CN107987297A - 一种耐磨办公用塑料文件夹 - Google Patents

一种耐磨办公用塑料文件夹 Download PDF

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CN107987297A
CN107987297A CN201711356808.3A CN201711356808A CN107987297A CN 107987297 A CN107987297 A CN 107987297A CN 201711356808 A CN201711356808 A CN 201711356808A CN 107987297 A CN107987297 A CN 107987297A
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顾建强
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Suzhou Saiside Engineering Equipment Co Ltd
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Abstract

本发明公开了一种装修用抗菌防霉涂料，其特征在于，按质量份数计包括以下组分：液体水性环氧树脂：30‑45份、复合纤维素：8‑12份、纤维素醚：4‑5份、水处理剂：0.1‑0.3份、润湿剂：4‑6份、分散剂：6‑10份、消泡剂：4‑6份、纳米材料溶液：30‑40份、烷基醇酰胺:3‑5份、苄基二甲基酮缩醇：1‑2份、改性填料：10‑15份、交联型丙烯酸酯乳液：60‑70份、丙烯酸丁酯：6‑9份、成膜助剂：11‑13份、颜料：11‑16份、防腐剂：8‑15份、增稠剂:13‑16份、去离子水：80‑100份；本发明具有优异的抗菌防霉性能，同时绿色环保。

Description

一种耐磨办公用塑料文件夹
技术领域
本发明涉及到办公用品技术领域，具体来讲是一种耐磨办公用塑料文件夹。
背景技术
现有的文件夹产品在长期使用过程磨损严重，严重影响到美观，而且强度没有办法满足需求，容易损坏，使用寿命较短，需要需要一种强度高、且耐磨性好的产品替代。
发明内容
本发明所要解决的技术问题是，针对以上现有技术存在的缺点，提供一种耐磨办公用塑料文件夹。
本发明解决以上技术问题的技术方案是：一种高强耐磨办公用塑料文件夹，包括文件夹本体，该文件夹本体按质量份数计包括以下组分：聚乙烯：20-30份、聚氯乙烯：30-40份、聚丙烯：20-25份、纳米材料溶液：15-18份、复合纤维素：6-9份、硬脂酸锌：3-6份、云母粉：5-12 份、纳米二氧化钛：4-6份、聚四氟乙烯：15-18份、纳米锌粉：3-4份、三氧化二锑：1-2份、有改性聚酯丙烯酸酯：3-6 份、硫酸钡：6-9份、硅油：6-8 份，γ-氨丙基三乙氧基硅烷：2-6份、纳米碳酸钙：8-10 份，增稠剂：6-7份、增韧剂：5-8 份、抗氧化剂：2-3份、偶联剂：4-6份。
本发明进一步限定的技术方案是：
前述的复合纤维素为玻璃纤维素和羟甲基纤维素按照3:2配比的混合物。
前述的增稠剂为硅藻土、膨润土或高岭土一种或几种混合物。
前述的增韧剂为邻苯二甲酸二甲酯。
前述的抗氧化剂为二丁基羟基甲苯。
前述的偶联剂为硅烷偶联剂。
前述的耐高温耐磨涂层制备方法，具体包括以下步骤：
步骤一：将聚乙烯、聚氯乙烯、聚丙烯和聚四氟乙烯混合放置搅拌机中进行搅拌，速度为300-400r/min，时间为20-30min，然后加入纳米材料溶液、硫酸钡、γ-氨丙基三乙氧基硅烷和增稠剂，继续搅拌40-50min，备用；
步骤二：将复合纤维素和云母粉放置打浆机中进行打浆，得到浆料后，加入到步骤一中，加入增塑剂和抗氧化剂、和偶联剂以400-500r/min搅拌50-55min，使其混合均匀，采用挤出设备生产制得塑料板材；
步骤三：将硅油加热至150-160℃，然后加入有改性聚酯丙烯酸酯进行搅拌，充分均匀后加入硬脂酸锌、纳米二氧化钛、纳米锌粉和纳米碳酸钙，以500-550r/min搅拌30-40min，得到耐磨层；
步骤四：塑料片材表面喷涂耐磨涂料，然后放入固化装置中进行耐磨涂料的半固化，制得具有半固化的耐磨涂层的板材 ；
步骤五：将上述对耐磨涂层进行半固化后的板材进行裁切，裁切成所需大小的产品片材后 送入吸塑机中进行吸塑成型。
本发明的有益效果是：本发明添加纳米材料溶液，不仅增加其耐磨性，又能提高吸收隔热性、表面拒水性、防霉杀菌和防污性，且稳定性更好；加入聚四氟乙烯，其耐大气老化性好长期暴露于大气中，表面及性能保持不变，延长了使用寿命；添加纳米锌粉，不仅能够提高其强度和耐磨性，也可作抗菌剂，起到抗菌作用，本发明还具有制作简单、大大节省了劳动力、降低了生产难度，提高了生产效率和产品的良品率，有利于大规模生产，降低产品的生产成 本，从而提高产品的市场竞争力。
具体实施方式
实施例1
本实施例提供一种耐磨办公用塑料文件夹，按质量份数计包括以下组分：聚乙烯：26份、聚氯乙烯：35份、聚丙烯：22份、纳米材料溶液：17份、复合纤维素：7份、硬脂酸锌：4份、云母粉：8 份、纳米二氧化钛：4份、聚四氟乙烯：15份、纳米锌粉：3份、三氧化二锑：1份、有改性聚酯丙烯酸酯：3份、硫酸钡：7份、硅油：6份，γ-氨丙基三乙氧基硅烷：3份、纳米碳酸钙：8份，增稠剂：6份、增韧剂：5 份、抗氧化剂：2份、偶联剂：5份，
其中，复合纤维素为玻璃纤维素和羟甲基纤维素按照3:2配比的混合物；
增稠剂为硅藻土、膨润土或高岭土一种或几种混合物；
增韧剂为邻苯二甲酸二甲酯；
抗氧化剂为二丁基羟基甲苯；
偶联剂为硅烷偶联剂。
本实施例提供一种耐磨办公用塑料文件夹的制备方法，具体包括以下步骤：
步骤一：将聚乙烯、聚氯乙烯、聚丙烯和聚四氟乙烯混合放置搅拌机中进行搅拌，速度为300r/min，时间为30min，然后加入纳米材料溶液、硫酸钡、γ-氨丙基三乙氧基硅烷和增稠剂，继续搅拌45min，备用；
步骤二：将复合纤维素和云母粉放置打浆机中进行打浆，得到浆料后，加入到步骤一中，加入增塑剂和抗氧化剂、和偶联剂以400r/min搅拌55min，使其混合均匀，采用挤出设备生产制得塑料板材；
步骤三：将硅油加热至155℃，然后加入有改性聚酯丙烯酸酯进行搅拌，充分均匀后加入硬脂酸锌、纳米二氧化钛、纳米锌粉和纳米碳酸钙，以500r/min搅拌40min，得到耐磨层；
步骤四：塑料片材表面喷涂耐磨涂料，然后放入固化装置中进行耐磨涂料的半固化，制得具有半固化的耐磨涂层的板材 ；
步骤五：将上述对耐磨涂层进行半固化后的板材进行裁切，裁切成所需大小的产品片材后 送入吸塑机中进行吸塑成型。
实施例2
本实施例提供一种耐磨办公用塑料文件夹，包括文件夹本体，该文件夹本体按质量份数计包括以下组分：聚乙烯：28份、聚氯乙烯：39份、聚丙烯：24份、纳米材料溶液：17份、复合纤维素：8份、硬脂酸锌：5份、云母粉：10 份、纳米二氧化钛：5份、聚四氟乙烯：17份、纳米锌粉：4份、三氧化二锑：2份、有改性聚酯丙烯酸酯：5 份、硫酸钡：7份、硅油：7 份，γ-氨丙基三乙氧基硅烷：4份、纳米碳酸钙：10 份，增稠剂：7份、增韧剂：7 份、抗氧化剂：3份、偶联剂：6份；
其中，复合纤维素为玻璃纤维素和羟甲基纤维素按照3:2配比的混合物；
增稠剂为硅藻土、膨润土或高岭土一种或几种混合物；
增韧剂为邻苯二甲酸二甲酯；
抗氧化剂为二丁基羟基甲苯；
偶联剂为硅烷偶联剂。
本实施例提供一种耐磨办公用塑料文件夹的制备方法，具体包括以下步骤：
步骤一：将聚乙烯、聚氯乙烯、聚丙烯和聚四氟乙烯混合放置搅拌机中进行搅拌，速度为400r/min，时间为20min，然后加入纳米材料溶液、硫酸钡、γ-氨丙基三乙氧基硅烷和增稠剂，继续搅拌50min，备用；
步骤二：将复合纤维素和云母粉放置打浆机中进行打浆，得到浆料后，加入到步骤一中，加入增塑剂和抗氧化剂、和偶联剂以500r/min搅拌55min，使其混合均匀，采用挤出设备生产制得塑料板材；
步骤三：将硅油加热至160℃，然后加入有改性聚酯丙烯酸酯进行搅拌，充分均匀后加入硬脂酸锌、纳米二氧化钛、纳米锌粉和纳米碳酸钙，以550r/min搅拌40min，得到耐磨层；
步骤四：塑料片材表面喷涂耐磨涂料，然后放入固化装置中进行耐磨涂料的半固化，制得具有半固化的耐磨涂层的板材 ；
步骤五：将上述对耐磨涂层进行半固化后的板材进行裁切，裁切成所需大小的产品片材后 送入吸塑机中进行吸塑成型。
除上述实施例外，本发明还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案，均落在本发明要求的保护范围。

Claims (7)

1.一种耐磨办公用塑料文件夹，包括文件夹本体，其特征在于，该文件夹本体按质量份数计包括以下组分：聚乙烯：20-30份、聚氯乙烯：30-40份、聚丙烯：20-25份、纳米材料溶液：15-18份、复合纤维素：6-9份、硬脂酸锌：3-6份、云母粉：5-12 份、纳米二氧化钛：4-6份、聚四氟乙烯：15-18份、纳米锌粉：3-4份、三氧化二锑：1-2份、有改性聚酯丙烯酸酯：3-6 份、硫酸钡：6-9份、硅油：6-8 份，γ-氨丙基三乙氧基硅烷：2-6份、纳米碳酸钙：8-10 份，增稠剂：6-7份、增韧剂：5-8 份、抗氧化剂：2-3份、偶联剂：4-6份。
2.根据权利要求1所述的耐磨办公用塑料文件夹，其特征在于，所述复合纤维素为玻璃纤维素和羟甲基纤维素按照3:2配比的混合物。
3.根据权利要求1所述的耐磨办公用塑料文件夹，其特征在于，所述增稠剂为硅藻土、膨润土或高岭土一种或几种混合物。
4.根据权利要求1所述的耐磨办公用塑料文件夹，其特征在于，所述增韧剂为邻苯二甲酸二甲酯。
5.根据权利要求1所述的耐磨办公用塑料文件夹，其特征在于，所述抗氧化剂为二丁基羟基甲苯。
6.根据权利要求1所述的耐磨办公用塑料文件夹，其特征在于，所述偶联剂为硅烷偶联剂。
7.根据权利要求1所述的高强耐磨办公用塑料文件夹制备方法，其特征在于，具体包括以下步骤：
步骤一：将聚乙烯、聚氯乙烯、聚丙烯和聚四氟乙烯混合放置搅拌机中进行搅拌，速度为300-400r/min，时间为20-30min，然后加入纳米材料溶液、硫酸钡、γ-氨丙基三乙氧基硅烷和增稠剂，继续搅拌40-50min，备用；
步骤二：将复合纤维素和云母粉放置打浆机中进行打浆，得到浆料后，加入到步骤一中，加入增塑剂和抗氧化剂、和偶联剂以400-500r/min搅拌50-55min，使其混合均匀，然后采用挤出设备生产制得塑料板材；
步骤三：将硅油加热至150-160℃，然后加入有改性聚酯丙烯酸酯进行搅拌，充分均匀后加入硬脂酸锌、纳米二氧化钛、纳米锌粉和纳米碳酸钙，以500-550r/min搅拌30-40min，得到耐磨层；
步骤四：塑料片材表面喷涂耐磨涂料，然后放入固化装置中进行耐磨涂料的半固化，制得具有半固化的耐磨涂层的板材 ；
步骤五：将上述对耐磨涂层进行半固化后的板材进行裁切，裁切成所需大小的产品片材后 送入吸塑机中进行吸塑成型。
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