CN107902953A - A kind of artificial quartz stone plate and preparation method thereof - Google Patents
A kind of artificial quartz stone plate and preparation method thereof Download PDFInfo
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- CN107902953A CN107902953A CN201711144669.8A CN201711144669A CN107902953A CN 107902953 A CN107902953 A CN 107902953A CN 201711144669 A CN201711144669 A CN 201711144669A CN 107902953 A CN107902953 A CN 107902953A
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- artificial quartz
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
- C04B2111/545—Artificial marble
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of artificial quartz stone plate and preparation method thereof, expected by weight by A, B material and C material be made, A material, B material and C material all comprising unsaturated-resin, pigment, auxiliary agent, silica flour, 26 mesh quartz, 40 mesh quartz, 100 mesh quartz.Its preparation method is：(1) A material, B material and C material are prepared in respective agitator respectively, A are expected, B material and C material are put into be stirred 3~5 minutes with the speed of 300~500rpm in batch mixer according to weight proportion and obtain mixed material；(2) mixed material is entered into cloth in material distributing machine through electronic measurement, be then charged into mould, be sent into preformer and carry out precompressed 2 times, the material pressed in advance is sent into crusher in crushing, pass through material distributing machine cloth again, be then charged into making sheet mould, vibrate extrusion forming under vacuo using moulding press；(3) molding plate is sent into solidification case to cure；(4) plate after curing is struck off, fixed thick, polishing.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of artificial quartz stone plate and preparation method thereof.
Background technology
For artificial quartz in lump using unsaturated-resin as matrix, main stuffing is the nothings such as natural siliceous sand, silica flour, glass particle
Machine material, then added with additives such as curing agent, be made under conditions of negative-pressure vacuum by dither shaping, heating cure
Plate, its quality is hard, compact structure, has the incomparable wear-resisting, high temperature resistant of other ornament materials, anticorrosive, antiseepage
The characteristic such as saturating.Lithotome is increasingly exhausted as a kind of non-renewable resources, and artificial quartz in lump is its best substitute.
At the same time, artificial quartz in lump can use much discarded material such as glass as raw material, thus in environmental protection
Resource reutilization is realized at the same time, and saves significantly on cost, these advantages allow artificial quartz in lump to become building and fill
The hot spot and trend of pool industry.Artificial quartz in lump is widely used in kitchen countertop, laboratory table top, windowsill, bar desk, ground, wall
Face etc..Higher place artificial quartz in lump is required to be all suitable in construction material.
At present, the principal element for restricting artificial quartz in lump development is exactly product quality and excessive production cost.In economy
The fast-developing present age, people increasingly focus on grade of living, and development of the product quality for artificial quartz in lump is most important.It is existing
Somebody make quartzite slate there are density unevenness, it is yielding, color and decorative pattern are single the defects of, be difficult in quality and pattern
Reach the effect of high natural-like stone, seriously affect the surface effect of artificial quartz in lump, be unfavorable for the beauty of indoor decoration.This
Outside, it is many to influence the factor of artificial quartz in lump product quality, mainly there is raw material, equipment and production technology etc..
The content of the invention
In view of the problems of the existing technology, the present invention provides a kind of artificial quartz stone plate and preparation method thereof.
A kind of artificial quartz stone plate, is made of following A material, B material and C material by weight：
A material are made of following components：
B material are made of following components：
C material are made of following components：
Further, the weight ratio 3~5 of the A material, B material and C material：1~3：1.
It is further preferred that the weight ratio 4 of the A material, B material and C material：2：1.
Further, the unsaturated-resin by 25~30 parts of styrene, 20~25 parts of phthalic anhydrides, 15~20 parts of cis-butenedioic anhydrides, 7~
10 parts of ethylene glycol, 7~10 parts of propane diols, 12~18 parts of neopentyl glycols and 0.005~0.01 part of polymerization inhibitor pass through in a kettle
High-temperature stirring polymerisation is made.
Further, ethylene glycol, propane diols and neopentyl glycol are added in reaction kettle according to proportioning, stir and progressively rise
Temperature is preferably warming up to 200 DEG C, reacts to acid number and reach 25~30mg KOH/g, add phthalic anhydride and cis-butenedioic anhydride to 190~210 DEG C
Step Condensation reacts 6~7h, and acid number reaches 35~45mg KOH/g after the reaction was complete, and decompression vacuum pumping, then adds polymerization inhibitor,
Then styrene is added after cooling to 80~100 DEG C, preferably cools to 90 DEG C, is uniformly mixing to obtain the unsaturated-resin.
Further, wherein the polymerization inhibitor is hydroquinone.
Further, the pigment be titanium dioxide, carbon black powder, iron oxide red, iron oxide yellow powder, dark green, one kind in phthalocyanine blue
It is or a variety of.
Further, the auxiliary agent is that weight ratio is 4~5：1 silane coupling agent and the tertiary fourth of peroxidating -2- ethyl acids
Ester.
It is further preferred that the weight ratio of the coupling agent and the peroxidating -2- ethyl acid tert-butyl esters is 4：1.
Further, the granularity of the silica flour is the mesh of 325 mesh~800.
A kind of preparation method of artificial quartz stone plate, comprises the following steps：
(1) A material, B material and C material are prepared in respective agitator respectively, first by unsaturated-resin and face in agitator
Material stirring 5~8 minutes, adds auxiliary agent and stirs 2~3 minutes, is subsequently added into silica flour, 26 mesh quartz, 40 mesh quartz, 100 mesh
Quartz, is stirred with the speed of 500~1000rpm and respectively obtains within 5~8 minutes uniform A material, B material and C material, A is expected, B expects and C
Material is put into stir 3~5 minutes with the speed of 300~500rpm in batch mixer according to weight proportion obtains mixed material；
(2) mixed material is entered into cloth in material distributing machine through electronic measurement, be then charged into mould, be sent into preformer and carry out
Precompressed 2 times, crusher in crushing is sent into by the material pressed in advance, then by material distributing machine cloth, is then charged into making sheet mould, using into
Swaging machine vibrates extrusion forming under vacuo, obtains molding plate；
(3) molding plate feeding solidification case is cured, the plate after being cured；
(4) plate after curing is struck off, fixed thick, polishing treatment, up to the artificial quartz stone plate.
Further, the shaping pressing time is 150~180s in step (2), and the compacting frequency of the moulding press is 50
~55Hz, pressure are 1.8~3.0MPa.
Further, the vacuum of vacuum described in step (2) is -100~-95Pa.
Further, cured temperature described in step (3) is 80~90 DEG C, and the time is 50~70min.
By a series of continuous processings such as colour match, formulation optimization, mechanization batch mixings, original quartz color list is broken away from
First, stiff, uninteresting eye impressions, final obtained properties of product and pattern are simultaneously deposited, and product hardness reaches more than 7-8 grades, close
Degree reaches >=2.4g/cm3More than, it is more natural, more three-dimensional in terms of grain effect and pattern, truer, incomparably close to rare natural
Marble.
The present invention using 26 mesh quartz, 40 mesh quartz, 100 mesh quartz according to specified weight number grading, coordinate 325 mesh~
The silica flour of 800 mesh, after pigment, unsaturated-resin, auxiliary agent is added, by precompressed twice, crushes, under vacuo vibration pressurization
Shaping, grain effect and the pattern aspect of obtained quartzite slate are very natural, three-dimensional, true, can be with natural marble
Match in excellence or beauty.At the same time quartz collocation silica flour, unsaturated-resin, the auxiliary agent of specific mesh number can obtain high rigidity, wear-resisting, high temperature resistant,
The excellent performance such as acid and alkali-resistance, impermeable.
Beneficial effects of the present invention：
(1) quartzite slate color of the invention and texture are natural, true, can compare favourably with natural marble；
(2) quartzite slate hardness of the invention is high, durable, has good wear-resisting, high temperature resistant, acid and alkali-resistance, prevents
Penetration Signature；
(3) quartzite slate raw material sources of the invention are wide, and cost is relatively low；
(4) preparation method of the invention is to the of less demanding of equipment, and production efficiency is high, can substantially reduce and be produced into
This, is adapted to large-scale production.
Embodiment
In order to preferably explain the present invention, it is described further in conjunction with specific examples below, but the present invention is unlimited
In specific embodiment.
Embodiment 1
A kind of artificial quartz stone plate, is made of following A material, B material and C material by weight：
A material are made of following components：
B material are made of following components：
C material are made of following components：
The auxiliary agent is that weight ratio is 4：1 silane coupling agent and the peroxidating -2- ethyl acid tert-butyl esters.
The granularity of the silica flour is 325 mesh.
The unsaturated-resin by 25 parts of styrene, 20 parts of phthalic anhydrides, 15 parts of cis-butenedioic anhydrides, 7 parts of ethylene glycol, 7 parts of propane diols, 12 parts
Neopentyl glycol and 0.005 part of hydroquinone are made by high-temperature stirring polymerisation in a kettle.
Ethylene glycol, propane diols and neopentyl glycol be added in reaction kettle according to proportioning, stirs and is progressively warming up to 200
DEG C, react to acid number and reach 25~30mg KOH/g, add phthalic anhydride and cis-butenedioic anhydride Step Condensation reacts 6~7h, after the reaction was complete
Acid number reaches 35~45mg KOH/g, then decompression vacuum pumping adds hydroquinone, and benzene second is added after then cooling to 90 DEG C
Alkene, is uniformly mixing to obtain the unsaturated-resin.
The preparation method of the artificial quartz stone plate, comprises the following steps：
(1) A material, B material and C material are prepared in respective agitator respectively, first by unsaturated-resin and face in agitator
Material stirring 5~8 minutes, adds auxiliary agent and stirs 2~3 minutes, is subsequently added into silica flour, 26 mesh quartz, 40 mesh quartz, 100 mesh
Quartz, is stirred with the speed of 500~1000rpm and respectively obtains within 5~8 minutes uniform A material, B material and C material, A is expected, B expects and C
Material is put into stir 3~5 minutes with the speed of 300~500rpm in batch mixer according to weight proportion obtains mixed material；
(2) mixed material is entered into cloth in material distributing machine through electronic measurement, be then charged into mould, be sent into preformer and carry out
Precompressed 2 times, crusher in crushing is sent into by the material pressed in advance, then by material distributing machine cloth, is then charged into making sheet mould, using into
Swaging machine (vacuum is -100~-95Pa) vibration extrusion forming under vacuo, obtains molding plate, and the shaping pressing time is
150~180s, the compacting frequency of the moulding press is 50~55Hz, pressure 2.0MPa；
(3) molding plate feeding solidification case is cured, cured temperature is 80~90 DEG C, the time for 50~
70min, the plate after being cured；
(4) plate after curing is struck off, fixed thick, polishing treatment, up to the artificial quartz stone plate.
The hardness (Mohs' hardness) of the artificial quartz stone plate of the present embodiment reaches 7 grades, and surface texture is rich in three-dimensional sense, color
It is color beautiful.
Embodiment 2
A kind of artificial quartz stone plate, is made of following A material, B material and C material by weight：
A material are made of following components：
B material are made of following components：
C material are made of following components：
The auxiliary agent is that weight ratio is 4：1 silane coupling agent and the peroxidating -2- ethyl acid tert-butyl esters.
The granularity of the silica flour is 800 mesh.
The unsaturated-resin is by 30 parts of styrene, 25 parts of phthalic anhydrides, 20 parts of cis-butenedioic anhydrides, 10 parts of ethylene glycol, 10 parts of propane diols, 18
Part neopentyl glycol and 0.01 part of hydroquinone are made by high-temperature stirring polymerisation in a kettle.
Ethylene glycol, propane diols and neopentyl glycol be added in reaction kettle according to proportioning, stirs and is progressively warming up to 200
DEG C, react to acid number and reach 25~30mg KOH/g, add phthalic anhydride and cis-butenedioic anhydride Step Condensation reacts 6~7h, after the reaction was complete
Acid number reaches 35~45mg KOH/g, then decompression vacuum pumping adds hydroquinone, and benzene second is added after then cooling to 90 DEG C
Alkene, is uniformly mixing to obtain the unsaturated-resin.
The preparation method of the artificial quartz stone plate, comprises the following steps：
(1) A material, B material and C material are prepared in respective agitator respectively, first by unsaturated-resin and face in agitator
Material stirring 5~8 minutes, adds auxiliary agent and stirs 2~3 minutes, is subsequently added into silica flour, 26 mesh quartz, 40 mesh quartz, 100 mesh
Quartz, is stirred with the speed of 500~1000rpm and respectively obtains within 5~8 minutes uniform A material, B material and C material, A is expected, B expects and C
Material is put into stir 3~5 minutes with the speed of 300~500rpm in batch mixer according to weight proportion obtains mixed material；
(2) mixed material is entered into cloth in material distributing machine through electronic measurement, be then charged into mould, be sent into preformer and carry out
Precompressed 2 times, crusher in crushing is sent into by the material pressed in advance, then by material distributing machine cloth, is then charged into making sheet mould, using into
Swaging machine (vacuum is -100~-95Pa) vibration extrusion forming under vacuo, obtains molding plate, and the shaping pressing time is
150~180s, the compacting frequency of the moulding press is 50~55Hz, pressure 3.0MPa；
(3) molding plate feeding solidification case is cured, cured temperature is 80~90 DEG C, the time for 50~
70min, the plate after being cured；
(4) plate after curing is struck off, fixed thick, polishing treatment, up to the artificial quartz stone plate.
The hardness (Mohs' hardness) of the artificial quartz stone plate of the present embodiment reaches 7 grades, and surface texture is rich in three-dimensional sense, color
It is color beautiful.
Embodiment 3
A kind of artificial quartz stone plate, is made of following A material, B material and C material by weight：
A material are made of following components：
B material are made of following components：
C material are made of following components：
The auxiliary agent is that weight ratio is 4：1 silane coupling agent and the peroxidating -2- ethyl acid tert-butyl esters.
The granularity of the silica flour is 600 mesh.
The unsaturated-resin by 28 parts of styrene, 22 parts of phthalic anhydrides, 18 parts of cis-butenedioic anhydrides, 8 parts of ethylene glycol, 8 parts of propane diols, 15 parts
Neopentyl glycol and 0.008 part of hydroquinone are made by high-temperature stirring polymerisation in a kettle.
Ethylene glycol, propane diols and neopentyl glycol be added in reaction kettle according to proportioning, stirs and is progressively warming up to 200
DEG C, react to acid number and reach 25~30mg KOH/g, add phthalic anhydride and cis-butenedioic anhydride Step Condensation reacts 6~7h, after the reaction was complete
Acid number reaches 35~45mg KOH/g, then decompression vacuum pumping adds hydroquinone, and benzene second is added after then cooling to 90 DEG C
Alkene, is uniformly mixing to obtain the unsaturated-resin.
The preparation method of the artificial quartz stone plate, comprises the following steps：
(1) A material, B material and C material are prepared in respective agitator respectively, first by unsaturated-resin and face in agitator
Material stirring 5~8 minutes, adds auxiliary agent and stirs 2~3 minutes, is subsequently added into silica flour, 26 mesh quartz, 40 mesh quartz, 100 mesh
Quartz, is stirred with the speed of 500~1000rpm and respectively obtains within 5~8 minutes uniform A material, B material and C material, A is expected, B expects and C
Material is put into stir 3~5 minutes with the speed of 300~500rpm in batch mixer according to weight proportion obtains mixed material；
(2) mixed material is entered into cloth in material distributing machine through electronic measurement, be then charged into mould, be sent into preformer and carry out
Precompressed 2 times, crusher in crushing is sent into by the material pressed in advance, then by material distributing machine cloth, is then charged into making sheet mould, using into
Swaging machine (vacuum is -100~-95Pa) vibration extrusion forming under vacuo, obtains molding plate, and the shaping pressing time is
150~180s, the compacting frequency of the moulding press is 50~55Hz, pressure 3.0MPa；
(3) molding plate feeding solidification case is cured, cured temperature is 80~90 DEG C, the time for 50~
70min, the plate after being cured；
(4) plate after curing is struck off, fixed thick, polishing treatment, up to the artificial quartz stone plate.
The hardness (Mohs' hardness) of the artificial quartz stone plate of the present embodiment reaches 7 grades, and surface texture is rich in three-dimensional sense, color
It is color beautiful.
The foregoing is merely the specific embodiment of the present invention, it is not intended to limit the scope of the invention, every utilization
The equivalent transformation that the present invention makees, is directly or indirectly used in other relevant technical fields, is similarly included in the present invention's
Among scope of patent protection.
Claims (10)
1. a kind of artificial quartz stone plate, it is characterised in that be made by weight of following A material, B material and C material：
A material are made of following components：
B material are made of following components：
C material are made of following components：
2. artificial quartz stone plate according to claim 1, it is characterised in that the unsaturated-resin is by 25~30 parts of benzene
Ethene, 20~25 parts of phthalic anhydrides, 15~20 parts of cis-butenedioic anhydrides, 7~10 parts of ethylene glycol, 7~10 parts of propane diols, 12~18 parts of neopentyl glycols and
0.005~0.01 part of polymerization inhibitor is made by high-temperature stirring polymerisation in a kettle.
3. artificial quartz stone plate according to claim 2, it is characterised in that according to proportioning by ethylene glycol, propane diols and
Neopentyl glycol is added in reaction kettle, is stirred and is progressively warming up to 190~210 DEG C, reacts to acid number and reach 25~30mg KOH/
G, adds phthalic anhydride and cis-butenedioic anhydride Step Condensation reacts 6~7h, and acid number reaches 35~45mg KOH/g after the reaction was complete, and decompression is taken out true
Sky, then adds polymerization inhibitor, and styrene is added after then cooling to 80~100 DEG C, is uniformly mixing to obtain the unsaturated tree
Fat, wherein the polymerization inhibitor is hydroquinone.
4. artificial quartz stone plate according to claim 1, it is characterised in that the weight ratio 3 of the A material, B material and C material
~5：1~3：1.
5. artificial quartz stone plate according to claim 1, it is characterised in that the auxiliary agent is that weight ratio is 4~5：1
Silane coupling agent and the peroxidating -2- ethyl acid tert-butyl esters.
6. artificial quartz stone plate according to claim 1, it is characterised in that the granularity of the silica flour for 325 mesh~
800 mesh.
A kind of 7. preparation method of artificial quartz stone plate according to any one of the claims, it is characterised in that
Comprise the following steps：
(1) A material, B material and C material are prepared in respective agitator respectively, first stir unsaturated-resin and pigment in agitator
Mix 5~8 minutes, add auxiliary agent and stir 2~3 minutes, be subsequently added into silica flour, 26 mesh quartz, 40 mesh quartz, 100 mesh quartz,
Stirred with the speed of 500~1000rpm and respectively obtain within 5~8 minutes uniform A material, B material and C material, A is expected, B material and C material according to
Weight proportion, which is put into stir 3~5 minutes with the speed of 300~500rpm in batch mixer, obtains mixed material；
(2) mixed material is entered into cloth in material distributing machine through electronic measurement, be then charged into mould, be sent into preformer and carry out precompressed
2 times, the material pressed in advance is sent into crusher in crushing, then by material distributing machine cloth, be then charged into making sheet mould, pressed using shaping
Machine vibrates extrusion forming under vacuo, obtains molding plate；
(3) molding plate feeding solidification case is cured, the plate after being cured；
(4) plate after curing is struck off, fixed thick, polishing treatment, up to the artificial quartz stone plate.
8. the preparation method of artificial quartz stone plate according to claim 7, it is characterised in that shaping pressure in step (2)
Time processed is 150~180s, and the compacting frequency of the moulding press is 50~55Hz, and pressure is 1.8~3.0MPa.
9. the preparation method of artificial quartz stone plate according to claim 7, it is characterised in that true described in step (2)
Empty vacuum is -100~-95Pa.
10. the preparation method of artificial quartz stone plate according to claim 7, it is characterised in that solid described in step (3)
The temperature of change is 80~90 DEG C, and the time is 50~70min.
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| CN201711144669.8A CN107902953A (en) | 2017-11-17 | 2017-11-17 | A kind of artificial quartz stone plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711144669.8A CN107902953A (en) | 2017-11-17 | 2017-11-17 | A kind of artificial quartz stone plate and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114986662A (en) * | 2022-06-17 | 2022-09-02 | 佛山市晖锐新材料有限公司 | Forming process of stone with skin feeling effect |
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|---|---|---|---|---|
| CN103193966A (en) * | 2013-04-27 | 2013-07-10 | 肇庆福田化学工业有限公司 | Unsaturated polyester resin for artificial stone and synthesis method thereof |
| EP2826797A1 (en) * | 2013-07-18 | 2015-01-21 | HILTI Aktiengesellschaft | Hardener components, mortar mass containing the same and their use |
| CN104446145A (en) * | 2014-11-21 | 2015-03-25 | 广东中旗新材料科技有限公司 | Double-color double-pattern artificial quartz stone plate and production process thereof |
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2017
- 2017-11-17 CN CN201711144669.8A patent/CN107902953A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103193966A (en) * | 2013-04-27 | 2013-07-10 | 肇庆福田化学工业有限公司 | Unsaturated polyester resin for artificial stone and synthesis method thereof |
| EP2826797A1 (en) * | 2013-07-18 | 2015-01-21 | HILTI Aktiengesellschaft | Hardener components, mortar mass containing the same and their use |
| CN104446145A (en) * | 2014-11-21 | 2015-03-25 | 广东中旗新材料科技有限公司 | Double-color double-pattern artificial quartz stone plate and production process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114986662A (en) * | 2022-06-17 | 2022-09-02 | 佛山市晖锐新材料有限公司 | Forming process of stone with skin feeling effect |
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