CN108051566A - A kind of gushing water experimental rig and its test method - Google Patents

A kind of gushing water experimental rig and its test method Download PDF

Info

Publication number
CN108051566A
CN108051566A CN201711496793.0A CN201711496793A CN108051566A CN 108051566 A CN108051566 A CN 108051566A CN 201711496793 A CN201711496793 A CN 201711496793A CN 108051566 A CN108051566 A CN 108051566A
Authority
CN
China
Prior art keywords
water tank
water
partition plate
model casing
gushing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711496793.0A
Other languages
Chinese (zh)
Inventor
李博
韦韬
王先庆
陈丽霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou University
Original Assignee
Guizhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guizhou University filed Critical Guizhou University
Priority to CN201711496793.0A priority Critical patent/CN108051566A/en
Publication of CN108051566A publication Critical patent/CN108051566A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/24Earth materials

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Analytical Chemistry (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Remote Sensing (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Strength Of Materials By Application Of Mechanical Stress (AREA)

Abstract

The invention discloses a kind of gushing water experimental rig and its test methods, it includes water tank and model casing, water tank is arranged at the bottom of the model casing, the outer wall of model casing is equipped with several monitoring elements, there are variable conduit partition plate and partition plate at the top of the water tank, variable conduit partition plate and partition plate the upper surface of are equipped with porous disc, force (forcing) pump and constant pressure valve are connected with by filling pipe between the water tank and water tank, the outlet conduit of the force (forcing) pump is equipped with pressure gauge, the bottom inside of water tank is equipped with heating unit, there are several inlet openings on the side wall of the water tank, have between the side wall of water tank and variable conduit partition plate into Ban Kou, it is described into having drain valve on the bottom of plate mouth.The gushing water phenomenon under different test temperature and hydraulic pressure and different gushing water flow velocitys can be reached, the present apparatus can carry out different test materials gushing water experiment, simple in structure, multiple functional.

Description

A kind of gushing water experimental rig and its test method
Technical field
The present invention relates to a kind of gushing water experimental rig, more particularly to a kind of gushing water experimental rig and its test method belong to Hydrogeology studying technological domain.
Background technology
Complicated geological conditions situation is that we solve the problems, such as the difficult point of subsurface geology, for underground water occurrence condition and Speech, there are the storage space and passage of different shape, including gap, crack, solution cavity.Gushing water in coal-mine is in mining engineering More insoluble problem has the particularity and complexity at various scenes, to study its operation principle and solution, Need to simulate the condition and the origin cause of formation at various scenes, in the prior art, generally by carrying out gushing water analog simulation examination in laboratory It tests, but simulated experiment is substantially using Plane stress model.But simulated experiment is all single hole water filling, does not account for single note Water influences the pressure inhomogeneities in loading procedure, does not also account for influence of the water inrush channel form to gushing water, is opened in mine During adopting, subterranean depth can reach 300 ~ 700m, and subsurface temperature increases with the increase of buried depth, previous experimental condition Middle adjustable parameter is less, it is impossible to the temperature and temperature of Adjustment Tests and the synergy of pressure, it is impossible to which precise and high efficiency simulation is each The underground gushing water situation of a depth.
The content of the invention
The technical problem to be solved by the present invention is to:A kind of temperature for indoor gushing water simulation test is provided and becomes hydraulic pressure note Water and the experimental rig that can become water passage with porous water filling, can reach different test temperature and hydraulic pressure and difference Gushing water flow velocity under gushing water phenomenon, intake simultaneously by multiple inlet openings, can uniformly to test material load;By changing The shape of the water passage become at the top of water tank is tested, and the present apparatus can carry out different situations simulation gushing water experiment, It is simple in structure, it is multiple functional, it solves the problems, such as above-mentioned.
The technical scheme is that:A kind of gushing water experimental rig, it includes water tank and model casing, the bottom of the model casing There is water tank in portion, and the outer wall of model casing is equipped with several monitoring elements, has variable conduit partition plate and partition plate at the top of the water tank, Variable conduit partition plate and partition plate the upper surface of are equipped with porous disc, and force (forcing) pump is connected with by filling pipe between the water tank and water tank And constant pressure valve, the outlet conduit of the force (forcing) pump are equipped with pressure gauge, the bottom inside of water tank is equipped with heating unit, the water storage There are several inlet openings on the side wall of case, have between the side wall of water tank and variable conduit partition plate into Ban Kou, the bottom into plate mouth On have drain valve.
The side wall of the water tank is equipped with temperature controller, and the temperature controller is connected with heating unit, the side of water tank Wall is equipped with liquid level gauge, and the size of water tank is 1m × 1m × 1m, and material is intensity height, high temperature resistant, long lifespan, good corrosion resistance Mild steel.
The size of the filling pipe is:Internal diameter 20mm, outer diameter 30mm, material are that inner ring is mild steel, and outer shroud is plastic-aluminum Pipe.
It is fixedly connected with reinforcing rib on the outer wall of the model casing, the reinforcing rib is channel steel or angle steel, the ruler of model casing Very little is 1m × 2m × 2m, and material is intensity height, high temperature resistant, long lifespan, the mild steel of good corrosion resistance.
The porous disc is equipped with several equally distributed through holes, and the material of porous disc is intensity height, high temperature resistant, service life The long, mild steel of good corrosion resistance, size are 1m × 2m × 0.01m.
Have the through hole of several forms on the variable conduit partition plate, variable conduit partition plate among water tank side wall into plate mouth into Enter water tank crown center, agree with water-stop sheet closed, the size of variable conduit partition plate is 0.7m × 1m × 0.01m, variable conduit every The material of plate is mild steel.
The water-stop sheet is waterproof plate, and water-stop sheet is divided into two pieces of both sides being fixed at the top of water tank, with variable conduit every Plate agrees with closed, and size is 0.65m × 1m × 0.01m, and the material of water-stop sheet is mild steel.
The force (forcing) pump is piston pump or screw pump.
The heating unit is electrical heating.
A kind of test method of gushing water experimental rig, including following eight step:
First, assembly model test system:Test material is inserted to the inside of model casing according to test requirements document, according to test requirements document cloth If monitoring element;
2nd, start heating unit, required water temperature is tested by temperature controller setting;
3rd, the bottom of storage tank drain valve is closed, open constant pressure valve and sets pressure needed for experiment;
4th, according to experiment needs, by deformation channel partition by being inserted into water tank top into plate mouth;
5th, force (forcing) pump is opened, the waterfront economy waterpipe of water tank is pressurizeed by constant pressure valve, inlet opening to water tank water filling;
6th, force (forcing) pump is automatically stopped pressurization after water filling reaches rated pressure, and observing and nursing tank test material locally adds in bottom Under conditions of pressure, osmotic pressure, displacement, deformation etc. mechanics parameters variation;
7th, draining after the test:When after the test, opening drain valve can discharge the water in water tank;
8th, repeat to test:Again through temperature controller set water temperature, by level pressure pressure regulating valve and replace variable conduit every Plate is combined repetition experiment again.
The beneficial effects of the invention are as follows:Compared with existing device, the present invention is in original single water pressure factor controlling Experimental rig under, an electric calorifie installation has been added inside water filling water tank, in water tank external linkage there are one temperature controller, has been led to Setting rated temperature is crossed, the temperature that water temperature is kept to be needed always for experiment.In another external pressure control, pressure gauge and pressure are improved to The constant pressure valve of power valve one can effectively prevent the pressurization of water from flowing back, and can be precisely controlled the precision of loading, installation operation is more just It is prompt simple.Pass through above-mentioned structure to improve, it now is possible to different water temperature hydraulic pressure are simulated in gushing water experimental test, because ground water temperature Degree is positively correlated with buried depth, it now is possible to be tested by different temperatures pressure to simulate the gushing water of different depth;Temperature affects The interior energy of water can reflect that different water temperatures are to the extent of the destruction of test material under different temperatures by testing.Improving simulation examination The accuracy tested has a better effect.It is capable of the Water hydraulic static pressure loading that relents of precise and high efficiency completion model test.With it is existing Technology is compared, and the present invention is by above technical scheme, on the basis of original single hole water filling, by increasing on the outside of water tank Several water injection holes to water tank water filling simultaneously, improve waterflood injection rate, while the also uniformity of Optimized loading, can test Material deformation stage keeps stable water pressure.Compared with original baffle, by above technical scheme, can make experiment needs the present invention The water passage for the various forms wanted, can simulate the geological conditions situation of the complexity such as gap, crack, solution cavity, tomography can also lead to It crosses and changes the area that size changes passage, have a better effect in the accuracy for improving simulation test.
Description of the drawings
Fig. 1 is the structural diagram of the present invention.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below with reference to this specification attached drawing to this hair It is bright to be described in further detail.
Embodiment 1:As shown in Figure 1, a kind of gushing water experimental rig, it includes water tank 15 and model casing 1, the model casing Water tank 17 is arranged at 1 bottom, and the outer wall of model casing 1 is equipped with several monitoring elements 2, and variable conduit is arranged at the top of the water tank 17 Partition plate 5 and partition plate 6, variable conduit partition plate 5 and partition plate 6 the upper surface of are equipped with porous disc 4, pass through between the water tank 15 and water tank 17 Filling pipe 16 is connected with force (forcing) pump 11 and constant pressure valve 10, and the outlet conduit of the force (forcing) pump 11 is equipped with pressure gauge 10, water tank 15 bottom inside is equipped with heating unit 14, there is several inlet openings 9 on the side wall of the water tank 17, the side wall of water tank 17 with Have between variable conduit partition plate 5 into plate mouth 7, it is described into having drain valve 8 on the bottom of plate mouth 7.
The side wall of the water tank 15 is equipped with temperature controller 13, and the temperature controller 13 is connected with heating unit 14, The side wall of water tank 15 is equipped with liquid level gauge 12, and the size of water tank 15 is 1m × 1m × 1m, and material is intensity height, high temperature resistant, service life The long, mild steel of good corrosion resistance.
The size of the filling pipe 16 is:Internal diameter 20mm, outer diameter 30mm, material are that inner ring is mild steel, and outer shroud is aluminium Modeling pipe.
It is fixedly connected with reinforcing rib 3 on the outer wall of the model casing 1, the reinforcing rib 3 is channel steel or angle steel, model casing 1 Size for 1m × 2m × 2m, material is intensity height, high temperature resistant, long lifespan, the mild steel of good corrosion resistance.
The porous disc 4 is equipped with several equally distributed through holes, and the material of porous disc 4 is intensity height, high temperature resistant, service life The long, mild steel of good corrosion resistance, size are 1m × 2m × 0.01m.
Have the through hole of several forms on the variable conduit partition plate 5, variable conduit partition plate 5 among 17 side wall of water tank into plate Mouthfuls 7 enter 17 crown centers of water tank, agree with water-stop sheet 6 closed, and the size of variable conduit partition plate 5 is 0.7m × 1m × 0.01m, The material of variable conduit partition plate 5 is mild steel.
The water-stop sheet 6 is waterproof plate, and water-stop sheet 6 is divided to the both sides for being fixed on 17 top of water tank for two pieces, with accommodation Road partition plate 5 agrees with closed, and size is 0.65m × 1m × 0.01m, and the material of water-stop sheet 6 is mild steel.
The force (forcing) pump 11 is piston pump or screw pump.
The heating unit 14 is electrical heating.
A kind of test method of gushing water experimental rig, including following eight step:
First, assembly model test system:Test material is inserted to the inside of model casing 1 according to test requirements document, according to test requirements document Lay monitoring element 2;
2nd, start heating unit 14, required water temperature is tested by the setting of temperature controller 13;
3rd, 17 bottom discharge valve 8 of water tank is closed, open constant pressure valve 10 and sets pressure needed for experiment;
4th, according to experiment needs, by deformation channel partition 5 by being inserted into water tank top into plate mouth 7;
5th, force (forcing) pump 11 is opened, the waterfront economy waterpipe 16 of water tank 15 is by constant pressure valve 10, inlet opening 9 to 17 water filling of water tank Pressurization;
6th, force (forcing) pump 11 is automatically stopped pressurization after water filling reaches rated pressure, and test material is local in bottom in observing and nursing case 1 Under conditions of pressurization, osmotic pressure, displacement, deformation etc. mechanics parameters variation;
7th, draining after the test:When after the test, opening drain valve 8 can discharge the water in water tank 17;
8th, repeat to test:Water temperature is set again through temperature controller 13, pressure is adjusted by constant pressure valve 10 and is replaced flexible Road partition plate 5 is combined repetition experiment again.
Part is not described in detail by the present invention, is the known technology of those skilled in the art of the present technique.Finally illustrate, more than it is real Example is applied to be merely illustrative of the technical solution of the present invention and unrestricted, although having been carried out specifically to the present invention with reference to preferred embodiment It is bright, it will be understood by those of ordinary skill in the art that, technical scheme can be modified or replaced equivalently, and The objective and scope of technical solution of the present invention are not departed from, should be covered by the scope of the claims of the present invention.

Claims (10)

1. a kind of gushing water experimental rig, it includes water tank(15)And model casing(1), it is characterised in that:The model casing(1)Bottom There is water tank in portion(17), model casing(1)Outer wall be equipped with several monitoring elements(2), the water tank(17)Top have change Channel partition(5)And partition plate(6), variable conduit partition plate(5)And partition plate(6)The upper surface of be equipped with porous disc(4), the water tank(15)With Water tank(17)Between pass through filling pipe(16)It is connected with force (forcing) pump(11)And constant pressure valve(10), the force (forcing) pump(11)Go out Mouth pipeline is equipped with pressure gauge(10), water tank(15)Bottom inside be equipped with heating unit(14), the water tank(17)Side There are several inlet openings on wall(9), water tank(17)Side wall and variable conduit partition plate(5)Between have into Ban Kou(7), it is described into Ban Kou (7)Bottom on have drain valve(8).
2. a kind of gushing water experimental rig according to claim 1, it is characterised in that:The water tank(15)Side wall be equipped with Temperature controller(13), the temperature controller(13)With heating unit(14)Connection, water tank(15)Side wall be equipped with liquid level Meter(12), water tank(15)Size for 1m × 1m × 1m, material is mild steel.
3. a kind of model casing for gushing water experimental rig according to claim 1, it is characterised in that:The filling pipe (16)Size be:Internal diameter 20mm, outer diameter 30mm, material are that inner ring is mild steel, and outer shroud is aluminium-plastic pipe.
4. a kind of model casing for gushing water experimental rig according to claim 1, it is characterised in that:The model casing (1)Outer wall on be fixedly connected with reinforcing rib(3), the reinforcing rib(3)For channel steel or angle steel, model casing(1)Size be 1m × 2m × 2m, material are mild steel.
5. a kind of model casing for gushing water experimental rig according to claim 1, it is characterised in that:The porous disc (4)It is equipped with several equally distributed through holes, porous disc(4)Material for mild steel, size is 1m × 2m × 0.01m.
6. a kind of model casing for gushing water simulation test in porous intake chamber according to claim 1, it is characterised in that: The variable conduit partition plate(5)On have the through holes of several forms, variable conduit partition plate(5)From water tank(17)Among side wall into Ban Kou (7) water tank is entered(17)Crown center, with water-stop sheet(6)Agree with closed, variable conduit partition plate(5)Size for 0.7m × 1m × 0.01m, variable conduit partition plate(5)Material be mild steel.
7. a kind of model casing for gushing water simulation test in porous intake chamber according to claim 1, it is characterised in that: The water-stop sheet(6)For waterproof plate, water-stop sheet(6)It is divided into two pieces and is fixed on water tank(17)The both sides at top, with variable conduit Partition plate(5)Agree with it is closed, size be 0.65m × 1m × 0.01m, water-stop sheet(6)Material be mild steel.
8. a kind of gushing water experimental rig according to claim 1, it is characterised in that:The force (forcing) pump(11)For piston pump or Screw pump.
9. a kind of gushing water experimental rig according to claim 1, it is characterised in that:The heating unit(14)Add for electricity Heat.
10. a kind of test method of gushing water experimental rig according to claim 1, it is characterised in that:Test method includes Eight step below:
Assembly model test system:Test material is inserted by model casing according to test requirements document(1)Inside, according to test requirements document cloth If monitoring element(2);
Start heating unit(14), pass through temperature controller(13)Required water temperature is tested in setting;
Close water tank(17)Bottom discharge valve(8), open constant pressure valve(10)And set pressure needed for experiment;
According to experiment needs, channel partition will be deformed(5)By into Ban Kou(7)It is inserted into water tank top;
Open force (forcing) pump(11), water tank(15)Waterfront economy waterpipe(16)Pass through constant pressure valve(10), inlet opening(9)To water tank (17) water filling is pressurizeed;
Water filling reaches force (forcing) pump after rated pressure(11)It is automatically stopped pressurization, observing and nursing case(1)Interior test material is in bottom office Portion pressurization under conditions of, osmotic pressure, displacement, deformation etc. mechanics parameters variation;
Draining after the test:When after the test, drain valve is opened(8), can be by water tank(17)Interior water discharge;
It repeats to test:Again through temperature controller(13)Water temperature is set, passes through constant pressure valve(10)Adjust pressure and more transformation Channel partition(5)Repetition experiment is combined again.
CN201711496793.0A 2017-12-31 2017-12-31 A kind of gushing water experimental rig and its test method Pending CN108051566A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711496793.0A CN108051566A (en) 2017-12-31 2017-12-31 A kind of gushing water experimental rig and its test method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711496793.0A CN108051566A (en) 2017-12-31 2017-12-31 A kind of gushing water experimental rig and its test method

Publications (1)

Publication Number Publication Date
CN108051566A true CN108051566A (en) 2018-05-18

Family

ID=62129790

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711496793.0A Pending CN108051566A (en) 2017-12-31 2017-12-31 A kind of gushing water experimental rig and its test method

Country Status (1)

Country Link
CN (1) CN108051566A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109030782A (en) * 2018-08-20 2018-12-18 临沂大学 A kind of water sand is prominent to gush pilot system and monitoring method
CN109470839A (en) * 2018-11-22 2019-03-15 山东科技大学 Simulate the physical test device and method of deep-seated fault formation, fault activation and inrush through faults
CN111238990A (en) * 2020-02-05 2020-06-05 山东大学 Fault activation water inrush evolution test system and test method under multi-field coupling effect
CN115541844B (en) * 2022-09-15 2023-06-16 西南交通大学 Tunnel water burst test device and method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101576458A (en) * 2009-06-08 2009-11-11 中国矿业大学(北京) Geomechanics test platform for water invasion regularity of mine
CN103674597A (en) * 2013-12-18 2014-03-26 中国矿业大学(北京) Bi-directional variable cross-section water pressure bearing circulation testing system used for coal mine water burst model test
CN106197944A (en) * 2016-07-13 2016-12-07 中国矿业大学 The testing system apparatus of simulation complex condition deep tunnel inrush through faults and method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101576458A (en) * 2009-06-08 2009-11-11 中国矿业大学(北京) Geomechanics test platform for water invasion regularity of mine
CN103674597A (en) * 2013-12-18 2014-03-26 中国矿业大学(北京) Bi-directional variable cross-section water pressure bearing circulation testing system used for coal mine water burst model test
CN106197944A (en) * 2016-07-13 2016-12-07 中国矿业大学 The testing system apparatus of simulation complex condition deep tunnel inrush through faults and method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109030782A (en) * 2018-08-20 2018-12-18 临沂大学 A kind of water sand is prominent to gush pilot system and monitoring method
CN109030782B (en) * 2018-08-20 2020-12-22 临沂大学 Water sand inrush test system and monitoring method
CN109470839A (en) * 2018-11-22 2019-03-15 山东科技大学 Simulate the physical test device and method of deep-seated fault formation, fault activation and inrush through faults
CN109470839B (en) * 2018-11-22 2023-07-21 山东科技大学 Physical test device and method for simulating deep fault formation, fault activation and fault water burst
CN111238990A (en) * 2020-02-05 2020-06-05 山东大学 Fault activation water inrush evolution test system and test method under multi-field coupling effect
CN115541844B (en) * 2022-09-15 2023-06-16 西南交通大学 Tunnel water burst test device and method

Similar Documents

Publication Publication Date Title
CN108051566A (en) A kind of gushing water experimental rig and its test method
CN111443182B (en) Supergravity hydrate research experiment system and method
CN105735965B (en) Coal bed gas well pit shaft internal drainage gas production visual Simulation experimental provision and analogy method
CN103195417B (en) A kind of experimental technique of Simulated Water horizontal well current limliting staged fracturing
CN105865874B (en) A kind of sample preparation device suitable for sandy soil laboratory test
CN110542649B (en) Multifunctional liquid single-phase flow flowing corrosion testing loop
CN105675328A (en) Test method for simulating mechanical properties of riser in deepwater drilling condition
CN103207136B (en) Waterpower-electric power apparatus for measuring permeability coefficient and measuring method
CN104534284B (en) Urban underground pipeline fault simulation system
CN101560880A (en) Supercritical well bore multi-phase flow test device
CN106706416A (en) Test device capable of simulating basement bottom plate stress under effect of pressure water and use method thereof
CN111679061B (en) Frozen soil stratum melting and sedimentation test simulation device and method
CN106442209A (en) Fractured rock mass water inrush and sand inrush simulation experiment device capable of continuously supplying water and sand
CN111691881B (en) Device and method for simulating thermal settlement of hydrate-containing stratum
CN106812523A (en) A kind of multiple seam coal bed gas well mining physical simulating device and its experimental technique
CN104454491A (en) Experimental method and experimental platform for adjustable high-lift water hydraulic ram pump
CN206256908U (en) A kind of pit shaft and formation fracture Coupled Flow analogue experiment installation
CN209780859U (en) Low-permeability conglomerate oil reservoir fracturing horizontal well productivity simulation model
CN101936158A (en) Test method for wellbore multiphase flow under supercritical condition
CN110514533B (en) Triaxial device suitable for testing mechanical properties of soil body under water circulation permeation effect and application method
CN109442226A (en) Simulate the device of liquid hydrocarbon pipe leakage and the method using device measuring and calculating leakage rate
CN206161484U (en) Impermeability test appearance
CN108051360A (en) A kind of model casing for gushing water simulation test in porous intake chamber
CN208444219U (en) A kind of temperature change hydraulic pressure water filling device for indoor gushing water simulation test
CN202064944U (en) Pressure crack filling anti-sand model

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180518

RJ01 Rejection of invention patent application after publication