、その製造法、および該触媒を用いたｃｏ２ の接触水素化方法
US5578189A (en) 1995-01-11 1996-11-26 Ceramatec, Inc. Decomposition and removal of H2 S into hydrogen and sulfur
CA2253161A1 (en) 1998-04-16 1999-10-16 Karl Tze-Tang Chuang Electrochemical oxidation of hydrogen sulfide
JP2001214288A (ja) * 2000-01-28 2001-08-07 Nippon Mitsubishi Oil Corp 水素および硫黄の製造方法
US20030215696A1 (en) 2002-05-14 2003-11-20 Chuang Karl T. Electrode catalysts for H2S fuel cell
US7278068B1 (en) 2003-03-05 2007-10-02 Sierra Design Group Method and system for providing power-hit tolerant state machines and data storage
US7378068B2 (en) 2005-06-01 2008-05-27 Conocophillips Company Electrochemical process for decomposition of hydrogen sulfide and production of sulfur
US7985332B2 (en) 2007-12-20 2011-07-26 Exxonmobil Research And Engineering Company Electrodesulfurization of heavy oils using a divided electrochemical cell
US20120055808A1 (en) 2009-05-14 2012-03-08 Basf Se Process for the electrolytic dissociation of hydrogen sulfide
UA99863C2 (uk) 2010-12-14 2012-10-10 Институт Биоорганической Химии И Нефтехимии Нан Украины Спосіб сумісної утилізації сірководню і оксидів вуглецю та пристрій для його реалізації
FR2981368B1 (fr) * 2011-10-12 2013-11-15 Areva Procede de generation d'hydrogene et d'oxygene par electrolyse de vapeur d'eau
JP5939501B2 (ja) * 2011-10-14 2016-06-22 住友電気工業株式会社 ガス分解装置、ガス分解方法及びガス分解発電装置
JP6067344B2 (ja) * 2012-11-20 2017-01-25 株式会社東芝 光化学反応システム

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3249522A (en) * 1965-02-23 1966-05-03 Socony Mobil Oil Co Inc Electrochemical oxidation of hydrogen sulfide
CN1906122A (zh) * 2003-12-26 2007-01-31 株式会社杰士汤浅 氢制造方法和用于该方法的氢制造装置
UA61556U (uk) * 2010-12-14 2011-07-25 Институт Биоорганической Химии И Нефтехимии Нан Украины Пристрій для сумісної утилізації сірководню і оксидів вуглецю
UA62880U (uk) * 2010-12-14 2011-09-26 Институт Биоорганической Химии И Нефтехимии Нан Украины Спосіб сумісної утилізації сірководню і оксидів вуглецю
CN104024478A (zh) * 2011-07-06 2014-09-03 液体光有限公司 二氧化碳捕集和转化成有机产物
CN103160849A (zh) * 2011-12-12 2013-06-19 清华大学 二氧化碳电化学还原转化利用的方法

Also Published As

Publication number Publication date
US9951430B2 (en) 2018-04-24
SG11201708519QA (en) 2017-11-29
EP3283669A1 (en) 2018-02-21
JP6728226B2 (ja) 2020-07-22
SA517390159B1 (ar) 2022-05-08
KR20180019526A (ko) 2018-02-26
US20160305029A1 (en) 2016-10-20
WO2016167835A1 (en) 2016-10-20
JP2018519414A (ja) 2018-07-19
CN108093633A (zh) 2018-05-29
EP3283669B1 (en) 2022-02-23

Similar Documents

Publication Publication Date Title
CN108093633B (zh) 共处理二氧化碳和硫化氢的方法
JP2018519414A5 (https=)
US11795552B2 (en) Production of hydrogen or carbon monoxide from waste gases
CN112853389B (zh) 一种基于高温高压电解技术的电化学合成装置
US20070163889A1 (en) Method and apparatus for producing hydrogen
CN102056866A (zh) 通过还原二氧化碳(CO2)和/或一氧化碳(CO)制备CxHyO2型化合物的方法
US20220136117A1 (en) Method and system for recovering hydrogen and converting a carbon compound to a valualbe organic product
KR20240031247A (ko) 통합 수소 생산 방법 및 시스템
US20220205113A1 (en) Electrocatalytic hydrogen recovery from hydrogen sulfide and application of the circular hydrogen economy for hydrotreatment
US11795551B2 (en) Production of hydrogen with recycle
Ipsakis et al. An electrocatalytic membrane-assisted process for hydrogen production from H2S in Black Sea: Preliminary results
KR20240024070A (ko) 전기화학적 개질을 통한 수소 생산
Wolf et al. Internal biogas reforming in solid oxide and proton conducting fuel cells: progress, challenges and perspectives
US12018392B2 (en) Methods for producing syngas from H2S and CO2 in an electrochemical cell
Kraia et al. Electrochemical performance of Co3O4/CeO2 electrodes in H2S/H2O atmospheres in a proton-conducting ceramic symmetrical cell with BaZr0. 7Ce0. 2Y0. 1O3 solid electrolyte
CN101103140A (zh) 制备氢方法和装置
Cheng et al. 2 Anodes
Chuang et al. Evolution of fuel cells powered by H2S-containing gases
WO2018236685A1 (en) SELF-CONTAINING SOLID OXIDE FUEL CELL SYSTEM AND METHOD FOR SUPPLYING A GAS WELL
Ragu Recovery and Use of Ammonia From Coke-Making Processes
Zha et al. Gd2Ti2-XMoXO7-based anode materials for H2S-air solid oxide fuel cells
Yu et al. Engineering nanostructured fuel electrodes for high-performance, durable SOCs through infiltration
EP4692424A1 (en) Steam electrolysis device and steam electrolysis method
JP2025527326A (ja) 酸化剤注入によるアンモニアを利用した電気化学的水素生成
EP3978650A1 (en) Electrochemical cell

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant