CN107674595A - A kind of high-temperature Resistance Adhesives and preparation method thereof - Google Patents
A kind of high-temperature Resistance Adhesives and preparation method thereof Download PDFInfo
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- CN107674595A CN107674595A CN201711085946.2A CN201711085946A CN107674595A CN 107674595 A CN107674595 A CN 107674595A CN 201711085946 A CN201711085946 A CN 201711085946A CN 107674595 A CN107674595 A CN 107674595A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of high-temperature Resistance Adhesives and preparation method thereof, belong to chemical technology field.It is made up of the raw material of following parts by weight：2~6 parts of 5~15 parts of polyvinyl butyral, 4~10 parts of triethanolamine, 5~15 parts of expoxy propane phenyl ether, 4~12 parts of benzisothia oxazolone, 3~9 parts of hydrop diisopropylbenzene (DIPB), 4~10 parts of hydroxypropyl PASELLI EASYGEL, 3~9 parts of N methyl pyrrolidones, 4~10 parts of hydrop diisopropylbenzene (DIPB), 3~9 parts of methacrylic acid, 4~10 parts of antioxidant and crosslinking agent.The adhesive of the present invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has good caking property, and bond effect is good, and making is simple, cost is cheap, function admirable.
Description
Technical field
The present invention relates to a kind of high-temperature Resistance Adhesives and preparation method thereof, belong to chemical technology field.
Background technology
Adhesive, refer to homogeneity or the technology that heterogeneous body surface is linked together with adhesive, there is stress distribution to connect
The features such as continuous, in light weight, technological temperature is low.It is glued especially suitable for unlike material, different-thickness, ultra-thin specification and complex component
Connection.Splicing RECENT DEVELOPMENTS is most fast, and application industry is extremely wide.The sorting technique of adhesive is a lot, can be divided into heat by application process
Curable type, heat molten type, room temperature curing type, pressure sensitive etc.；It is divided into structural type, non-configuration or special gelatin by application；Connecing form can
It is divided into water-soluble, emulsion type, solvent-borne type and various solid-state versions etc.；Traditional adhesive production cost is high, and using effect is bad.
The content of the invention
The purpose of the present invention is to make up the deficiencies in the prior art, there is provided a kind of high-temperature Resistance Adhesives and preparation method thereof.This
The adhesive of invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has good caking property, glues
It is good to tie effect, and making is simple, cost is cheap, function admirable.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of high-temperature Resistance Adhesives, by following parts by weight
Raw material be made：5~15 parts of polyvinyl butyral, 4~10 parts of triethanolamine, 5~15 parts of expoxy propane phenyl ether, benzisothia
4~12 parts of oxazolone, 3~9 parts of hydrop diisopropylbenzene (DIPB), 4~10 parts of hydroxypropyl PASELLI EASYGEL, 1-METHYLPYRROLIDONE
3~9 parts, 4~10 parts of hydrop diisopropylbenzene (DIPB), 3~9 parts of methacrylic acid, 4~10 parts of antioxidant and crosslinking agent 2~6
Part.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, it is made up of the raw material of following parts by weight：10 parts of polyvinyl butyral, 7 parts of triethanolamine, expoxy propane
10 parts of phenyl ether, 8 parts of benzisothia oxazolone, 6 parts of hydrop diisopropylbenzene (DIPB), 7 parts of hydroxypropyl PASELLI EASYGEL, N- methyl
4 parts of 6 parts of pyrrolidones, 7 parts of hydrop diisopropylbenzene (DIPB), 6 parts of methacrylic acid, 7 parts of antioxidant and crosslinking agent.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
A kind of preparation method of high-temperature Resistance Adhesives, comprises the following steps：
(1) raw material of following parts by weight is weighed：5~15 parts of polyvinyl butyral, 4~10 parts of triethanolamine, epoxy third
5~15 parts of alkane phenyl ether, 4~12 parts of benzisothia oxazolone, 3~9 parts of hydrop diisopropylbenzene (DIPB), the starch phosphate of hydroxypropyl two
4~10 parts of ester, 3~9 parts of 1-METHYLPYRROLIDONE, 4~10 parts of hydrop diisopropylbenzene (DIPB), 3~9 parts of methacrylic acid, add
Enter in reactor, progressively heat up, and be slowly stirred, start timing when temperature rises to 95 DEG C, be incubated 10~30min, enter simultaneously
Row at the uniform velocity stirs, until reaching reaction end；
(2) 100 DEG C are continuously heating to, antioxidant and 2~6 parts of crosslinking agent that parts by weight are 4~10 parts is added, stirs
After mixing uniformly, the high-temperature Resistance Adhesives are produced.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the parts by weight of step (1) described raw material are：10 parts of polyvinyl butyral, 7 parts of triethanolamine, epoxy
10 parts of propane phenyl ether, 8 parts of benzisothia oxazolone, 6 parts of hydrop diisopropylbenzene (DIPB), 7 parts of hydroxypropyl PASELLI EASYGEL, N-
6 parts of methyl pyrrolidone, 7 parts of hydrop diisopropylbenzene (DIPB), 6 parts of methacrylic acid.
Further, the parts by weight of step (2) described antioxidant are 6 parts, and the parts by weight of the crosslinking agent are 9 parts.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
The beneficial effects of the invention are as follows：
(1) adhesive of the invention has good resistance to elevated temperatures, at high temperature can be with normal use, while has very
Good caking property, bond effect are good.
(2) making of the invention is simple, cost is cheap, function admirable, is adapted to large-scale production.
Embodiment
The principle and feature of the present invention are described below in conjunction with specific embodiment, example is served only for explaining this hair
It is bright, it is not intended to limit the scope of the present invention.
Embodiment 1：
The high-temperature Resistance Adhesives of the present embodiment, it is made up of the raw material of following weight：Polyvinyl butyral 5kg, triethanolamine
10kg, expoxy propane phenyl ether 5kg, benzisothia oxazolone 12kg, hydrop diisopropylbenzene (DIPB) 3kg, the starch phosphorus of hydroxypropyl two
Acid esters 10kg, 1-METHYLPYRROLIDONE 3kg, hydrop diisopropylbenzene (DIPB) 10kg, methacrylic acid 3kg, vitamin E oil 10kg
With glyoxal 2kg.
The preparation method of above-mentioned high-temperature Resistance Adhesives, comprises the following steps：
(1) raw material of following weight is weighed：Polyvinyl butyral 5kg, triethanolamine 10kg, expoxy propane phenyl ether 5kg,
Benzisothia oxazolone 12kg, hydrop diisopropylbenzene (DIPB) 3kg, hydroxypropyl PASELLI EASYGEL 10kg, 1-METHYLPYRROLIDONE
3kg, hydrop diisopropylbenzene (DIPB) 10kg, methacrylic acid 3kg, add in reactor, progressively heat up, and be slowly stirred, treat
Temperature starts timing when rising to 95 DEG C, be incubated 10min, while is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, vitamin E oil 10kg and glyoxal 2kg is added, after stirring, produces described resistance to
High temperature adhesive.
Embodiment 2：
The high-temperature Resistance Adhesives of the present embodiment, it is made up of the raw material of following weight：Polyvinyl butyral 10kg, triethanolamine
7kg, expoxy propane phenyl ether 10kg, benzisothia oxazolone 8kg, hydrop diisopropylbenzene (DIPB) 6kg, the starch phosphate of hydroxypropyl two
Ester 7kg, 1-METHYLPYRROLIDONE 6kg, hydrop diisopropylbenzene (DIPB) 7kg, methacrylic acid 6kg, vitamin E oil 7kg and second
Dialdehyde 4kg.
The preparation method of above-mentioned high-temperature Resistance Adhesives, comprises the following steps：
(1) raw material of following weight is weighed：Polyvinyl butyral 10kg, triethanolamine 7kg, expoxy propane phenyl ether
10kg, benzisothia oxazolone 8kg, hydrop diisopropylbenzene (DIPB) 6kg, hydroxypropyl PASELLI EASYGEL 7kg, N- crassitude
Ketone 6kg, hydrop diisopropylbenzene (DIPB) 7kg, methacrylic acid 6kg, add in reactor, progressively heat up, and be slowly stirred, treat
Temperature starts timing when rising to 95 DEG C, be incubated 20min, while is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, vitamin E oil 7kg and glyoxal 4kg is added, after stirring, produces described resistance to
High temperature adhesive.
Embodiment 3：
The high-temperature Resistance Adhesives of the present embodiment, it is made up of the raw material of following weight：Polyvinyl butyral 15kg, triethanolamine
4kg, expoxy propane phenyl ether 15kg, benzisothia oxazolone 4kg, hydrop diisopropylbenzene (DIPB) 9kg, the starch phosphate of hydroxypropyl two
Ester 4kg, 1-METHYLPYRROLIDONE 9kg, hydrop diisopropylbenzene (DIPB) 4kg, methacrylic acid 9kg, antioxidant 4kg and crosslinking
Agent 6kg.
The preparation method of above-mentioned high-temperature Resistance Adhesives, comprises the following steps：
(1) raw material of following weight is weighed：Polyvinyl butyral 15kg, triethanolamine 4kg, expoxy propane phenyl ether
15kg, benzisothia oxazolone 4kg, hydrop diisopropylbenzene (DIPB) 9kg, hydroxypropyl PASELLI EASYGEL 4kg, N- crassitude
Ketone 9kg, hydrop diisopropylbenzene (DIPB) 4kg, methacrylic acid 9kg, add in reactor, progressively heat up, and be slowly stirred, treat
Temperature starts timing when rising to 95 DEG C, be incubated 30min, while is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, vitamin E oil 4kg and glyoxal 6kg is added, after stirring, produces described resistance to
High temperature adhesive.
Comparative example
The adhesive of certain domestic producer is taken, it includes the raw material of following weight：Succinic acid 10kg, triethanolamine 4kg, epoxy
Propane phenyl ether 8kg, 1,3-PD 6kg, adipic acid 10kg, hydrop diisopropylbenzene (DIPB) 6kg, calcium chloride 5kg, with implementation
Example 1-3 obtained by high-temperature Resistance Adhesives contrast, viscous material phase same material fine powder 300kg.Comparing result is as shown in table 1.
The comparing result of the prior art of table 1 and the method for the present invention
As can be seen here, adhesive of the invention has good resistance to elevated temperatures, at high temperature can be with normal use, simultaneously
It is good with good caking property, bond effect.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (7)
1. a kind of high-temperature Resistance Adhesives, it is characterised in that be made up of the raw material of following parts by weight：Polyvinyl butyral 5~15
Part, 4~10 parts of triethanolamine, 5~15 parts of expoxy propane phenyl ether, 4~12 parts of benzisothia oxazolone, hydrop diisopropyl
3~9 parts of benzene, 4~10 parts of hydroxypropyl PASELLI EASYGEL, 3~9 parts of 1-METHYLPYRROLIDONE, hydrop diisopropylbenzene (DIPB) 4~
2~6 parts of 10 parts, 3~9 parts of methacrylic acid, 4~10 parts of antioxidant and crosslinking agent.
2. a kind of high-temperature Resistance Adhesives according to claim 1, it is characterised in that by the raw material system of following parts by weight
Into：10 parts of polyvinyl butyral, 7 parts of triethanolamine, 10 parts of expoxy propane phenyl ether, 8 parts of benzisothia oxazolone, hydrop
6 parts of diisopropylbenzene (DIPB), 7 parts of hydroxypropyl PASELLI EASYGEL, 6 parts of 1-METHYLPYRROLIDONE, 7 parts of hydrop diisopropylbenzene (DIPB), first
4 parts of 6 parts of base acrylic acid, 7 parts of antioxidant and crosslinking agent.
3. a kind of high-temperature Resistance Adhesives according to claim 1 or 2, it is characterised in that the antioxidant is vitamin E
Oil, the crosslinking agent are glyoxal.
4. a kind of preparation method of high-temperature Resistance Adhesives, it is characterised in that comprise the following steps：
(1) raw material of following parts by weight is weighed：5~15 parts of polyvinyl butyral, 4~10 parts of triethanolamine, expoxy propane benzene
5~15 parts of base ether, 4~12 parts of benzisothia oxazolone, 3~9 parts of hydrop diisopropylbenzene (DIPB), hydroxypropyl PASELLI EASYGEL 4
~10 parts, 3~9 parts of 1-METHYLPYRROLIDONE, 4~10 parts of hydrop diisopropylbenzene (DIPB), 3~9 parts of methacrylic acid, add anti-
Answer in kettle, progressively heat up, and be slowly stirred, start timing when temperature rises to 95 DEG C, be incubated 10~30mi n, while carry out even
Speed stirring, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds antioxidant and 2~6 parts of crosslinking agent that parts by weight are 4~10 parts, stirring is equal
After even, the high-temperature Resistance Adhesives are produced.
A kind of 5. preparation method of high-temperature Resistance Adhesives according to claim 4, it is characterised in that step (1) described original
The parts by weight of material are：10 parts of polyvinyl butyral, 7 parts of triethanolamine, 10 parts of expoxy propane phenyl ether, benzisothia oxazolone 8
Part, 6 parts of hydrop diisopropylbenzene (DIPB), 7 parts of hydroxypropyl PASELLI EASYGEL, 6 parts of 1-METHYLPYRROLIDONE, hydrop two
7 parts of isopropylbenzene, 6 parts of methacrylic acid.
6. the preparation method of a kind of high-temperature Resistance Adhesives according to claim 4, it is characterised in that step (2) is described anti-
The parts by weight of oxidant are 7 parts, and the parts by weight of the crosslinking agent are 4 parts.
7. the preparation method of a kind of high-temperature Resistance Adhesives according to claim any one of 4-6, it is characterised in that described anti-
Oxidant is vitamin E oil, and the crosslinking agent is glyoxal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711085946.2A CN107674595A (en) | 2017-11-07 | 2017-11-07 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711085946.2A CN107674595A (en) | 2017-11-07 | 2017-11-07 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107674595A true CN107674595A (en) | 2018-02-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711085946.2A Withdrawn CN107674595A (en) | 2017-11-07 | 2017-11-07 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107674595A (en) |
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2017
- 2017-11-07 CN CN201711085946.2A patent/CN107674595A/en not_active Withdrawn
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Application publication date: 20180209 |