CN108003727B - A method of preparing imitative porcelain building decoration materials - Google Patents
A method of preparing imitative porcelain building decoration materials Download PDFInfo
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- CN108003727B CN108003727B CN201711382908.3A CN201711382908A CN108003727B CN 108003727 B CN108003727 B CN 108003727B CN 201711382908 A CN201711382908 A CN 201711382908A CN 108003727 B CN108003727 B CN 108003727B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Abstract
The invention belongs to the technical fields of ornament materials preparation, provide a kind of method for preparing imitative porcelain building decoration materials.After acrylonitrile-butadiene-styrene copolymer is formed powder using muscovite is modified by this method, creamy material, which is configured to, with acrylic resin, ceramic powder is applied to building material surface, it is processed by shot blasting, by polishing heat, so that the acrylonitrile-butadiene-styrene copolymer powder bonding of hot melt is obtained one layer of hard acrylic acid of densification and imitate porcelain film, obtains imitative porcelain building decoration materials.So that being firmly bonded, being not easily to fall off, there is excellent waterproof anti-mold effect and weatherability.
Description
Technical field
The invention belongs to the technical fields of ornament materials preparation, provide a kind of side for preparing imitative porcelain building decoration materials
Method.
Background technique
With the economic development of society and the progress of civilization, living standards of the people and quality of life are increased accordingly, to house
The requirement of quality is also higher and higher, and increasingly tends to epoch forward position to the aesthetic of things, therefore increasingly pay attention to decoration material
The selection of material, various novel building decoration materials have obtained extensive development and application, special face decoration material, with
In recent years to green, environmental protection, the progress of ecology, health and comfortable life idea, great variation has occurred.
Building materials faced deorative is one of important content of building decoration, and its object is to improve in the resistance nature of building materials
The ability that the invasion such as various factors such as dust, sleet, frost, solarization destroy, and cooperatively meet with construction material structure heat preservation, every
The functional requirements such as heat, sound insulation, waterproof, beautification have both two kinds of functions of protection and beautification.Common veneer building materials are divided into three classes:
Spray class, such as coating, paint；Paste class, such as ceramic tile, facing paper, various stone materials；Plate class, such as glass curtain wall, decorative panel
Deng.Wherein coating, which refers to, with base's secure bond and can form the material of complete and tough and tensile protective film coated on body surface, build
Building coating is a kind of relatively inexpensive material of modem architectural ornament material, construction is simple, short time limit, work efficiency height, good decorating effect,
The features such as easy to maintenance, but waterproof, mould proof, anticorrosion and other effects are poor.Decorative Building Stone includes natural ornamental stone (Dali
Stone, granite) and artificial stone, natural ornamental stone good decorating effect is durable, and artificial stone is with light-weight, intensity is high, resistance to
The advantages that burn into price is low, easy for construction, but there is the problems such as cost is high, and process is more complex, it influences further to develop
It uses.
For above situation, people increasingly pay attention to the research and application of building materials surface lining in recent years.Extensively at present
General application is facing paper, is used primarily in plank, bamboo clappers, modeling are trembled and posted on the building materials such as plate, synthetic wood-based board, with institute on facing paper
The pattern of print comes decorative building material surface, reaches beautification or emulation and other effects, but facing paper is more crisp easy to crack, insecure, do not prevent
Water, easily mildew.The more superior plastics matter decorating film research for posting building materials of performance and application are less, are current surface lining development
Important directions.
Certain effect has been achieved in terms of imitation porcelain decoration material, especially building decoration veneer film both at home and abroad at present.Its
Middle Guo Jian has invented a kind of imitation porcelain decoration material and preparation method (Chinese invention patent application number 201710540747.X), material
Include: melamine resin, modified attapulgite clay, active carbon, methylcellulose, polyvinyl alcohol, epoxy resin, fill out
Agent, curing agent, colorant are filled, the preparation method comprises the following steps: first by melamine resin and polyvinyl alcohol, epoxy resin, suitable quantity of water,
After being mixed evenly, modified attapulgite clay, active carbon are added, then shearing 10~20min of dispersion adds residue
Component stirs.In addition, contain wisdom invented a kind of wear-resisting building materials and ornaments film of high light and its production method (in
State's application number of invention patent 201410040838.3), steps are as follows: first is that stock, second is that the dissolution and separation of polyurethane resin
The preparation of liquid, third is that the preparation of UV oil, fourth is that high-accuracy sleeve colour temperature control is printed, fifth is that basement membrane bottom-surface coated Chemical Decomposition liquid, six
It is coating UV oil, seventh is that pasting PET protection film.
As it can be seen that in the prior art in building materials surface lining there is more crisp easy to crack, insecure, non-watertight, easy mildew in facing paper
The problem of, coating class and stone materials, there is also bond the problems such as insecure, easy to fall off, weather resistance is poor, while preparation process
Complexity, it is at high cost, environment is caused centainly to pollute, and the research and application of building decoration film are less at present.
Summary of the invention
In response to this, the present invention proposes that a kind of method for preparing imitative porcelain building decoration materials, technical point are to lead to
It crosses building material surface waterborne film-forming and heat bonding hardening overlay film preparation covering acrylic acid imitates the decorative building material of porcelain film, preparation process
It is environment friendly and pollution-free, and to bond it is stronger, not easily to fall off, while also have excellent waterproof anti-mold effect；In addition, into one
Step production simple production process, at low cost, can large-scale promotion production.
Specific technical solution of the present invention is as follows:
A method of imitative porcelain building decoration materials being prepared, specific step is as follows for preparation:
(1) it is attached to muscovite with mass ratio 100:5-10 grinding acrylonitrile-butadiene-styrene (ABS) and muscovite
Acrylonitrile-butadiene-styrene copolymer subparticle surface, the acrylonitrile-butadiene-styrene copolymer being miniaturize
Modified powder；
(2) by the resulting acrylonitrile-butadiene-styrene copolymer modified powder of step (1), acrylic resin, ceramic powder,
Water is mixed by certain parts by weight, is added in dispersion machine, and emulsifier, antioxidant and the colorant of certain part by weight is then added,
Action of forced stirring is opened, obtains creamy material after being sufficiently mixed；Wherein 37~41 parts by weight of acrylic resin, 6~9 weight of ceramic powder
Part, 5~10 parts by weight of acrylonitrile-butadiene-styrene copolymer modified powder, 40~52 parts by weight of water, emulsifier 0.1~0.3
Parts by weight, 0.1~0.2 parts by weight of antioxidant, 0.05~0.1 parts by weight of colorant；
(3) step (2) resulting creamy material is spread evenly across building material surface, then building materials is carried out using polishing machine
The heat that polishing treatment, polishing machine and building materials friction generate, evaporates the moisture in creamy material, acrylonitrile-butadiene-benzene second
The modified powder secure bond of alkene copolymer forms the hard acrylate film of one layer of densification in building material surface, obtains imitative porcelain building dress
Exterior material.
Preferably, step (1) nano-level grinder is vertical lapping machine, valve body grinder, horizontal mill or disc type
One of grinder, the partial size of the acrylonitrile-butadiene-styrene copolymer modified powder after grinding are 50~200nm.
Preferably, step (2) emulsifier is alkyl phenol polyoxyethylene ether, diglycerol polypropylene glycol ether, diglycerol gather
At least one of propylene glycol or fatty alcohol polyoxyethylene ether.
Preferably, step (2) antioxidant is zinc dialkyl dithiophosphate, vulcanization hydrocarbon boric acid mantoquita, N- phenyl-α-
At least one of naphthylamines, alkyl phenthazine, tributyl phosphite or triphenyl phosphite.
Preferably, step (2) colorant is titanium white, lithopone, lead chromate yellow, barba hispanica, lead chromate yellow, uranium yellow or iron oxide
It is at least one of red.
Preferably, step (2) dispersion machine is one in emulsion dispersion machine, high-speed dual-shaft dispersion machine or stirring dispersion machine
Kind, 800~1000r/min of the speed of mainshaft, jitter time is 15~30min.
After acrylonitrile-butadiene-styrene copolymer is formed powder using muscovite is modified by the present invention, with acrylic acid tree
Rouge, ceramic powder are configured to creamy material and are applied to building material surface, are processed by shot blasting, by polishing heat, make the propylene of hot melt
Nitrile-butadiene-styrene copolymer powder bonding obtains one layer of hard acrylic acid of densification and imitates porcelain film, obtains imitative porcelain building
Ornament materials.Building imitation porcelain material prepared by the present invention has excellent firm pasting, waterproofness, anti-mold effect, weatherability
Aspect also has significant advantage.
The present invention provides a kind of methods for preparing imitative porcelain building decoration materials, compared with prior art, spy outstanding
Point and excellent effect are:
1. building decoration materials prepared by the present invention, imitative ceramic effect is good, can be widely applied to indoor outdoor building materials veneer finishing.
2. preparation method of the invention, by the way that the creamy material for being applied to building material surface to be processed by shot blasting, so that bonding
Securely, not easily to fall off, there is excellent waterproof anti-mold effect and weatherability.
3. preparation process of the invention is generated without noxious pollutant, the feature of environmental protection is splendid.
It, can large-scale promotion use 4. preparation process of the invention is easy to operate, at low cost.
Specific embodiment
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention
Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
(1) acrylonitrile-butadiene-styrene (ABS) and muscovite are ground in vertical lapping machine with mass ratio 100:5, is made white
Mica is attached to acrylonitrile-butadiene-styrene copolymer subparticle surface, and obtaining partial size is 50~200nm miniaturization
Acrylonitrile-butadiene-styrene copolymer modified powder；
(2) resulting acrylonitrile-butadiene-styrene copolymer modified powder, acrylic resin, ceramic powder, water are mixed,
It is added in dispersion machine, emulsifier alkyl phenol polyoxyethylene ether, antioxidant zinc dialkyl dithiophosphate, colorant, which is then added, is
Lithopone opens action of forced stirring, speed of mainshaft 800r/min, jitter time 15min；Creamy material is obtained after being sufficiently mixed；
Wherein 37 parts by weight of acrylic resin, 6 parts by weight of ceramic powder, 5 parts by weight of acrylonitrile-butadiene-styrene copolymer modified powder,
40 parts by weight of water, 0.1 parts by weight of emulsifier, 0.1 parts by weight of antioxidant, 0.05 parts by weight of colorant；
(3) step (2) resulting creamy material is spread evenly across building material surface, then building materials is carried out using polishing machine
The heat that polishing treatment, polishing machine and building materials friction generate, evaporates the moisture in creamy material, acrylonitrile-butadiene-benzene second
The modified powder secure bond of alkene copolymer forms the hard acrylate film of one layer of densification in building material surface, obtains imitative porcelain building dress
Exterior material.
Imitative porcelain building decoration materials prepared by embodiment 1, test sticking strength, washability number, as shown in table 1.
Embodiment 2
(1) acrylonitrile-butadiene-styrene (ABS) and muscovite are ground in vertical lapping machine with mass ratio 100:6, is made white
Mica is attached to acrylonitrile-butadiene-styrene copolymer subparticle surface, and obtaining partial size is 50~200nm miniaturization
Acrylonitrile-butadiene-styrene copolymer modified powder；
(2) resulting acrylonitrile-butadiene-styrene copolymer modified powder, acrylic resin, ceramic powder, water are mixed,
It is added in dispersion machine, it is lead chromium that emulsifier diglycerol polypropylene glycol ether, antioxidant vulcanization hydrocarbon boric acid mantoquita, colorant, which is then added,
Huang opens action of forced stirring, speed of mainshaft 800r/min, jitter time 20min；Creamy material is obtained after being sufficiently mixed；Wherein
40 parts by weight of acrylic resin, 6 parts by weight of ceramic powder, 8 parts by weight of acrylonitrile-butadiene-styrene copolymer modified powder, water 40
Parts by weight, 0.2 parts by weight of emulsifier, 0.1 parts by weight of antioxidant, 0.05 parts by weight of colorant；
(3) step (2) resulting creamy material is spread evenly across building material surface, then building materials is carried out using polishing machine
The heat that polishing treatment, polishing machine and building materials friction generate, evaporates the moisture in creamy material, acrylonitrile-butadiene-benzene second
The modified powder secure bond of alkene copolymer forms the hard acrylate film of one layer of densification in building material surface, obtains imitative porcelain building dress
Exterior material.
Imitative porcelain building decoration materials prepared by embodiment 2, test sticking strength, washability number, as shown in table 1.
Embodiment 3
(1) acrylonitrile-butadiene-styrene (ABS) and muscovite are ground in disk grinder with mass ratio 100:10, is made
Muscovite is attached to acrylonitrile-butadiene-styrene copolymer subparticle surface, obtains partial size as 50~200nm miniaturization
Acrylonitrile-butadiene-styrene copolymer modified powder；
(2) resulting acrylonitrile-butadiene-styrene copolymer modified powder, acrylic resin, ceramic powder, water are mixed,
It is added in dispersion machine, emulsifier fatty alcohol polyoxyethylene ether, antioxidant triphenyl phosphite, colorant iron oxide is then added
It is red, open action of forced stirring, speed of mainshaft 1000r/min, jitter time 30min；Creamy material is obtained after being sufficiently mixed；Wherein
41 parts by weight of acrylic resin, 9 parts by weight of ceramic powder, 10 parts by weight of acrylonitrile-butadiene-styrene copolymer modified powder, water
40 parts by weight, 0.3 parts by weight of emulsifier, 0.2 parts by weight of antioxidant, 0.1 parts by weight of colorant；
(3) step (2) resulting creamy material is spread evenly across building material surface, then building materials is carried out using polishing machine
The heat that polishing treatment, polishing machine and building materials friction generate, evaporates the moisture in creamy material, acrylonitrile-butadiene-benzene second
The modified powder secure bond of alkene copolymer forms the hard acrylate film of one layer of densification in building material surface, obtains imitative porcelain building dress
Exterior material.
Imitative porcelain building decoration materials prepared by embodiment 3, test sticking strength, washability number, as shown in table 1.
Embodiment 4
(1) acrylonitrile-butadiene-styrene (ABS) and muscovite are ground in valve body grinder with mass ratio 100:8, is made white
Mica is attached to acrylonitrile-butadiene-styrene copolymer subparticle surface, and obtaining partial size is 50~200nm miniaturization
Acrylonitrile-butadiene-styrene copolymer modified powder；
(2) resulting acrylonitrile-butadiene-styrene copolymer modified powder, acrylic resin, ceramic powder, water are mixed,
It is added in dispersion machine, emulsifier fatty alcohol polyoxyethylene ether, antioxidant tributyl phosphite, colorant lead chromate yellow is then added,
Open action of forced stirring, speed of mainshaft 800r/min, jitter time 30min；Creamy material is obtained after being sufficiently mixed；Wherein propylene
41 parts by weight of acid resin, 9 parts by weight of ceramic powder, 5 parts by weight of acrylonitrile-butadiene-styrene copolymer modified powder, 45 weight of water
Part, 0.1 parts by weight of emulsifier, 0.2 parts by weight of antioxidant, 0.1 parts by weight of colorant；
(3) step (2) resulting creamy material is spread evenly across building material surface, then building materials is carried out using polishing machine
The heat that polishing treatment, polishing machine and building materials friction generate, evaporates the moisture in creamy material, acrylonitrile-butadiene-benzene second
The modified powder secure bond of alkene copolymer forms the hard acrylate film of one layer of densification in building material surface, obtains imitative porcelain building dress
Exterior material.
Imitative porcelain building decoration materials prepared by embodiment 4, test sticking strength, washability number, as shown in table 1.
Table 1:
Claims (6)
1. a kind of method for preparing imitative porcelain building decoration materials, specific step is as follows for preparation: (1) by acrylonitrile-butadiene-benzene
Ethylene copolymer and muscovite make muscovite be attached to acrylonitrile-butadiene-styrene (ABS) copolymerization with mass ratio 100:5-10 grinding
Object subparticle surface, the acrylonitrile-butadiene-styrene copolymer modified powder being miniaturize；
(2) the resulting acrylonitrile-butadiene-styrene copolymer modified powder of step (1), acrylic resin, ceramic powder, water are pressed
Certain parts by weight mixing, is added in dispersion machine, emulsifier, antioxidant and the colorant of certain part by weight is then added, open
Action of forced stirring obtains creamy material after being sufficiently mixed；Wherein 37~41 parts by weight of acrylic resin, 6~9 parts by weight of ceramic powder,
Acrylonitrile-butadiene-styrene copolymer modified 5~10 parts by weight of powder, 40~52 parts by weight of water, the emulsifier .3 of 0 .1~0 weight
Measure part, 0.1~0.2 parts by weight of antioxidant, 0.05~0.1 parts by weight of colorant；
(3) step (2) resulting creamy material is spread evenly across building material surface, then building materials is polished using polishing machine
The heat that processing, polishing machine and building materials friction generate, evaporates the moisture in creamy material, acrylonitrile-butadiene-styrene (ABS) is total
Polymerized powder secure bond forms the hard acrylate film of one layer of densification in building material surface, obtains imitative porcelain building decoration material
Material.
2. a kind of method for preparing imitative porcelain building decoration materials according to claim 1, it is characterised in that: step (1) is described
Grinding uses nano-level grinder, and the nano-level grinder is vertical lapping machine, valve body grinder, horizontal mill or disc type grinding
One of machine, the partial size of the acrylonitrile-butadiene-styrene copolymer modified powder after grinding are 50~200nm.
3. a kind of method for preparing imitative porcelain building decoration materials according to claim 1, it is characterised in that: step (2) is described
Emulsifier is at least one of alkyl phenol polyoxyethylene ether, diglycerol polypropylene glycol ether or fatty alcohol polyoxyethylene ether.
4. a kind of method for preparing imitative porcelain building decoration materials according to claim 1, it is characterised in that: step (2) is described
Antioxidant is zinc dialkyl dithiophosphate, vulcanization hydrocarbon boric acid mantoquita, N- phenyl-α-naphthylamine, alkyl phenthazine, three fourth of phosphorous acid
At least one of ester or triphenyl phosphite.
5. a kind of method for preparing imitative porcelain building decoration materials according to claim 1, it is characterised in that: step (2) is described
Colorant is at least one of titanium white, lithopone, lead chromate yellow, barba hispanica, uranium yellow or iron oxide red.
6. a kind of method for preparing imitative porcelain building decoration materials according to claim 1, it is characterised in that: step (2) is described
Dispersion machine is one of emulsion dispersion machine, high-speed dual-shaft dispersion machine or stirring dispersion machine, 800~1000r/min of the speed of mainshaft,
Jitter time is 15~30min.
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| CN1740246A (en) * | 2005-09-15 | 2006-03-01 | 刘庆宁 | Granite imitating paint and its prepn process and imitation granite making process |
| JP2006117797A (en) * | 2004-10-21 | 2006-05-11 | Kansai Paint Co Ltd | Water-based primer composition |
| CN103709589A (en) * | 2014-01-04 | 2014-04-09 | 华东理工大学 | Mica-ABS (Acrylonitrile Butadiene Styrene) flame-retardant insulation material and preparation method thereof |
| CN106010045A (en) * | 2016-06-29 | 2016-10-12 | 芜湖县双宝建材有限公司 | Anticorrosion waterproof building wall coating |
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- 2017-12-20 CN CN201711382908.3A patent/CN108003727B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006117797A (en) * | 2004-10-21 | 2006-05-11 | Kansai Paint Co Ltd | Water-based primer composition |
| CN1740246A (en) * | 2005-09-15 | 2006-03-01 | 刘庆宁 | Granite imitating paint and its prepn process and imitation granite making process |
| CN103709589A (en) * | 2014-01-04 | 2014-04-09 | 华东理工大学 | Mica-ABS (Acrylonitrile Butadiene Styrene) flame-retardant insulation material and preparation method thereof |
| CN106010045A (en) * | 2016-06-29 | 2016-10-12 | 芜湖县双宝建材有限公司 | Anticorrosion waterproof building wall coating |
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