CN107488026A - A kind of high strength ceramics brick adobe of parian and preparation method thereof - Google Patents

A kind of high strength ceramics brick adobe of parian and preparation method thereof Download PDF

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Publication number
CN107488026A
CN107488026A CN201710684486.9A CN201710684486A CN107488026A CN 107488026 A CN107488026 A CN 107488026A CN 201710684486 A CN201710684486 A CN 201710684486A CN 107488026 A CN107488026 A CN 107488026A
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China
Prior art keywords
adobe
parian
strength ceramics
ceramics brick
brick adobe
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CN201710684486.9A
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Chinese (zh)
Inventor
朱月虎
黄旺明
谭旭日
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GUANGDONG JINPAI CERAMIC CO Ltd
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GUANGDONG JINPAI CERAMIC CO Ltd
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Priority to CN201710684486.9A priority Critical patent/CN107488026A/en
Publication of CN107488026A publication Critical patent/CN107488026A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/10Eliminating iron or lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/6261Milling
    • C04B35/62615High energy or reactive ball milling
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/608Green bodies or pre-forms with well-defined density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/61Mechanical properties, e.g. fracture toughness, hardness, Young's modulus or strength

Abstract

The invention discloses a kind of high strength ceramics brick adobe of parian, and it includes following component according to the weight percentage of raw materials:Potassium sand 22~40%, potassium albite 15~30%, potassium feldspar 10~20%, black mud 10~22%, kaolin 2~10%, bentonite 2~6%, raw talcum 1~4%.The present invention is by adjusting raw material components and formula, add the mixed material containing a certain amount of clay, and add bentonite, realize to greatly reduce and ensure that adobe has enough intensity in adobe on the basis of black mud addition, solves the dysoxidizable problem of adobe simultaneously, it suppresses the green strength >=1.0MPa formed, can bear equipment mechanical efficiency problem and green compact in drying kiln internal drainage stress impact, and good oxidation susceptibility is shown in later stage firing process, phenomena such as wherein interbed is less prone to pin hole, black line, bubble.

Description

A kind of high strength ceramics brick adobe of parian and preparation method thereof
Technical field
The present invention relates to decorative building material Material Field, the high strength ceramics brick adobe and its system of more particularly to a kind of parian Preparation Method.
Background technology
Natural marble is that original rock acts on the metamorphic rock to be formed by HTHP in the earth's crust in the earth's crust.In belonging to Admant material, mainly it is made up of calcite, lime stone, serpentine and dolomite.Due to containing impurity, and calcium carbonate is in air In acted on by carbon dioxide, carbide, aqueous vapor, easy weathering and corrosion, surface is tarnished quickly.Natural marble is One of conventional TERRAZZO, wide in variety, usage history is long, can highlight the elegant of building.Natural flowers marble matter Ground is fine and close but hardness is little, and texture is natural and tripping, is the stone decoration material increasingly liked and pursued at present.However, day Right marble is as non-renewable resources, and savings amount is limited, and not only rare cost was again higher, particularly some preciousness rarenesses Stone of marble, limited exploration now.Utilization of the national governments for non-renewable resources in recent years are tight Add limitation so that the market demand is not being met, and hardness is little, easy weathering and corrosion feature, makes natural marble Use range is also subject to certain restrictions.
The use thickness ratio conventional ceramic brick of natural marble is thick, thus the thickness of imitating natural marble Ceramic Tiles is also made every effort to Thicker than conventional ceramic brick, the thickness of conventional ceramic brick is prepared typically in 1cm or so when using conventional ceramic brick adobe batch mixing When thickness is more than 1cm Ceramic Tiles, the melting deformation in sintering process is easily caused, burns till poor rear translucency, low intensity, contraction The defects of rate is big.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art, there is provided a kind of high strength ceramics brick brick of parian Base, while a kind of preparation method of the adobe is provided.
The technical solution used in the present invention is:A kind of high strength ceramics brick adobe of parian, it presses raw material weight hundred Divide includes following component than meter:
Specifically, the potassium sand in the present invention is mixed material.The potassium sand that preferably potassium content of the invention is 3~8%, its performance It is stable, there is some strength, can suitably reduce black mud dosage containing a certain amount of raw ore clay, during use, help oxidation, adjustment is matched somebody with somebody Volumetric expansion that can be in plasticity, sintering process can partial offset sintering shrinkage, prevent melting of the adobe in sintering process from becoming The performances such as the effect such as shape, the intensity for improving ceramic adobe.
The mineral of the alumino-silicate of the alkali metal such as the potassium feldspar in the present invention, mainly K, Na or alkaline-earth metal, its quality It is stable, non-plastic raw material can be played before burning till, drying for adobe is reduced and shrink and deform, improve drying property, shorten dry The dry time;Flux can be used as to reduce firing temperature when burning till, promote quartz and kaolin melting, and diffuse into one another in the liquid phase Permeate and accelerate the formation of mullite.It causes the feldspar vitreum that adobe raw material generates in melting to be filled in mullite grains Between, make adobe fine and close and reduce space, so as to improve its mechanical strength and dielectric properties.In addition, the generation of feldspar glass is also The translucency of adobe can be improved.Incorporation of the potassium feldspar in Ceramic Tiles adobe is different and different with the requirement of raw material difference, product, It is mainly used in reducing firing temperature, improves into porcelain speed.
Potassium albite in the present invention belongs to a variety of feldspar mixtures, and it contains a certain amount of clay, stable performance, has certain Intensity, firing temperature can be both reduced during use, improves into porcelain speed, can adjust again in formula plasticity, sintering process Volumetric expansion can partial offset sintering shrinkage, prevent the melting deformation of adobe in sintering process etc. effect, improve ceramic tile The performances such as the intensity of base.
Black mud in the present invention, be a kind of outward appearance darkly, the mixing of grey, finely divided a variety of hydrous alumino silicates mineral Body.Preferable particle size of the present invention is less than 2 μm, and the black mud that the present invention preferably aluminum content is 22~32%.Black mud raw ore passes through washing Partial impurities therein can be removed, moisture content is higher, the black mud that the present invention preferably moisture content is 30~38%, and it belongs to high viscous Clay, plasticity and associativity are very strong, and dry body strength is high, shrink greatly, have very strong ion exchangeable.However, black mud is being made pottery Content in ceramic tile adobe is bigger, and adobe oxidation is just more difficult to, thus suitable black mud addition is significant.
Bentonite in the present invention has plasticity and caking property with water, the admixture of non-plastic raw material, and it is through kiln 1145 Bubble is not likely to produce after~1200 DEG C of firings, intensity is fine, mainly to improve adobe plasticity, increases green strength.
As the further improvement of such scheme, by weight percentage including following chemical constituent:
A kind of preparation method of the high strength ceramics brick adobe of parian as described above, it is comprised the technical steps that:
1) each component is well mixed according to the weight percentage of raw materials, puts into ball mill and carry out wet ball grinding, ball milling is thin It is 0.063mm apertures screen over-size in the range of 0.5~0.8% to spend, and it is 34~36% to control moisture, obtains slurry;
2) slurry obtained by step 1) is sieved with the screen cloth of 80~100 mesh, is put into old in mud pit, iron removaling of sieving afterwards, Stir, by spray drying, obtain powder;
3) coloring treatment is carried out to powder obtained by step 2) according to demand, it is compressing after cloth, drying, obtain adobe.
In the present invention, in order to shorten Ball-milling Time and ensure that slurry fineness is more stable, enter one as such scheme Step is improved, using aluminum oxide as ball-milling medium during the step 1) wet ball grinding, 40mm aluminum oxide ballstones in ball mill: 50mm aluminum oxide ballstones:The ratio of 60mm aluminum oxide ballstones is 3:5:2.
As the further improvement of such scheme, the flow rate of slurry obtained by step 1) is 40~60s, and slurry proportion is 1.67 ~1.72g/ml.
In the present invention, in order that obtaining blank has good plasticity, forming requirements can be met, and ensure that adobe has enough Intensity, will not be deformed, as the further improvement of such scheme, the old time described in step 2) is 10~14h.
As the further improvement of such scheme, the moisture of the powder obtained by step 2) is 6.4~7.1%.Specifically Ground, on the premise of blank plasticity is ensured, powder water content should be lacked as far as possible, to shorten drying time, strengthen the close of blank Degree and intensity.
As the further improvement of such scheme, the size distribution of powder obtained by step 2) for it is more than 30 mesh≤6%, 60 mesh Under 40~60%, 100 mesh sieves≤4%, unit weight >=0.9g/ml.Specifically, the size distribution order degree is low, i.e., it is fixed not formed To arrangement, it can avoid forming anisotropic structure in molding blank, cause drying distortions or even ftracture, while can improve powder Expect mobility, powder is quickly filled with each corner of mould, to ensure that the even density of adobe is consistent.
The beneficial effects of the invention are as follows:The present invention is added containing a certain amount of clay by adjusting raw material components and formula Mixed material, and add bentonite, realizes to greatly reduce in adobe and ensure that adobe has on the basis of black mud addition Enough intensity, while solve the dysoxidizable problem of adobe, it suppresses the green strength >=1.0MPa formed, can bear to set Standby mechanical efficiency problem and green compact show good oxygen in drying kiln internal drainage stress impact in later stage firing process Change performance, phenomena such as wherein interbed is less prone to pin hole, black line, bubble.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are Commercially available prod;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or Preparation method.
Embodiment 1
A kind of high strength ceramics brick adobe of parian, it includes following component according to the weight percentage of raw materials:
And the adobe includes following chemical constituent by weight percentage:
Wherein, the potassium content of the potassium sand is 3%;Black mud is 22% containing aluminium.
Preparation method:
1) each component is well mixed according to the weight percentage of raw materials, puts into ball mill and carry out wet ball grinding, ball milling is thin It is 0.063mm apertures screen over-size in the range of 0.5~0.8% to spend, and it is 34~36% to control moisture, obtains slurry, its slurry Flow velocity is 40~60s, and slurry proportion is 1.67~1.72g/ml;
2) slurry obtained by step 1) is sieved with the screen cloth of 80 mesh, is put into old 10h in mud pit, iron removaling of sieving afterwards, stirs Mix uniformly, by spray drying, obtain powder, its powder moisture is 6.4~7.1%;
3) coloring treatment is carried out to powder obtained by step 2) according to demand, it is compressing after cloth, drying, obtain embodiment 1 adobe.
Embodiment 2
A kind of high strength ceramics brick adobe of parian, it includes following component according to the weight percentage of raw materials:
And the adobe includes following chemical constituent by weight percentage:
Wherein, the potassium content of the potassium sand is 8%;Black mud is 32% containing aluminium.
Preparation method:
1) each component is well mixed according to the weight percentage of raw materials, puts into ball mill and carry out wet ball grinding, ball milling is thin It is 0.063mm apertures screen over-size in the range of 0.5~0.8% to spend, and it is 34~36% to control moisture, obtains slurry, its slurry Flow velocity is 40~60s, and slurry proportion is 1.67~1.72g/ml;
2) slurry obtained by step 1) is sieved with the screen cloth of 100 mesh, is put into old 14h in mud pit, iron removaling of sieving afterwards, stirs Mix uniformly, by spray drying, obtain powder, its powder moisture is 6.4~7.1%;
3) coloring treatment is carried out to powder obtained by step 2) according to demand, it is compressing after cloth, drying, obtain embodiment 2 adobes.
Embodiment 3
A kind of high strength ceramics brick adobe of parian, it includes following component according to the weight percentage of raw materials:
And the adobe includes following chemical constituent by weight percentage:
Wherein, the potassium content of the potassium sand is 4%;The aluminum content of black mud is 25%.
Preparation method:
1) each component is well mixed according to the weight percentage of raw materials, puts into ball mill and carry out wet ball grinding, ball milling is thin It is 0.063mm apertures screen over-size in the range of 0.5~0.8% to spend, and it is 34~36% to control moisture, obtains slurry, its slurry Flow velocity is 40~60s, and slurry proportion is 1.67~1.72g/ml;
2) slurry obtained by step 1) is sieved with the screen cloth of 80 mesh, is put into old 12h in mud pit, iron removaling of sieving afterwards, stirs Mix uniformly, by spray drying, obtain powder, its powder moisture is 6.4~7.1%;
3) coloring treatment is carried out to powder obtained by step 2) according to demand, it is compressing after cloth, drying, obtain embodiment 3 adobes.
Embodiment 4
A kind of high strength ceramics brick adobe of parian, it includes following component according to the weight percentage of raw materials:
And the adobe includes following chemical constituent by weight percentage:
Wherein, the potassium content of the potassium sand is 6%;The aluminum content of black mud is 29%.
Preparation method:
1) each component is well mixed according to the weight percentage of raw materials, puts into ball mill and carry out wet ball grinding, ball milling is thin It is 0.063mm apertures screen over-size in the range of 0.5~0.8% to spend, and it is 34~36% to control moisture, obtains slurry, its slurry Flow velocity is 40~60s, and slurry proportion is 1.67~1.72g/ml;
2) slurry obtained by step 1) is sieved with the screen cloth of 80 mesh, is put into old 13h in mud pit, iron removaling of sieving afterwards, stirs Mix uniformly, by spray drying, obtain powder, its powder moisture is 6.4~7.1%;
3) coloring treatment is carried out to powder obtained by step 2) according to demand, it is compressing after cloth, drying, obtain embodiment 4 adobes.
Embodiment 5:Properties detect
The gained adobe of embodiment 1~4 is respectively placed in roller kilns, high temperature burns under 1145~1200 DEG C of temperature conditionss Into rear to carry out properties detection for adobe, its result is as shown in table 1 below.
The properties testing result of table 1
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made, The protection category of the present invention all should be belonged to.

Claims (11)

1. the high strength ceramics brick adobe of a kind of parian, it is characterised in that according to the weight percentage of raw materials including following component:
2. the high strength ceramics brick adobe of a kind of parian according to claim 1, it is characterised in that by weight percentage Meter includes following chemical constituent:
A kind of 3. high strength ceramics brick adobe of parian according to claim 1, it is characterised in that:The potassium sand contains Potassium amount is 3~8%.
A kind of 4. high strength ceramics brick adobe of parian according to claim 1, it is characterised in that:The black mud contains Aluminum amount is 22~32%.
5. a kind of preparation method of the high strength ceramics brick adobe of parian as described in any one of Claims 1 to 4, its feature It is, comprises the technical steps that:
1) each component is well mixed according to the weight percentage of raw materials, puts into ball mill and carry out wet ball grinding, ball milling fineness is For 0.063mm apertures screen over-size in the range of 0.5~0.8%, it is 34~36% to control moisture, obtains slurry;
2) slurry obtained by step 1) is sieved with the screen cloth of 80~100 mesh, is put into old in mud pit, iron removaling of sieving afterwards, stirs Uniformly, by spray drying, powder is obtained;
3) coloring treatment is carried out to powder obtained by step 2) according to demand, it is compressing after cloth, drying, obtain adobe.
A kind of 6. preparation method of the high strength ceramics brick adobe of parian according to claim 5, it is characterised in that:Step Using aluminum oxide as ball-milling medium during rapid 1) described wet ball grinding, 40mm aluminum oxide ballstones in ball mill:50mm is aoxidized Aluminium ball stone:The ratio of 60mm aluminum oxide ballstones is 3:5:2.
A kind of 7. preparation method of the high strength ceramics brick adobe of parian according to claim 5, it is characterised in that:Step It is rapid 1) obtained by flow rate of slurry be 40~60s, slurry proportion is 1.67~1.72g/ml.
A kind of 8. preparation method of the high strength ceramics brick adobe of parian according to claim 5, it is characterised in that:Step It is rapid 2) described in the old time be 10~14h.
A kind of 9. preparation method of the high strength ceramics brick adobe of parian according to claim 5, it is characterised in that:Step It is rapid 2) obtained by powder moisture be 6.4~7.1%.
A kind of 10. preparation method of the high strength ceramics brick adobe of parian according to claim 5, it is characterised in that: The size distribution of powder obtained by step 2) for it is more than 30 mesh≤6%, 60 mesh 40~60%, under 100 mesh sieves≤4%, unit weight >= 0.9g/ml。
CN201710684486.9A 2017-08-11 2017-08-11 A kind of high strength ceramics brick adobe of parian and preparation method thereof Pending CN107488026A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314435A (en) * 2018-01-25 2018-07-24 广东金牌陶瓷有限公司 A kind of high anti-break and high strength degree ceramics sheet slab and its manufacturing method
CN108793953A (en) * 2018-06-29 2018-11-13 河源市东源鹰牌陶瓷有限公司 Low clay glazed tile green body of a kind of low temperature fast firing and preparation method thereof
CN109053154A (en) * 2018-09-21 2018-12-21 广东博华陶瓷有限公司 A kind of full porcelain marble Ceramic Tiles of 1.8 meters × 0.9 meter large scale and its production technology of the design of imitating natural marble plate

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CN102515703A (en) * 2011-12-20 2012-06-27 四川新中源陶瓷有限公司 Production technology of super-flat high-crystal stone tile
JP2012184153A (en) * 2011-03-07 2012-09-27 Nippon Merion Kk Method for manufacturing ultra-lightweight porcelain by slip casting
CN103664151A (en) * 2013-11-19 2014-03-26 沈阳新东方陶瓷有限公司 Medium-white polished ceramic tile
CN105948702A (en) * 2016-05-13 2016-09-21 佛山市唯格瓷砖有限责任公司 Porcelain plate blank powder and preparation technology thereof
CN105984017A (en) * 2015-03-03 2016-10-05 佛山市东鹏陶瓷有限公司 Method for producing natural stone imitating polished tile

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012184153A (en) * 2011-03-07 2012-09-27 Nippon Merion Kk Method for manufacturing ultra-lightweight porcelain by slip casting
CN102515703A (en) * 2011-12-20 2012-06-27 四川新中源陶瓷有限公司 Production technology of super-flat high-crystal stone tile
CN103664151A (en) * 2013-11-19 2014-03-26 沈阳新东方陶瓷有限公司 Medium-white polished ceramic tile
CN105984017A (en) * 2015-03-03 2016-10-05 佛山市东鹏陶瓷有限公司 Method for producing natural stone imitating polished tile
CN105948702A (en) * 2016-05-13 2016-09-21 佛山市唯格瓷砖有限责任公司 Porcelain plate blank powder and preparation technology thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314435A (en) * 2018-01-25 2018-07-24 广东金牌陶瓷有限公司 A kind of high anti-break and high strength degree ceramics sheet slab and its manufacturing method
CN108793953A (en) * 2018-06-29 2018-11-13 河源市东源鹰牌陶瓷有限公司 Low clay glazed tile green body of a kind of low temperature fast firing and preparation method thereof
CN109053154A (en) * 2018-09-21 2018-12-21 广东博华陶瓷有限公司 A kind of full porcelain marble Ceramic Tiles of 1.8 meters × 0.9 meter large scale and its production technology of the design of imitating natural marble plate

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Application publication date: 20171219