CN107903853A - A kind of high-temperature Resistance Adhesives and preparation method thereof - Google Patents
A kind of high-temperature Resistance Adhesives and preparation method thereof Download PDFInfo
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- CN107903853A CN107903853A CN201711205163.3A CN201711205163A CN107903853A CN 107903853 A CN107903853 A CN 107903853A CN 201711205163 A CN201711205163 A CN 201711205163A CN 107903853 A CN107903853 A CN 107903853A
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- isobutyl
- resistance adhesives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of high-temperature Resistance Adhesives and preparation method thereof, belong to chemical technology field.It is made of the raw material of following parts by weight：5~9 parts of 10~20 parts of polytetrahydrofuran ether glycol, 5~9 parts of triethanolamine, 4~12 parts of propylene oxide phenyl ether, 3~9 parts of isobutyl ethyl triethoxy silicane, 4~10 parts of Isobutyl methacrylate, 5~15 parts of dibutyl phthalate, 5~15 parts of hydroxypropyl PASELLI EASYGEL, 5~9 parts of N methyl pyrrolidones, 4~12 parts of furfuryl alcohol resin, 5~9 parts of antioxidant and crosslinking agent.The adhesive of the present invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has good caking property, and bond effect is good, and prepares simple, of low cost, function admirable.
Description
Technical field
The present invention relates to a kind of high-temperature Resistance Adhesives and preparation method thereof, belong to chemical technology field.
Background technology
Adhesive, refers to homogeneity or the technology that heterogeneous body surface is linked together with adhesive, and there is stress distribution to connect
The features such as continuous, light-weight, technological temperature is low.It is glued especially suitable for unlike material, different-thickness, ultra-thin specification and complex component
Connection.Splicing RECENT DEVELOPMENTS is most fast, and application industry is extremely wide.The sorting technique of adhesive is very much, can be divided into heat by application process
Curable type, heat molten type, room temperature curing type, pressure sensitive etc.；It is divided into structural type, non-configuration or special gelatin by application；Connecing form can
It is divided into water-soluble, emulsion type, solvent-borne type and various solid-state versions etc.；Traditional adhesive production cost is high, and using effect is bad.
The content of the invention
The purpose of the present invention is make up the deficiencies in the prior art, there is provided a kind of high-temperature Resistance Adhesives and preparation method thereof.This
The adhesive of invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has good caking property, glues
It is good to tie effect, and prepares simple, of low cost, function admirable.
The technical solution that the present invention solves above-mentioned technical problem is as follows：A kind of high-temperature Resistance Adhesives, by following parts by weight
Raw material be made：10~20 parts of polytetrahydrofuran ether glycol, 5~9 parts of triethanolamine, 4~12 parts of propylene oxide phenyl ether, isobutyl
3~9 parts of ethyl triethoxy silicane, 4~10 parts of Isobutyl methacrylate, 5~15 parts of dibutyl phthalate, hydroxypropyl two form sediment
5~15 parts of powder phosphate, 5~9 parts of 1-methyl-2-pyrrolidinone, 4~12 parts of furfuryl alcohol resin, 5~9 parts of antioxidant and crosslinking agent 5
~9 parts.
Based on the above technical solutions, the present invention can also be improved as follows.
Further, it is made of the raw material of following parts by weight：15 parts of polytetrahydrofuran ether glycol, 7 parts of triethanolamine, epoxy
8 parts of propane phenyl ether, 6 parts of isobutyl ethyl triethoxy silicane, 7 parts of Isobutyl methacrylate, 10 parts of dibutyl phthalate, hydroxyl
7 parts of 10 parts of propyl group PASELLI EASYGEL, 7 parts of 1-methyl-2-pyrrolidinone, 8 parts of furfuryl alcohol resin, 7 parts of antioxidant and crosslinking agent.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
A kind of preparation method of high-temperature Resistance Adhesives, includes the following steps：
(1) raw material of following parts by weight is weighed：10~20 parts of polytetrahydrofuran ether glycol, 5~9 parts of triethanolamine, ring
4~12 parts of Ethylene Oxide phenyl ether, 3~9 parts of isobutyl ethyl triethoxy silicane, 4~10 parts of Isobutyl methacrylate, phthalic acid
5~15 parts of dibutyl ester, 5~15 parts of hydroxypropyl PASELLI EASYGEL, 5~9 parts of 1-methyl-2-pyrrolidinone, 4~12 parts of furfuryl alcohol resin,
Add in reaction kettle, progressively heat up, and be slowly stirred, start timing when temperature rises to 90 DEG C, keep the temperature 20~40min, at the same time
At the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, antioxidant and 5~9 parts of crosslinking agent that parts by weight are 5~9 parts is added, stirs
After mixing uniformly, up to the high-temperature Resistance Adhesives.
Based on the above technical solutions, the present invention can also be improved as follows.
Further, the parts by weight of step (1) described raw material are：15 parts of polytetrahydrofuran ether glycol, 7 parts of triethanolamine,
8 parts of propylene oxide phenyl ether, 6 parts of isobutyl ethyl triethoxy silicane, 7 parts of Isobutyl methacrylate, dibutyl phthalate 10
Part, 10 parts of hydroxypropyl PASELLI EASYGEL, 7 parts of 1-methyl-2-pyrrolidinone, 8 parts of furfuryl alcohol resin.
Further, the parts by weight of step (2) described antioxidant are 7 parts, and the parts by weight of the crosslinking agent are 7 parts.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
The beneficial effects of the invention are as follows：
(1) adhesive of the invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has very
Good caking property, bond effect are good.
(2) preparation method of the invention is simple, of low cost, function admirable, is adapted to large-scale production.
Embodiment
The principle of the present invention and feature are described below in conjunction with specific embodiment, example is served only for explaining this hair
It is bright, it is not intended to limit the scope of the present invention.
Embodiment 1：
The high-temperature Resistance Adhesives of the present embodiment, are made of the raw material of following weight：Polytetrahydrofuran ether glycol 10kg, three second
Hydramine 9kg, propylene oxide phenyl ether 4kg, isobutyl ethyl triethoxy silicane 9kg, Isobutyl methacrylate 4kg, phthalic acid
Dibutyl ester 15kg, hydroxypropyl PASELLI EASYGEL 5kg, 1-methyl-2-pyrrolidinone 9kg, furfuryl alcohol resin 4kg, vitamin E oil 5kg and
Glyoxal 9kg.
The preparation method of above-mentioned high-temperature Resistance Adhesives, includes the following steps：
(1) raw material of following weight is weighed：Polytetrahydrofuran ether glycol 10kg, triethanolamine 9kg, propylene oxide phenyl ether
4kg, isobutyl ethyl triethoxy silicane 9kg, Isobutyl methacrylate 4kg, dibutyl phthalate 15kg, two starch of hydroxypropyl
Phosphate 5kg, 1-methyl-2-pyrrolidinone 9kg, furfuryl alcohol resin 4kg, add in reaction kettle, progressively heat up, and are slowly stirred, and treat temperature
Degree starts timing when rising to 90 DEG C, keep the temperature 20min, be carried out at the same time and at the uniform velocity stir, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds 5kg vitamin E oils and 9kg glyoxals, after stirring evenly, up to described resistance to
High temperature adhesive.
Embodiment 2：
The high-temperature Resistance Adhesives of the present embodiment, are made of the raw material of following weight：Polytetrahydrofuran ether glycol 15kg, three second
Hydramine 7kg, propylene oxide phenyl ether 8kg, isobutyl ethyl triethoxy silicane 6kg, Isobutyl methacrylate 7kg, phthalic acid
Dibutyl ester 10kg, hydroxypropyl PASELLI EASYGEL 10kg, 1-methyl-2-pyrrolidinone 7kg, furfuryl alcohol resin 8kg, vitamin E oil 7kg
With glyoxal 7kg.
The preparation method of above-mentioned high-temperature Resistance Adhesives, includes the following steps：
(1) raw material of following weight is weighed：Polytetrahydrofuran ether glycol 15kg, triethanolamine 7kg, propylene oxide phenyl ether
8kg, isobutyl ethyl triethoxy silicane 6kg, Isobutyl methacrylate 7kg, dibutyl phthalate 10kg, two starch of hydroxypropyl
Phosphate 10kg, 1-methyl-2-pyrrolidinone 7kg, furfuryl alcohol resin 8kg, add in reaction kettle, progressively heat up, and are slowly stirred, and treat
Temperature starts timing when rising to 90 DEG C, keep the temperature 30min, be carried out at the same time and at the uniform velocity stir, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds vitamin E oil 7kg and glyoxal 7kg, after stirring evenly, up to described resistance to
High temperature adhesive.
Embodiment 3：
The high-temperature Resistance Adhesives of the present embodiment, are made of the raw material of following weight：Polytetrahydrofuran ether glycol 20kg, three second
Hydramine 5kg, propylene oxide phenyl ether 12kg, isobutyl ethyl triethoxy silicane 3kg, Isobutyl methacrylate 10kg, O-phthalic
Dibutyl phthalate 5kg, hydroxypropyl PASELLI EASYGEL 15kg, 1-methyl-2-pyrrolidinone 5kg, furfuryl alcohol resin 12kg, vitamin E oil
9kg and glyoxal 5kg.
The preparation method of above-mentioned high-temperature Resistance Adhesives, includes the following steps：
(1) raw material of following weight is weighed：Polytetrahydrofuran ether glycol 20kg, triethanolamine 5kg, propylene oxide phenyl ether
12kg, isobutyl ethyl triethoxy silicane 3kg, Isobutyl methacrylate 10kg, dibutyl phthalate 5kg, hydroxypropyl two form sediment
Powder phosphate 15kg, 1-methyl-2-pyrrolidinone 5kg, furfuryl alcohol resin 12kg, add in reaction kettle, progressively heat up, and are slowly stirred,
Start timing when temperature rises to 90 DEG C, keep the temperature 40min, be carried out at the same time and at the uniform velocity stir, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds vitamin E oil 9kg and glyoxal 5kg, after stirring evenly, up to described resistance to
High temperature adhesive.
Comparative example
The adhesive of certain domestic producer is taken, it includes the raw material of following weight：Polytetrahydrofuran ether glycol 15kg, three ethanol
Amine 4kg, propylene oxide phenyl ether 10kg, isobutyl ethyl triethoxy silicane 5kg, adipic acid 9kg, Isobutyl methacrylate 5kg, neighbour
Dibatyl phithalate 8kg, with embodiment 1-3 obtained by high-temperature Resistance Adhesives contrast, viscous material identical material fine powder
200kg.Comparing result is as shown in table 1.
The comparing result of 1 prior art of table and the method for the present invention
It can be seen from the above that the adhesive of the present invention has good resistance to elevated temperatures, at high temperature can be with normal use, at the same time
It is good with good caking property, bond effect.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on, should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of high-temperature Resistance Adhesives, it is characterised in that be made of the raw material of following parts by weight：Polytetrahydrofuran ether glycol 10
~20 parts, 5~9 parts of triethanolamine, 4~12 parts of propylene oxide phenyl ether, 3~9 parts of isobutyl ethyl triethoxy silicane, methacrylic acid
4~10 parts of isobutyl ester, 5~15 parts of dibutyl phthalate, 5~15 parts of hydroxypropyl PASELLI EASYGEL, N- crassitudes
5~9 parts of 5~9 parts of ketone, 4~12 parts of furfuryl alcohol resin, 5~9 parts of antioxidant and crosslinking agent.
2. a kind of high-temperature Resistance Adhesives according to claim 1, it is characterised in that by the raw material system of following parts by weight
Into：15 parts of polytetrahydrofuran ether glycol, 7 parts of triethanolamine, 8 parts of propylene oxide phenyl ether, 6 parts of isobutyl ethyl triethoxy silicane, first
7 parts of base isobutyl acrylate, 10 parts of dibutyl phthalate, 10 parts of hydroxypropyl PASELLI EASYGEL, 1-methyl-2-pyrrolidinone 7
Part, 8 parts of furfuryl alcohol resin, 7 parts of antioxidant and 7 parts of crosslinking agent.
3. a kind of high-temperature Resistance Adhesives according to claim 1 or 2, it is characterised in that the antioxidant is vitamin E
Oil, the crosslinking agent are glyoxal.
4. a kind of preparation method of high-temperature Resistance Adhesives, it is characterised in that include the following steps：
(1) raw material of following parts by weight is weighed：10~20 parts of polytetrahydrofuran ether glycol, 5~9 parts of triethanolamine, epoxy third
4~12 parts of alkane phenyl ether, 3~9 parts of isobutyl ethyl triethoxy silicane, 4~10 parts of Isobutyl methacrylate, two fourth of phthalic acid
5~15 parts of ester, 5~15 parts of hydroxypropyl PASELLI EASYGEL, 5~9 parts of 1-methyl-2-pyrrolidinone, 4~12 parts of furfuryl alcohol resin, add
In reaction kettle, progressively heat up, and be slowly stirred, start timing when temperature rises to 90 DEG C, keep the temperature 20~40mi n, be carried out at the same time
At the uniform velocity stir, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds antioxidant and 5~9 parts of crosslinking agent that parts by weight are 5~9 parts, stirring is equal
After even, up to the high-temperature Resistance Adhesives.
A kind of 5. preparation method of high-temperature Resistance Adhesives according to claim 4, it is characterised in that step (1) described original
The parts by weight of material are：15 parts of polytetrahydrofuran ether glycol, 7 parts of triethanolamine, 8 parts of propylene oxide phenyl ether, three second of isobutyl group
6 parts of epoxide silicon, 7 parts of Isobutyl methacrylate, 10 parts of dibutyl phthalate, 10 parts of hydroxypropyl PASELLI EASYGEL, N-
7 parts of methyl pyrrolidone, 8 parts of furfuryl alcohol resin.
6. the preparation method of a kind of high-temperature Resistance Adhesives according to claim 4, it is characterised in that step (2) is described anti-
The parts by weight of oxidant are 7 parts, and the parts by weight of the crosslinking agent are 7 parts.
7. according to a kind of preparation method of high-temperature Resistance Adhesives of claim 4-6 any one of them, it is characterised in that described anti-
Oxidant is vitamin E oil, and the crosslinking agent is glyoxal.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711205163.3A CN107903853A (en) | 2017-11-27 | 2017-11-27 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711205163.3A CN107903853A (en) | 2017-11-27 | 2017-11-27 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
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| CN107903853A true CN107903853A (en) | 2018-04-13 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238321A (en) * | 2015-10-13 | 2016-01-13 | 罗志坤 | High temperature-resistant glue and preparation method thereof |
| CN105238335A (en) * | 2015-10-13 | 2016-01-13 | 罗志坤 | Heat-resistant glue and preparation method thereof |
| CN106336846A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Novel high temperature resistant adhesive and preparation method thereof, |
| CN106336845A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | High temperature resistant adhesive and preparation method thereof |
| CN106336837A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Heat resistant adhesive and preparation method thereof |
-
2017
- 2017-11-27 CN CN201711205163.3A patent/CN107903853A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238321A (en) * | 2015-10-13 | 2016-01-13 | 罗志坤 | High temperature-resistant glue and preparation method thereof |
| CN105238335A (en) * | 2015-10-13 | 2016-01-13 | 罗志坤 | Heat-resistant glue and preparation method thereof |
| CN106336846A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Novel high temperature resistant adhesive and preparation method thereof, |
| CN106336845A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | High temperature resistant adhesive and preparation method thereof |
| CN106336837A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Heat resistant adhesive and preparation method thereof |
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