CN107325549B - Yellowing-resistant reinforced nylon 66 material and preparation method thereof - Google Patents
Yellowing-resistant reinforced nylon 66 material and preparation method thereof Download PDFInfo
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- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 39
- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000004383 yellowing Methods 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000003365 glass fiber Substances 0.000 claims abstract description 44
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 239000004677 Nylon Substances 0.000 claims abstract description 19
- 229920001778 nylon Polymers 0.000 claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- 239000007822 coupling agent Substances 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 10
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 9
- 239000010452 phosphate Substances 0.000 claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000006136 alcoholysis reaction Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 4
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 3
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 3
- 235000011010 calcium phosphates Nutrition 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 229910000398 iron phosphate Inorganic materials 0.000 claims description 2
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 2
- 239000004137 magnesium phosphate Substances 0.000 claims description 2
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 2
- 229960002261 magnesium phosphate Drugs 0.000 claims description 2
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 2
- 235000011009 potassium phosphates Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000002791 soaking Methods 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000005955 Ferric phosphate Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 229940032958 ferric phosphate Drugs 0.000 description 2
- 229910000399 iron(III) phosphate Inorganic materials 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention provides a yellowing-resistant reinforced nylon 66 material and a preparation method thereof. The preparation method comprises the following steps: dispersing a functional monomer and a phosphate heat stabilizer into a coupling agent, adding ethanol for dilution and alcoholysis, and adjusting the pH value of the slurry to 3.2-3.8; and (3) infiltrating and drying the glass fiber through the prepared sizing agent in advance to obtain the treated glass fiber. Uniformly mixing nylon 66, long carbon chain nylon and an antioxidant by using a high-speed stirrer, adding the mixture from a main feeding port of a double-screw extruder, adding the treated special glass fiber from a side feeding port, extruding, drawing into strips, and granulating to obtain the yellowing-resistant reinforced nylon 66 composite material. The yellowing resistance of the material prepared by the invention is far higher than that of other common reinforced materials.
Description
Technical Field
The invention relates to the field of macromolecules, and particularly relates to a yellowing-resistant reinforced nylon 66 material and a preparation method thereof.
Background
Nylon 66 is used as engineering plastic and widely applied to different industries such as automobiles, electronic appliances, civil products and the like; especially, after the glass fiber is reinforced, the strength and the heat resistance are greatly improved, and the application range of the glass fiber reinforced heat-resistant glass fiber is greatly expanded. However, the amido bond in the molecular structure of the material has strong reducibility, so the material is very easy to be oxidized and yellowed in the drying process and the injection molding processing process, and the application of the material to light-colored products is limited.
At present, two ways are mainly adopted for improving the color change of nylon 66, one way is the process of directly adding an antioxidant to relieve the color change; another way is to make the alloy by adding some of the same kind of materials with low discoloration.
However, for high molecular materials, both of the above two approaches have drawbacks; wherein, the direct addition of the antioxidant has limited effect because of low addition amount and difficult uniform dispersion; while the direct addition of low discoloration materials to make the alloy would compromise the high strength of nylon 66. Therefore, a nylon 66 material with good yellowing resistance on the basis of ensuring the mechanical property of the material is urgently needed to be found.
Disclosure of Invention
The technical problem to be solved is as follows: the invention aims to provide a yellowing-resistant reinforced nylon 66 material, which inhibits the yellowing of reinforced nylon 66, ensures the mechanical property of the material and solves the application problem of reinforced nylon 66 on light-colored products. .
The technical scheme is as follows: the yellowing-resistant reinforced nylon 66 material comprises the following components in percentage by weight:
nylon 66100 parts,
10-50 parts of long carbon chain nylon,
40-80 parts of alkali-free glass fiber,
1-3 parts of functional monomer,
0.5 to 1.5 portions of coupling agent,
0.5 to 1.5 portions of phosphate heat stabilizer,
0.5-1.5 parts of antioxidant;
wherein the functional monomer is a group which chemically reacts with a nylon amido bond.
Further, the long carbon chain nylon is one or more of nylon 610, nylon 612, nylon 1010, nylon 1012 or nylon 1212.
Further, the functional monomer of the yellowing-resistant reinforced nylon 66 material is one or more of maleic anhydride, acrylic acid or methacrylic acid.
Further, the relative viscosity of the nylon 66 is 1.8-4.0.
Further, the anti-yellowing reinforced nylon 66 material is characterized in that the coupling agent is one or more of a silane coupling agent, an aluminate coupling agent or a carbonate coupling agent.
Further, the yellowing-resistant reinforced nylon 66 material is characterized in that the phosphate heat stabilizer is one or more of sodium phosphate, calcium phosphate, iron phosphate, copper phosphate, potassium phosphate or magnesium phosphate.
Further, the anti-yellowing reinforced nylon 66 material is characterized in that the antioxidant is one or more of antioxidant 1010, antioxidant 1076, antioxidant 1098, antioxidant 245 or antioxidant 445.
The preparation method of the yellowing-resistant reinforced nylon 66 material comprises the following steps:
(1) uniformly stirring and mixing the functional monomer, the phosphate heat stabilizer and the coupling agent, adding ethanol for dispersing, diluting and alcoholyzing, and adjusting the pH value of the solution to 3.2-3.8 to obtain special slurry for processing the glass fiber;
(2) infiltrating the glass fiber with special size, and drying to obtain special glass fiber with treated surface;
(3) adding nylon 66, long carbon chain nylon and an antioxidant into a low-speed stirrer, uniformly mixing, adding a small amount of white oil in the mixing process for adhesion, and uniformly mixing to obtain premixed particles;
(4) and (3) adding the premix obtained in the step (3) into a main feeding hopper of a double-screw extruder, and adding the special glass fiber obtained in the step (2) through side feeding, wherein the extrusion temperature is between 240 ℃ and 270 ℃.
Has the advantages that: according to the invention, the phosphate heat stabilizer is dispersed on the surface of the glass fiber innovatively, and the impregnating compound and the reaction type auxiliary agent are simultaneously dispersed on the surface of the glass fiber, so that the resin is ensured to have chemical bond bonding on the interface bonded with the glass fiber, and the heat stabilizer also plays a role sufficiently to inhibit the oxidative discoloration of amido bond. The yellowing-resistant reinforced nylon 66 material disclosed by the invention has the mechanical properties of the material and solves the problem that the light-colored reinforced nylon 66 is easy to yellow.
Detailed Description
Example 1
Stirring and mixing 1.2kg of maleic anhydride, 0.5kg of sodium phosphate and 0.5kg of silane coupling agent KH550 uniformly, adding 10000ml of ethanol for dispersing and alcoholysis, and adjusting the pH value of the solution to 3.2 to obtain special slurry for treating glass fibers; then, soaking 48kg of alkali-free glass fiber by using special slurry, and drying to obtain special glass fiber with the surface treated; adding 100kg of nylon 66, 10kg of nylon 612 and 0.5kg of antioxidant 1098 into a low-speed stirrer, uniformly mixing, and adding a small amount of white oil for adhesion in the mixing process to obtain a premix; finally, adding the premix into a main feeding bin of a double-screw extruder, and adding the treated special glass fiber through side feeding, wherein the extrusion temperature is 240 ℃; and (5) drawing strips, cooling and cutting into granules. The particles were dried in an oven at 80 ℃ for 5 hours and then injection molded with standard ISO bars and standard plaques, and the standard plaques were then baked in an oven at 140 ℃ for 4 hours to test the b-value, each test result is shown in Table 1.
Example 2
1kg of acrylic monomer, 1kg of ferric phosphate and 0.5kg of silane coupling agent KH550 are stirred and mixed uniformly, 10000ml of ethanol is added for dispersion and alcoholysis, and the pH value of the solution is adjusted to 3.8, so that the special slurry for treating the glass fiber is obtained; then, 53kg of glass fiber is soaked by special size and dried to obtain special glass fiber with treated surface; adding 100kg of nylon 66, 20kg of nylon 610, 0.5kg of antioxidant 1098 and 0.5kg of antioxidant 445 into a low-speed stirrer, uniformly mixing, and adding a small amount of white oil for adhesion in the mixing process to obtain a premix; finally, adding the premix into a main feeding bin of a double-screw extruder, and adding the treated special glass fiber through side feeding, wherein the extrusion temperature is 270 ℃; and (5) drawing strips, cooling and cutting into granules. The particles were dried in an oven at 80 ℃ for 5 hours and then injection molded with standard ISO bars and standard plaques, and the standard plaques were then baked in an oven at 140 ℃ for 4 hours to test the b-value, each test result is shown in Table 1.
Example 3
Uniformly stirring and mixing 1.5kg of maleic anhydride, 1.5kg of calcium phosphate and 0.5kg of silane coupling agent KH550, adding 10000ml of ethanol for dispersing and alcoholysis, and adjusting the pH value of the solution to 3.2 to obtain special slurry for treating glass fibers; then soaking 58kg of glass fiber by special size, and drying to obtain special glass fiber with treated surface; adding 100kg of nylon 66, 30kg of nylon 1012 and 0.5kg of antioxidant 1098 into a low-speed stirrer, uniformly mixing, and adding a small amount of white oil for adhesion in the mixing process to obtain a premix; finally, adding the premix into a main feeding bin of a double-screw extruder, and adding the treated special glass fiber through side feeding, wherein the extrusion temperature is 240 ℃; and (5) drawing strips, cooling and cutting into granules. The particles were dried in an oven at 80 ℃ for 5 hours and then injection molded with standard ISO bars and standard plaques, and the standard plaques were then baked in an oven at 140 ℃ for 4 hours to test the b-value, each test result is shown in Table 1.
Example 4
1kg of maleic anhydride, 0.5kg of sodium phosphate and 0.5kg of silane coupling agent KH550 are stirred and mixed uniformly, 10000ml of ethanol is added for dispersion and alcoholysis, and the PH value of the solution is adjusted to 3.8, so that the special size for treating the glass fiber is obtained; then, soaking 40kg of alkali-free glass fiber by special size, and drying to obtain special glass fiber with treated surface; adding 100kg of nylon 66, 10kg of nylon 612 and 0.5kg of antioxidant 1098 into a low-speed stirrer, uniformly mixing, and adding a small amount of white oil for adhesion in the mixing process to obtain a premix; finally, adding the premix into a main feeding bin of a double-screw extruder, and adding the treated special glass fiber through side feeding, wherein the extrusion temperature is 270 ℃; and (5) drawing strips, cooling and cutting into granules. The particles were dried in an oven at 80 ℃ for 5 hours and then injection molded with standard ISO bars and standard plaques, and the standard plaques were then baked in an oven at 140 ℃ for 4 hours to test the b-value, each test result is shown in Table 1.
Example 5
Uniformly stirring and mixing 3kg of acrylic monomer, 1.5kg of ferric phosphate and 1.5kg of silane coupling agent KH550, adding 10000ml of ethanol for dispersing and alcoholysis, and adjusting the pH value of the solution to 3.5 to obtain special slurry for treating glass fibers; then, soaking 80kg of glass fiber by special size, and drying to obtain special glass fiber with treated surface; adding 100kg of nylon 66, 50kg of nylon 610, 0.5kg of antioxidant 1098 and 1kg of antioxidant 445 into a low-speed stirrer, uniformly mixing, and adding a small amount of white oil in the mixing process for adhesion to obtain a premix; finally, adding the premix into a main feeding bin of a double-screw extruder, and adding the treated special glass fiber through side feeding, wherein the extrusion temperature is 270 ℃; and (5) drawing strips, cooling and cutting into granules. The particles were dried in an oven at 80 ℃ for 5 hours and then injection molded with standard ISO bars and standard plaques, and the standard plaques were then baked in an oven at 140 ℃ for 4 hours to test the b-value, each test result is shown in Table 1.
Table 1: comparison of test Performance between examples 1-5 and conventional enhanced PA66
Note: delta b = bAfter baking-bBefore baking
From the test results in table 1, it can be seen that the b value increase of the standard color plate after 4 hours of baking in the oven at 140 ℃ is significantly reduced, the minimum is 1.0, which is far lower than 6 of the common reinforced material, and the strength and toughness of the product are ensured by the strong force between the glass fiber and the value.
Claims (7)
1. The yellowing-resistant reinforced nylon 66 material is characterized by comprising the following components in parts by weight: nylon 66100 parts, long carbon chain nylon 10-50 parts, alkali-free glass fiber 40-80 parts, functional monomer 1-3 parts, coupling agent 0.5-1.5 parts, phosphate heat stabilizer 0.5-1.5 parts, antioxidant 0.5-1.5 parts; wherein the functional monomer contains a group which is chemically reacted with a nylon amido bond and is selected from one or more of maleic anhydride, acrylic acid or methacrylic acid;
the preparation method comprises the following steps: (1) stirring and mixing the functional monomer, the phosphate heat stabilizer and the coupling agent uniformly, adding ethanol for dispersing, diluting and alcoholysis, and adjusting the pH value of the solution to 3.2-3.8 to obtain special slurry for processing glass fibers; (2) infiltrating and drying the glass fiber through special size to obtain special glass fiber with treated surface; (3) adding nylon 66, long carbon chain nylon and an antioxidant into a low-speed stirrer, uniformly mixing, adding a small amount of white oil in the mixing process for adhesion, and uniformly mixing to obtain premixed particles; and (4) adding the premix obtained in the step (3) into a main feeding hopper of a double-screw extruder, and adding the special glass fiber obtained in the step (2) through side feeding, wherein the extrusion temperature is between 240 ℃ and 270 ℃.
2. The yellowing-resistant reinforced nylon 66 material according to claim 1, wherein: the long carbon chain nylon is one or more of nylon 610, nylon 612, nylon 1010, nylon 1012 or nylon 1212.
3. The yellowing-resistant reinforced nylon 66 material according to claim 1, wherein: the relative viscosity of the nylon 66 is between 1.8 and 4.0.
4. The yellowing-resistant reinforced nylon 66 material according to claim 1, wherein: the coupling agent is one or more of silane coupling agents, aluminate coupling agents or carbonate coupling agents.
5. The yellowing-resistant reinforced nylon 66 material according to claim 1, wherein: the phosphate heat stabilizer is one or more of sodium phosphate, calcium phosphate, iron phosphate, copper phosphate, potassium phosphate or magnesium phosphate.
6. The yellowing-resistant reinforced nylon 66 material according to claim 1, wherein: the antioxidant is one or more of antioxidant 1010, antioxidant 1076, antioxidant 1098, antioxidant 245 or antioxidant 445.
7. The method for preparing the yellowing-resistant reinforced nylon 66 material according to any one of claims 1 to 6, comprising the following steps: (1) stirring and mixing the functional monomer, the phosphate heat stabilizer and the coupling agent uniformly, adding ethanol for dispersing, diluting and alcoholysis, and adjusting the pH value of the solution to 3.2-3.8 to obtain special slurry for processing glass fibers; (2) infiltrating and drying the glass fiber through special size to obtain special glass fiber with treated surface; (3) adding nylon 66, long carbon chain nylon and an antioxidant into a low-speed stirrer, uniformly mixing, adding a small amount of white oil in the mixing process for adhesion, and uniformly mixing to obtain premixed particles; and (4) adding the premix obtained in the step (3) into a main feeding hopper of a double-screw extruder, and adding the special glass fiber obtained in the step (2) through side feeding, wherein the extrusion temperature is between 240 ℃ and 270 ℃.
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| CN108385203B (en) * | 2018-02-12 | 2021-01-26 | 广东新会美达锦纶股份有限公司 | Preparation method of discoloration-resistant antibacterial polyamide fiber |
| CN108385202B (en) * | 2018-02-12 | 2021-01-26 | 广东新会美达锦纶股份有限公司 | Color-changing-resistant antibacterial polyamide fiber |
| EP3901208A4 (en) * | 2019-12-06 | 2022-04-06 | LG Chem, Ltd. | Thermoplastic molding composition and automobile parts comprising molded material thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07118926A (en) * | 1993-10-26 | 1995-05-09 | Asahi Chem Ind Co Ltd | Yellowing-resistant poly(hexamethylene adipamide) fiber |
| CN101544821A (en) * | 2009-04-29 | 2009-09-30 | 株洲时代工程塑料制品有限责任公司 | High performance nylon composite for railway fastener gauge apron and its preparation method |
| CN105038218A (en) * | 2015-09-01 | 2015-11-11 | 东莞市华盈新材料有限公司 | PA66 composite material and preparation method thereof |
| CN106867247A (en) * | 2017-01-23 | 2017-06-20 | 泰州艳阳天塑料科技有限公司 | A kind of high temperature resistant, high intensity color inhibition reinforced PA66 and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07118926A (en) * | 1993-10-26 | 1995-05-09 | Asahi Chem Ind Co Ltd | Yellowing-resistant poly(hexamethylene adipamide) fiber |
| CN101544821A (en) * | 2009-04-29 | 2009-09-30 | 株洲时代工程塑料制品有限责任公司 | High performance nylon composite for railway fastener gauge apron and its preparation method |
| CN105038218A (en) * | 2015-09-01 | 2015-11-11 | 东莞市华盈新材料有限公司 | PA66 composite material and preparation method thereof |
| CN106867247A (en) * | 2017-01-23 | 2017-06-20 | 泰州艳阳天塑料科技有限公司 | A kind of high temperature resistant, high intensity color inhibition reinforced PA66 and preparation method thereof |
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