CN108043207A - A kind of composition for removing aldehydes and eliminating the unusual smell - Google Patents
A kind of composition for removing aldehydes and eliminating the unusual smell Download PDFInfo
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- CN108043207A CN108043207A CN201810043093.4A CN201810043093A CN108043207A CN 108043207 A CN108043207 A CN 108043207A CN 201810043093 A CN201810043093 A CN 201810043093A CN 108043207 A CN108043207 A CN 108043207A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
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- Environmental & Geological Engineering (AREA)
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- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
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Abstract
The invention discloses a kind of except aldehydes and the composition to eliminate the unusual smell, said composition includes each component of following weight percents：0.5% 2% hydramine, 0.5% 5% eliminating smell agent, 0.1% 5% surfactant, 0.01% 2% antiseptic and inhibiting bacteria function agent, surplus is water.Present invention discover that alcamine compound has except aldehyde, the performance except organic acid, have preferably except aldehyde effect compared to single compound after being particularly two kinds of alcohol amine compounds mixing.The composition of the present invention is not required illumination that can be chemically reacted with aldehydes, and nontoxic, and reaction product will not cause secondary pollution.One layer of effective film is formed in the surface of solids after present composition sprinkling, it is not easily to fall off, human body will not be inhaled into, is capable of the removal aldehydes and gas with foreign flavor of continuous and effective.
Description
Technical field
The present invention relates to eliminate the unusual smell technical field except aldehyde, and in particular to a kind of except aldehydes and the composition to eliminate the unusual smell.
Background technology
The outstanding problem of indoor and environment inside car pollution at present is aldehyde material and gas with foreign flavor.Aldehydes can harm to the human body
Greatly, incubation period is long, is referred to as in " indoor first pollution source ", and excessive aldehyde material is easy to cause newborn teratogenesis, the white blood of children
Disease, teenager's memory and intelligence decline.The gas with foreign flavor such as Ammonia, sulfide, organic acid are not only unpleasant but also there may be certain
Toxicity.The method except aldehyde taste removal is used for currently on the market, can be mainly divided into following a few classes：(1) it is ventilated, it is most simple and effective
Method, but be not suitable for closing environment.(2) porous material physical absorption, such as activated carbon, bamboo charcoal and diatomite etc. are inhaled
Attached efficiency is low, and invertibity is big.(3) photocatalyst (photochemical catalyst) decomposes, however is required for ultraviolet or radiation of visible light.Therefore,
It is most important for solving pollution of indoor environment to develop new aldehydes remover.
The content of the invention
It is an object of the present invention to provide a kind of except aldehydes and the composition to eliminate the unusual smell, said composition can be fast and effective
Removal the peculiar smell such as aldehydes and organic acid, Ammonia, sulfide gas.
Present invention technical solution used for the above purpose is as follows：
A kind of composition for removing aldehydes and eliminating the unusual smell, the composition include each component of following weight percents：
The antiseptic and inhibiting bacteria function agent of 0.5%-2% hydramine, the eliminating smell agent of 0.5%-5%, the surfactant of 0.1%-5%, 0.01%-2%,
Surplus is water.
Preferably, the hydramine is selected from 2- aminoisobutanols, amino-methyl-propanediol, 2- amino-1,3-propanediols, 3- ammonia
One or more in base -1,2- propylene glycol, tromethamine.
It is further preferred that the hydramine for 2- aminoisobutanols, amino-methyl-propanediol, 2- amino-1,3-propanediols,
The mixture that wherein arbitrary two kinds of 3- amido-1,2-propanediols, tromethamine.
Preferably, the eliminating smell agent is selected from zinc ricinate, the one or two of soybean ethyl sulfuric acid ethyl ester morpholine.
Preferably, the surfactant is selected from nonionic surfactant, amphoteric surfactant, cationic surface and lives
One or more in property agent, anion surfactant.
Preferably, the surfactant is selected from C8-14Alkyl dimethyl amine oxide, fatty alcohol polyoxyethylene ether, alkyl sugar
Glycosides, fatty alcohol.
Preferably, the antiseptic and inhibiting bacteria function agent is selected from poly hexamethylene biguanide, polyhexamethylene list guanidine, benzalkonium chloride, double last of the ten Heavenly stems
One or more in base alkyl dimethyl ammonium chloride, benzethonium chloride, chlorohexidene, Phenoxyethanol.
Preferably, the composition has further included essence, ethyl alcohol, polyvinyl alcohol.
Compared with prior art, beneficial effects of the present invention are as follows：
1, present invention discover that alcamine compound has except aldehyde, the performance except organic acid, particularly two kinds of alcohol amine compounds
Have after mixing compared to single compound and preferably remove aldehyde effect.The composition of the present invention is not required illumination that can be sent out with aldehydes
Biochemical reaction, and it is nontoxic, and reaction product will not cause secondary pollution.
2, the present composition can not only remove aldehyde, and can remove most life stink, to organic acid, Ammonia, vulcanization
The gas with foreign flavor such as object have good removal effect.In addition, the composition of the present invention can effectively be pressed down by adding antiseptic and inhibiting bacteria function agent
The growth of surrounding bacterial processed inhibits the generation of gas with foreign flavor from root, enhances the effect for continuing taste removal.
3, one layer of effective film is formed in the surface of solids after present composition sprinkling, it is not easily to fall off, it will not be inhaled
Enter human body, be capable of the removal aldehydes and gas with foreign flavor of continuous and effective.
Specific embodiment
Illustrate technical scheme below by way of specific embodiment.The equal city of raw materials and reagents used in the present invention
Selling can obtain.
Embodiment 1
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein amino fourth by weight ratio using following raw material
Triol 1%, benzalkonium chloride 0.1%, dodecyldimethylamine oxide 0.5%, soybean ethyl sulfuric acid ethyl ester morpholine 2%, essence
0.05%, distilled water 96.35%.
Preparation process is as follows：In clean container distilled water, benzalkonium chloride, ammonia are sequentially added according to above-mentioned weight proportion
Dodecyldimethylamine oxide, soybean ethyl sulfuric acid ethyl ester morpholine, essence are added after base butantriol stirring and dissolving.Detection group
Product is packed after point content qualification.
This product can be sprayed directly on in room air, removed in furniture surface, car inside, fabric leather to remove aldehyde
Taste.
Embodiment 2
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein amino fourth by weight ratio using following raw material
Triol 1.5%, benzalkonium chloride 0.1%, dodecyldimethylamine oxide 0.5%, fatty alcohol polyoxyethylene ether 0.5%, soybean
Ethyl sulfuric acid ethyl ester morpholine 1%, zinc ricinate 2%, essence 0.05%, distilled water 94.35%.
Preparation process is as follows：In clean container distilled water, benzalkonium chloride, ammonia are sequentially added according to above-mentioned weight proportion
Added after base butantriol, amino-methyl-propanediol stirring and dissolving dodecyldimethylamine oxide, fatty alcohol polyoxyethylene ether,
Soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate, essence.Product is packed after stirring evenly rear detected components content qualification.
Embodiment 3
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein 2- amino by weight ratio using following raw material
Isobutanol 0.5%, tromethamine 1.0%, benzalkonium chloride 0.05%, poly hexamethylene biguanide 0.1%, dodecyl dimethyl
Amine oxide 0.5%, fatty alcohol polyoxyethylene ether 0.5%, polyvinyl alcohol 1%, soybean ethyl sulfuric acid ethyl ester morpholine 2%, distilled water
94.35%.
Preparation process is as follows：Distilled water is sequentially added according to above-mentioned weight proportion, polyvinyl alcohol stirs in clean container
Add benzalkonium chloride, poly hexamethylene biguanide, tromethamine, 2- aminoisobutanols after mixing dissolving, add amine oxide, fatty alcohol
Polyoxyethylene ether, soybean ethyl sulfuric acid ethyl ester morpholine.Product is packed after stirring evenly rear detected components content qualification.
Embodiment 4
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein amino fourth by weight ratio using following raw material
Triol 1.5%, amino-methyl-propanediol 0.5%, benzethonium chloride 0.1%, Phenoxyethanol 0.2%, dodecyl dimethyl oxidation
Amine 0.5%, fatty alcohol polyoxyethylene ether 0.5%, polyvinyl alcohol 1%, zinc ricinate 2%, distilled water 93.7%.
Preparation process is as follows：Distilled water is sequentially added according to above-mentioned weight proportion, polyvinyl alcohol stirs in clean container
Add benzethonium chloride, tromethamine, amino-methyl-propanediol after mixing dissolving, dodecyl dimethyl oxidation is added after dissolving
Amine, fatty alcohol polyoxyethylene ether, Phenoxyethanol, zinc ricinate.Product is packed after stirring evenly rear detected components content qualification.
Embodiment 5
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein amino fourth by weight ratio using following raw material
Triol 1.5%, amino-methyl-propanediol 0.5%, benzalkonium chloride 0.1%, dodecyldimethylamine oxide 0.5%, fatty alcohol
Polyoxyethylene ether 0.5%, soybean ethyl sulfuric acid ethyl ester morpholine 1%, zinc ricinate 2%, essence 0.05%, distilled water
93.85%.
Preparation process is as follows：In clean container distilled water, benzalkonium chloride, ammonia are sequentially added according to above-mentioned weight proportion
Alkyl dimethyl amine oxide, fatty alcohol polyoxyethylene ether, soybean are added after base butantriol, amino-methyl-propanediol stirring and dissolving
Ethyl sulfuric acid ethyl ester morpholine, zinc ricinate, essence.Product is packed after stirring evenly rear detected components content qualification.
Comparative example 1
Using the common aldehyde remover in market (Japan tree send aldehyde remover) as a comparison case 1, the composition progress with the present invention
Except aldehyde Contrast on effect.
Comparative example 2
Make, to ratio 2, to carry out except aldehyde Contrast on effect with the composition of the present invention using activated carbon (Shanghai Europe hair bamboo charcoal bag).
Comparative example 3
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein amino fourth by weight ratio using following raw material
Triol 0.5%, amino-methyl-propanediol 0.5%, benzalkonium chloride 0.1%, alkyl dimethyl amine oxide 0.5%, soybean ethyl sulphur
Acetoacetic ester morpholine 2%, essence 0.05%, distilled water 96.35%.
Preparation process is as follows：In clean container distilled water, benzalkonium chloride, ammonia are sequentially added according to above-mentioned weight proportion
Alkyl dimethyl amine oxide, soybean ethyl sulfuric acid ethyl ester morpholine, essence are added after base butantriol stirring and dissolving.Detected components contain
Product is packed after amount is qualified.This product can be sprayed directly on in room air, used in furniture surface, car inside, fabric leather
To remove aldehyde taste removal.
Comparative example 3 and embodiment 1 difference lies in：Tromethamine and amino-methyl-propanediol two are used in comparative example 3
Kind alcohol amine compound, other components proportioning all same, carries out as with embodiment 1 except aldehyde Contrast on effect.
Comparative example 4
A kind of composition for removing aldehydes and eliminating the unusual smell, is mixed, wherein amino fourth by weight ratio using following raw material
Triol 1%, benzalkonium chloride 0.1%, soybean ethyl sulfuric acid ethyl ester morpholine 2%, essence 0.05%, distilled water 96.85%.
Preparation process is as follows：In clean container distilled water, benzalkonium chloride, ammonia are sequentially added according to above-mentioned weight proportion
Alkyl dimethyl amine oxide, soybean ethyl sulfuric acid ethyl ester morpholine, essence are added after base butantriol stirring and dissolving.Detected components contain
Product is packed after amount is qualified.This product can be sprayed directly on in room air, used in furniture surface, car inside, fabric leather
To remove aldehyde taste removal.
Comparative example 4 and embodiment 1 difference lies in：Surfactant alkyl dimethyl amine oxide is not added in comparative example 4,
Distilled water proportioning is corresponding to be increased, and other components proportioning all same is carried out as with embodiment 1 except aldehyde Contrast on effect.
The aldehyde deodorizing effect that removes of product is tested
Table 1 below be above-described embodiment 1-5 and comparative example 1-4 according to《QB/T 2761-2006 indoor air purification products
Clean-up effect assay method》That detects product removes aldehyde effect, initial concentration of formaldehyde 2mg/m3, embodiment 1-5 and comparative example 1-4
Sample usage amount all same.
Table 1 removes aldehyde effect data
| Test sample | Formaldehyde removal rate % after 2h | Formaldehyde removal rate after for 24 hours |
| Embodiment 1 | 84.6 | 92.9 |
| Embodiment 2 | 86.5 | 94.6 |
| Embodiment 3 | 93.8 | 97.1 |
| Embodiment 4 | 93.3 | 98.2 |
| Embodiment 5 | 94.5 | 98.5 |
| Comparative example 1 | 65.8 | 91.4 |
| Comparative example 2 | 32.3 | 76.6 |
| Comparative example 3 | 92.5 | 98.3 |
| Comparative example 4 | 72.5 | 90.5 |
Using the effect that eliminates the unusual smell of the test product of the present invention as a comparison sample of eliminating smell agent (beautiful faery's smelly eliminating is easy) in the market
Fruit.The following table 2 is the removal rate test result of the invention simulated in laboratory conditions with comparison sample to gas with foreign flavor, represents gas
Body is isovaleric acid (100ppm), ammonia (200ppm), hydrogen sulfide (200ppm).The data result shows the present composition to different
Taste gas has very strong removal effect, especially there is good effect to organic acid molecule.
Table 2 eliminates the unusual smell effect data
The fungistatic effect of product
According to《The evaluation method of QB/T 2738-2012 daily chemical products antibacterials and fungistatic effect》Test product bacteriostasis property.
Table 3 is the test result of embodiment 3,4, the results showed that they are to Escherichia coli 8099, staphylococcus aureus (ATCC
6538), the bacteriostasis rate of Candida albicans (ATCC 10231) three kinds of typical bacterias has good biocidal property up to more than 99.9%
Energy.
Therefore, product of the invention is in addition to removing aldehydes odorous gas, moreover it is possible to the growth and breeding of some microorganisms is controlled,
Inhibit the generation of stink from root, on the other hand can also prevent the long bacterium of product itself.
3 fungistatic effect data of table
Other performances of product
Hydramine in the present composition with formaldehyde be response type except aldehyde, therefore the product of the present invention can reduce formaldehyde quickly
Concentration, for 24 hours after formaldehyde removal rate up to more than 98%, show the present invention product have it is good except effect of formaldehyde.In addition,
The filming performance of the present invention is very good, and product is sprayed at the surface of solids, and after naturally dry, layer of transparent is formed in the surface of solids
Film, with dry cloth wiping will not wipe easily, when need remove product when, with wet cloth wiping can remove.
In conclusion the present invention except aldehydes and the composition that eliminates the unusual smell, not only except aldehyde effect is good, asepsis environment-protecting, maintenance
Time is long, and also has good removal effect to some special bad smells, there is preferable application prospect.
The part preferred embodiment of the present invention is above are only, the present invention is not limited in the content of embodiment.For ability
For technical staff in domain, can there are various change and change in the conception range of technical solution of the present invention, that is made appoints
What changes and change, within the scope of the present invention.
Claims (8)
- It is 1. a kind of except aldehydes and the composition to eliminate the unusual smell, which is characterized in that the composition includes each of following weight percents Component：The anti-corrosion suppression of 0.5%-2% hydramine, the eliminating smell agent of 0.5%-5%, the surfactant of 0.1%-5%, 0.01%-2% Microbial inoculum, surplus are water.
- It is 2. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The hydramine is selected from 2- ammonia One in base isobutanol, amino-methyl-propanediol, 2- amino -1,3- propylene glycol, 3- amido-1,2-propanediols, tromethamine Kind is a variety of.
- It is 3. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The hydramine is 2- amino Isobutanol, amino-methyl-propanediol, 2- amino -1,3- propylene glycol, 3- amido-1,2-propanediols, tromethamine are wherein arbitrary Two kinds of mixture.
- It is 4. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The eliminating smell agent is selected from castor The one or two of numb zinc oleate, soybean ethyl sulfuric acid ethyl ester morpholine.
- It is 5. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The surfactant choosing From one kind in nonionic surfactant, amphoteric surfactant, cationic surfactant, anion surfactant or It is a variety of.
- It is 6. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The surfactant choosing From C8-14Alkyl dimethyl amine oxide, fatty alcohol polyoxyethylene ether, alkyl glycosides, fatty alcohol.
- It is 7. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The antiseptic and inhibiting bacteria function agent choosing From poly hexamethylene biguanide, polyhexamethylene list guanidine, benzalkonium chloride, double-track suspended self-propelled conveyor, benzethonium chloride, chlorohexidene, One or more in Phenoxyethanol.
- It is 8. as described in claim 1 a kind of except aldehydes and the composition to eliminate the unusual smell, it is characterised in that：The composition further includes There are essence, ethyl alcohol, polyvinyl alcohol.
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Cited By (11)
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| CN109497094A (en) * | 2018-11-08 | 2019-03-22 | 长兴蓝杉生物科技有限公司 | A kind of footgear deodorizing antibiotic composition and preparation method thereof containing zinc ricinate |
| CN110787625A (en) * | 2019-11-19 | 2020-02-14 | 西安鑫鑫环保科技有限公司 | Formaldehyde scavenging agent for decoration |
| CN111733597A (en) * | 2020-06-02 | 2020-10-02 | 苏州工业园区安诺科斯化妆品研发有限公司 | A mask deodorant and its preparation method |
| CN112457924A (en) * | 2020-12-09 | 2021-03-09 | 四川同庆南风洗涤用品有限责任公司 | Peculiar smell removing ferment bathroom cleaner and preparation method thereof |
| CN112569763A (en) * | 2020-12-11 | 2021-03-30 | 梁岱晖 | Composition for removing aldehydes and modified activated carbon applied to composition |
| CN113082931A (en) * | 2019-12-23 | 2021-07-09 | 3M创新有限公司 | Composition for removing aldehydes and benzene series, application thereof and modified activated carbon |
| CN113277627A (en) * | 2021-04-19 | 2021-08-20 | 广西壮族自治区环境保护科学研究院 | Method for treating and recycling urban black and odorous water sludge |
| WO2022126597A1 (en) * | 2020-12-18 | 2022-06-23 | Dow Global Technologies Llc | Oxygenated solvent odorant removal composition |
| CN114682078A (en) * | 2022-03-31 | 2022-07-01 | 湖南科美洁环保科技有限公司 | Deodorization method for refuse landfill |
| CN115253638A (en) * | 2022-07-19 | 2022-11-01 | 金久湘遇环保新材料(重庆)有限公司 | Nanometer aldehyde-removing anion liquid for purifying air and preparation method thereof |
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Cited By (13)
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| CN109497094A (en) * | 2018-11-08 | 2019-03-22 | 长兴蓝杉生物科技有限公司 | A kind of footgear deodorizing antibiotic composition and preparation method thereof containing zinc ricinate |
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Application publication date: 20180518 |