CN107652918A - A kind of flame retardant type adhesive and preparation method thereof - Google Patents
A kind of flame retardant type adhesive and preparation method thereof Download PDFInfo
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- CN107652918A CN107652918A CN201711084463.0A CN201711084463A CN107652918A CN 107652918 A CN107652918 A CN 107652918A CN 201711084463 A CN201711084463 A CN 201711084463A CN 107652918 A CN107652918 A CN 107652918A
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- parts
- flame retardant
- dipb
- type adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/06—Esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J101/00—Adhesives based on cellulose, modified cellulose, or cellulose derivatives
- C09J101/08—Cellulose derivatives
- C09J101/26—Cellulose ethers
- C09J101/28—Alkyl ethers
- C09J101/284—Alkyl ethers with hydroxylated hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of flame retardant type adhesive and preparation method thereof, belong to chemical technology field.It is made up of the raw material of following parts by weight：2~6 parts of 4~10 parts of polyvinyl butyral, 2~8 parts of triethanolamine, 4~10 parts of expoxy propane phenyl ether, 2~8 parts of benzisothia oxazolone, 4~10 parts of hydrop diisopropylbenzene (DIPB), 5~15 parts of hydroxypropyl PASELLI EASYGEL, 4~10 parts of N methyl pyrrolidones, 4~10 parts of hydrop diisopropylbenzene (DIPB), 4~12 parts of methyl hydroxyethylcellulose, 4~10 parts of antioxidant and crosslinking agent.The adhesive of the present invention has good fire resistance, at high temperature can be with normal use, while has good caking property, and bond effect is good, and making is simple, cost is cheap, function admirable.
Description
Technical field
The present invention relates to a kind of flame retardant type adhesive and preparation method thereof, belong to chemical technology field.
Background technology
Adhesive, refer to homogeneity or the technology that heterogeneous body surface is linked together with adhesive, there is stress distribution to connect
The features such as continuous, in light weight, technological temperature is low.It is glued especially suitable for unlike material, different-thickness, ultra-thin specification and complex component
Connection.Splicing RECENT DEVELOPMENTS is most fast, and application industry is extremely wide.The sorting technique of adhesive is a lot, can be divided into heat by application process
Curable type, heat molten type, room temperature curing type, pressure sensitive etc.；It is divided into structural type, non-configuration or special gelatin by application；Connecing form can
It is divided into water-soluble, emulsion type, solvent-borne type and various solid-state versions etc.；Traditional adhesive production cost is high, and using effect is bad.
The content of the invention
The purpose of the present invention is to make up the deficiencies in the prior art, there is provided a kind of flame retardant type adhesive and preparation method thereof.This
The adhesive of invention has good fire resistance, at high temperature can be with normal use, while has good caking property, bonds
Effect is good, and making is simple, cost is cheap, function admirable.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of flame retardant type adhesive, by following parts by weight
Raw material be made：4~10 parts of polyvinyl butyral, 2~8 parts of triethanolamine, 4~10 parts of expoxy propane phenyl ether, benzisothia
2~8 parts of oxazolone, 4~10 parts of hydrop diisopropylbenzene (DIPB), 5~15 parts of hydroxypropyl PASELLI EASYGEL, 1-METHYLPYRROLIDONE
4~10 parts, 4~10 parts of hydrop diisopropylbenzene (DIPB), 4~12 parts of methyl hydroxyethylcellulose, 4~10 parts of antioxidant and friendship
Join 2~6 parts of agent.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, it is made up of the raw material of following parts by weight：7 parts of polyvinyl butyral, 5 parts of triethanolamine, expoxy propane
7 parts of phenyl ether, 5 parts of benzisothia oxazolone, 7 parts of hydrop diisopropylbenzene (DIPB), 10 parts of hydroxypropyl PASELLI EASYGEL, N- methyl
4 parts of 7 parts of pyrrolidones, 7 parts of hydrop diisopropylbenzene (DIPB), 8 parts of methyl hydroxyethylcellulose, 7 parts of antioxidant and crosslinking agent.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
A kind of preparation method of flame retardant type adhesive, comprises the following steps：
(1) raw material of following parts by weight is weighed：4~10 parts of polyvinyl butyral, 2~8 parts of triethanolamine, expoxy propane
4~10 parts of phenyl ether, 2~8 parts of benzisothia oxazolone, 4~10 parts of hydrop diisopropylbenzene (DIPB), hydroxypropyl PASELLI EASYGEL
5~15 parts, 4~10 parts of 1-METHYLPYRROLIDONE, 4~10 parts of hydrop diisopropylbenzene (DIPB), methyl hydroxyethylcellulose 4~12
Part, add in reactor, progressively heat up, and be slowly stirred, start timing when temperature rises to 95 DEG C, be incubated 10~30min, together
Shi Jinhang is at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, antioxidant and 2~6 parts of crosslinking agent that parts by weight are 4~10 parts is added, stirs
After mixing uniformly, the flame retardant type adhesive is produced.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the parts by weight of step (1) described raw material are：7 parts of polyvinyl butyral, 5 parts of triethanolamine, epoxy third
7 parts of alkane phenyl ether, 5 parts of benzisothia oxazolone, 7 parts of hydrop diisopropylbenzene (DIPB), 10 parts of hydroxypropyl PASELLI EASYGEL, N- first
7 parts of base pyrrolidones, 7 parts of hydrop diisopropylbenzene (DIPB), 8 parts of methyl hydroxyethylcellulose.
Further, the parts by weight of step (2) described antioxidant are 6 parts, and the parts by weight of the crosslinking agent are 9 parts.
Further, the antioxidant is vitamin E oil, and the crosslinking agent is glyoxal.
The beneficial effects of the invention are as follows：
(1) adhesive of the invention has good fire resistance, at high temperature can be with normal use, while has very well
Caking property, bond effect is good.
(2) making of the invention is simple, cost is cheap, function admirable, is adapted to large-scale production.
Embodiment
The principle and feature of the present invention are described below in conjunction with specific embodiment, example is served only for explaining this hair
It is bright, it is not intended to limit the scope of the present invention.
Embodiment 1：
The flame retardant type adhesive of the present embodiment, is made up of the raw material of following weight：Polyvinyl butyral 4kg, triethanolamine
8kg, expoxy propane phenyl ether 4kg, benzisothia oxazolone 8kg, hydrop diisopropylbenzene (DIPB) 4kg, the starch phosphate of hydroxypropyl two
Ester 15kg, 1-METHYLPYRROLIDONE 4kg, hydrop diisopropylbenzene (DIPB) 10kg, methyl hydroxyethylcellulose 4kg, vitamin E oil
10kg and glyoxal 2kg.
The preparation method of above-mentioned flame retardant type adhesive, comprises the following steps：
(1) raw material of following weight is weighed：Polyvinyl butyral 4kg, triethanolamine 8kg, expoxy propane phenyl ether 4kg,
Benzisothia oxazolone 8kg, hydrop diisopropylbenzene (DIPB) 4kg, hydroxypropyl PASELLI EASYGEL 15kg, 1-METHYLPYRROLIDONE
4kg, hydrop diisopropylbenzene (DIPB) 10kg, methyl hydroxyethylcellulose 4kg, add in reactor, progressively heat up, and slowly stir
Mix, start timing when temperature rises to 95 DEG C, be incubated 10min, while at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, vitamin E oil 10kg and glyoxal 2kg is added, after stirring, produces the resistance
Combustion type adhesive.
Embodiment 2：
The flame retardant type adhesive of the present embodiment, is made up of the raw material of following weight：Polyvinyl butyral 7kg, triethanolamine
5kg, expoxy propane phenyl ether 7kg, benzisothia oxazolone 5kg, hydrop diisopropylbenzene (DIPB) 7kg, the starch phosphate of hydroxypropyl two
Ester 10kg, 1-METHYLPYRROLIDONE 7kg, hydrop diisopropylbenzene (DIPB) 7kg, methyl hydroxyethylcellulose 8kg, vitamin E oil
7kg and glyoxal 4kg.
The preparation method of above-mentioned flame retardant type adhesive, comprises the following steps：
(1) raw material of following weight is weighed：：Polyvinyl butyral 7kg, triethanolamine 5kg, expoxy propane phenyl ether 7kg,
Benzisothia oxazolone 5kg, hydrop diisopropylbenzene (DIPB) 7kg, hydroxypropyl PASELLI EASYGEL 10kg, 1-METHYLPYRROLIDONE
7kg, hydrop diisopropylbenzene (DIPB) 7kg, methyl hydroxyethylcellulose 8kg, add in reactor, progressively heat up, and slowly stir
Mix, start timing when temperature rises to 95 DEG C, be incubated 20min, while at the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, vitamin E oil 7kg and glyoxal 4kg is added, after stirring, produces the resistance
Combustion type adhesive.
Embodiment 3：
The flame retardant type adhesive of the present embodiment, is made up of the raw material of following weight：Polyvinyl butyral 10kg, triethanolamine
2kg, expoxy propane phenyl ether 10kg, benzisothia oxazolone 2kg, hydrop diisopropylbenzene (DIPB) 10kg, the starch phosphorus of hydroxypropyl two
It is acid esters 5kg, 1-METHYLPYRROLIDONE 10kg, hydrop diisopropylbenzene (DIPB) 4kg, methyl hydroxyethylcellulose 12kg, anti-oxidant
Agent 4kg and crosslinking agent 6kg.
The preparation method of above-mentioned flame retardant type adhesive, comprises the following steps：
(1) raw material of following weight is weighed：Polyvinyl butyral 10kg, triethanolamine 2kg, expoxy propane phenyl ether
10kg, benzisothia oxazolone 2kg, hydrop diisopropylbenzene (DIPB) 10kg, hydroxypropyl PASELLI EASYGEL 5kg, N- methylpyrrole
Alkanone 10kg, hydrop diisopropylbenzene (DIPB) 4kg, methyl hydroxyethylcellulose 12kg, add in reactor, progressively heat up, and
It is slowly stirred, starts timing when temperature rises to 95 DEG C, be incubated 30min, while at the uniform velocity stirred, until reaches reaction eventually
Point；
(2) 100 DEG C are continuously heating to, vitamin E oil 4kg and glyoxal 6kg is added, after stirring, produces the resistance
Combustion type adhesive.
Comparative example
The adhesive of certain domestic producer is taken, it includes the raw material of following weight：Succinic acid 10kg, triethanolamine 4kg, epoxy
Propane phenyl ether 8kg, 1,3-PD 6kg, adipic acid 10kg, hydrop diisopropylbenzene (DIPB) 6kg, calcium chloride 5kg, with implementation
Example 1-3 obtained flame-retardant type adhesives contrast, viscous material phase same material fine powder 300kg.Comparing result is as shown in table 1.
The comparing result of the prior art of table 1 and the method for the present invention
As can be seen here, adhesive of the invention has good fire resistance, can have simultaneously with normal use at high temperature
There is good caking property, bond effect is good.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (7)
1. a kind of flame retardant type adhesive, it is characterised in that be made up of the raw material of following parts by weight：Polyvinyl butyral 4~10
Part, 2~8 parts of triethanolamine, 4~10 parts of expoxy propane phenyl ether, 2~8 parts of benzisothia oxazolone, hydrop diisopropylbenzene (DIPB)
4~10 parts, 5~15 parts of hydroxypropyl PASELLI EASYGEL, 4~10 parts of 1-METHYLPYRROLIDONE, hydrop diisopropylbenzene (DIPB) 4~
2~6 parts of 10 parts, 4~12 parts of methyl hydroxyethylcellulose, 4~10 parts of antioxidant and crosslinking agent.
2. a kind of flame retardant type adhesive according to claim 1, it is characterised in that by the raw material system of following parts by weight
Into：7 parts of polyvinyl butyral, 5 parts of triethanolamine, 7 parts of expoxy propane phenyl ether, 5 parts of benzisothia oxazolone, hydrop two
7 parts of isopropylbenzene, 10 parts of hydroxypropyl PASELLI EASYGEL, 7 parts of 1-METHYLPYRROLIDONE, 7 parts of hydrop diisopropylbenzene (DIPB), methyl
4 parts of 8 parts of hydroxyethyl cellulose, 7 parts of antioxidant and crosslinking agent.
3. a kind of flame retardant type adhesive according to claim 1 or 2, it is characterised in that the antioxidant is vitamin E
Oil, the crosslinking agent are glyoxal.
4. a kind of preparation method of flame retardant type adhesive, it is characterised in that comprise the following steps：
(1) raw material of following parts by weight is weighed：4~10 parts of polyvinyl butyral, 2~8 parts of triethanolamine, expoxy propane phenyl
4~10 parts of ether, 2~8 parts of benzisothia oxazolone, 4~10 parts of hydrop diisopropylbenzene (DIPB), hydroxypropyl PASELLI EASYGEL 5~
15 parts, 4~10 parts of 1-METHYLPYRROLIDONE, 4~10 parts of hydrop diisopropylbenzene (DIPB), 4~12 parts of methyl hydroxyethylcellulose,
Add in reactor, progressively heat up, and be slowly stirred, start timing when temperature rises to 95 DEG C, be incubated 10~30min, simultaneously
At the uniform velocity stirred, until reaching reaction end；
(2) 100 DEG C are continuously heating to, adds antioxidant and 2~6 parts of crosslinking agent that parts by weight are 4~10 parts, stirring is equal
After even, the flame retardant type adhesive is produced.
A kind of 5. preparation method of flame retardant type adhesive according to claim 4, it is characterised in that step (1) described original
The parts by weight of material are：7 parts of polyvinyl butyral, 5 parts of triethanolamine, 7 parts of expoxy propane phenyl ether, 5 parts of benzisothia oxazolone,
7 parts of hydrop diisopropylbenzene (DIPB), 10 parts of hydroxypropyl PASELLI EASYGEL, 7 parts of 1-METHYLPYRROLIDONE, hydrop two are different
7 parts of propyl benzene, 8 parts of methyl hydroxyethylcellulose.
6. the preparation method of a kind of flame retardant type adhesive according to claim 4, it is characterised in that step (2) is described anti-
The parts by weight of oxidant are 7 parts, and the parts by weight of the crosslinking agent are 4 parts.
7. the preparation method of a kind of flame retardant type adhesive according to claim any one of 4-6, it is characterised in that described anti-
Oxidant is vitamin E oil, and the crosslinking agent is glyoxal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711084463.0A CN107652918A (en) | 2017-11-07 | 2017-11-07 | A kind of flame retardant type adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711084463.0A CN107652918A (en) | 2017-11-07 | 2017-11-07 | A kind of flame retardant type adhesive and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107652918A true CN107652918A (en) | 2018-02-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711084463.0A Pending CN107652918A (en) | 2017-11-07 | 2017-11-07 | A kind of flame retardant type adhesive and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371602A (en) * | 2014-10-31 | 2015-02-25 | 青岛昌安达药业有限公司 | High-temperature-resistant adhesive |
| CN106336845A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | High temperature resistant adhesive and preparation method thereof |
-
2017
- 2017-11-07 CN CN201711084463.0A patent/CN107652918A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371602A (en) * | 2014-10-31 | 2015-02-25 | 青岛昌安达药业有限公司 | High-temperature-resistant adhesive |
| CN106336845A (en) * | 2016-08-22 | 2017-01-18 | 桂林新艺制冷设备有限责任公司 | High temperature resistant adhesive and preparation method thereof |
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Application publication date: 20180202 |