CN107982094A - A kind of freeze proof moist moisturizing cleaning product and preparation method thereof - Google Patents
A kind of freeze proof moist moisturizing cleaning product and preparation method thereof Download PDFInfo
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- CN107982094A CN107982094A CN201711338582.4A CN201711338582A CN107982094A CN 107982094 A CN107982094 A CN 107982094A CN 201711338582 A CN201711338582 A CN 201711338582A CN 107982094 A CN107982094 A CN 107982094A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/005—Preparations for sensitive skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Abstract
A kind of freeze proof moist moisturizing cleaning product, by weight containing anion surfactant 0.1 25%, nonionic surfactant 0.01 10%, amphoteric surfactant 0.1 10%, cation opsonizing agent 0.01 3%, pearling agent 0 3%, complexing agent 0.01 1%, pH adjusting agent 0.01 0.5%, preservative 0.0001 1%, anti-corrosion synergist 0.0001 0.3%, essence 0.01 0.5%, thickener 0.01 3%, freeze proof moist moisture-keeping composition 0.001 4%, surplus is purified water.The present invention also provides a kind of preparation method of above-mentioned freeze proof moist moisturizing cleaning product.The cleaning product of the present invention has Low-temperature antifreeze and the function of moist moisturizing concurrently at the same time, and safe, gentle, can ensure that cleaning product can normally, preferably use in low temperature environment, have effects that moist moisturizing while clearing skin and hair.
Description
Technical field
The present invention relates to cosmetic technical field, and in particular to a kind of freeze proof moist moisturizing cleaning product and its preparation side
Method.
Background technology
In traditional cleaning product, surfactant is one of important component, wherein especially with laureth sulfuric acid
Ester sodium, coconut oleoyl amine DEA, dodecanamide propyl hydroxy sulfo lycine, PEG-150 distearates and similar surface are lived
The use of property agent is most commonly seen.But the Low-temperature antifreeze energy force difference of the cleaning product produced by such surfactant, by temperature
Have a great influence, g., jelly-like or icing phenomenon often occurs under low temperature environment of the temperature less than 10 DEG C, seriously affects product
Using effect, big inconvenience is brought to consumer in winter or some other low temperature environments using the cleaning product；At the same time
The cleaning degreasing power of such cleaning product is too strong, and skin after cleaning, hair can be caused over-drying, user is caused significantly
With rear uncomfortable sensation.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of freeze proof moist moisturizing cleaning product and preparation method thereof, this
Kind cleaning product has Low-temperature antifreeze and the function of moist moisturizing concurrently at the same time, and safe, gentle.The technical solution of use is as follows：
A kind of freeze proof moist moisturizing cleaning product, it is characterised in that by weight containing anion surfactant 0.1-25%,
Nonionic surfactant 0.01-10%, amphoteric surfactant 0.1-10%, cation opsonizing agent 0.01-3%, pearling agent
0-3%, complexing agent 0.01-1%, pH adjusting agent 0.01-0.5%, preservative 0.0001-1%, anti-corrosion synergist 0.001-
0.3%, essence 0.01-0.5%, thickener 0.01-3%, freeze proof moist moisture-keeping composition 0.001-4%, surplus is purified water；
The freeze proof moist moisture-keeping composition is PPG-20 methyls ether, PEG-7 glyceryl cocoates, caprylic/capric glyceride type
A variety of combinations in Natrulon H-10 esters, C12-13 alcohol lactate and dimethyl silicone polymer.
Above-mentioned cleaning product can be hand cleanser, shampoo, shower cream or shampoo used also as bath lotion.
In preferred solution, above-mentioned anionic surface work agent is laureth sodium sulfovinate, laureth sulfosuccinic
Acid esters disodium, bay alcohol sulfuric ester ammonium and one kind in laruyl alcohol sodium sulfovinate or many of combination.
In preferred solution, above-mentioned non-ionic surfactant is that coconut oleoyl amine DEA, coconut oleoyl amine MEA, PEG-150 bis- are hard
One kind or many of combination in resin acid ester and lauryl glucoside.
In preferred solution, above-mentioned amphoteric surface's work agent is dodecanamide propyl hydroxy sulfo lycine, cocamidopropyl propyl amide sweet tea
The combination of one kind or two of which in dish alkali and sodium cocoamphoacetate.
In preferred solution, above-mentioned cation opsonizing agent is polyquaternium -7, Polyquaternium-10 and melon glue hydroxypropyl trimethylammonium
The combination of one kind or two of which in ammonium chloride.Above-mentioned cation opsonizing agent has and improves increase foam, antistatic, soft
Skin care and hair etc. act on, and the cleaning product thereby using the present invention has more excellent moisture feeling, is provided for user
A kind of more comfortable, more pleasant use is felt.
In preferred solution, above-mentioned pearling agent is one in glycol distearate, ethylene glycol monostearate and mica
The combination of kind or two of which.Above-mentioned pearling agent can make cleaning product appearance show a kind of effect of pearly-lustre, produce washing
Product appearance has more aesthetic feeling.
In preferred solution, above-mentioned complexing agent is disodium ethylene diamine tetraacetate（That is EDTA disodiums）With ethylenediamine tetra-acetic acid four
Sodium（That is tetra- sodium of EDTA）One or both of combination.Above-mentioned complexing agent can with water metal ion formed complexing from
The compound of son, so as to play the role of softening of water, enhancing dirt-removing power and anti-corrosion ability etc., makes the structure of cleaning product more
Stablize.
In preferred solution, above-mentioned pH adjusting agent is citric acid, lactic acid, butanedioic acid, anisic acid, sodium hydroxide, potassium hydroxide
With one kind in triethanolamine or many of combination.
In preferred solution, foregoing preservatives are Phenoxyethanol, phenmethylol, sodium benzoate, potassium sorbate, acyl in DMDM second
One kind or many of combination in urea, methylchloroisothiazandnone and methylisothiazolinone.
In preferred solution, foregoing preservatives synergist be one kind in Sensiva SC50, hexylene glycol and ethohexadiol or its
In two kinds of combination.
In preferred solution, above-mentioned thickener is the combination of one kind or two of which in sodium chloride, ammonium chloride and carbomer.
In above-mentioned cleaning product, using PPG-20 methyls ether, PEG-7 glyceryl cocoates, caprylic/capric glycerine
A variety of combination compositions in esters Natrulon H-10 esters, C12-13 alcohol lactate and dimethyl silicone polymer are freeze proof moist
Moisture-keeping composition（Choose PPG-20 methyls ether, PEG-7 glyceryl cocoates, caprylic/capric glyceride type Natrulon H-10
After a variety of in esters, C12-13 alcohol lactate and dimethyl silicone polymer, it is uniformly mixed, you can obtain freeze proof moist moisturizing
Composition）, can applied in cleaning product, making cleaning product that there is Low-temperature antifreeze, moist and moisturizing multi-efficiency at the same time
Significantly prevent cleaning product in winter or some other low temperature environments（Less than 10 DEG C）There is g., jelly-like or the phenomenon of icing, protect
Card cleaning product can normally, preferably use in low temperature environment, have to moisten while clearing skin and hair and protect
The effect of wet, maintain the normal barrier function after skin and hair cleaning.Wherein PPG-20 methyls ether has preferable anti-
Jelly and moisture-keeping function；PEG-7 glyceryl cocoates have preferable freeze proof and moisture-keeping function；Caprylic/capric glyceride is birdsed of the same feather flock together sweet
Oily -10 esters have preferable freeze proof, moist and moisture-keeping function；C12-13 alcohol lactate preferably moistens and moisture-keeping function,
Have the function that to improve product system viscosity at the same time；And dimethyl silicone polymer is a kind of excellent skin and hair conditioner,
There is preferable freeze proof and moisten effect at the same time.Each component synergistic effect, makes cleaning product in freeze proof moist moisture-keeping composition
Freeze proof moist performance of keeping humidity is more excellent, than individually using freeze proof moist moisture-keeping function Jia Gengming caused by any of which
It is aobvious.
In a kind of preferred solution, above-mentioned freeze proof moist moisture-keeping composition is by PEG-7 glyceryl cocoates and PPG-20 methyl
Glucose ether forms, and the part by weight of PEG-7 glyceryl cocoates and PPG-20 methyl ethers is 1:（0.01-0.12）.More
It is preferred that the part by weight of PEG-7 glyceryl cocoates and PPG-20 methyl ethers is 1:0.06.
In another preferred solution, above-mentioned freeze proof moist moisture-keeping composition is by caprylic/capric glyceride type Natrulon H-10
Esters, C12-13 alcohol lactate and PPG-20 methyls ether composition, caprylic/capric glyceride type Natrulon H-10 esters,
The part by weight of C12-13 alcohol lactate and PPG-20 methyl ethers is 12:（0.5-5）:（0.1-0.4）.More preferably sad/
The part by weight of glycerol decanoate class Natrulon H-10 esters, C12-13 alcohol lactate and PPG-20 methyl ethers is 12:1:
0.25。
In another preferred solution, above-mentioned freeze proof moist moisture-keeping composition is by dimethyl silicone polymer and PEG-7 glycerine coconut palms
Oleate forms, and the part by weight of dimethyl silicone polymer and PEG-7 glyceryl cocoates is 2:（0.5-4）.It is more preferably poly-
The part by weight of dimethyl siloxane and PEG-7 glyceryl cocoates is 2:1.
In another preferred solution, above-mentioned freeze proof moist moisture-keeping composition is by caprylic/capric glyceride type Natrulon H-10
Esters, PEG-7 glyceryl cocoates and PPG-20 methyls ether composition, caprylic/capric glyceride type Natrulon H-10 ester
The part by weight of class, PEG-7 glyceryl cocoates and PPG-20 methyl ethers is 2.5:（0.5-5）:（0.1-0.4）.It is more excellent
Select caprylic/capric glyceride type Natrulon H-10 esters, the weight of PEG-7 glyceryl cocoates and PPG-20 methyl ethers
Ratio is 2.5:1:0.25.
In another preferred solution, above-mentioned freeze proof moist moisture-keeping composition is by caprylic/capric glyceride type Natrulon H-10
Esters and PPG-20 methyls ether composition, caprylic/capric glyceride type Natrulon H-10 esters and PPG-20 methyl ethers
Part by weight be 2:（0.5-4）.More preferably caprylic/capric glyceride type Natrulon H-10 esters and PPG-20 methyl ethers
Part by weight be 2:1.
The present invention also provides a kind of preparation method of above-mentioned freeze proof moist moisturizing cleaning product, it is characterised in that including following
Step：By anion surfactant, nonionic surfactant, zwitterionic surfactant, cation opsonizing agent, pearly-lustre
Agent, complexing agent and pH adjusting agent are added in purified water, obtain the first mixed material；Then the first mixed material is stirred
And 70-95 DEG C is heated to, 10-30 minutes then are kept the temperature to the first mixed material in the case of stirring, then by the first mixture
Material is cooled to 40-45 DEG C；Then preservative, anti-corrosion synergist, essence, thickener and freeze proof taste are added into the first mixed material
Moisten moisture-keeping composition, and stir evenly, obtain the freeze proof moist moisturizing cleaning product.
The cleaning product of the present invention has Low-temperature antifreeze and the function of moist moisturizing, and safety, gentle, concrete embodiment concurrently at the same time
：It can significantly prevent cleaning product in winter or some other low temperature environments（Less than 10 DEG C）There is g., jelly-like or icing
Phenomenon, ensures that cleaning product can normally, preferably use in low temperature environment；Have while clearing skin and hair
The effect of moistening moisturizing, maintains the normal barrier function after skin and hair cleaning.The cleaning product of the present invention is suitable for vast
Crowd, the cleaning product particularly suitable as children and infant.
Embodiment
Embodiment 1
The cleaning product of the present embodiment is shower cream.
The freeze proof moist moisturizing cleaning product of the present embodiment contains anion surfactant 11.25% by weight（Its
Middle laureth sodium sulfovinate 11%, laureth sulfosuccinate disodium 0.25%）, nonionic surfactant 3%
（It is coconut oleoyl amine DEA）, amphoteric surfactant 3%（It is dodecanamide propyl hydroxy sulfo lycine）, cationic conditioning
Agent 1.7%（Wherein guar hydroxypropyltrimonium chloride 0.2%, polyquaternium -7 1.5%）, pearling agent 1.2%（It is second
Glycol distearate）, complexing agent 0.1%（It is EDTA disodiums）, pH adjusting agent 0.1%（It is citric acid）, preservative
0.3512%（Wherein DMDM hydantoins 0.2%, methylchloroisothiazandnone 0.0009%, methylisothiazolinone 0.0003%,
Phenmethylol 0.15%）, anti-corrosion synergist 0.0015%（It is Sensiva SC50）, essence 0.3%, thickener 1.3%（It is chlorine
Change sodium）, freeze proof moist moisture-keeping composition 0.53%（Wherein PEG-7 glyceryl cocoates 0.5%, PPG-20 methyl ethers
0.03%）, surplus is purified water.
First, anion surfactant, nonionic surfactant, amphoteric surfactant are equipped with according to the above ratio
, cation opsonizing agent, pearling agent, complexing agent, pH adjusting agent, preservative, anti-corrosion synergist, essence, thickener, freeze proof taste
Moisten moisture-keeping composition and purified water.
Then, freeze proof moist moisturizing cleaning product is prepared according to the following steps：By anion surfactant, non-ionic surface
Activating agent, zwitterionic surfactant, cation opsonizing agent, pearling agent, complexing agent and pH adjusting agent are added in purified water,
Obtain the first mixed material；Then the first mixed material is stirred and is heated to 85 DEG C, it is then right in the case of stirring
First mixed material keeps the temperature 30 minutes, then the first mixed material is cooled to 40 DEG C；Then added into the first mixed material anti-
Rotten agent, anti-corrosion synergist, essence, thickener and freeze proof moist moisture-keeping composition, and stir evenly, obtain the freeze proof moist guarantor
Wet washing product.
Embodiment 2
The present embodiment cleaning product is shampoo used also as bath lotion.
The freeze proof moist moisturizing cleaning product of the present embodiment contains anion surfactant 12% by weight（It is the moon
Laureth sodium sulfovinate）, nonionic surfactant 3.5%（Wherein coconut oleoyl amine DEA 3%, lauryl glucoside
0.5%）, amphoteric surfactant 3%（It is dodecanamide propyl hydroxy sulfo lycine）, cation opsonizing agent 1.7%（It is wherein poly-
Quaternary ammonium salt -10 0.2%, polyquaternium -7 1.5%）, complexing agent 0.1%（It is EDTA disodiums）, pH adjusting agent 0.15%（
For citric acid）, preservative 0.25075%（Wherein DMDM hydantoins 0.1%, methylchloroisothiazandnone 0.0005625%, first
Base isothiazolinone 0.0001875%, phenmethylol 0.15%）, anti-corrosion synergist 0.15%（It is hexylene glycol）, essence 0.3%, increases
Thick dose 2.8%（It is sodium chloride）, freeze proof moist moisture-keeping composition 1.325%（Wherein caprylic/capric glyceride type polyglycereol-
10 esters 1.2%, C12-13 alcohol lactate 0.1%, PPG-20 methyls ether 0.025%）, surplus is purified water.
First, anion surfactant, nonionic surfactant, amphoteric surfactant are equipped with according to the above ratio
, cation opsonizing agent, complexing agent, pH adjusting agent, preservative, anti-corrosion synergist, essence, thickener, freeze proof moist moisturizing group
Compound and purified water.
Then, freeze proof moist moisturizing cleaning product is prepared according to the following steps：By anion surfactant, non-ionic surface
Activating agent, zwitterionic surfactant, cation opsonizing agent, complexing agent and pH adjusting agent are added in purified water, obtain
One mixed material；Then the first mixed material is stirred and is heated to 95 DEG C, it is then mixed to first in the case of stirring
Compound material keeps the temperature 10 minutes, then the first mixed material is cooled to 45 DEG C；Then preservative is added into the first mixed material, is prevented
Rotten synergist, essence, thickener and freeze proof moist moisture-keeping composition, and stir evenly, obtain the freeze proof moist moisturizing washing
Product.
Embodiment 3
The cleaning product of the present embodiment is shampoo.
The freeze proof moist moisturizing cleaning product of the present embodiment contains anion surfactant 12% by weight（Laruyl alcohol
Polyethers sodium sulfovinate 10%, bay alcohol sulfuric ester ammonium 2%）, nonionic surfactant 4.5%（Lauryl glucoside 2%, cocounut oil acyl
Amine DEA 2.5%）, amphoteric surfactant 3%（It is sodium cocoamphoacetate）, cation opsonizing agent 1.2%（Melon
Glue hydroxypropyl-trimethyl ammonium chloride 0.2%, polyquaternium -7 1%）, pearling agent 0.8%（It is glycol distearate）, network
Mixture 0.1%（It is EDTA disodiums）, pH adjusting agent 0.15%（Citric acid 0.1, sodium hydroxide 0.05）, preservative 0.8%
（Wherein Phenoxyethanol 0.2%, phenmethylol 0.2%, sodium benzoate 0.4%）, anti-corrosion synergist 0.002%（It is that ethylhexyl is sweet
Oil）, essence 0.3%, thickener 1.6%（Wherein carbomer 0.2%, sodium chloride 1.4%）, freeze proof moist moisture-keeping composition 1.5%
（Wherein dimethyl silicone polymer 1%, PEG-7 glyceryl cocoates 0.5%）, surplus is purified water.
First, anion surfactant, nonionic surfactant, amphoteric surfactant are equipped with according to the above ratio
, cation opsonizing agent, pearling agent, complexing agent, pH adjusting agent, preservative, anti-corrosion synergist, essence, thickener, freeze proof taste
Moisten moisture-keeping composition and purified water.
Then, freeze proof moist moisturizing cleaning product is prepared according to the following steps：Freeze proof moist moisturizing is prepared according to the following steps to wash
Wash product：By anion surfactant, nonionic surfactant, zwitterionic surfactant, cation opsonizing agent, network
Mixture and pH adjusting agent are added in purified water, obtain the first mixed material；Then the first mixed material is stirred and added
Heat then keeps the temperature 30 minutes, then the first mixed material is cooled to 40 to the first mixed material in the case of stirring to 75 DEG C
℃；Then preservative, anti-corrosion synergist, essence, thickener and freeze proof moist moisture-keeping composition are added into the first mixed material,
And stir evenly, obtain the freeze proof moist moisturizing cleaning product.
Also freeze proof moist moisturizing cleaning product can be prepared according to the following steps：By anion surfactant, non-ionic surface
Activating agent, zwitterionic surfactant, guar hydroxypropyltrimonium chloride, pearling agent, complexing agent and citric acid add
Into purified water, the first mixed material is obtained；Then the first mixed material is stirred and is heated to 75 DEG C, then stirred
In the case of 30 minutes are kept the temperature to the first mixed material, then the first mixed material is cooled to 40 DEG C；Then to the first mixture
Preservative, anti-corrosion synergist, essence, freeze proof moist moisture-keeping composition and carbomer are added in material, and is stirred evenly；Hydrogen is put into again
Sodium oxide molybdena adjusts pH value, then puts into polyquaternium -7 and sodium chloride successively, stirs evenly, obtain the freeze proof moist moisturizing and wash
Wash product.
Embodiment 4
The cleaning product of the present embodiment is shampoo used also as bath lotion
The freeze proof moist moisturizing cleaning product of the present embodiment contains anion surfactant 11% by weight（Wherein laruyl alcohol
Polyethers sodium sulfovinate 10%, laureth sulfosuccinate disodium 1%）, nonionic surfactant 4%（Wherein cocounut oil acyl
Amine DEA 3%, lauryl glucoside 1%）, amphoteric surfactant 3%（It is dodecanamide propyl hydroxy sulfo lycine）, sun
Ion conditioner 1.1%（Wherein Polyquaternium-10 0.1%, polyquaternium -7 1%）, complexing agent 0.1%（It is EDTA bis-
Sodium）, pH adjusting agent 0.25%（It is citric acid）, preservative 0.8%（Wherein phenmethylol 0.2%, sodium benzoate 0.3%, sorb
Sour potassium 0.3%）, anti-corrosion synergist 0.002%（Wherein Sensiva SC50 0.001%, hexylene glycol 0.001%）, essence 0.3%, increases
Thick dose 0.9%（It is sodium chloride）, freeze proof moist moisture-keeping composition 0.75%（Wherein caprylic/capric glyceride type Natrulon H-10
Esters 0.5, PEG-7 glyceryl cocoates 0.2, PPG-20 methyls ether 0.05）, surplus is purified water.
First, anion surfactant, nonionic surfactant, amphoteric surfactant are equipped with according to the above ratio
, cation opsonizing agent, complexing agent, pH adjusting agent, preservative, anti-corrosion synergist, essence, thickener, freeze proof moist moisturizing group
Compound and purified water.
Then, freeze proof moist moisturizing cleaning product is prepared according to the following steps：By anion surfactant, non-ionic surface
Activating agent, zwitterionic surfactant, cation opsonizing agent, complexing agent and pH adjusting agent are added in purified water, obtain
One mixed material；Then the first mixed material is stirred and is heated to 85 DEG C, it is then mixed to first in the case of stirring
Compound material keeps the temperature 20 minutes, then the first mixed material is cooled to 40 DEG C；Then preservative is added into the first mixed material, is prevented
Rotten synergist, essence, thickener and freeze proof moist moisture-keeping composition, and stir evenly, obtain the freeze proof moist moisturizing washing
Product.
Embodiment 5
The cleaning product of the present embodiment is hand cleanser.
The freeze proof moist moisturizing cleaning product of the present embodiment contains anion surfactant 9% by weight（The wherein moon
Laureth sodium sulfovinate 8%, laureth sulfosuccinate disodium 1%）, nonionic surfactant 2.5%（It is coconut palm
Oleamide DEA）, amphoteric surfactant 3%（It is dodecanamide propyl hydroxy sulfo lycine）, cation opsonizing agent
0.02%（It is Polyquaternium-10）, complexing agent 0.1%（It is EDTA disodiums）, pH adjusting agent 0.05%（It is lemon
Acid）, preservative 0.30075%（Wherein DMDM hydantoins 0.1%, methylchloroisothiazandnone 0.0005625%, the different thiophene of methyl
Oxazoline ketone 0.0001875%, phenmethylol 0.2%）, anti-corrosion synergist 0.002%（It is ethohexadiol）, essence 0.15%, thickener
1.6%（It is sodium chloride）, freeze proof moist moisture-keeping composition 0.15%（Wherein caprylic/capric glyceride type Natrulon H-10 esters
0.1%, PPG-20 methyl ether 0.05%）, surplus is purified water.
First, anion surfactant, nonionic surfactant, amphoteric surfactant are equipped with according to the above ratio
, cation opsonizing agent, complexing agent, pH adjusting agent, preservative, anti-corrosion synergist, essence, thickener, freeze proof moist moisturizing group
Compound and purified water.
Then, freeze proof moist moisturizing cleaning product is prepared according to the following steps：By anion surfactant, non-ionic surface
Activating agent, zwitterionic surfactant, cation opsonizing agent, complexing agent and pH adjusting agent are added in purified water, obtain
One mixed material；Then the first mixed material is stirred and is heated to 80 DEG C, it is then mixed to first in the case of stirring
Compound material keeps the temperature 25 minutes, then the first mixed material is cooled to 40 DEG C；Then preservative is added into the first mixed material, is prevented
Rotten synergist, essence, thickener and freeze proof moist moisture-keeping composition, and stir evenly, obtain the freeze proof moist moisturizing washing
Product.
Comparative example
The cleaning product of comparative example（Shampoo used also as bath lotion）Contain guar hydroxypropyltrimonium chloride 0.2%, bay by weight
Alcohol polyethers sulfosuccinate disodium 0.25%, glycol distearate 1.2%, laureth sodium sulfovinate 11%, cocounut oil acyl
Amine DEA 3%, dodecanamide propyl hydroxy sulfo lycine 3%, polyquaternium -7 1.5%, citric acid 0.1%, DMDM hydantoins
0.2%, methylchloroisothiazandnone 0.0009%, methylisothiazolinone 0.0003%, phenmethylol 0.15%, Sensiva SC50
0.0015%, essence 0.3%, sodium chloride 1.3%, surplus is purified water.After being equipped with raw material in proportion, by melon glue hydroxypropyl trimethylammonium
Ammonium chloride, laureth sulfosuccinate disodium, glycol distearate, laureth sodium sulfovinate, cocounut oil
In acid amides DEA, dodecanamide propyl hydroxy sulfo lycine, polyquaternium -7, citric acid input purified water, 90 are heated with stirring to
DEG C it is allowed to be completely dissolved, insulated and stirred 30 minutes；40 DEG C are cooled to, then puts into DMDM hydantoins, methyl chloride isothiazoline
Ketone, methylisothiazolinone, phenmethylol, Sensiva SC50, essence, sodium chloride, stir evenly, and obtain the cleaning product
Shampoo used also as bath lotion.
It is the performance test and test effect to the cleaning product of above-described embodiment 1-5 and comparative example below：
First, viscosity test
Table 1 is the detection knot to the viscosity at different temperatures of cleaning product made from embodiment 1-5 with NDJ-1 rotary viscosimeters
Fruit.
Table 1
The testing result of table 1 shows：The cleaning product shampoo used also as bath lotion of comparative example（Control group）In 0~10 DEG C of low temperature ring of low temperature
Viscosity is both greater than 30000Mpa.S substantially under border, and all g., jelly-like phenomenon occurs, and mobility is very poor, and lotion does not glue glass substantially
Glass cup and glass bar, can not Pick Wire；And the present invention 1 shower cream of cleaning product embodiment, 2 shampoo used also as bath lotion of embodiment, implement
Viscosity is substantially all under the low temperature environment of 0~10 DEG C of low temperature for 3 shampoo of example, 4 shampoo used also as bath lotion of embodiment and 5 hand cleanser of embodiment
Less than 15000Mpa.S, there is not g., jelly-like or icing phenomenon, the cleaning product that its anti-freezing property is substantially better than comparative example is washed
Send out shower cream.
2nd, skin tight feeling and moisture of skin experiment
30 healthy volunteers are organized, select a piece of intact region in its human arm respectively, take 3g samples to go cleaning should
Region, the tight feeling for the skin after twenty minutes of then testing and assessing, and 4 it is small when inner skin water regime and take its average value.Inspection
The result of survey is as shown in table 2 and table 4.
Table 2
Table 3
| Grade | Symbol | Standard of perfection |
| 0 | - | There is no tight feeling |
| 1 | ± | Indistinctly there is tight feeling |
| 2 | + | There is slight tight feeling |
| 3 | ++ | There is obvious tight feeling, there is slight gargalesthesia |
| 4 | +++ | Serious tight feeling, hence it is evident that trace gargalesthesia, rubefaction |
Table 4
The evaluating result of table 2 shows：Embodiment 1, embodiment 2, embodiment 3, the cleaning product of embodiment 4 and embodiment 5 use
Skin does not have tight feeling completely after twenty minutes；And the cleaning product shampoo used also as bath lotion of comparative example is substantially felt using skin after twenty minutes
Feel tight feeling and slight gargalesthesia.The cleaning product shower cream of this explanation embodiment 1, the cleaning product hair washing of embodiment 2 are washed one's hair
Bath lotion, the cleaning product shampoo of embodiment 3, the cleaning product of the cleaning product shampoo used also as bath lotion of embodiment 4 and embodiment 5
The moist degree of hand cleanser, will be substantially better than the shampoo used also as bath lotion of comparative example.
The test result of table 4 shows：The cleaning product shower cream of embodiment 1, the cleaning product hair washing of embodiment 2 are taken a shower
The cleaning product of dew, the cleaning product shampoo of embodiment 3, the cleaning product shampoo used also as bath lotion of embodiment 4 and embodiment 5 is washed
After hand liquid cleans on the skin, the moisture that skin measures respectively after 0.5h, 1h, 2h, 3h, 4h is all considerably higher than contrast
The cleaning product shampoo used also as bath lotion of example.The cleaning product shower cream of this explanation embodiment 1, the cleaning product hair washing of embodiment 2 are washed one's hair
Bath lotion, the cleaning product shampoo of embodiment 3, the cleaning product of the cleaning product shampoo used also as bath lotion of embodiment 4 and embodiment 5
Hand cleanser, its moisture retention will be apparently higher than the shampoo used also as bath lotion of comparative example.
Claims (10)
1. a kind of freeze proof moist moisturizing cleaning product, it is characterised in that by weight containing anion surfactant 0.1-
25%, nonionic surfactant 0.01-10%, amphoteric surfactant 0.1-10%, cation opsonizing agent 0.01-3%, pearl
Photo etching 0-3%, complexing agent 0.01-1%, pH adjusting agent 0.01-0.5%, preservative 0.0001-1%, anti-corrosion synergist
0.001-0.3%, essence 0.01-0.5%, thickener 0.01-3%, freeze proof moist moisture-keeping composition 0.001-4%, surplus is pure
Change water；The freeze proof moist moisture-keeping composition is that PPG-20 methyls ether, PEG-7 glyceryl cocoates, caprylic/capric are sweet
A variety of combinations in grease class Natrulon H-10 esters, C12-13 alcohol lactate and dimethyl silicone polymer.
2. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The anionic surface work agent is the moon
In laureth sodium sulfovinate, laureth sulfosuccinate disodium, bay alcohol sulfuric ester ammonium and laruyl alcohol sodium sulfovinate
One kind or many of combination；The non-ionic surfactant is coconut oleoyl amine DEA, coconut oleoyl amine MEA, PEG-150
One kind or many of combination in distearate and lauryl glucoside；Amphoteric surface's work agent is lauramide third
The group of one kind or two of which in base hydroxy sulfo lycine, Cocoamidopropyl betaine and sodium cocoamphoacetate
Close.
3. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The cation opsonizing agent is poly- season
The combination of one kind or two of which in ammonium salt -7, Polyquaternium-10 and guar hydroxypropyltrimonium chloride.
4. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The pearling agent is that ethylene glycol two is hard
The combination of one kind or two of which in resin acid ester, ethylene glycol monostearate and mica；The complexing agent is ethylenediamine tetrem
The combination of one or both of acid disodium and tetrasodium ethylenediamine tetraacetate；The pH adjusting agent is citric acid, lactic acid, amber
One kind or many of combination in acid, anisic acid, sodium hydroxide, potassium hydroxide and triethanolamine；The preservative is benzene
Oxyethanol, phenmethylol, sodium benzoate, potassium sorbate, DMDM hydantoins, methylchloroisothiazandnone and methylisothiozoline
One kind or many of combination in ketone；The preservative synergist is in Sensiva SC50, hexylene glycol and ethohexadiol
A kind of or two of which combination；The thickener is the group of one kind or two of which in sodium chloride, ammonium chloride and carbomer
Close.
5. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The freeze proof moist moisture-keeping composition
It is made of PEG-7 glyceryl cocoates and PPG-20 methyl ethers, PEG-7 glyceryl cocoates and PPG-20 methyl Portugal
The part by weight of sugar ether is 1:（0.01-0.12）.
6. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The freeze proof moist moisture-keeping composition
It is made of caprylic/capric glyceride type Natrulon H-10 esters, C12-13 alcohol lactate and PPG-20 methyl ethers, octanoic acid/
The part by weight of glycerol decanoate class Natrulon H-10 esters, C12-13 alcohol lactate and PPG-20 methyl ethers is 12:
（0.5-5）:（0.1-0.4）.
7. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The freeze proof moist moisture-keeping composition
It is made of dimethyl silicone polymer and PEG-7 glyceryl cocoates, dimethyl silicone polymer and PEG-7 glyceryl cocoates
Part by weight is 2:（0.5-4）.
8. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The freeze proof moist moisture-keeping composition
It is made of caprylic/capric glyceride type Natrulon H-10 esters, PEG-7 glyceryl cocoates and PPG-20 methyl ethers, it is pungent
The part by weight of acid/glycerol decanoate class Natrulon H-10 esters, PEG-7 glyceryl cocoates and PPG-20 methyl ethers
For 2.5:（0.5-5）:（0.1-0.4）.
9. freeze proof moist moisturizing cleaning product according to claim 1, it is characterized in that：The freeze proof moist moisture-keeping composition
It is made of caprylic/capric glyceride type Natrulon H-10 esters and PPG-20 methyl ethers, caprylic/capric glyceride is birdsed of the same feather flock together sweet
The part by weight of oily -10 esters and PPG-20 methyl ethers is 2:（0.5-4）.
10. the preparation method of the freeze proof moist moisturizing cleaning product described in claim 1, it is characterised in that comprise the following steps：
By anion surfactant, nonionic surfactant, zwitterionic surfactant, cation opsonizing agent, pearling agent, network
Mixture and pH adjusting agent are added in purified water, obtain the first mixed material；Then the first mixed material is stirred and added
Heat then keeps the temperature 10-30 minutes to the first mixed material in the case of stirring to 70-95 DEG C, then the first mixed material is dropped
Temperature is to 40-45 DEG C；Then preservative, anti-corrosion synergist, essence, thickener and freeze proof moist guarantor are added into the first mixed material
Wet composition, and stir evenly, obtain the freeze proof moist moisturizing cleaning product.
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| CN113556939A (en) * | 2018-12-27 | 2021-10-26 | 3M创新有限公司 | Antimicrobial compositions with 1, 2-alkanediols |
| CN109652233A (en) * | 2019-01-25 | 2019-04-19 | 广州二广生物科技有限公司 | Cosmetic applicators detergent and preparation method thereof |
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| CN111568786A (en) * | 2020-06-24 | 2020-08-25 | 广州美兮生物科技有限公司 | Concentrated hand sanitizer and preparation method and use method thereof |
| CN111991271A (en) * | 2020-09-17 | 2020-11-27 | 佛山市南海区桂城埃菲尔化妆品有限公司 | Gilding bath cream and preparation method thereof |
| CN112336671A (en) * | 2020-11-20 | 2021-02-09 | 山东消博士消毒科技股份有限公司 | Skin-care disinfectant and preparation method thereof |
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| CN112516007B (en) * | 2020-12-15 | 2023-05-05 | 上海家化联合股份有限公司 | Cleaning composition |
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Application publication date: 20180504 |