CN107935561A - Magnesial refractory material - Google Patents

Magnesial refractory material Download PDF

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Publication number
CN107935561A
CN107935561A CN201711443235.8A CN201711443235A CN107935561A CN 107935561 A CN107935561 A CN 107935561A CN 201711443235 A CN201711443235 A CN 201711443235A CN 107935561 A CN107935561 A CN 107935561A
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CN
China
Prior art keywords
parts
refractory material
magnesial
component
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711443235.8A
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Chinese (zh)
Inventor
王红超
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LUOYANG SHENJIA KILN CO Ltd
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LUOYANG SHENJIA KILN CO Ltd
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Priority to CN201711443235.8A priority Critical patent/CN107935561A/en
Publication of CN107935561A publication Critical patent/CN107935561A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/03Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
    • C04B35/04Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241Chromium oxides, chromates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669Resistance against chemicals, e.g. against molten glass or molten salts
    • C04B2235/9692Acid, alkali or halogen resistance

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention relates to magnesial refractory material, the mass fraction of its component and each component is 20 30 parts of magnesia powder, 5 10 parts of silicon powder, 15 parts of chromium oxide, 13 parts of titanium oxide, 25 parts of zirconium oxide, 0.5 1 parts of carborundum.By above-mentioned technical proposal, a kind of magnesial refractory material of present invention refractoriness under alkaline environment is high, service life length, and the magnesia brick being prepared using the material is resistant to more than 2000 DEG C of high temperature.

Description

Magnesial refractory material
Technical field
The invention belongs to technical field of refractory materials, more particularly to a kind of magnesial refractory material.
Background technology
Refractory material refers to that refractoriness is not less than 1580 DEG C of a kind of inorganic non-metallic material.Refractoriness refers to refractory material Bullet sample is in the case of no loading, and resistance high temperature action is without softening molten Celsius temperature.But only come with refractoriness Definition cannot describe refractory material comprehensively, and 1580 DEG C are not absolute.Now being defined as all physicochemical properties allows it The material used in high temperature environments is known as refractory material.Refractory material is widely used in metallurgy, chemical industry, oil, machine-building, silicon The industrial circles such as hydrochlorate, power, dosage is maximum in metallurgical industry, accounts for the 50%~60% of total output.
Application to refractory in steel, non-ferrous metal, glass, cement, ceramics, petrochemical industry, machinery, boiler, light industry, electric power, The every field of the national economy such as military project, is to ensure that above-mentioned industry production run and technology develop essential basic material, Irreplaceable important function is played in hot industry production development.Wherein magnesia refractories is a kind of high-quality alkaline fire resisting Material, has a variety of excellent performances, therefore enjoys consumers.But what existing magnesia refractories can carry Temperature is limited and service life is short, it would be highly desirable to improves.
The content of the invention
It is an object of the present invention to propose a kind of high temperature magnesial that can be suitable for alkaline environment and service life length Refractory material, thus more suitable for practicality.
The object of the invention to solve the technical problems is realized using following technical scheme.According to proposed by the present invention The mass fraction of a kind of magnesial refractory material, its component and each component is 20-30 parts of magnesia powder, 5-10 parts of silicon powder, oxygen Change 1-5 parts of chromium, 1-3 parts of titanium oxide, 2-5 parts of zirconium oxide, 0.5-1 parts of carborundum.
The object of the invention to solve the technical problems is also further realized using following technical scheme.
The mass fraction of foregoing magnesial refractory material, its component and each component is 20 parts of magnesia powder, silicon powder 5 Part, 1 part of chromium oxide, 1 part of titanium oxide, 2 parts of zirconium oxide, 0.5 part of carborundum.
The mass fraction of foregoing magnesial refractory material, its component and each component is 25 parts of magnesia powder, silicon powder 13 Part, 3 parts of chromium oxide, 2 parts of titanium oxide, 3 parts of zirconium oxide, 0.8 part of carborundum.
The mass fraction of foregoing magnesial refractory material, its component and each component is 30 parts of magnesia powder, silicon powder 10 Part, 5 parts of chromium oxide, 3 parts of titanium oxide, 5 parts of zirconium oxide, 1 part of carborundum.
By above-mentioned technical proposal, a kind of magnesial refractory material of present invention refractoriness under alkaline environment is high, uses Long lifespan, the magnesia brick being prepared using the material are resistant to more than 2000 DEG C of high temperature.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, and in order to allow the above and other objects, features and advantages of the present invention can Become apparent, described in detail below especially exemplified by preferred embodiment.
Embodiment
Further to illustrate the present invention to reach the technological means and effect that predetermined goal of the invention is taken, below in conjunction with Preferred embodiment, to according to a kind of its embodiment of magnesial refractory material proposed by the present invention, structure, feature and its Effect, describes in detail as after.
Embodiment 1
The mass fraction of a kind of magnesial refractory material of the present invention, its component and each component is 20 parts of magnesia powder, silicon is micro- 5 parts of powder, 1 part of chromium oxide, 1 part of titanium oxide, 2 parts of zirconium oxide, 0.5 part of carborundum.
Embodiment 2
The mass fraction of a kind of magnesial refractory material of the present invention, its component and each component is 25 parts of magnesia powder, silicon is micro- 13 parts of powder, 3 parts of chromium oxide, 2 parts of titanium oxide, 3 parts of zirconium oxide, 0.8 part of carborundum.
Embodiment 3
The mass fraction of a kind of magnesial refractory material of the present invention, its component and each component is 30 parts of magnesia powder, silicon is micro- 10 parts of powder, 5 parts of chromium oxide, 3 parts of titanium oxide, 5 parts of zirconium oxide, 1 part of carborundum.
The above described is only a preferred embodiment of the present invention, limitation in any form is not done to the present invention, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification For the equivalent embodiment of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention To any simple modification, equivalent change and modification made for any of the above embodiments, in the range of still falling within technical solution of the present invention.

Claims (3)

1. magnesial refractory material, it is characterised in that:The mass fraction of its component and each component is 20-30 parts of magnesia powder, silicon 5-10 parts of micro mist, 1-5 parts of chromium oxide, 1-3 parts of titanium oxide, 2-5 parts of zirconium oxide, 0.5-1 parts of carborundum.
2. magnesial refractory material according to claim 1, it is characterised in that:The mass fraction of its component and each component For 20 parts of magnesia powder, 5 parts of silicon powder, 1 part of chromium oxide, 1 part of titanium oxide, 2 parts of zirconium oxide, 0.5 part of carborundum.
3. magnesial refractory material according to claim 1, it is characterised in that:The mass fraction of its component and each component For 30 parts of magnesia powder, 10 parts of silicon powder, 5 parts of chromium oxide, 3 parts of titanium oxide, 5 parts of zirconium oxide, 1 part of carborundum.
CN201711443235.8A 2017-12-27 2017-12-27 Magnesial refractory material Pending CN107935561A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711443235.8A CN107935561A (en) 2017-12-27 2017-12-27 Magnesial refractory material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711443235.8A CN107935561A (en) 2017-12-27 2017-12-27 Magnesial refractory material

Publications (1)

Publication Number Publication Date
CN107935561A true CN107935561A (en) 2018-04-20

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Country Status (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101786894A (en) * 2009-01-26 2010-07-28 通用电气公司 Treated refractory materials and preparation method
CN105330303A (en) * 2015-09-28 2016-02-17 洛阳暖盈电子技术有限公司 Novel magnesia refractory material
CN106554207A (en) * 2015-09-25 2017-04-05 洛阳暖盈电子技术有限公司 A kind of high temperature magnesia refractories

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101786894A (en) * 2009-01-26 2010-07-28 通用电气公司 Treated refractory materials and preparation method
CN106554207A (en) * 2015-09-25 2017-04-05 洛阳暖盈电子技术有限公司 A kind of high temperature magnesia refractories
CN105330303A (en) * 2015-09-28 2016-02-17 洛阳暖盈电子技术有限公司 Novel magnesia refractory material

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Application publication date: 20180420