CN107827434A - A kind of high-strength ceramic metallic composite - Google Patents
A kind of high-strength ceramic metallic composite Download PDFInfo
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- CN107827434A CN107827434A CN201711188460.1A CN201711188460A CN107827434A CN 107827434 A CN107827434 A CN 107827434A CN 201711188460 A CN201711188460 A CN 201711188460A CN 107827434 A CN107827434 A CN 107827434A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 title claims abstract description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000004927 clay Substances 0.000 claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000010428 baryte Substances 0.000 claims abstract description 12
- 229910052601 baryte Inorganic materials 0.000 claims abstract description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 12
- 239000010941 cobalt Substances 0.000 claims abstract description 12
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 12
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 12
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 12
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 12
- 229940078499 tricalcium phosphate Drugs 0.000 claims abstract description 12
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims abstract description 12
- 235000019731 tricalcium phosphate Nutrition 0.000 claims abstract description 12
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 12
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 12
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000007688 edging Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 239000011449 brick Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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Abstract
A kind of high-strength ceramic metallic composite, include the raw material of parts by weight：The parts by weight of clay 70 90, the parts by weight of barite 10 15, the parts by weight of zirconium dioxide 13 18, the parts by weight of calcium carbonate 8 17, the parts by weight of zircon 35 55, the parts by weight of nanometer silicon carbide 24 26, the parts by weight of tricalcium phosphate 13, the parts by weight of copper 2.5 3.6, the parts by weight of cobalt 0.9 2.7, the parts by weight of titanium 8 11.The invention has the advantages that on the basis of existing technology, there is provided a kind of high-strength ceramic metallic composite.
Description
Technical field
The present invention relates to Material Field, specifically, is related to a kind of high-strength ceramic metallic composite.
Background technology
Ceramics are by clay, quartz sand and other inorganic non-metallic raw materials, through dispensing, ball milling, powder processed, shaping, sintering
Etc. the tabular or block elements of technique productions, it is widely used in decoration and protection building, the metope of structures and ground.With
Real estate is developed rapidly so that the production and consumption of ceramic tile is all got a larger development, while will to the performance of ceramics
Seek also more and more higher.But ceramic most low intensity in the market, not hard enough, frangible, usability is poor, can not meet city
Field demand.
Thus, how to obtain a kind of high-strength ceramic metallic composite is current china industry urgent problem.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of high-strength ceramic metallic composite.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：
A kind of high-strength ceramic metallic composite, include the raw material of parts by weight：Clay 70-90 parts by weight, barite 10-
15 parts by weight, zirconium dioxide 13-18 parts by weight, calcium carbonate 8-17 parts by weight, zircon 35-55 parts by weight, nanometer silicon carbide 24-
26 parts by weight, tricalcium phosphate 1-3 parts by weight, copper 2.5-3.6 parts by weight, cobalt 0.9-2.7 parts by weight, titanium 8-11 parts by weight.
The beneficial effects of the invention are as follows：On the basis of existing technology, there is provided a kind of high-strength ceramic metallic composite.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement:
Further, it includes the raw material of parts by weight：The parts by weight of clay 70, the parts by weight of barite 10, the weight of zirconium dioxide 13
Part, the parts by weight of calcium carbonate 8, the parts by weight of zircon 35, the parts by weight of nanometer silicon carbide 24, the parts by weight of tricalcium phosphate 1, the weight of copper 2.5
Part, the parts by weight of cobalt 0.9, the parts by weight of titanium 8.
Further, it includes the raw material of parts by weight：The parts by weight of clay 90, the parts by weight of barite 15, the weight of zirconium dioxide 18
Part, the parts by weight of calcium carbonate 17, the parts by weight of zircon 55, the parts by weight of nanometer silicon carbide 26, the parts by weight of tricalcium phosphate 3, the weight of copper 3.6
Part, the parts by weight of cobalt 2.7, the parts by weight of titanium 11.
Further, it includes the raw material of parts by weight：The parts by weight of clay 80, the parts by weight of barite 12, the weight of zirconium dioxide 15
Part, the parts by weight of calcium carbonate 13, the parts by weight of zircon 42, the parts by weight of nanometer silicon carbide 25, the parts by weight of tricalcium phosphate 2.3, the weight of copper 3.2
Measure part, the parts by weight of cobalt 1.9, the parts by weight of titanium 9.
Further, its preparation method includes：
(1) raw material is weighed in mass ratio, is well mixed, is crushed, wet ball grinding 5-10h, and 150-200 mesh sieves are crossed after drying,
It is stand-by；
(2) the waterglass mixing 20- that quality is compound weight 2-4% will be added in powder made from above-mentioned steps (1)
30min, 10-15h is stood, the solid content of the waterglass is 35%；
(3) by step (2) be well mixed powder be sent to forming machine under 60-80MPa it is compressing, then will suppress
Adobe deliver in dry kiln dry to water content be 3-5% dry body；
(4) dry body is warming up to 1160-1220 DEG C with 5-10 DEG C/mi n speed, is incubated 2-3h, then with 10-15 DEG C/
Min speed is cooled to 750-850 DEG C, is incubated 0.5-1h, is cooled to normal temperature, is got product through edging, packaging.
Embodiment
The principle and feature of the present invention are described with reference to embodiments, the given examples are served only to explain the present invention,
It is not intended to limit the scope of the present invention.
Embodiment 1
A kind of high-strength ceramic metallic composite, include the raw material of parts by weight：The parts by weight of clay 70, the weight of barite 10
Part, the parts by weight of zirconium dioxide 13, the parts by weight of calcium carbonate 8, the parts by weight of zircon 35, the parts by weight of nanometer silicon carbide 24, tricalcium phosphate 1
Parts by weight, the parts by weight of copper 2.5, the parts by weight of cobalt 0.9, the parts by weight of titanium 8.
Its preparation method includes：
(1) raw material is weighed in mass ratio, is well mixed, is crushed, wet ball grinding 5h, and 150 mesh sieves are crossed after drying, it is stand-by；
(2) the waterglass mixing 20min that quality is compound weight 2% will be added in powder made from above-mentioned steps (1),
10h is stood, the solid content of the waterglass is 35%；
(3) by the powder that step (2) is well mixed be sent to forming machine under 60MPa it is compressing, then will suppress
The dry body dried to water content is 3% is delivered in dry kiln in adobe；
(4) dry body is warming up to 1160 DEG C with 5 DEG C/min speed, is incubated 3h, then be cooled to 10 DEG C/min speed
750 DEG C, 0.5h is incubated, is cooled to normal temperature, got product through edging, packaging.
Embodiment 2
A kind of high-strength ceramic metallic composite, include the raw material of parts by weight：The parts by weight of clay 90, the weight of barite 15
Part, the parts by weight of zirconium dioxide 18, the parts by weight of calcium carbonate 17, the parts by weight of zircon 55, the parts by weight of nanometer silicon carbide 26, tricalcium phosphate
3 parts by weight, the parts by weight of copper 3.6, the parts by weight of cobalt 2.7, the parts by weight of titanium 11.
Its preparation method includes：
(1) raw material is weighed in mass ratio, is well mixed, is crushed, wet ball grinding 10h, and 200 mesh sieves are crossed after drying, it is stand-by；
(2) the waterglass mixing 30min that quality is compound weight 4% will be added in powder made from above-mentioned steps (1),
15h is stood, the solid content of the waterglass is 35%；
(3) by the powder that step (2) is well mixed be sent to forming machine under 80MPa it is compressing, then will suppress
The dry body dried to water content is 5% is delivered in dry kiln in adobe；
(4) dry body is warming up to 1220 DEG C with 10 DEG C/min speed, is incubated 3h, then be cooled to 15 DEG C/min speed
850 DEG C, 1h is incubated, is cooled to normal temperature, got product through edging, packaging.
Embodiment 3
A kind of high-strength ceramic metallic composite, include the raw material of parts by weight：The parts by weight of clay 80, the weight of barite 12
Part, the parts by weight of zirconium dioxide 15, the parts by weight of calcium carbonate 13, the parts by weight of zircon 42, the parts by weight of nanometer silicon carbide 25, tricalcium phosphate
2.3 parts by weight, the parts by weight of copper 3.2, the parts by weight of cobalt 1.9, the parts by weight of titanium 9.
Its preparation method includes：
(1) raw material is weighed in mass ratio, is well mixed, is crushed, wet ball grinding 10h, and 200 mesh sieves are crossed after drying, it is stand-by；
(2) the waterglass mixing 30min that quality is compound weight 4% will be added in powder made from above-mentioned steps (1),
15h is stood, the solid content of the waterglass is 35%；
(3) by the powder that step (2) is well mixed be sent to forming machine under 80MPa it is compressing, then will suppress
The dry body dried to water content is 5% is delivered in dry kiln in adobe；
(4) dry body is warming up to 1220 DEG C with 10 DEG C/min speed, is incubated 3h, then be cooled to 15 DEG C/min speed
850 DEG C, 1h is incubated, is cooled to normal temperature, got product through edging, packaging.
Comparative example 1
Commercially available general ceramic material.
Comparative sample 1 in the sample 1-3 and comparative example that are obtained in embodiment 1-3 is carried out to the test of performance respectively, surveyed
Its breakdown strength, the modulus of rupture and resistance to elevated temperatures are tried, it is as a result as shown in the table.
| Breakdown strength/N | The modulus of rupture/MPa | Resistance to elevated temperatures | |
| Embodiment 1 | 3082 | 52 | It is outstanding |
| Embodiment 2 | 3085 | 51 | It is outstanding |
| Embodiment 3 | 3081 | 50 | It is outstanding |
| Comparative example 1 | 857 | 29 | Typically |
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (5)
- A kind of 1. high-strength ceramic metallic composite, it is characterised in that the raw material including parts by weight：Clay 70-90 parts by weight, Barite 10-15 parts by weight, zirconium dioxide 13-18 parts by weight, calcium carbonate 8-17 parts by weight, zircon 35-55 parts by weight, nanometer Carborundum 24-26 parts by weight, tricalcium phosphate 1-3 parts by weight, copper 2.5-3.6 parts by weight, cobalt 0.9-2.7 parts by weight, titanium 8-11 weights Measure part.
- A kind of 2. high-strength ceramic metallic composite according to claim 1, it is characterised in that the original including parts by weight Material：The parts by weight of clay 70, the parts by weight of barite 10, the parts by weight of zirconium dioxide 13, the parts by weight of calcium carbonate 8, the parts by weight of zircon 35, The parts by weight of nanometer silicon carbide 24, the parts by weight of tricalcium phosphate 1, the parts by weight of copper 2.5, the parts by weight of cobalt 0.9, the parts by weight of titanium 8.
- A kind of 3. high-strength ceramic metallic composite according to claim 1, it is characterised in that the original including parts by weight Material：The parts by weight of clay 90, the parts by weight of barite 15, the parts by weight of zirconium dioxide 18, the parts by weight of calcium carbonate 17, the weight of zircon 55 Part, the parts by weight of nanometer silicon carbide 26, the parts by weight of tricalcium phosphate 3, the parts by weight of copper 3.6, the parts by weight of cobalt 2.7, the parts by weight of titanium 11.
- A kind of 4. high-strength ceramic metallic composite according to claim 1, it is characterised in that the original including parts by weight Material：The parts by weight of clay 80, the parts by weight of barite 12, the parts by weight of zirconium dioxide 15, the parts by weight of calcium carbonate 13, the weight of zircon 42 Part, the parts by weight of nanometer silicon carbide 25, the parts by weight of tricalcium phosphate 2.3, the parts by weight of copper 3.2, the parts by weight of cobalt 1.9, the parts by weight of titanium 9.
- 5. according to a kind of any high-strength ceramic metallic composites of claim 1-4, it is characterised in that its preparation method Including：(1) raw material is weighed in mass ratio, is well mixed, is crushed, wet ball grinding 5-10h, and 150-200 mesh sieves are crossed after drying, it is stand-by；(2) the waterglass mixing 20- that quality is compound weight 2-4% will be added in powder made from above-mentioned steps (1) 30min, 10-15h is stood, the solid content of the waterglass is 35%；(3) powder that step (2) is well mixed is sent to forming machine compressing, brick that then will be suppressed under 60-80MPa Base delivers in dry kiln the dry body dried to water content is 3-5%；(4) dry body is warming up to 1160-1220 DEG C with 5-10 DEG C/min speed, is incubated 2-3h, then the speed with 10-15 DEG C/min Rate is cooled to 750-850 DEG C, is incubated 0.5-1h, is cooled to normal temperature, is got product through edging, packaging.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108774717A (en) * | 2018-07-03 | 2018-11-09 | 合肥连森裕腾新材料科技开发有限公司 | A kind of corrosion-resistant ceramic based composites and preparation method thereof |
| CN108796401A (en) * | 2018-07-03 | 2018-11-13 | 合肥连森裕腾新材料科技开发有限公司 | A kind of refractory ceramics based composites and preparation method thereof |
| CN108930005A (en) * | 2018-07-19 | 2018-12-04 | 合肥连森裕腾新材料科技开发有限公司 | A kind of high-strength ceramic based composites and preparation method thereof |
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| CN104803658A (en) * | 2015-04-27 | 2015-07-29 | 苏州统明机械有限公司 | Corrosion resistant ceramic and preparation method thereof |
| CN107226682A (en) * | 2017-07-26 | 2017-10-03 | 合肥铭佑高温技术有限公司 | A kind of high-temperature flame-proof ceramics and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104803658A (en) * | 2015-04-27 | 2015-07-29 | 苏州统明机械有限公司 | Corrosion resistant ceramic and preparation method thereof |
| CN107226682A (en) * | 2017-07-26 | 2017-10-03 | 合肥铭佑高温技术有限公司 | A kind of high-temperature flame-proof ceramics and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108774717A (en) * | 2018-07-03 | 2018-11-09 | 合肥连森裕腾新材料科技开发有限公司 | A kind of corrosion-resistant ceramic based composites and preparation method thereof |
| CN108796401A (en) * | 2018-07-03 | 2018-11-13 | 合肥连森裕腾新材料科技开发有限公司 | A kind of refractory ceramics based composites and preparation method thereof |
| CN108930005A (en) * | 2018-07-19 | 2018-12-04 | 合肥连森裕腾新材料科技开发有限公司 | A kind of high-strength ceramic based composites and preparation method thereof |
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Application publication date: 20180323 |