CN107954693A - A kind of refractory ceramics metallic composite - Google Patents

A kind of refractory ceramics metallic composite Download PDF

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Publication number
CN107954693A
CN107954693A CN201711188517.8A CN201711188517A CN107954693A CN 107954693 A CN107954693 A CN 107954693A CN 201711188517 A CN201711188517 A CN 201711188517A CN 107954693 A CN107954693 A CN 107954693A
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weight
parts
refractory ceramics
metallic composite
clay
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王云荣
关剑轩
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Guilin Yanshan District Youth Activity Center
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Guilin Yanshan District Youth Activity Center
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    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C04B2235/3212Calcium phosphates, e.g. hydroxyapatite
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    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
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    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • C04B2235/402Aluminium
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Abstract

A kind of refractory ceramics metallic composite, includes the raw material of parts by weight:70 90 parts by weight of clay, 10 15 parts by weight of barite, 13 18 parts by weight of zirconium dioxide, 8 17 parts by weight of volcanic rock, 35 55 parts by weight of zircon, 24 26 parts by weight of silica flour, 13 parts by weight of tricalcium phosphate, 2.5 3.6 parts by weight of copper, 0.9 2.7 parts by weight of cobalt, 8 11 parts by weight of aluminium.The invention has the advantages that on the basis of existing technology, there is provided a kind of refractory ceramics metallic composite.

Description

A kind of refractory ceramics metallic composite
Technical field
The present invention relates to Material Field, specifically, is related to a kind of refractory ceramics metallic composite.
Background technology
Ceramics are by clay, quartz sand and other inorganic non-metallic raw materials, through dispensing, ball milling, powder processed, shaping, sintering Etc. the tabular or block elements of technique productions, it is widely used in decoration and protection building, the metope of structures and ground.With Real estate develops rapidly so that the production and consumption of ceramic tile is all got a larger development, while will to the performance of ceramics Ask also higher and higher.But intensity is low mostly for ceramics currently on the market, not hard enough, frangible, usability is poor, can not meet city Field demand.
Thus, how to obtain a kind of refractory ceramics metallic composite is current china industry urgent problem.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of refractory ceramics metallic composite.
The technical solution that the present invention solves above-mentioned technical problem is as follows:
A kind of refractory ceramics metallic composite, includes the raw material of parts by weight:Clay 70-90 parts by weight, barite 10- 15 parts by weight, zirconium dioxide 13-18 parts by weight, volcanic rock 8-17 parts by weight, zircon 35-55 parts by weight, silica flour 24-26 weight Part, tricalcium phosphate 1-3 parts by weight, copper 2.5-3.6 parts by weight, cobalt 0.9-2.7 parts by weight, aluminium 8-11 parts by weight.
The beneficial effects of the invention are as follows:On the basis of existing technology, there is provided a kind of refractory ceramics metallic composite.
Based on the above technical solutions, the present invention can also be improved as follows:
Further, it includes the raw material of parts by weight:70 parts by weight of clay, 10 parts by weight of barite, 13 weight of zirconium dioxide Part, 8 parts by weight of volcanic rock, 35 parts by weight of zircon, 24 parts by weight of silica flour, 1 parts by weight of tricalcium phosphate, 2.5 parts by weight of copper, cobalt 0.9 parts by weight, 8 parts by weight of aluminium.
Further, it includes the raw material of parts by weight:90 parts by weight of clay, 15 parts by weight of barite, 18 weight of zirconium dioxide Part, 17 parts by weight of volcanic rock, 55 parts by weight of zircon, 26 parts by weight of silica flour, 3 parts by weight of tricalcium phosphate, 3.6 parts by weight of copper, cobalt 2.7 parts by weight, 11 parts by weight of aluminium.
Further, it includes the raw material of parts by weight:80 parts by weight of clay, 12 parts by weight of barite, 15 weight of zirconium dioxide Part, 13 parts by weight of volcanic rock, 42 parts by weight of zircon, 25 parts by weight of silica flour, 2.3 parts by weight of tricalcium phosphate, 3.2 parts by weight of copper, 1.9 parts by weight of cobalt, 9 parts by weight of aluminium.
Further, its production method includes:
(1) raw material is weighed in mass ratio, is uniformly mixed, is crushed, wet ball grinding 5-10h, and 150-200 mesh sieves are crossed after drying, It is stand-by;
(2) the waterglass mixing 20- that quality is mixture weight 2-4% will be added in powder made from above-mentioned steps (1) 30min, stands 10-15h, the solid content of the waterglass is 35%;
(3) by step (2) be uniformly mixed powder be sent to forming machine under 60-80MPa it is compressing, then will suppress Adobe send into dry kiln it is dry to the dry body that water content is 3-5%;
(4) dry body is warming up to 1160-1220 DEG C with the speed of 5-10 DEG C/min, keeps the temperature 2-3h, then with 10-15 DEG C/min Speed be cooled to 750-850 DEG C, keep the temperature 0.5-1h, be cooled to room temperature, got product through edging, packaging.
Embodiment
The principle of the present invention and feature are described with reference to embodiments, the given examples are served only to explain the present invention, It is not intended to limit the scope of the present invention.
Embodiment 1
A kind of refractory ceramics metallic composite, includes the raw material of parts by weight:70 parts by weight of clay, 10 weight of barite Part, 13 parts by weight of zirconium dioxide, 8 parts by weight of volcanic rock, 35 parts by weight of zircon, 24 parts by weight of silica flour, 1 weight of tricalcium phosphate Part, 2.5 parts by weight of copper, 0.9 parts by weight of cobalt, 8 parts by weight of aluminium.
Its production method includes:
(1) raw material is weighed in mass ratio, is uniformly mixed, is crushed, wet ball grinding 5h, and 150 mesh sieves are crossed after drying, it is stand-by;
(2) the waterglass mixing 20min that quality is mixture weight 2% will be added in powder made from above-mentioned steps (1), 10h is stood, the solid content of the waterglass is 35%;
(3) by the powder that step (2) is uniformly mixed be sent to forming machine under 60MPa it is compressing, then will suppress Adobe is sent into dry kiln dry to the dry body that water content is 3%;
(4) dry body is warming up to 1160 DEG C with the speed of 5 DEG C/min, keeps the temperature 3h, then be cooled to the speed of 10 DEG C/min 750 DEG C, 0.5h is kept the temperature, is cooled to room temperature, got product through edging, packaging.
Embodiment 2
A kind of refractory ceramics metallic composite, includes the raw material of parts by weight:90 parts by weight of clay, 15 weight of barite Part, 18 parts by weight of zirconium dioxide, 17 parts by weight of volcanic rock, 55 parts by weight of zircon, 26 parts by weight of silica flour, 3 weight of tricalcium phosphate Part, 3.6 parts by weight of copper, 2.7 parts by weight of cobalt, 11 parts by weight of aluminium.
Its production method includes:
(1) raw material is weighed in mass ratio, is uniformly mixed, is crushed, wet ball grinding 10h, and 200 mesh sieves are crossed after drying, it is stand-by;
(2) the waterglass mixing 30min that quality is mixture weight 4% will be added in powder made from above-mentioned steps (1), 15h is stood, the solid content of the waterglass is 35%;
(3) by the powder that step (2) is uniformly mixed be sent to forming machine under 80MPa it is compressing, then will suppress Adobe is sent into dry kiln dry to the dry body that water content is 5%;
(4) dry body is warming up to 1220 DEG C with the speed of 10 DEG C/min, keeps the temperature 3h, then be cooled to the speed of 15 DEG C/min 850 DEG C, 1h is kept the temperature, is cooled to room temperature, got product through edging, packaging.
Embodiment 3
A kind of refractory ceramics metallic composite, includes the raw material of parts by weight:80 parts by weight of clay, 12 weight of barite Part, 15 parts by weight of zirconium dioxide, 13 parts by weight of volcanic rock, 42 parts by weight of zircon, 25 parts by weight of silica flour, 2.3 weight of tricalcium phosphate Measure part, 3.2 parts by weight of copper, 1.9 parts by weight of cobalt, 9 parts by weight of aluminium.
Its production method includes:
(1) raw material is weighed in mass ratio, is uniformly mixed, is crushed, wet ball grinding 10h, and 200 mesh sieves are crossed after drying, it is stand-by;
(2) the waterglass mixing 30min that quality is mixture weight 4% will be added in powder made from above-mentioned steps (1), 15h is stood, the solid content of the waterglass is 35%;
(3) by the powder that step (2) is uniformly mixed be sent to forming machine under 80MPa it is compressing, then will suppress Adobe is sent into dry kiln dry to the dry body that water content is 5%;
(4) dry body is warming up to 1220 DEG C with the speed of 10 DEG C/min, keeps the temperature 3h, then be cooled to the speed of 15 DEG C/min 850 DEG C, 1h is kept the temperature, is cooled to room temperature, got product through edging, packaging.
Comparative example 1
Commercially available general ceramic material.
Contrast sample 1 in the sample 1-3 and comparative example that are obtained in embodiment 1-3 is carried out to the test of performance respectively, is surveyed Its breakdown strength, the modulus of rupture and resistance to elevated temperatures are tried, it is as a result as shown in the table.
Breakdown strength/N The modulus of rupture/MPa Resistance to elevated temperatures
Embodiment 1 3282 52 It is outstanding
Embodiment 2 3285 54 It is outstanding
Embodiment 3 3281 58 It is outstanding
Comparative example 1 857 29 Generally
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent replacement, improvement and so on, should all be included in the protection scope of the present invention.

Claims (5)

  1. A kind of 1. refractory ceramics metallic composite, it is characterised in that the raw material including parts by weight:Clay 70-90 parts by weight, Barite 10-15 parts by weight, zirconium dioxide 13-18 parts by weight, volcanic rock 8-17 parts by weight, zircon 35-55 parts by weight, silica flour 24-26 parts by weight, tricalcium phosphate 1-3 parts by weight, copper 2.5-3.6 parts by weight, cobalt 0.9-2.7 parts by weight, aluminium 8-11 parts by weight.
  2. A kind of 2. refractory ceramics metallic composite according to claim 1, it is characterised in that the original including parts by weight Material:70 parts by weight of clay, 10 parts by weight of barite, 13 parts by weight of zirconium dioxide, 8 parts by weight of volcanic rock, 35 parts by weight of zircon, 24 parts by weight of silica flour, 1 parts by weight of tricalcium phosphate, 2.5 parts by weight of copper, 0.9 parts by weight of cobalt, 8 parts by weight of aluminium.
  3. A kind of 3. refractory ceramics metallic composite according to claim 1, it is characterised in that the original including parts by weight Material:90 parts by weight of clay, 15 parts by weight of barite, 18 parts by weight of zirconium dioxide, 17 parts by weight of volcanic rock, 55 weight of zircon Part, 26 parts by weight of silica flour, 3 parts by weight of tricalcium phosphate, 3.6 parts by weight of copper, 2.7 parts by weight of cobalt, 11 parts by weight of aluminium.
  4. A kind of 4. refractory ceramics metallic composite according to claim 1, it is characterised in that the original including parts by weight Material:80 parts by weight of clay, 12 parts by weight of barite, 15 parts by weight of zirconium dioxide, 13 parts by weight of volcanic rock, 42 weight of zircon Part, 25 parts by weight of silica flour, 2.3 parts by weight of tricalcium phosphate, 3.2 parts by weight of copper, 1.9 parts by weight of cobalt, 9 parts by weight of aluminium.
  5. 5. according to a kind of any refractory ceramics metallic composites of claim 1-4, it is characterised in that its production method Including:
    (1) raw material is weighed in mass ratio, is uniformly mixed, is crushed, wet ball grinding 5-10h, and 150-200 mesh sieves are crossed after drying, it is stand-by;
    (2) the waterglass mixing 20- that quality is mixture weight 2-4% will be added in powder made from above-mentioned steps (1) 30min, stands 10-15h, the solid content of the waterglass is 35%;
    (3) powder that step (2) is uniformly mixed is sent to forming machine compressing, brick that then will be suppressed under 60-80MPa Base send into dry kiln dry to the dry body that water content is 3-5%;
    (4) dry body is warming up to 1160-1220 DEG C with the speed of 5-10 DEG C/min, keeps the temperature 2-3h, then the speed with 10-15 DEG C/min Rate is cooled to 750-850 DEG C, keeps the temperature 0.5-1h, is cooled to room temperature, and is got product through edging, packaging.
CN201711188517.8A 2017-11-24 2017-11-24 A kind of refractory ceramics metallic composite Withdrawn CN107954693A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774717A (en) * 2018-07-03 2018-11-09 合肥连森裕腾新材料科技开发有限公司 A kind of corrosion-resistant ceramic based composites and preparation method thereof
CN108796401A (en) * 2018-07-03 2018-11-13 合肥连森裕腾新材料科技开发有限公司 A kind of refractory ceramics based composites and preparation method thereof
CN114749217A (en) * 2022-05-07 2022-07-15 南京开特环保科技有限公司 Honeycomb ceramic catalyst active coating and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104803658A (en) * 2015-04-27 2015-07-29 苏州统明机械有限公司 Corrosion resistant ceramic and preparation method thereof
CN107226682A (en) * 2017-07-26 2017-10-03 合肥铭佑高温技术有限公司 A kind of high-temperature flame-proof ceramics and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104803658A (en) * 2015-04-27 2015-07-29 苏州统明机械有限公司 Corrosion resistant ceramic and preparation method thereof
CN107226682A (en) * 2017-07-26 2017-10-03 合肥铭佑高温技术有限公司 A kind of high-temperature flame-proof ceramics and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774717A (en) * 2018-07-03 2018-11-09 合肥连森裕腾新材料科技开发有限公司 A kind of corrosion-resistant ceramic based composites and preparation method thereof
CN108796401A (en) * 2018-07-03 2018-11-13 合肥连森裕腾新材料科技开发有限公司 A kind of refractory ceramics based composites and preparation method thereof
CN114749217A (en) * 2022-05-07 2022-07-15 南京开特环保科技有限公司 Honeycomb ceramic catalyst active coating and preparation method thereof

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