CN108084728A - 抗静电防刺穿包装袋 - Google Patents

抗静电防刺穿包装袋 Download PDF

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CN108084728A
CN108084728A CN201711380421.1A CN201711380421A CN108084728A CN 108084728 A CN108084728 A CN 108084728A CN 201711380421 A CN201711380421 A CN 201711380421A CN 108084728 A CN108084728 A CN 108084728A
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parts
packaging bag
antistatic anti
puncture
internal layer
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缪磊
孙建军
邱丰
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Suzhou Star Fire Plentiful Environmental Packaging Co Ltd
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Abstract

本发明公开了一种抗静电防刺穿包装袋，属于高分子材料领域。针对现有包装袋抗静电性能不强、稳定性不好、容易被划破或刺穿的问题，本发明公开了一种稳定性好，抗静电性能强，防刺穿的包装袋材料，包括袋体和内层，袋体和内层通过胶黏剂粘接，内层由以下重量份数的原料组成，天然橡胶30～60份，热塑性弹性体20～40份，丁苯橡胶10～20份，碳酸钙5～15份，氧化锌5～8份，白炭黑1～5份，乳化剂1～6份，非极性溶剂1～6份，季铵盐1～3份，金属盐1～3份，分散剂0.1～1份，稳定剂0.5～2份，本发明的包装袋内层材料的抗静电性强，高效持久，对人体安全，对环境无污染。

Description

抗静电防刺穿包装袋
技术领域
本发明属于高分子材料领域，更具体地说，涉及一种抗静电防刺穿包装袋。
背景技术
防静电包装袋是采用防静电物质制作的包装袋，也叫防静电屏蔽袋。具有自身“不起”静电和能屏蔽外界静电的特性，常用于包装对静电敏感且易被静电损坏的敏感器件，例如电子电路PCB板成品或半成品包装。
目前，抗静电高分子材料对周围环境超敏感，容易受到外部环境影响而造成失去抗静电的作用，另外，由于抗静电包装袋一般用于电子产品的包装，电子产品的电器元件容易划伤或刺穿包装袋，使其防静电作用失效。
发明内容
针对上述问题，本发明提供一种稳定性好，抗静电性能强，防刺穿的包装袋材料。
为了解决上述问题，本发明所采用的技术方案如下：
一种抗静电防刺穿包装袋，包括袋体和内层，所述袋体通过胶黏剂与所述内层粘接，所述内层由以下重量份数的原料组成：天然橡胶30～60份，热塑性弹性体20～40份，丁苯橡胶10～20份，碳酸钙5～15份，氧化锌5～8份，白炭黑1～5份，乳化剂1～6份，非极性溶剂1～6份，季铵盐1～3份，金属盐1～3份，分散剂0.1～1份，稳定剂0.5～2份。
更进一步地，所述分散剂为三聚磷酸钠或十二烷基硫酸钠。
更进一步地，所述稳定剂为硬脂酸锌、硬脂酸钙、硬脂酸镁中的至少一种。
更进一步地，所述乳化剂为十二烷基磺酸钠、海藻酸丙二醇酯、聚乙烯醇中的一种。
更进一步地，所述非极性溶剂为醋酸乙酯、液体石蜡或肉豆蔻酸异丙酯中的一种。
更进一步地，所述季铵盐选自十二烷基三甲基氯化铵、十二烷基二甲基苄基氯化铵、聚氮杂环季铵盐、聚季铵盐中的一种或一种以上。
更进一步地，所述金属盐为氯化铁或四氯化锡。
更进一步地，所述包装袋由以下重量份数的原料组成：低压聚乙烯60～75份，碳酸钙粉10～15份，聚乙烯醇5～10份，聚乙二醇5～10份，硅烷偶联剂2～5份，硬脂酸钙1～3份，聚氧乙烯硬脂酸酯1～3份，增塑剂1～2份。
更进一步地，所述胶黏剂由以下重量份数的原料组成：聚酯乳液10份，甲苯1～5份，白金触媒乳液0.05～0.1份，酒精0.5～1份。
相比于现有技术，本发明的有益效果为：
(1)本发明的包装袋内层材料的抗静电性强，不受周围环境的影响而改变其抗静电性能，持久性强，同时保持较好的拉伸强度，具有较佳的耐热性；由于该材料具有较好的拉伸强度，所以该材料用作包装袋内层材料时，可以防止袋内的尖锐物品刺穿或划伤袋体，有效增加了整个袋体的使用寿命，保证了袋内物品的安全；
(2)本发明所采用的抗静电剂高效持久，与弹性体、橡胶以及其他添加剂均有良好的相容性，不影响各自的物理化学性能；
(3)本发明的包装袋所采用的材料组份不含有重金属等有害的VOC物质，对人体安全，对环境无污染。
具体实施方式
下面结合具体实施例对本发明进一步进行描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
本实施例1的一种抗静电防刺穿包装袋，内层由以下重量份数的原料组成：天然橡胶30份，热塑性弹性体40份，丁苯橡胶15份，碳酸钙10份，氧化锌5份，白炭黑5份，十二烷基磺酸钠6份，醋酸乙酯2份，十二烷基三甲基氯化铵3份，氯化铁1份，三聚磷酸钠0.6份，硬脂酸锌0.5份；
袋体由以下重量份数的原料组成：低压聚乙烯60份，碳酸钙粉15份，聚乙烯醇8份，聚乙二醇5份，硅烷偶联剂2份，硬脂酸钙3份，聚氧乙烯硬脂酸酯1份，增塑剂1份；
袋体和内层之间的胶黏剂由以下重量份数的原料组成：聚酯乳液10份，甲苯2份，白金触媒乳液0.05份，酒精0.5份。
实施例2
本实施例1的一种抗静电防刺穿包装袋，内层由以下重量份数的原料组成：天然橡胶60份，热塑性弹性体20份，丁苯橡胶20份，碳酸钙5份，氧化锌8份，白炭黑3份，海藻酸丙二醇酯1份，液体石蜡1份，十二烷基二甲基苄基氯化铵1份，氯化铁3份，三聚磷酸钠0.1份，硬脂酸钙2份；
袋体由以下重量份数的原料组成：低压聚乙烯75份，碳酸钙粉10份，聚乙烯醇5份，聚乙二醇10份，硅烷偶联剂3份，硬脂酸钙2份，聚氧乙烯硬脂酸酯2份，增塑剂2份；
袋体和内层之间的胶黏剂由以下重量份数的原料组成：聚酯乳液10份，甲苯3份，白金触媒乳液0.1份，酒精1份。
实施例3
本实施例1的一种抗静电防刺穿包装袋，内层由以下重量份数的原料组成：天然橡胶40份，热塑性弹性体35份，丁苯橡胶10份，碳酸钙12份，氧化锌5份，白炭黑1份，聚乙烯醇2份，肉豆蔻酸异丙酯6份，聚氮杂环季铵盐2份，四氯化锡1份，十二烷基硫酸钠1份，硬脂酸锌镁1份；
袋体由以下重量份数的原料组成：低压聚乙烯70份，碳酸钙粉15份，聚乙烯醇10份，聚乙二醇10份，硅烷偶联剂4份，硬脂酸钙1份，聚氧乙烯硬脂酸酯3份，增塑剂1.5份；
袋体和内层之间的胶黏剂由以下重量份数的原料组成：聚酯乳液10份，甲苯1份，白金触媒乳液0.06份，酒精0.9份。
实施例4
本实施例1的一种抗静电防刺穿包装袋，内层由以下重量份数的原料组成：天然橡胶50份，热塑性弹性体25份，丁苯橡胶18份，碳酸钙15份，氧化锌6份，白炭黑2份，十二烷基磺酸钠4份，肉豆蔻酸异丙酯1份，聚季铵盐1份，四氯化锡2份，十二烷基硫酸钠0.5份，硬脂酸锌2份；
袋体由以下重量份数的原料组成：低压聚乙烯65份，碳酸钙粉11份，聚乙烯醇7份，聚乙二醇9份，硅烷偶联剂5份，硬脂酸钙3份，聚氧乙烯硬脂酸酯1份，增塑剂1份；
袋体和内层之间的胶黏剂由以下重量份数的原料组成：聚酯乳液10份，甲苯5份，白金触媒乳液0.08份，酒精0.8份。
本发明所述的聚酯乳液、白金触媒乳液、甲苯、酒精等都为化工领域的常见原料，皆可在市场上购得，其他未明确指明牌号的物质均选用本领域常用牌号。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变形，这些改进和变形也应视为本发明的保护范围。

Claims (9)

1.一种抗静电防刺穿包装袋，包括袋体和内层，所述袋体通过胶黏剂与所述内层粘接，其特征在于，所述内层由以下重量份数的原料组成：天然橡胶30～60份，热塑性弹性体20～40份，丁苯橡胶10～20份，碳酸钙5～15份，氧化锌5～8份，白炭黑1～5份，乳化剂1～6份，非极性溶剂1～6份，季铵盐1～3份，金属盐1～3份，分散剂0.1～1份，稳定剂0.5～2份。
2.根据权利要求1所述的抗静电防刺穿包装袋，其特征在于，所述分散剂为三聚磷酸钠或十二烷基硫酸钠。
3.根据权利要求1所述的抗静电防刺穿包装袋，其特征在于，所述稳定剂为硬脂酸锌、硬脂酸钙、硬脂酸镁中的至少一种。
4.根据权利要求1、2或3任一项所述的抗静电防刺穿包装袋，其特征在于，所述乳化剂为十二烷基磺酸钠、海藻酸丙二醇酯、聚乙烯醇中的一种。
5.根据权利要求4所述的抗静电防刺穿包装袋，其特征在于，所述非极性溶剂为醋酸乙酯、液体石蜡或肉豆蔻酸异丙酯中的一种。
6.根据权利要求4所述的抗静电防刺穿包装袋，其特征在于，所述季铵盐选自十二烷基三甲基氯化铵、十二烷基二甲基苄基氯化铵、聚氮杂环季铵盐、聚季铵盐、双季铵盐中的一种或一种以上。
7.根据权利要求4所述的抗静电防刺穿包装袋，其特征在于，所述金属盐为氯化铁或四氯化锡。
8.根据权利要求1、2、3、5、6或7任一项所述的抗静电防刺穿包装袋，其特征在于，所述包装袋由以下重量份数的原料组成：低压聚乙烯60～75份，碳酸钙粉10～15份，聚乙烯醇5～10份，聚乙二醇5～10份，硅烷偶联剂2～5份，硬脂酸钙1～3份，聚氧乙烯硬脂酸酯1～3份，增塑剂1～2份。
9.根据权利要求1、2、3、5、6或7任一项所述的抗静电防刺穿包装袋，其特征在于，所述胶黏剂由以下重量份数的原料组成：聚酯乳液10份，甲苯1～5份，白金触媒乳液0.05～0.1份，酒精0.5～1份。
CN201711380421.1A 2017-12-20 2017-12-20 抗静电防刺穿包装袋 Pending CN108084728A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486890A (zh) * 2008-04-30 2009-07-22 上海工程技术大学 一种抗静电剂及其抗静电聚氨酯弹性体材料
CN101987949A (zh) * 2009-07-31 2011-03-23 常熟市长江胶带有限公司 一种抗静电胶黏剂
CN104356436A (zh) * 2014-10-29 2015-02-18 昆山古加拉高分子科技有限公司 一种抗静电高分子材料
CN106146968A (zh) * 2016-06-28 2016-11-23 安徽徽隆包装有限公司 一种抗静电塑料包装袋

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486890A (zh) * 2008-04-30 2009-07-22 上海工程技术大学 一种抗静电剂及其抗静电聚氨酯弹性体材料
CN101987949A (zh) * 2009-07-31 2011-03-23 常熟市长江胶带有限公司 一种抗静电胶黏剂
CN104356436A (zh) * 2014-10-29 2015-02-18 昆山古加拉高分子科技有限公司 一种抗静电高分子材料
CN106146968A (zh) * 2016-06-28 2016-11-23 安徽徽隆包装有限公司 一种抗静电塑料包装袋

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