CN105255445A - Novel high-temperature-resistant adhesive and preparation method thereof - Google Patents
Novel high-temperature-resistant adhesive and preparation method thereof Download PDFInfo
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- CN105255445A CN105255445A CN201510657155.7A CN201510657155A CN105255445A CN 105255445 A CN105255445 A CN 105255445A CN 201510657155 A CN201510657155 A CN 201510657155A CN 105255445 A CN105255445 A CN 105255445A
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Abstract
The invention discloses a novel high-temperature-resistant adhesive and a preparation method thereof, and belongs to the technical field of chemical industry. The novel high-temperature-resistant adhesive is prepared from, by weight, 5-10 parts of hydrogenated rosin glyceride, 3-9 parts of tricresyl phosphate, 5-10 parts of glycidol phenyl ether, 1-5 parts of polyvinyl alcohol resin, 3-9 parts of ethylenediamine tetraacetic acid, 2-6 parts of polyurethane resin, 2-6 parts of calcium chloride, 1-5 parts of fly ash, 1-5 parts of diaminodiphenyl-methane, 2-6 parts of quartz sand, 4-10 parts of light calcium carbonate, 8-15 parts of antioxidants and 4-10 parts of crosslinking agents. The adhesive has the very good high temperature resistance, so that the adhesive can be normally used at high temperature; meanwhile, the adhesive has the very good adhesiveness, so that the adhesive effect is good; in addition, the adhesive is easy to prepare, low in cost and excellent in property.
Description
Technical field
The present invention relates to sizing agent of a kind of novel fire resistant and preparation method thereof, belong to chemical technology field.
Background technology
Sizing agent, refers to the technology that homogeneity or heterogeneous body surface sizing agent link together to have the features such as stress distribution is continuous, lightweight, technological temperature is low.Glued joint the connection being specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide.The sorting technique of sizing agent is a lot, can be divided into heat curing-type, hot-melting type, room temperature curing type, pressure sensitive etc. by application method; Structure-type, non-configuration or special gelatin is divided into by application; Connect form and can be divided into water-soluble, water-latex type, solvent-borne type and various solid-state versions etc.; Tradition sizing agent production cost is high, and result of use is bad.
Summary of the invention
The object of the invention is to make up the deficiencies in the prior art, sizing agent of a kind of novel fire resistant and preparation method thereof is provided.Sizing agent of the present invention has good resistance to elevated temperatures, at high temperature can normally use, and has good cohesiveness simultaneously, and bond effect is good, and makes simple, with low cost, excellent property.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: a kind of sizing agent of novel fire resistant, comprises the raw material of following parts by weight: hydrogenated rosin glyceride 5 ~ 10 parts, tritolyl phosphate 3 ~ 9 parts, propylene oxide phenyl ether 5 ~ 10 parts, polyvinyl alcohol resin 1 ~ 5 part, ethylenediamine tetraacetic acid (EDTA) 3 ~ 9 parts, urethane resin 2 ~ 6 parts, 2 ~ 6 parts, calcium chloride, 1 ~ 5 part, flyash, diaminodiphenyl-methane 1 ~ 5 part, quartz sand 2 ~ 6 parts, light calcium carbonate 4 ~ 10 parts, antioxidant 8 ~ 15 parts and linking agent 4 ~ 10 parts.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the raw material of following parts by weight is comprised: hydrogenated rosin glyceride 7 parts, tritolyl phosphate 6 parts, propylene oxide phenyl ether 8 parts, polyvinyl alcohol resin 3 parts, ethylenediamine tetraacetic acid (EDTA) 6 parts, urethane resin 4 parts, 4 parts, calcium chloride, 3 parts, flyash, diaminodiphenyl-methane 3 parts, quartz sand 4 parts, light calcium carbonate 7 parts, antioxidant 12 parts and linking agent 7 parts.
Further, described antioxidant is vitamin E oil, and described linking agent is oxalic dialdehyde.
A making method for the sizing agent of novel fire resistant, comprises the steps:
(1) raw material of following parts by weight is taken: hydrogenated rosin glyceride 5 ~ 10 parts, tritolyl phosphate 3 ~ 9 parts, propylene oxide phenyl ether 5 ~ 10 parts, polyvinyl alcohol resin 1 ~ 5 part, ethylenediamine tetraacetic acid (EDTA) 3 ~ 9 parts, urethane resin 2 ~ 6 parts, 2 ~ 6 parts, calcium chloride, 1 ~ 5 part, flyash, diaminodiphenyl-methane 1 ~ 5 part, quartz sand 2 ~ 6 parts, light calcium carbonate 4 ~ 10 parts, add in reactor, progressively heat up, and slowly stir, timing is started when temperature rises to 95 DEG C, be incubated 30 minutes, at the uniform velocity stir, until reach reaction end simultaneously;
(2) continue to be warming up to 100 DEG C, adding parts by weight is the antioxidant of 8 ~ 15 parts and the linking agent of 4 ~ 10 parts, after stirring, obtains the sizing agent of described novel fire resistant.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the parts by weight of step (1) described raw material are: hydrogenated rosin glyceride 7 parts, tritolyl phosphate 6 parts, propylene oxide phenyl ether 8 parts, polyvinyl alcohol resin 3 parts, ethylenediamine tetraacetic acid (EDTA) 6 parts, urethane resin 4 parts, 4 parts, calcium chloride, 3 parts, flyash, diaminodiphenyl-methane 3 parts, quartz sand 4 parts, light calcium carbonate 7 parts.
Further, the parts by weight of step (2) described antioxidant are 12 parts, and the parts by weight of described linking agent are 7 parts.
Further, described antioxidant is vitamin E oil, and described linking agent is oxalic dialdehyde.
The invention has the beneficial effects as follows:
(1) sizing agent of the present invention has good resistance to elevated temperatures, at high temperature can normally use, and has good cohesiveness simultaneously, and bond effect is good.
(2) simple, with low cost, the excellent property of making of the present invention, is applicable to large-scale production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
(1) raw material of following weight is taken: hydrogenated rosin glyceride 5kg, tritolyl phosphate 9kg, propylene oxide phenyl ether 5kg, polyvinyl alcohol resin 5kg, ethylenediamine tetraacetic acid (EDTA) 3kg, urethane resin 6kg, calcium chloride 2kg, flyash 5kg, diaminodiphenyl-methane 1kg, quartz sand 6kg, light calcium carbonate 4kg, add in reactor, progressively heat up, and slowly stir, timing is started when temperature rises to 95 DEG C, be incubated 30 minutes, at the uniform velocity stir, until reach reaction end simultaneously;
(2) continue to be warming up to 100 DEG C, adding weight is the vitamin E oil of 8kg and the oxalic dialdehyde of 10kg, after stirring, obtains the sizing agent of described novel fire resistant.
Embodiment 2:
(1) raw material of following weight is taken: hydrogenated rosin glyceride 7kg, tritolyl phosphate 6kg, propylene oxide phenyl ether 8kg, polyvinyl alcohol resin 3kg, ethylenediamine tetraacetic acid (EDTA) 6kg, urethane resin 4kg, calcium chloride 4kg, flyash 3kg, diaminodiphenyl-methane 3kg, quartz sand 4kg, light calcium carbonate 7kg, add in reactor, progressively heat up, and slowly stir, timing is started when temperature rises to 95 DEG C, be incubated 30 minutes, at the uniform velocity stir, until reach reaction end simultaneously;
(2) continue to be warming up to 100 DEG C, adding weight is the vitamin E oil of 12kg and the oxalic dialdehyde of 7kg, after stirring, obtains the sizing agent of described novel fire resistant.
Embodiment 3:
(1) raw material of following weight is taken: hydrogenated rosin glyceride 10kg, tritolyl phosphate 3kg, propylene oxide phenyl ether 10kg, polyvinyl alcohol resin 1kg, ethylenediamine tetraacetic acid (EDTA) 9kg, urethane resin 2kg, calcium chloride 6kg, flyash 1kg, diaminodiphenyl-methane 5kg, quartz sand 2kg, light calcium carbonate 10kg, add in reactor, progressively heat up, and slowly stir, timing is started when temperature rises to 95 DEG C, be incubated 30 minutes, at the uniform velocity stir, until reach reaction end simultaneously;
(2) continue to be warming up to 100 DEG C, adding weight is the vitamin E oil of 15kg and the oxalic dialdehyde of 4kg, after stirring, obtains the sizing agent of described novel fire resistant.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (7)
1. the sizing agent of a novel fire resistant, it is characterized in that, comprise the raw material of following parts by weight: hydrogenated rosin glyceride 5 ~ 10 parts, tritolyl phosphate 3 ~ 9 parts, propylene oxide phenyl ether 5 ~ 10 parts, polyvinyl alcohol resin 1 ~ 5 part, ethylenediamine tetraacetic acid (EDTA) 3 ~ 9 parts, urethane resin 2 ~ 6 parts, 2 ~ 6 parts, calcium chloride, 1 ~ 5 part, flyash, diaminodiphenyl-methane 1 ~ 5 part, quartz sand 2 ~ 6 parts, light calcium carbonate 4 ~ 10 parts, antioxidant 8 ~ 15 parts and linking agent 4 ~ 10 parts.
2. the sizing agent of a kind of novel fire resistant according to claim 1, it is characterized in that, comprise the raw material of following parts by weight: hydrogenated rosin glyceride 7 parts, tritolyl phosphate 6 parts, propylene oxide phenyl ether 8 parts, polyvinyl alcohol resin 3 parts, ethylenediamine tetraacetic acid (EDTA) 6 parts, urethane resin 4 parts, 4 parts, calcium chloride, 3 parts, flyash, diaminodiphenyl-methane 3 parts, quartz sand 4 parts, light calcium carbonate 7 parts, antioxidant 12 parts and linking agent 7 parts.
3. the sizing agent of a kind of novel fire resistant according to claim 1 and 2, is characterized in that, described antioxidant is vitamin E oil, and described linking agent is oxalic dialdehyde.
4. a making method for the sizing agent of novel fire resistant, is characterized in that, comprises the steps:
(1) raw material of following parts by weight is taken: hydrogenated rosin glyceride 5 ~ 10 parts, tritolyl phosphate 3 ~ 9 parts, propylene oxide phenyl ether 5 ~ 10 parts, polyvinyl alcohol resin 1 ~ 5 part, ethylenediamine tetraacetic acid (EDTA) 3 ~ 9 parts, urethane resin 2 ~ 6 parts, 2 ~ 6 parts, calcium chloride, 1 ~ 5 part, flyash, diaminodiphenyl-methane 1 ~ 5 part, quartz sand 2 ~ 6 parts, light calcium carbonate 4 ~ 10 parts, add in reactor, progressively heat up, and slowly stir, timing is started when temperature rises to 95 DEG C, be incubated 30 minutes, at the uniform velocity stir, until reach reaction end simultaneously;
(2) continue to be warming up to 100 DEG C, adding parts by weight is the antioxidant of 8 ~ 15 parts and the linking agent of 4 ~ 10 parts, after stirring, obtains the sizing agent of described novel fire resistant.
5. the making method of the sizing agent of a kind of novel fire resistant according to claim 4, it is characterized in that, the parts by weight of step (1) described raw material are: hydrogenated rosin glyceride 7 parts, tritolyl phosphate 6 parts, propylene oxide phenyl ether 8 parts, polyvinyl alcohol resin 3 parts, ethylenediamine tetraacetic acid (EDTA) 6 parts, urethane resin 4 parts, 4 parts, calcium chloride, 3 parts, flyash, diaminodiphenyl-methane 3 parts, quartz sand 4 parts, light calcium carbonate 7 parts.
6. the making method of the sizing agent of a kind of novel fire resistant according to claim 4, is characterized in that, the parts by weight of step (2) described antioxidant are 12 parts, and the parts by weight of described linking agent are 7 parts.
7. the making method of the sizing agent of a kind of novel fire resistant according to any one of claim 4-6, is characterized in that, described antioxidant is vitamin E oil, and described linking agent is oxalic dialdehyde.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510657155.7A CN105255445A (en) | 2015-10-13 | 2015-10-13 | Novel high-temperature-resistant adhesive and preparation method thereof |
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| CN201510657155.7A CN105255445A (en) | 2015-10-13 | 2015-10-13 | Novel high-temperature-resistant adhesive and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106336837A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Heat resistant adhesive and preparation method thereof |
| CN106336846A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Novel high temperature resistant adhesive and preparation method thereof, |
| CN107629723A (en) * | 2017-10-20 | 2018-01-26 | 桂林市春晓环保科技有限公司 | A kind of high viscosity adhesive and preparation method thereof |
| CN107652926A (en) * | 2017-10-20 | 2018-02-02 | 桂林市春晓环保科技有限公司 | A kind of thermosol and preparation method thereof |
| CN107722815A (en) * | 2017-10-20 | 2018-02-23 | 桂林市春晓环保科技有限公司 | A kind of environment friendly heat resistant adhesive and preparation method thereof |
| CN107793990A (en) * | 2017-11-07 | 2018-03-13 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of low temperature adhesive and preparation method thereof |
| CN107841278A (en) * | 2017-10-20 | 2018-03-27 | 桂林市春晓环保科技有限公司 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881590A (en) * | 2014-03-10 | 2014-06-25 | 苏州捷德瑞精密机械有限公司 | Metal adhesive and preparation method thereof |
| CN104387994A (en) * | 2014-10-30 | 2015-03-04 | 田琳琳 | Metal binding agent |
| CN104403621A (en) * | 2014-11-04 | 2015-03-11 | 张桂华 | Efficient metal adhesive |
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2015
- 2015-10-13 CN CN201510657155.7A patent/CN105255445A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881590A (en) * | 2014-03-10 | 2014-06-25 | 苏州捷德瑞精密机械有限公司 | Metal adhesive and preparation method thereof |
| CN104387994A (en) * | 2014-10-30 | 2015-03-04 | 田琳琳 | Metal binding agent |
| CN104403621A (en) * | 2014-11-04 | 2015-03-11 | 张桂华 | Efficient metal adhesive |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106336837A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Heat resistant adhesive and preparation method thereof |
| CN106336846A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | Novel high temperature resistant adhesive and preparation method thereof, |
| CN107629723A (en) * | 2017-10-20 | 2018-01-26 | 桂林市春晓环保科技有限公司 | A kind of high viscosity adhesive and preparation method thereof |
| CN107652926A (en) * | 2017-10-20 | 2018-02-02 | 桂林市春晓环保科技有限公司 | A kind of thermosol and preparation method thereof |
| CN107722815A (en) * | 2017-10-20 | 2018-02-23 | 桂林市春晓环保科技有限公司 | A kind of environment friendly heat resistant adhesive and preparation method thereof |
| CN107841278A (en) * | 2017-10-20 | 2018-03-27 | 桂林市春晓环保科技有限公司 | A kind of high-temperature Resistance Adhesives and preparation method thereof |
| CN107793990A (en) * | 2017-11-07 | 2018-03-13 | 桂林奥尼斯特节能环保科技有限责任公司 | A kind of low temperature adhesive and preparation method thereof |
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Application publication date: 20160120 |