CN105802170B - A kind of plug-in dalle of Soft Roll lightweight and preparation method thereof - Google Patents
A kind of plug-in dalle of Soft Roll lightweight and preparation method thereof Download PDFInfo
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- CN105802170B CN105802170B CN201610190165.9A CN201610190165A CN105802170B CN 105802170 B CN105802170 B CN 105802170B CN 201610190165 A CN201610190165 A CN 201610190165A CN 105802170 B CN105802170 B CN 105802170B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to the field of building materials, it is related to a kind of plug-in dalle of Soft Roll lightweight and preparation method thereof, the plug-in dalle of Soft Roll lightweight is obtained using vinylite, acrylic modified epoxy resin, organic siliconresin, light inorganic material as main material by rendering, vibration, vacuum, curing molding.Compared with traditional external wall decorative material, a kind of plug-in dalle of Soft Roll lightweight of the invention with light, hardness is high, decorative pattern dazzle it is beautiful it is adjustable, have excellent weather resistance, with the bond strength of cement is high, impact resistant strength is excellent, has good application value.
Description
Technical field
The invention belongs to the field of building materials, it is related to a kind of plug-in dalle of Soft Roll lightweight and preparation method thereof.
Background technique
Generally mostly plug-in natural marble, outer patch Ceramic Tiles, exterior wall are true for external wall decorative material used in the country at present
Mineral varnish etc., using natural marble or outer patch ceramics, over time, the binding force of natural marble and keel and
The binding force of ceramics and metope can be decreased obviously, furthermore the mass ratio of natural marble and ceramics is heavier, it is easy to be occurred
Peeling phenomenon jeopardizes the personal and property safety of the people, and the intensity of natural marble and ceramics it is relatively low installation process with
And be easy to that disrepair phenomenon occurs in the use process in later period, influence decorations effect.Exterior wall true stone paint does not have the matter of stone material
Sense, surface cannot do the effect of light, and weatherability is poor is easy to influence decorative effect.
Summary of the invention
The present invention is directed to the problems such as above-mentioned external wall decorative material, devises a kind of plug-in dalle of Soft Roll lightweight and its system
Preparation Method.
In order to achieve the above object, the technical solution adopted by the present invention is a kind of plug-in dalle of Soft Roll lightweight, according to
Weight fraction includes following component:
Preferably, the vinylite is methyl methacrylate, unsaturated polyester resin, bisphenol type epoxy second
One or more of alkenyl esters resin.
Preferably, the acrylic modified epoxy resin is acrylic acid modified Bisphenol F epoxy resin, acrylic acid modified
One or more of bisphenol-s epoxy resin, acrylic acid modified bisphenol-A epoxy resin.
Preferably, the organic siliconresin is one or both of methyl silicon resin, ethyl silicone resin.
Preferably, granule filling material and weight fraction that the filler material is 40-82 parts by weight fraction are 50-66 parts
Powder filler composition；The granular filler is the lightweight quartz sand that particle size is 10-120 mesh；The powder filler is grain
Diameter size is at least one of white carbon black and hollow glass micropearl of 325-1500 mesh.
Preferably, the surface modifier is α-morpholine methyl triethoxy silicon substrate, 1- propyl -1- (triethoxysilicane
Base) urethanes, one or more of isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters.
Preferably, the curing agent is benzoyl peroxide, in diacetyl peroxide, the peroxidating trimethylacetic acid tert-butyl ester
It is one or more of.
Preferably, the promotor is one of dimethylaniline, diethylaniline, dimethyl-p-toluidine or several
Kind.
Preferably, the reinforcing agent is nitrile rubber, liquid hydroxy'terminated butadiene nitrile rubber, the liquid end ring of liquid Amino End Group
One or more of oxygroup nitrile rubber, the colorant are one or both of toner, mill base.
The method for preparing the plug-in dalle of Soft Roll lightweight in claim 1, specifically includes the following steps:
(1) all raw materials are proportionally weighed, are uniformly mixed, after being distributed into mold, thickness is about 3mm；Take a small amount of compound tree
It is poured into again after rouge and coloring material for mixing after mold and carries out vacuum vibration, time of vibration 2-3min, vibration frequency 50-80HZ, very
Reciprocal of duty cycle is maintained at -0.07Mpa to -0.1Mpa.Obtain material a.
(2) material a obtained by step (1) being formed using intermediate temperature setting, the intermediate temperature setting temperature is 90-120 DEG C, Gu
Change molding time is 70-100min, obtains solidification decorative panel b.
(3) the curing molding plate b in step (2) is subjected to the processing of surface troweling, obtains finished product dalle c
Compared with prior art, the advantages and positive effects of the present invention are,
A kind of plug-in plate of Soft Roll lightweight of the invention is stronger with the binding force of cement, light weight, good weatherability, resistance to punching
Hit intensity is relatively high with hardness, and decorative effect is gorgeous.
Specific embodiment
To better understand the objects, features and advantages of the present invention, below with reference to embodiment to this hair
It is bright to be described further.It should be noted that in the absence of conflict, the feature in embodiments herein and embodiment can
To be combined with each other.
In the following description, numerous specific details are set forth in order to facilitate a full understanding of the present invention, still, the present invention may be used also
To be implemented using other modes described herein are different from, therefore, the present invention is not limited to the specific of specification is described below
The limitation of embodiment.
Embodiment 1 present embodiments provides a kind of plug-in plate of Soft Roll lightweight and preparation method thereof, each original in the plate
Material and its additional amount are as follows: 23 parts of vinylite, 12 parts of acrylic modified epoxy resin, 18 parts of organic siliconresin, inorganic filler
36 parts, 2 parts of surface modifier, 2 parts of curing agent, 0.5 part of promotor, 6 parts of reinforcing agent, 0.5 part of colorant.Vinylite is by methyl
35 parts of methyl acrylate, 40 parts of unsaturated polyester resin, 25 parts of bisphenol type epoxy vinyl ester resin be formulated；Acrylic acid
Modified epoxy is by 34 parts of acrylic acid modified Bisphenol F epoxy resin, 33 parts of acrylic acid modified bisphenol-s epoxy resin, third
33 parts of the modified hydrogenated bisphenol A type epoxy resin of olefin(e) acid is formulated；Organic siliconresin is by 55 parts of methyl silicon resin, ethyl silicone resin
45 parts are formulated；Inorganic fillings are formulated by 32 parts of granular filler and 68 parts of powder filler, granular filler 16-30
Purpose lightweight quartz sand；Powder filler is the white carbon black and hollow glass micropearl of 1200 mesh, mass ratio 1:8.
Surface modifier is by α -40 parts of morpholine methyl triethoxy silicon substrate, 1- propyl -1- (triethoxysilicane in the present embodiment
Base) 35 parts of urethanes, 25 parts of titanate esters of isopropyl three (dioctylphyrophosphoric acid acyloxy) be formulated；Curing agent is by mistake
39 parts of Benzoyl Oxide, 41 parts of diacetyl peroxide, 20 parts of the peroxidating trimethylacetic acid tert-butyl ester are formulated；Promotor is dimethyl
55 parts of aniline, 18 parts of diethylaniline, 27 parts of dimethyl-p-toluidine be formulated；Reinforcing agent by liquid Amino End Group butyronitrile rubber
40 parts of glue, 34 parts of liquid hydroxy'terminated butadiene nitrile rubber, 26 parts of the epoxy terminated nitrile rubber of liquid are formulated；Colorant is by mill base
55%, toner 45% is formulated.
The preparation method comprises the following steps: weighing all raw materials first, in accordance with ratio, it is uniformly mixed, after being distributed into mold, thickness is about 3mm.
It takes and carries out vacuum vibration, time of vibration 2.4min, vibration frequency after pouring into mold again after a small amount of hybrid resin and coloring material for mixing
60Hz, vacuum degree are -0.08Mpa, are formed using intermediate temperature setting, and the molding temperature of intermediate temperature setting is 100 DEG C, curing time
For 80min, troweling processing finally is carried out to plate surface.
Embodiment 2 present embodiments provides a kind of Soft Roll, the plug-in plate of lightweight and preparation method thereof, each in the plate
Raw material and its additional amount are as follows: 31 parts of vinylite, 13.4 parts of acrylic modified epoxy resin, 16 parts of organic siliconresin, inorganic
31 parts of filler, 1.5 parts of surface modifier, 1 part of curing agent, 0.1 part of promotor, 5.5 parts of reinforcing agent, 0.5 part of colorant.Vinyl tree
Rouge is formulated by 60 parts of methyl methacrylate, 40 parts of unsaturated polyester resin；Acrylic modified epoxy resin is by acrylic acid
67 parts of modified bisphenol F epoxy resin, 33 parts of acrylic acid modified bisphenol-A epoxy resin be formulated；Organic siliconresin
It is methyl silicon resin；Inorganic fillings are formulated by 32 parts of granular filler and 68 parts of powder filler, granular filler 26-40
Purpose lightweight quartz sand；Powder filler is the white carbon black and hollow glass micropearl of 1500 mesh, mass ratio 1:9.
Surface modifier is by α -48 parts of morpholine methyl triethoxy silicon substrate, 1- propyl -1- (triethoxysilicane in the present embodiment
Base) 52 parts of urethanes be formulated；Curing agent by 68 parts of benzoyl peroxide, 32 parts of diacetyl peroxide prepare and
At；Promotor be 59 parts of dimethylaniline, 41 parts of diethylaniline be formulated；Reinforcing agent by liquid Amino End Group nitrile rubber
67 parts, 33 parts of the epoxy terminated nitrile rubber of liquid is formulated；Colorant is mill base.
The preparation method comprises the following steps: weighing all raw materials first, in accordance with ratio, it is uniformly mixed, after being distributed into mold, thickness is about 3mm.
It takes and carries out vacuum vibration after pouring into mold after a small amount of hybrid resin and coloring material for mixing again, time of vibration 2min, vibration frequency 65Hz,
Vacuum degree is -0.07Mpa, is formed using intermediate temperature setting, and the molding temperature of intermediate temperature setting is 110 DEG C, and curing time is
90min finally carries out troweling processing to plate surface.
Embodiment 3 present embodiments provides a kind of Soft Roll, the plug-in plate of lightweight and preparation method thereof, each in the plate
Raw material and its additional amount are as follows: 22 parts of vinylite, 13.2 parts of acrylic modified epoxy resin, 15.9 parts of organic siliconresin, nothing
38.44 parts of machine filler, 1.7 parts of surface modifier, 1.7 parts of curing agent, 0.3 part of promotor, 6.3 parts of reinforcing agent, 0.46 part of colorant.
Vinylite is by 39 parts of methyl methacrylate, 45 parts of unsaturated polyester resin, 16 parts of bisphenol type epoxy vinyl ester resin
It is formulated；Acrylic modified epoxy resin is by 67 parts of acrylic acid modified Bisphenol F epoxy resin, acrylic acid modified bisphenol S type
13 parts of epoxy resin, 20 parts of acrylic acid modified bisphenol-A epoxy resin be formulated；Organic siliconresin is by methyl silicon resin
76 parts, 34 parts of ethyl silicone resin are formulated；Inorganic fillings prepared by the powder filler of 37 parts of granular filler and 63 parts and
At the lightweight quartz sand of 40 mesh of granular filler；Powder filler is the white carbon black and hollow glass micropearl of 1300 mesh, and mass ratio is
1:7。
Surface modifier is by α -47 parts of morpholine methyl triethoxy silicon substrate, 1- propyl -1- (triethoxysilicane in the present embodiment
Base) 38 parts of urethanes, 15 parts of titanate esters of isopropyl three (dioctylphyrophosphoric acid acyloxy) be formulated；Curing agent is by mistake
36 parts of Benzoyl Oxide, 31 parts of diacetyl peroxide, 33 parts of the peroxidating trimethylacetic acid tert-butyl ester are formulated；Promotor is dimethyl
63 parts of aniline, 20 parts of diethylaniline, 17 parts of dimethyl-p-toluidine be formulated；Reinforcing agent by liquid Amino End Group butyronitrile rubber
37 parts of glue, 39 parts of liquid hydroxy'terminated butadiene nitrile rubber, 24 parts of the epoxy terminated nitrile rubber of liquid are formulated；Colorant is by mill base
70%, toner 30% is formulated.
The preparation method comprises the following steps: weighing all raw materials first, in accordance with ratio, it is uniformly mixed, after being distributed into mold, thickness is about 3mm.
It takes and carries out vacuum vibration after pouring into mold after a small amount of hybrid resin and coloring material for mixing again, time of vibration 3min, vibration frequency 60Hz,
Vacuum degree is -0.09Mpa, is formed using intermediate temperature setting, and the molding temperature of intermediate temperature setting is 110 DEG C, and curing time is
75min finally carries out troweling processing to plate surface.
The Soft Roll of 1-3 of the embodiment of the present invention, the plug-in plate progressive of lightweight can be detected, the results are shown in Table 1.
1 embodiment 1-3 Soft Roll of table, the plug-in plate testing result of lightweight
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
It imitates embodiment and is applied to other fields, but without departing from the technical solutions of the present invention, according to the technical essence of the invention
Any simple modification, equivalent variations and remodeling to the above embodiments, still fall within the protection scope of technical solution of the present invention.
Claims (10)
1. a kind of plug-in dalle of Soft Roll lightweight, which is characterized in that according to weight fraction include following component:
2. a kind of plug-in dalle of Soft Roll lightweight according to claim 1, which is characterized in that the vinylite is
One or more of unsaturated polyester resin, bisphenol type epoxy vinyl ester resin.
3. a kind of plug-in dalle of Soft Roll lightweight according to claim 2, which is characterized in that the acrylic acid modified ring
Oxygen resin is acrylic acid modified Bisphenol F epoxy resin, acrylic acid modified bisphenol-s epoxy resin, acrylic acid modified hydrogenation pair
One or more of phenol A type epoxy resin.
4. a kind of plug-in dalle of Soft Roll lightweight according to claim 3, which is characterized in that the organic siliconresin is
One or both of methyl silicon resin, ethyl silicone resin.
5. a kind of plug-in dalle of Soft Roll lightweight according to claim 4, which is characterized in that the filler material is by weight
The powder filler composition that the granule filling material and weight fraction that score is 40-82 parts are 50-66 parts；The granular filler is partial size
Size is the lightweight quartz sand of 10-120 mesh；The powder filler is the white carbon black and hollow glass that particle size is 325-1500 mesh
At least one of glass microballon.
6. a kind of plug-in dalle of Soft Roll lightweight according to claim 5, which is characterized in that the surface modifier is
One in 1- propyl -1- (triethoxy silicon substrate) urethanes, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters
Kind is several.
7. a kind of plug-in dalle of Soft Roll lightweight according to claim 6, which is characterized in that the curing agent is peroxide
Change one or more of benzoyl, diacetyl peroxide, peroxidating trimethylacetic acid tert-butyl ester.
8. a kind of plug-in dalle of Soft Roll lightweight according to claim 7, which is characterized in that the promotor is diformazan
One or more of base aniline, diethylaniline, dimethyl-p-toluidine.
9. a kind of plug-in dalle of Soft Roll lightweight according to claim 8, feature exist, the reinforcing agent is liquid end
One or more of the nitrile rubber of amino, liquid hydroxy'terminated butadiene nitrile rubber, the epoxy terminated nitrile rubber of liquid, the colorant
For one or both of toner, mill base.
10. the method for preparing the plug-in dalle of Soft Roll lightweight in claim 1, which is characterized in that specifically includes the following steps:
(1) all raw materials are proportionally weighed, are uniformly mixed, after being distributed into mold, thickness is about 3mm；Take a small amount of hybrid resin with
Vacuum vibration, time of vibration 2-3min, vibration frequency 50-80Hz, vacuum degree are carried out after pouring into mold after coloring material for mixing again
It is maintained at -0.07MP a to -0.1MP a.Obtain material a.
(2) material a obtained by step (1) is formed using intermediate temperature setting, the intermediate temperature setting temperature is 90-120 DEG C, is solidified into
The type time is 70-100min, obtains solidification decorative panel b.
(3) the curing molding plate b in step (2) is subjected to the processing of surface troweling, obtains finished product dalle c.
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| CN201610190165.9A CN105802170B (en) | 2016-03-30 | 2016-03-30 | A kind of plug-in dalle of Soft Roll lightweight and preparation method thereof |
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| CN105802170B true CN105802170B (en) | 2019-02-05 |
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Families Citing this family (5)
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| CN107555933B (en) * | 2017-08-31 | 2020-03-27 | 山东源根化学技术研发有限公司 | Light external decorative board and manufacturing method thereof |
| CN107311581B (en) * | 2017-08-31 | 2020-03-27 | 山东源根化学技术研发有限公司 | Light external decorative plate and preparation method thereof |
| CN107629374A (en) * | 2017-09-29 | 2018-01-26 | 镇江市星耀智能装备有限公司 | A kind of preparation method of environmentally friendly foaming plate |
| CN108409279A (en) * | 2018-02-10 | 2018-08-17 | 贵港市万升木业有限公司 | A method of sawdust is discarded using pine and prepares light decorative plate as raw material |
| CN109935751B (en) * | 2018-11-23 | 2022-07-19 | 万向一二三股份公司 | Battery module fixing panel and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1070205A (en) * | 1992-09-02 | 1993-03-24 | 北京东城紫光塑料电器厂 | High impact-resistant, anti-electrostatic unsaturated polyester composite and method for making and application |
| CN102046896A (en) * | 2008-03-21 | 2011-05-04 | 阿什工业技术有限责任公司 | Wallboard materials incorporating a microparticle matrix |
| CN104891861A (en) * | 2015-05-18 | 2015-09-09 | 赵景歧 | Inorganic lightweight aggregate thermal insulation board and preparation method thereof |
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2016
- 2016-03-30 CN CN201610190165.9A patent/CN105802170B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1070205A (en) * | 1992-09-02 | 1993-03-24 | 北京东城紫光塑料电器厂 | High impact-resistant, anti-electrostatic unsaturated polyester composite and method for making and application |
| CN102046896A (en) * | 2008-03-21 | 2011-05-04 | 阿什工业技术有限责任公司 | Wallboard materials incorporating a microparticle matrix |
| CN104891861A (en) * | 2015-05-18 | 2015-09-09 | 赵景歧 | Inorganic lightweight aggregate thermal insulation board and preparation method thereof |
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