CN107970478A - A kind of solid air freshening agent - Google Patents

A kind of solid air freshening agent Download PDF

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Publication number
CN107970478A
CN107970478A CN201711108287.XA CN201711108287A CN107970478A CN 107970478 A CN107970478 A CN 107970478A CN 201711108287 A CN201711108287 A CN 201711108287A CN 107970478 A CN107970478 A CN 107970478A
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parts
air freshening
solid air
freshening agent
agent according
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丁玉琴
殷磊
陈水
陈一水
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/012Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/96Regeneration, reactivation or recycling of reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/50Inorganic acids
    • B01D2251/502Hydrochloric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/602Oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/12Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/22Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Sustainable Development (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of solid air freshening agent, belong to household chemicals technical field.The present invention by 20~30 parts of mass fractions be 8~10% ferric chloride solution, 3~5 parts of bacteria celluloses, 5~6 parts of carbomers, 5~6 parts of fungicide, 5~6 parts of thickeners, 5~6 portions of preservatives, the polyethylenimine solution that 20~30 parts of mass fractions are 30~50%, 5~6 parts of emulsifying agents, 40~50 parts of agar solutions and 40~50 parts of water are placed in single-necked flask, and digital display tests the speed in constant temperature blender with magnetic force finally by single-necked flask, in temperature be 60~70 DEG C, under the conditions of rotating speed is 400~500r/min, heating stirring mixes, obtain mixture, releasing agent is sprayed into mould, mixture is poured into mould while hot again, it is then cooled to room temperature, the demoulding, up to solid air freshening agent.Solid air freshening agent provided by the invention has the function that well to remove formaldehyde and toluene.

Description

A kind of solid air freshening agent
Technical field
The invention discloses a kind of solid air freshening agent, belong to household chemicals technical field.
Background technology
Modern society, work rhythm is fast, dog-eat-dog, and for people to the environment for working and living, space and air quality will Ask higher and higher, the development of air freshener is exactly to meet people to having comfortable work and living environment, clean pure and fresh The needs of air and have developed.At present, not only product is single for the most of air fresheners of in the market, and yield is few, and can see To product be aerial fog type fluid product by iron flask filling mostly, there is many problems, and it is inconvenient such as to carry, and when use pierces Sharp property smell is dense, and fragrance is uneven, and the duration is short;The processing difficulties of iron flask box are packed, general enterprises are difficult to bear, and invest Greatly, production cost is high;Product is more containing non-active ingredients, may pollute etc.;These problems are unfavorable for the popularization and application of product.Gu Body air freshener, can effectively overcome the shortcomings of aerial fog type air freshener, have been to be concerned by more and more people, the market demand Amount increase is quickly.The basic preparation principle of solid air freshening agent is:By essence, deodorant and disinfection sanitizer and water, thickening The components such as agent, preservative, emulsifying agent mix, and water forms solid colloidal thing with thickener, this jelly is by essence, deodorant and kills Bacterium disinfectant contains wherein, and when solid colloidal thing is put in atmosphere, with the volatilization of wherein moisture, volume slowly reduces, Essence, deodorant and disinfection sanitizer are also slowly dispersed into air, so as to achieve the purpose that to make air fragrant, pure and fresh.Remove Outside this, traditional air freshener simply covers the stink in air mostly, and the harmful components in air are not purified Effect, while harmful components loss in atmosphere, exacerbates the degree of danger of room air in air freshener, and fit up residual The carcinogens such as the indoor formaldehyde and toluene that stay are also the big problem that annoying people, especially prominent in harm indoors, If the harmful substances such as formaldehyde in air toluene can be purified while fresh air, certainly will can promote air freshener to More comprehensive direction is developed.
Therefore, it is the shortcomings that how improving conventional air cleaning agent clean-up effect and bad bactericidal effect, comprehensive to obtain higher The air freshener of performance is closed, is that it is promoted and applies, meets industrial production demand urgent problem to be solved.
The content of the invention
The present invention solves the technical problem of:It is bad for conventional air cleaning agent clean-up effect and bactericidal effect A kind of shortcoming, there is provided solid air freshening agent.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of solid air freshening agent, is made of the raw material of following parts by weight:
20~30 parts of ferric chloride solution
3~5 parts of bacteria cellulose
5~6 parts of carbomer
5~6 parts of fungicide
5~6 parts of thickener
5~6 parts of preservative
20~30 parts of polyethylenimine solution
5~6 parts of emulsifying agent
40~50 parts of agar solution
40~50 parts of water
The carbomer is any one in CARBOPOL 971 NF, CARBOPOL 974P NF or carbomer940 NF.
The fungicide is carbendazim, thiophanate-methyl, metalaxyl, triazolone, olefin conversion, benzene miaow methyl cyclic-azole, propiconazole, Any one in Fluoxastrobin, kresoxim-methyl, Propamocarb, dimethomorph, cymoxanil or pyrimethanil.
The thickener is polyacrylamide, and polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, paraffin resin, gathers Acrylic acid, Polyacrylate Emulsion, butadiene rubber, butadiene-styrene rubber, polyurethane, polyureas, low-molecular polyethylene wax, methyl are fine Dimension is plain, hydroxypropyl methyl cellulose, any one or more mixture in sodium carboxymethylcellulose and hydroxyethyl cellulose.
The preservative is protamine, propolis, allicin, sodium Diacetate, sodium lactate, propylparaben, lactic acid Any one in streptostacin or hydrogen peroxide.
The emulsifying agent is lecithin, any one in monoglyceride or diglyceride.
The preparation process of the agar solution is:By agar and water in mass ratio 1:50~1:After 100 mixing swellings, heating is stirred Dissolving is mixed, up to agar solution.
The beneficial effects of the invention are as follows:
(1)The present invention by add add iron chloride, first, iron chloride can with adsorb into system in formaldehyde react, generate Carbon dioxide, oxygen, frerrous chloride and hydrochloric acid, play the role of well removing formaldehyde, then, react the carbon dioxide energy of generation Enough and polyethyleneimine reacts, and interacting between the product electric charge of generation spontaneously forms tridimensional network, enhances whole body The consistency of system, avoids external microbe from entering in system and causes solid air freshening agent corrupt, meanwhile, it will can adsorb into system In benzene fix, play the role of well removing benzene, secondly, generate the easy oxidation by air of frerrous chloride, generate iron chloride again, It can be recycled, extend solid air freshening agent service life, again, the hydrochloric acid of generation is evaporate into air, and there is sterilization to make With, and a small amount of hydrochloric acid is harmless, in addition, iron ion can promote agar to be crosslinked in system, forms three-dimensional network, further increases The strong consistency of whole system, avoids external microbe from entering in system and causes solid air freshening agent corrupt;
(2)For the present invention by adding bacteria cellulose, bacteria cellulose contains opsonigenous substance, the oxygen in opsonigenous substance Change enzyme decomposable asymmetric choice net to adsorb into the toluene in system, effectively remove indoor toluene, meanwhile, the iron ion in system can lift oxygen Change the activity of enzyme, the effect that solid air freshening agent decomposes toluene is further enhanced, in addition, bacteria cellulose can be with polyethyleneimine Strong hydrogen bond action is formed between amine, avoid polyethyleneimine by it is water-soluble go out, and it is uniformly distributed in bacteria cellulose net In network, so as to allow bacteria cellulose to be evenly distributed in system, play the role of preferably removing indoor toluene.
Embodiment
By agar and water in mass ratio 1:50~1:100 add in beaker, after being stirred 20~30min with glass bar, Stand 3~4h of swelling, then beaker immigration digital display tested the speed constant temperature blender with magnetic force, in temperature be 95~100 DEG C, rotating speed 400 Under the conditions of~500r/min, heating stirring dissolves 40~50min, up to agar solution;Count in parts by weight, by 20~30 parts of quality Fraction is 8~10% ferric chloride solution, and 3~5 parts of bacteria celluloses, 5~6 parts of carbomers, 5~6 parts of fungicide, 5~6 parts increase Thick dose, 5~6 portions of preservatives, the polyethylenimine solution that 20~30 parts of mass fractions are 30~50%, 5~6 parts of emulsifying agents, 40~ 50 parts of agar solutions and 40~50 parts of water are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed constant temperature blender with magnetic force In, it is 60~70 DEG C in temperature, under the conditions of rotating speed is 400~500r/min, heating stirring mixing, obtains mixture, into mould Releasing agent is sprayed, then mixture is poured into mould while hot, is then cooled to room temperature, is demoulded, up to solid air freshening agent.Institute It is any one in CARBOPOL 971 NF, CARBOPOL 974P NF or carbomer940 NF to state carbomer.The fungicide is Carbendazim, thiophanate-methyl, metalaxyl, triazolone, olefin conversion, benzene miaow methyl cyclic-azole, propiconazole, Fluoxastrobin, kresoxim-methyl, downy mildew Any one in prestige, dimethomorph, cymoxanil or pyrimethanil.The thickener is polyacrylamide, polyvinyl alcohol, polyethylene Pyrrolidones, polyethylene glycol oxide, paraffin resin, polyacrylic acid, Polyacrylate Emulsion, butadiene rubber, butadiene-styrene rubber, gathers Urethane, polyureas, low-molecular polyethylene wax, methylcellulose, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose and ethoxy are fine Any one or more mixture in dimension element.The preservative is protamine, propolis, allicin, sodium Diacetate, sodium lactate, Any one in propylparaben, nisin or hydrogen peroxide.The emulsifying agent is lecithin, single glycerine Any one in ester or diglyceride.The releasing agent is rose ethereal oil, any in jasmine essential oil or camellia essential oil It is a kind of.
Example 1
By agar and water in mass ratio 1:100 add in beaker, after being stirred 30min with glass bar, stand swelling 4h, then will Beaker moves into digital display and tests the speed constant temperature blender with magnetic force, is 100 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring is molten 50min is solved, up to agar solution;Count in parts by weight, by the ferric chloride solution that 30 parts of mass fractions are 10%, 5 parts of bacterial fibers Element, 6 parts of carbomers, 6 parts of fungicide, 6 parts of thickeners, 6 portions of preservatives, the polyethylenimine solution that 30 parts of mass fractions are 50%, 6 parts of emulsifying agents, 50 parts of agar solutions and 50 parts of water are placed in single-necked flask, and single-necked flask is placed in the digital display constant temperature magnetic force that tests the speed and is stirred Mix in device, be 70 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring mixing obtains mixture, is sprayed into mould de- Mould agent, then mixture is poured into mould while hot, room temperature is then cooled to, is demoulded, up to solid air freshening agent.The card ripple Nurse is CARBOPOL 971 NF.The fungicide is carbendazim.The thickener is polyacrylamide.The preservative is smart egg In vain.The emulsifying agent is phosphatide.The releasing agent is rose ethereal oil.
Example 2
By agar and water in mass ratio 1:100 add in beaker, after being stirred 30min with glass bar, stand swelling 4h, then will Beaker moves into digital display and tests the speed constant temperature blender with magnetic force, is 100 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring is molten 50min is solved, up to agar solution;Count in parts by weight, by 5 parts of bacteria celluloses, 6 parts of carbomers, 6 parts of fungicide, 6 parts of thickenings Agent, 6 portions of preservatives, the polyethylenimine solution that 30 parts of mass fractions are 50%, 6 parts of emulsifying agents, 50 parts of agar solutions and 50 parts of water are put In single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, be 70 DEG C in temperature, rotating speed is Under the conditions of 500r/min, heating stirring mixing, obtains mixture, releasing agent is sprayed into mould, then mixture is poured into mould while hot In tool, room temperature is then cooled to, is demoulded, up to solid air freshening agent.The carbomer is CARBOPOL 971 NF.It is described to kill Microbial inoculum is carbendazim.The thickener is polyacrylamide.The preservative is protamine.The emulsifying agent is phosphatide.It is described Releasing agent is rose ethereal oil.
Example 3
By agar and water in mass ratio 1:100 add in beaker, after being stirred 30min with glass bar, stand swelling 4h, then will Beaker moves into digital display and tests the speed constant temperature blender with magnetic force, is 100 DEG C in temperature, under the conditions of rotating speed is 500r/min, heating stirring is molten 50min is solved, up to agar solution;Count in parts by weight, by 30 parts of mass fractions be 10% ferric chloride solution, 6 parts of carbomers, 6 parts Fungicide, 6 parts of thickeners, 6 portions of preservatives, the polyethylenimine solution that 30 parts of mass fractions are 50%, 6 parts of emulsifying agents, 50 parts of fine jades Fat liquid and 50 parts of water are placed in single-necked flask, and single-necked flask is placed in digital display and is tested the speed in constant temperature blender with magnetic force, are in temperature 70 DEG C, under the conditions of rotating speed is 500r/min, heating stirring mixing, obtains mixture, sprays releasing agent into mould, then by mixture Pour into while hot in mould, be then cooled to room temperature, demould, up to solid air freshening agent.The carbomer is CARBOPOL 971 NF.The fungicide is carbendazim.The thickener is polyacrylamide.The preservative is protamine.The emulsifying agent is Phosphatide.The releasing agent is rose ethereal oil.
Comparative example:The solid air freshening agent of Shanghai bio tech ltd production.
The solid air freshening agent of the gained of example 1 to 3 and comparative example product are subjected to performance detection, specific detection method is such as Under:
1. clean-up effect:According to JC/T 1074 and with GB/T 18883 to test specimen except formaldehyde and toluene effect are detected, and press According to(1)Calculate 24h purification efficiencies;
Purification efficiency(Nt)=(C0-Ct)/C0×100% (1)
Wherein:NtFor purification efficiency, %;C0For initial concentration, mg/m3;CtFor instantaneous concentration, that is, test formaldehyde at different moments or Toluene concentration;T is to test test specimen, h;
2. bactericidal effect:Test specimen bactericidal effect is detected according to QB/T 4956.
Specific testing result is as shown in table 1:
Table 1
From 1 testing result of table, solid air freshening agent prepared by technical solution of the present invention has bactericidal effect and to air The characteristics of clean-up effect, the harmful components in can effectively purifying air while bacterium in removing air are net in air Have broad prospects in the development of agent industry.

Claims (6)

  1. A kind of 1. solid air freshening agent, it is characterised in that:It is made of the raw material of following parts by weight:
    20~30 parts of ferric chloride solution
    3~5 parts of bacteria cellulose
    5~6 parts of carbomer
    5~6 parts of fungicide
    5~6 parts of thickener
    5~6 parts of preservative
    20~30 parts of polyethylenimine solution
    5~6 parts of emulsifying agent
    40~50 parts of agar solution
    40~50 parts of water
    A kind of solid air freshening agent according to claim 1, it is characterised in that:The carbomer is CARBOPOL 971 NF, Any one in CARBOPOL 974P NF or carbomer940 NF.
  2. A kind of 2. solid air freshening agent according to claim 1, it is characterised in that:The fungicide is carbendazim, methyl Thiophanate, metalaxyl, triazolone, olefin conversion, benzene miaow methyl cyclic-azole, propiconazole, Fluoxastrobin, kresoxim-methyl, Propamocarb, dimethomorph, Any one or more mixture in cymoxanil and pyrimethanil.
  3. A kind of 3. solid air freshening agent according to claim 1, it is characterised in that:The thickener is polyacrylamide, Polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, paraffin resin, carbomer, polyacrylic acid, polyacrylate copolymerization Lotion, butadiene rubber, butadiene-styrene rubber, polyurethane, polyureas, low-molecular polyethylene wax, methylcellulose, hydroxypropyl methyl fiber Any one in element, sodium carboxymethylcellulose or hydroxyethyl cellulose.
  4. A kind of 4. solid air freshening agent according to claim 1, it is characterised in that:The preservative is protamine, propolis, Any one in allicin, sodium Diacetate, sodium lactate, propylparaben, nisin or hydrogen peroxide.
  5. A kind of 5. solid air freshening agent according to claim 1, it is characterised in that:The emulsifying agent is lecithin, single sweet Any one in grease or diglyceride.
  6. A kind of 6. solid air freshening agent according to claim 1, it is characterised in that:The preparation process of the agar solution is: By agar and water in mass ratio 1:50~1:After 100 mixing swellings, heating stirring dissolving, up to agar solution.
CN201711108287.XA 2017-11-11 2017-11-11 A kind of solid air freshening agent Pending CN107970478A (en)

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CN103604864A (en) * 2013-10-25 2014-02-26 中国电子科技集团公司第三十八研究所 Surface acoustic wave formaldehyde gas sensor based on electric conduction composite sensitive material
CN104073059A (en) * 2014-01-26 2014-10-01 王勇 Thermal disappearing ink
CN105980537A (en) * 2014-02-04 2016-09-28 宝洁公司 Long lasting freshening compositions
CN106729862A (en) * 2016-12-09 2017-05-31 江门市和馨香精技术有限公司 A kind of emulsifying purification of air gel and preparation method thereof
CN107206117A (en) * 2015-02-04 2017-09-26 日本瑞翁株式会社 Deodorant and its manufacture method

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0774264A1 (en) * 1995-11-20 1997-05-21 Espo, Ltd. Air purifying agent and air purifying method
US6019963A (en) * 1998-11-20 2000-02-01 D.S.C. Products, Inc. Deodorizing composition containing tea tree and eucalyptus oils
JP2005520004A (en) * 2002-03-13 2005-07-07 フイルメニツヒ ソシエテ アノニム Gel composition for diffusion device
CN101460056A (en) * 2006-03-30 2009-06-17 拜尔农作物科学股份公司 Active substance combinations with insecticidal properties
CN102028046A (en) * 2009-09-29 2011-04-27 日清奥利友集团株式会社 Method for manufacturing edible oil
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